• 제목/요약/키워드: 모델형태계산

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Measurements and Modeling of the Activity Coefficients and Solubilities of L-alanine in Aqueous Electrolyte Solutions (전해질 수용액에서 L-Alanine의 활동도계수와 용해도의 측정 및 모델링)

  • Lee, Bong-Seop;Kim, Ki-Chang
    • Korean Chemical Engineering Research
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    • v.48 no.4
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    • pp.519-533
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    • 2010
  • Activity oefficients and solubilities of L-Alanine in aqueous solutions containing each of four electrolytes(NaCl, KCl, $NaNO_3$ and $KNO_3$) were measured at 298.15 K. The measurements of activity coefficients were carried out in the electrochemical cell coupled with two ion-selective electrodes(cation and anion), and the solubilities were measured by the gravimetric analysis of saturated solutions in equilibrium with the solid phase of L-alanine. To model the activity coefficients and solubilities of amino acid in the amino acid/electrolyte aqueous solutions, thermodynamic relations of the residual Helmholtz free energy in the amino acid/electrolyte aqueous solutions were developed based on the perturbed-chain statistical associating fluid theory(PC-SAFT) combined with the primitive mean spherical approximation(primitive-MSA). In the present model, it is assumed that the zwitterions of L-alanine are associated with each other and cross-associated with water molecules, and also cross-associated with the cation and anion dissociated from an electrolyte(inorganic salt). The activity coefficients and solubilities of L-Alanine calculated from the theoretical model proposed in this work are found to be well agreeable with experimental data.

A Study on the Reliable Video Transmission Through Source/Channel Combined Optimal Quantizer for EREC Based Bitstream (EREC 기반 비트열을 위한 Source-Channel 결합 최적 양자화기 설계 및 이를 통한 안정적 영상 전송에 관한 연구)

  • 김용구;송진규;최윤식
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.25 no.12B
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    • pp.2094-2108
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    • 2000
  • 오류를 수반하는 통신망을 통한 멀티미디어 데이터의 응용은 최근 그 수요가 급증하고 있다. 하지만 그 구현은 많은 문제점들을 야기하는데, 전송된 비디오 데이터에 발생한 오류를 처리하는 문제가 그 중 하나이다. 이는 압축된 비트열에 발생한 오류가 영상의 시-공간 방향으로 심각한 전파 현상을 수반하기 때문이다. 이러한 심각한 오류 전파를 완화하기 위해 본 논문에서는 EREC라 알려진 오류 제한 기법을 적용하고, 적용된 EREC의 오류 전파 특성을 분석하였다. 이를 통해, 압축 부호화된 하나의 기본 블록 (매크로 블록)이 복호시 오류가 생길 확률을 추정하였으며, 추정된 확률의 근사를 통해 양 끝단(전송단과 수신단)에서의 비디오 화질 열화를 예측하였다. 추정 확률의 근사는 매 기본 블록에서 발생된 비트수에 대한 그 기본 블록이 복호시 오류가 생길 확률을 간단한 1차식을 통한 선형 회귀법으로 모델링 되었으며, 따라서 간단한 방법을 통해 양 끝단의 화질 열화를 효과적으로 예측할 수 있었다. 부호화된 비트열이 전송 오류에 보다 강인하게 되도록 하기 위해, 본 논문에서 개발된 화질 열화 모델을 양자화기 선택에 적용함으로써, 새로운 최적 양자화 기법을 제시하였다. 본 논문에서 제안된 최적 양자화 기법은, 기존의 양자기 최적화 기법들과는 달리, 복호단에서의 복원 영상 화질이 주어진 비트율에서 최적이 되도록 양자화를 수행한다. H.263 비디오 압축 규격에 적용한 제안 양자화 기법의 실험 결과를 통해, 제안 기법이 매우 적은 계산상의 부하를 비용으로 객관적 화질은 물론 주관적 화질까지 크게 개선할 수 있음을 확인할 수 있었다.내었다.Lc. lacti ssp. lactis의 젖산과 초산의 생성량은 각각 0.089, 0.003과 0.189, 0.003M이었다. 따라서 corn steep liquor는 L. fermentum와 Lc. lactis ssp, lactis 의 생장을 위해 질소 또는 탄소 공급원으로서 배지에 첨가 될 수 있는 우수한 농업 부산물로 판단되었다.징하며 WLWQ에 적용되는 몇 가지 제약을 관찰하고 이를 일반적인 언어원리로 설명한다. 첫째, XP는 주어로만 해석되는데 그 이유는 XP가 목적어 혹은 부가어 등 다른 기능을 할 경우 생략 부위가 생략의 복원 가능선 원리 (the deletion-up-to recoverability principle)를 위배하기 때문이다. 둘째, WLWQ가 내용 의문문으로만 해석되는데 그 이유는 양의 공리(the maxim of quantity: Grice 1975) 때문이다. 평서문으로 해석될 경우 WP에 들어갈 부분이 XP의 자질의 부분집합에 불과하므로 명제가 아무런 정보제공을 하지 못한다. 반면 의문문 자체는 정보제공을 추구하지 않으므로 앞에서 언급한 양의 공리로부터 자유롭다. 셋째, WLWQ의 XP는 주제어 표지 ‘는/-은’을 취하나 주어표지 ‘가/-이’는 취하지 못한다(XP-는/-은 vs. XP-가/-이). 이는 IP내부 에 비공범주의 존재 여부에 따라 C의 음운형태(PF)가 시성이 정해진다는 가설로 설명하고자 했다. WLWQ에 대한 우리의 논의가 옳다면, 본 논문은 다음과 같은 이론적 함의를 기닌다. 첫째, WLWQ의 존재는 생략에 대한 두 이론 즉 LF 복사 이론과 PF 삭제 이론

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Development of an Aerodynamic Simulation for Studying Microclimate of Plant Canopy in Greenhouse - (1) Study on Aerodynamic Resistance of Tomato Canopy through Wind Tunnel Experiment - (공기유동해석을 통한 온실내 식물군 미기상 분석기술 개발 - (1) 풍동실험을 통한 토마토 식물군의 공기저항 연구 -)

  • Lee In-Bok;Yun Nam-Kyu;Boulard Thierry;Roy Jean Claude;Lee Sung-Hyoun;Kim Gyoeng-Won;Lee Seung-Kee;Kwon Soon-Hong
    • Journal of Bio-Environment Control
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    • v.15 no.4
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    • pp.289-295
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    • 2006
  • A computational fluid dynamics (CFD) numerical model has been developed to effectively study the ventilation efficiency of multi-span greenhouses with internal crops. As the first step of the study, the internal plants of the CFD model had to be designed as a porous media because of the complexity of its physical shapes. In this paper, the results of the wind tunnel tests were introduced to find the aerodynamic resistance of the plant canopy. The Seogun tomato was used for this study which made significant effects on thermal and mass exchanges with the adjacent air as well as internal airflow resistance. With the main factors of wind speed, static pressure, and density of plant canopy, the aerodynamic resistance factor was statically found. It was finally found to be 0.26 which will be used later as an input data of the CFD model. Moreover, the experimental procedure of how to find the aerodynamic resistance of various plants using, wind tunnel was established through this study.

UHF Electromagnetic Perturbation due to the fluctuation of Conductivity in a Fault Zone (단층대의 전기전도도 변동에 의한 UHF 전자기장 교란)

  • Lee Choon-Ki;Lee Heuisoon;Kwon Byung-Doo;Oh SeokHoon;Lee Duk Kee
    • Geophysics and Geophysical Exploration
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    • v.6 no.2
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    • pp.87-94
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    • 2003
  • ULF geomagnetic field anomalies related to earthquakes have been reported and a mechnism that magnetic field variations could be generated by the induced telluric current due to the high frequency fluctuation of conductivity in a fault Bone have been proposed. In this study, we calculated electromagnetic anomalies using a simple fault model and investigated the possibility of significant perturbation. Since low frequency electromagnetic fields are modulated by the high frequency oscillation of conductivity and the modulated fields are concentrated in a narrow ULF band, the electromagnetic fields in ULF band could be perturbed significantly. The amplitude of electromagnetic field anomaly depends on various factors: the geometry and conductivity of fault zone, the magnitude and frequency of conductivity fluctuation, the resistivity structure of crust or mantle, the frequency bandwidth of observational data and so on. Therefore, it is strongly required to reveal the deep resistivity structure of crust a.: well ah the structure of fault zone and to ,select the optimal observation frequency band for the observation of electromagnetic activities related with earthquakes.

Study for Characteristic of Frictional Heat Transfer in Rotating Brake System (회전을 고려한 브레이크 디스크의 마찰열전달 연구)

  • Nam, Jiwoo;Ryou, Hong Sun;Cho, Seong Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.10
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    • pp.817-822
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    • 2017
  • The braking system is one of the most important components in vehicles and machines. It must exert a reliable braking force when they are brought to a halt. Generally, frictional heat is generated by converting kinetic energy into heat energy through friction. As the kinetic energy is converted into heat energy, high temperature heat is generated which affects the mechanical behavior of the braking system. Frictional heat affects the thermal expansion and friction coefficient of the brake system. If the temperature is not controlled, the brake performance will be decreased. Therefore, it is important to predict and control the heat generation of the brake. Various numerical analysis studies have been carried out to predict the frictional heat, but they assumed the existence of boundary conditions in the numerical analysis to simulate the frictional heat, because the simulation of frictional heat is difficult and time consuming. The results were based on the assumption that the frictional heat is different from the actual temperature distribution in a rotating brake system. Therefore, the reliability of the cooling effect or thermal stress using the results of these studies is insufficient. In order to overcome these limitations and establish a simulation procedure to predict the frictional heat, this study directly simulates the frictional heat generation by using a thermal-structure coupling element. In this study, we analyzed the thermo-mechanical behavior of a brake model, in order to investigate the thermal characteristics of brake systems by using the Finite Element method (FEM). This study suggests the necessity to directly simulate the frictional heating and it is hoped that it can provide the necessary information for simulations.

Research on the Transfer Factor for $C^{14}$ Ingestion Dose Evaluation in PWR plant (PWR 발전소에서 $C^{14}$ 섭취선량 평가를 위한 전이계수 연구)

  • Kim Soong-Pyung;Han Young-Ok;Park Kyeong-Rok
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.476-484
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    • 2005
  • This paper is to evaluate rather correctly $C^{14}$ ingestion dose that inhabitants around PWR plants can receive, and draw how to apply TF(Transfer Factor) to evaluate dose by the ingestion of animal products. For this, in this paper, dose assessment and analysis about existing materials related to TF were carried out, and the methodology to present TF was based on dose assessment and analysis result. The ingestion dose calculated using TFs presented by CSA and KEPRI was high or equal compared with SAM(Specific Activity Model) which is the most conservative, on the other hand, TFs given by NEC did not consider the effect according to volume change of animal at all, Therefore, it is judged that models used in the existing codes to asses the $C^{14}$ concentration into animal products must be improved to apply fundamentally hybrid model using transfer factors, that transfer factor on each animal products have to be developed through experiment for applying to our county.

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Performance of Oscillating Water Column type Wave Energy Converter in Oblique Waves (사파중 진동수주형 파력발전장치의 성능평가)

  • Jin, Jiyuan;Hyun, Beom-Soo;Hong, Keyyong;Liu, Zhen
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.17 no.3
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    • pp.182-188
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    • 2014
  • In an oscillating water column (OWC)-type wave energy conversion system, the performance of the OWC chamber depends on the chamber shape, as well as the incident wave direction and pressure drop produced by the turbine. Although the previous studies on OWC chambers have focused on wave absorbing performance in ideal operating conditions, incident waves do not always arrive normally to the OWC chamber in real sea conditions, especially in fixed devices. The present study deals with experiments and numerical calculations to investigate the effects of wave direction on the performance of the OWC chamber. The experiments were carried out in a three-dimensional wave basin for five different wave directions, including the effect of turbine using the corresponding orifice. The wave elevation inside the chamber was measured at the center point under various incident wave conditions. The numerical study was conducted by using a numerical wave tank-based volume-of-fluid model to compare the results with experimental data and to reveal the detailed flows around the chamber.

Electrochemical Hydrogenation Behavior of Surface-Treated Mg-based Alloys for Hydrogen Storage of Fuel Cell (연료전지의 수소저장용 마그네슘계 합금의 표면제어에 의한 전기화학적 수소화 거동 연구)

  • Kim, Ho-Sung;Lee, Jong-Ho;Boo, Seong-Jae
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.20 no.7
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    • pp.46-52
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    • 2006
  • The effects of surface treatment on the hydrogen storage properties of a $Mg_2Ni$ alloy particle were investigated by the microvoltammetric technique, in which a carbon-filament microelectrode was manipulated to make electrical contact with the particle in a KOH aqueous solution. It was found that the hydrogen storage properties of $Mg_2Ni$ at room temperature were improved by the surface treatment with a nickel plating solution. The sodium salts(sodium phosphate and sodium dihydrogen citrate) contained in the nickel plating solution made the alloy form an amorphous-like state, resulting in an improved hydrogen charge/discharge capacity at room temperature as high as about 150[mAh/g] from the original value of 17[mAh/g]. Potential-step experiment was carried out to determine the apparent chemical diffusion coefficient of hydrogen atom($D_{app}$) in the alloy. Since the alloy particle we used here was a dense, conductive sphere, the spherical diffusion model was employed for data analysis. $D_{app}$ was found to vary the order between $10^{-8}{\sim}10^{-9}[cm^2/s]$ over the course of hydrogenation and dehydrogenation process.

The Analysis of Reduction Efficiency of Soil Erosion and Sediment Yield by a Ginseng Area using GIS Tools

  • Lee, Geun-Sang;Jeon, Dae-Youn
    • Spatial Information Research
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    • v.17 no.4
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    • pp.431-443
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    • 2009
  • Recently, turbidity problem is one of the hot issues in dam and reservoir management works. Main reason to bring about high density turbid water is sediment yield by rainfall intensity energy. Because existing researches didn't consider diverse types of crops, it was difficult to calculate more accurate soil erosion and sediment yield. This study was evaluated the reduction efficiency of soil erosion and sediment yield using ginseng layer extracted from IKONOS satellite image, and the area and the ratio of ginseng area represented $0.290km^2$ and 0.94%. The reduction efficiency of soil erosion considering ginseng area represented low value in 0.9% using GIS-based RUSLE model, because the area of ginseng was small compared to areas of other agricultural lands. To reflect future land use change, this study was calculated the reduction efficiency of soil erosion and sediment yield by considering many scenarios as kinds of crops of paddy, dry field, orchard, and other agricultural areas convert to the ginseng district. As result of analysis of them according to scenarios, scenario (1) in which dry field was converted to ginseng area and scenario (2) in which fully agricultural lands were converted to ginseng area showed high reduction efficiency as 31.3% and 34.8% respectively, compared to existing research which didn't consider ginseng area. Methodology suggested in this study will be very efficient tools to help reservoir management related to high density turbid water.

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Fuzzy Control of Smart Base Isolation System using Genetic Algorithm (유전자알고리즘을 이용한 스마트 면진시스템의 퍼지제어)

  • Kim, Hyun-Su;Roschke, P.N.
    • Journal of the Earthquake Engineering Society of Korea
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    • v.9 no.2 s.42
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    • pp.37-46
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    • 2005
  • To date, many viable smart base isolation systems have been proposed and investigated. In this study, a novel friction pendulum system (FPS) and an MR damper are employed as the isolator and supplemental damping device, respectively, of the smart base isolation system. A fuzzy logic controller (FLC) is used to modulate the MR damper because the FLC has an inherent robustness and ability to handle non linearities and uncertainties. A genetic algorithm (GA) is used for optimization of the FLC. The main purpose of employing a GA is to determine appropriate fuzzy control rules as well to adjust parameters of the membership functions. To this end, a GA with a local improvement mechanism is applied. This method is efficient in improving local portions of chromosomes. Neuro fuzzy models are used to represent dynamic behavior of the MR damper and FPS. Effectiveness of the proposed method for optimal design of the FLC is judged based on computed responses to several historical earthquakes. It has been shown that the proposed method can find optimal fuzzy rules and the GA optimized FLC outperforms not only a passive control strategy but also a human designed FLC and a conventional semi active control algorithm.