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Determination of brightener concentrations in Watt-type Ni Electroplating bath using dilution titration-cyclic voltammetry stripping (DT-CVS) (희석 적정-순환전류전압법을 이용한 와트욕 내부 광택제 농도 모니터링)

  • Choe, Seung-Hoe;Gwon, Yeong-Hwan;Lee, Ju-Yeol;Kim, Man;Park, Yeong-Bae;Lee, Gyu-Hwan
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.30-30
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    • 2018
  • 스마트 도금공장을 구축하기 위해서는 도금액 내부의 화학 물질 농도 변화를 측정할 수 있는 화학 센서 기술이 필수적으로 요구된다. 와트욕은 대표적인 고속 니켈 도금액 중 하나로 기본적으로 황산니켈, 염화니켈, 보릭산의 염과 함께 케리어(type-1 광택제), 광택제(type 2-광택제), 응력 제어제 등의 유기 첨가제로 구성되어 있다. 이러한 유기 첨가제는 전차된 니켈층의 두께 균일도, 조도, 미세 구조, 내부 응력 등 다양한 특성을 제어하며, 정밀한 농도 관리가 필수적으로 요구되나, 분석 기술의 부재로 인하여 지금까지도 대부분의 액관리는 할셀법이나 작업자의 경험에 의존하고 있다. Cyclic voltammetry stripping(CVS) 방법은 전기화학 분석 과정에서 나타나는 첨가제의 가속, 감속 특성 등과 여기에 수반되는 stripping peak의 변화를 이용하여 개별 첨가제의 농도를 측정하는 방법이며, 지금까지 인쇄회로기판의 비아필 공정, 전해 동박 제조, 반도체 배선 등 구리도금 산업 전반에 걸쳐 첨가제 관리에 효과적으로 적용되고 있다. 그러나 수소 발생으로 인한 stripping 효율 문제로 인하여 니켈, 주석, 아연 등 표준 환원 전위가 높은 금속 도금액 내부 첨가제 농도 측정은 아직 어려운 상황이다. 본 연구에서는 이 문제를 극복하기 위해 염소를 과량 첨가한 구리 도금액을 CVS 분석의 base 용액으로 이용하여 니켈 도금액 내부 여러 광택제 (polyetylene glycol(PEG) 계열, thiourea 계열, 2-butyne-1,4-diol 등) 농도를 측정하는 법을 제시하였다. 제시된 방법은 CVS 분석 과정에서 구리-염소 사이의 상호 작용으로 인해 생성되는 3가지 stripping peak의 상대적인 크기 변화가 첨가제 농도에 따라 영향을 받는다는 사실에 기반하였다. 본 연구에서는 여기에 관한 원인에 대해 고찰하였으며, 제시된 방법을 통해 광택제 계열 첨가제 농도 측정을 선택적으로 할 수 있다는 것을 증명하였다.

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Wavelet Analysis of Visualized Image (가시화 영상의 웨이브렛 해석)

  • Park, Young-Sik;Kim, Okug-Gyu
    • Journal of the Institute of Convergence Signal Processing
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    • v.8 no.3
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    • pp.143-148
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    • 2007
  • The many studies have been proceeding to express accurately the feature of a sudden signal and a uncertain system in the image processing field. It is well know that Fourier Transform is widely used for frequency analysis of any signal. However, The frequency transform domain is not used for expressing the sudden signal change and non-stationary signal at the time-axis by this method. This paper describes of image analysis by discrete wavelet transform. Wavelet modulus maxima on transformed plane gives the Lipschitz exponent expression, which is useful to examine the characteristics of signal or the edge of an image. It is possible to reconstruct the original image only using the few maxima points. The fractal analysis is applied as an examples. The visualized image of oil flow on a ship model is analyzed. The fractal variable is obtained by the maxima analysis and the good results on the exprement is obtained by the visualized image analysis.

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Maxima Analysis from Visualized Image based on Multi-Resolution Analysis (다중해상도 웨이브렛 해석을 기본으로 한 가시화 영상의 극대값 해석)

  • Park, Young-Sik;Kim, Og-Gyu
    • Journal of the Institute of Convergence Signal Processing
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    • v.11 no.2
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    • pp.157-162
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    • 2010
  • In this paper we propose a fractal analysis based on the discrete wavelet transform. It is well known that Fourier Transform is widely used for frequency analysis of random signal. However, the frequency domain is not used for expressing the sudden signal change and non-stationary signal at the time-axis by this method. Maximum value in the wavelet modules can be expressed by the Lipschitz exponent, which is useful to represent the characteristics of signal or the edge of an image. It is possible to reconstruct the original image only by using the few maximum points. The v possible image It iusing oil was acquired to interpret the maximum value. ufter that, it was applied to the v possible image of a ship model. In addition, the fractal dimens by by the conlapse process of the sediment particle was examined. In this paper, the fractal dimens by has been obtained by the maximum value and the experiment obtained from the visualized image also acquired the same result as existing methods.

A VLSI Architecture of Systolic Array for FET Computation (고속 퓨리어 변환 연산용 VLSI 시스토릭 어레이 아키텍춰)

  • 신경욱;최병윤;이문기
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.25 no.9
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    • pp.1115-1124
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    • 1988
  • A two-dimensional systolic array for fast Fourier transform, which has a regular and recursive VLSI architecture is presented. The array is constructed with identical processing elements (PE) in mesh type, and due to its modularity, it can be expanded to an arbitrary size. A processing element consists of two data routing units, a butterfly arithmetic unit and a simple control unit. The array computes FFT through three procedures` I/O pipelining, data shuffling and butterfly arithmetic. By utilizing parallelism, pipelining and local communication geometry during data movement, the two-dimensional systolic array eliminates global and irregular commutation problems, which have been a limiting factor in VLSI implementation of FFT processor. The systolic array executes a half butterfly arithmetic based on a distributed arithmetic that can carry out multiplication with only adders. Also, the systolic array provides 100% PE activity, i.e., none of the PEs are idle at any time. A chip for half butterfly arithmetic, which consists of two BLC adders and registers, has been fabricated using a 3-um single metal P-well CMOS technology. With the half butterfly arithmetic execution time of about 500 ns which has been obtained b critical path delay simulation, totla FFT execution time for 1024 points is estimated about 16.6 us at clock frequency of 20MHz. A one-PE chip expnsible to anly size of array is being fabricated using a 2-um, double metal, P-well CMOS process. The chip was layouted using standard cell library and macrocell of BLC adder with the aid of auto-routing software. It consists of around 6000 transistors and 68 I/O pads on 3.4x2.8mm\ulcornerarea. A built-i self-testing circuit, BILBO (Built-In Logic Block Observation), was employed at the expense of 3% hardware overhead.

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Ultrasonographic Resistive Index of the Cranial Pancreaticoduodenal Artery in Normal Conscious Dogs (정상견에서 전방 췌장십이장 동맥의 초음파학적 혈관 저항지수)

  • Eom, Ki-Dong;Lee, Hae-oon;Seong, Yun-sang;Lee, Jeong-min;Lee, Jong-won;Oh, Tae-ho
    • Journal of Veterinary Clinics
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    • v.20 no.3
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    • pp.274-277
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    • 2003
  • The purpose of this study was to determine the range of resistive index(RI) of the cranial pancreaticoduodenal artery(cPDA) in the normal dog's and to assess the possibility of clinical application of RI for diagnosing a pancreatitis. Five patients with acute pancreatitis and 17 healthy adult beagle dogs were used. Duplex color Doppler ultrasonographic examination was performed by using a real-time scanner with 11-MHz linear-array transducer. The dogs were restrained in dorsal recumbency without the use of chemical agent. The mean RI of the normal pancreas(0.63$\pm$0.04) was significantly(t = 5.79, p = 0.001) different from acute pancreatitis dog(0.75$\pm$0.04). Duplex color Doppler ultrasonography was an useful technique for detecting and measuring RI of the cPDA. The evaluation of RI of the cPDA may be a valuable supportive diagnostic procedure for evaluating the pancreatitis or suspected in dogs.

Thermal Stability of a Nanostructured Exchange-coupled Trilayer (나노구조 교환결합 삼층박막의 열적 안정성 예측)

  • Lee, Jong-Min;Lim, S.H.
    • Journal of the Korean Magnetics Society
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    • v.20 no.2
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    • pp.75-82
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    • 2010
  • A recent progress on the prediction of the thermal stability of a nanostructured exchange-coupled trilayer is reviewed. An analytical/numerical combined method is used to calculate its magnetic energy barrier and hence the thermal stability parameter. An important feature of the method is the use of an analytical equation for the total energy that contains the magnetostatic fields. Under an assumption of the single domain state, the effective values of all the magnetostatic fields can be obtained by averaging their nonuniform values over the entire magnetic volume. In an equilibrium state, however, it is not easy to calculate the magnetostatic fields at the saddle point due to the absence of suitable methods of the accessing its magnetic configuration. This difficulty is overcome with the use of equations that link the magnetostatic fields at the saddle point and critical fields. Since the critical fields can readily be obtained by micromagnetic simulation, the present method should provide accurate results for the thermal stability of a nanostructured exchange-coupled trilayer.

Evaluation of Indoor Thermal Environment According to Air-Barrier Air Conditioning System in Perimeter Zone (페리미터존의 에어배리어 공조방식에 따른 실내 열환경 평가)

  • Park Byung-Yoon;Ham Heung-Don;Sohn Jang-Yeul
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.4
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    • pp.370-376
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    • 2005
  • For the purpose of investigating the effective removal of heating/cooling load from light-weighted building envelope, two air-conditioning systems, conventional parameter air-conditioning system and air-barrier system, are evaluated and compared by both experiment and simulation with six different cases during heating and cooling season. In addition, the characteristics of window-side building thermal load are assessed by varying supply air velocity in order to seek the optimal system operation condition. The results are as follows. 1) Air-barrier system is more effective to remove heating/cooling load at perimeter zone than conventional parameter air-conditioning system. Moreover, the better effectiveness appears during cooling season than during heating season. 2) The experiment during cooling season provides that indoor temperature of air-barrier system shows $1^{\circ}C$ less than that of the conventional system with similar outdoor air temperature profile, and indoor temperature distribution is more uniform throughout the experimented model space. It concludes that air-barrier system can achieve energy saving comparing to the conventional system. 3) The capturing efficiency of air-barrier system is 0.47 on heating season and 0.2 on cooling season with the same supply air volume. It results that the system performs effectively to remove building thermal load, moreover demonstrates high efficiency during cooling season. 4) The simulation results provide that capturing efficiency to evaluate the effective removal of building load from perimeter zone shows high value when supply air velocity is 1 m/s.

Treatment of an Occipital Fracture by Esquillectomy (골편적출술을 적용한 후두골 골절 치료)

  • Park, Jin-Uk;Cho, Ki-Rae;Chang, Dong-Woo;Choi, Seok-Hwa;Kim, Gon-Hyung
    • Journal of Veterinary Clinics
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    • v.27 no.4
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    • pp.450-452
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    • 2010
  • A 4-year-old male Yorkshire terrier was referred to us with signs of vomiting and unconsciousness due to a blunt head trauma. Gross examinations detected facial edema, subcutaneous hemorrhage and hypersalivation. A survey radiograph located an occipital fragment which was displaced caudally. A three-dimensional computed tomographic reconstruction demonstrated that the ventral portion of the fragment was attached incompletely. Because of the instability of the fragment, it was decided to perform an esquillectomy. After removing the fragment, the defect was reinforced with a muscular flap originating from the splenius muscle. The patient's condition gradually improved except for a slightly ataxic gait. At 20 months follow-up, there was no evidence of ataxia. The neurological status did not deteriorate before starting surgical intervention, although the patient sustained a skull fracture with severe intracranial hemorrhage. It is likely that the fragment being displaced outwardly played an important role in preventing an increase in intracranial pressure which could have led to neurological deterioration.

Characterization of the Schottky Barrier Height of the Pt/HfO2/p-type Si MIS Capacitor by Internal Photoemission Spectroscopy (내부 광전자방출 분광법을 이용한 Pt/HfO2/p-Si Metal-Insulator-Semiconductor 커패시터의 쇼트키 배리어 분석)

  • Lee, Sang Yeon;Seo, Hyungtak
    • Korean Journal of Materials Research
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    • v.27 no.1
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    • pp.48-52
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    • 2017
  • In this study, we used I-V spectroscopy, photoconductivity (PC) yield and internal photoemission (IPE) yield using IPE spectroscopy to characterize the Schottky barrier heights (SBH) at insulator-semiconductor interfaces of Pt/$HfO_2$/p-type Si metal-insulator-semiconductor (MIS) capacitors. The leakage current characteristics of the MIS capacitor were analyzed according to the J-V and C-V curves. The leakage current behavior of the capacitors, which depends on the applied electric field, can be described using the Poole-Frenkel (P-F) emission, trap assisted tunneling (TAT), and direct tunneling (DT) models. The leakage current transport mechanism is controlled by the trap level energy depth of $HfO_2$. In order to further study the SBH and the electronic tunneling mechanism, the internal photoemission (IPE) yield was measured and analyzed. We obtained the SBH values of the Pt/$HfO_2$/p-type Si for use in Fowler plots in the square and cubic root IPE yield spectra curves. At the Pt/$HfO_2$/p-type Si interface, the SBH difference, which depends on the electrical potential, is related to (1) the work function (WF) difference and between the Pt and p-type Si and (2) the sub-gap defect state features (density and energy) in the given dielectric.

Necrotizing Meningoencephalitis in a Yorkshire Terrier Dog (요크셔 테리어에서 발생한 괴사성 수막뇌염 1례)

  • Jeong Seong-Mok;Lee Yong-Jin;Kim Myung-Cheol;Cho Seong-Whan;Kim Duck-Hwan;Shin Sang-Tae;Park Seong-Jun;Cho Jong-Ki;Song Kun-Ho;Choi Ho-Jung;Lee Young-Won
    • Journal of Veterinary Clinics
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    • v.23 no.1
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    • pp.77-80
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    • 2006
  • A 3-year-old castrated male Yorkshire terrier was referred to the Veterinary Medical Teaching Hospital of Chungnam National University. The owner complained the history of seizure before one month. barking at night, wheezing with continuous chewing motion while breathing, recent decreases of vision and weight loss. Computed tomography revealed hypodense areas in the brain and ventriculomegaly, Multifocal lesions were noted in magnetic resonance images, which were hypointense in T1-weighted images and hyperintense in T2-weighted images. Ventriculomegaly and intracranial arachnoid cyst were also observed. Finally, it was diagnosed as necrotizing meningoencephalitis by histopathologic examination after necropsy.