• Journal of the Mineralogical Society of Korea
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• v.32 no.3
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• pp.185-200
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• 2019

This study aimed to liberate gold from invisible gold concentrate (Au = 1,840.00 g/t) through microwave nitric acid leaching experiments. For the purpose, this study conducted microwave-nitric acid leaching experiments and examined nitric acid concentration effect, microwave leaching time effect and sample addition effect. The results of the experiments were as follows: Au (gold) contents were not detected in all of the microwave leaching conditions. In the insoluble-residue, weight loss rate tended to decrease as the nitric acid concentration, microwave leaching time and sample addition increased. In an XRD analysis with solid-residue, it was suggested that gypsum and anglesite were formed due to dissolution of calcite and galena by nitric acid solution. When a fire assay was carried out with insoluble-residue, it was discovered that gold contents of the solid-residue were 1.3 (Au = 2,464.70 g/t) and 28.8 (52,952.80 g/t) times more than those of concentrate. But in the gold contents recovered, a severe gold nugget effect appeared. It is expected that the gold nugget effect will decrease if a sampling method of concentrate is improved in the microwave-nitric acid leaching experiments and filtering paper with smaller pore size is used for leaching solution and burned filter paper is used for sampling in lead-fire assay.

• Resources Recycling
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• v.25 no.3
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• pp.49-54
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• 2016

In this study, zircon sand is separated into zirconia and silica by using the Ar-$H_2$ arc plasma refining. And then silica is removed from it by the microwave leaching method to produce a high pure zirconia. Plasma melting consist of two sequential processes; reduction process with Ar gas only followed by refining process with Ar-$H_2$ gas. After cooling in chamber. The solid phase obtained at $240^{\circ}C$ were found to be composed of 20% sulfuric acid solution. The solution was used as a leaching solution with microwave irradiation to obtain a high purity zirconia.

• Journal of the Mineralogical Society of Korea
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• v.32 no.1
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• pp.1-14
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• 2019

This study used microwave-nitric acid leaching with the aim of removing penalty elements such as As and Bi. Moreover, enhanced gold content from the gold concentrate sample. The leaching conditions were changed: leaching time, nitric acid concentrations and solid-liquid ratio; In order to improve the removal of penalty elements. As a result of the experiment; sample weight loss rate, As and Bi removal rate and gold content in the solid-residues have been increased when the nitric acid concentration and leaching time were increased while the solid-liquid ratio was decreased. The leaching conditions for the maximum As and Bi removal and gold content were: leaching with a 6.0 M nitric acid solution doing 5 min. At these, the solid-residue sample weight loss was 87 %. As removal rate was 98.23 % and Bi was completely removed (100 %). Furthermore, gold content increased from 81.36 g/t to 487.32 g/t. The XRD of the solid residue showed that pyrite disappeared as the nitric acid concentration was increased, whereas sulfur peaks was increased, too.

• Journal of the Korean Geotechnical Society
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• v.32 no.11
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• pp.21-29
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• 2016

In this study, recycled aggregates crushed from waste concrete were sorted into three groups, 10-13 mm, 13-20 mm, and 20-25 mm. They were treated in different ways and then their crushability was evaluated for each treatment. Coffee waste was used for reducing their pH level. The pH of recycled aggregate was almost 11, regardless of aggregate sizes. The pH of coffee waste was nearly 5 and 10, 30, or 50 g of coffee waste was mixed with 1000 ml of distilled water and recycled aggregates. The lowest pH was about 6.2 when 50 g of coffee waste was mixed. Aggregates were treated with microwave or soaked for 1 day in vinegar (pH = 2) for neutralization reaction. Microwave treated and neutralized aggregates showed 3.3% and 6.2% higher crushing values compared to non-treated one, respectively. Neutralized treatment was more effective for crushing. In crushing tests, a sample height of 120 mm was tried, which gave 6.3% higher crushing value. A four stepped loading with each 100 kN gave 7.1% higher crushing value, compared to standard 100 mm height and 400 kN continuous loading.