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Magnetization and Magnetic Entropy Change in Superparamagnetic Co-Ferrite Nanoparticle (초상자성 코발트 페라이트 나노입자에 대한 자화 및 자기엔트로피 변화)

  • Ahn, Yang-Kyu;Choi, Eun-Jung
    • Journal of the Korean Magnetics Society
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    • v.18 no.2
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    • pp.63-66
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    • 2008
  • In order to the magnetization and magnetic entropy change for superparamagnetic ferrite nanoparticles, ultrafine cobalt ferrite particles were synthesized using a mircoemulsion method. The peak of X-ray diffraction pattern corresponds to a cubic spinel structure with the lattice constant 8.40 $\AA$. The average particle size, determined from X-ray diffraction line-broadening using Scherrer's, is 7.9 nm. The maximal magnetizations measured at 5 and 300 K are 24.3 emu/g and 17.2 emu/g, respectively. Superparamagnetic behavior of the sample is confirmed by the coincidence of the M vs. H/T plots at various temperatures. According to the thermodynamic theory, magnetic entropy change decreases with increasing temperature.

DEA모형을 이용한 공공기관 효율성분석에 관한 사례연구: 일선우체국을 중심으로

  • Kim, Tae-Ung
    • The Korean Journal of Financial Studies
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    • v.6 no.1
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    • pp.47-65
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    • 2000
  • 효율성은 산출물의 가치와 그 산출물을 창출해 내기 위해 생산과정에서 소비한 투입물 가치의 비율로 나타낸다 투입물이나 산출물의 시장가격이 존재하는 경우 이 값을 가중치로 이용하여 산출물과 투입물의 가치를 계산할 수 있다. 그러나 투입물과 산출물의 종류가 다양한 경우에는 투입물의 가치를 적절히 평가하기가 쉽지 않다. Data Envelopment Analysis(DEA)모형은 효율성을 여러 가지 투입물의 가중평균에 대한 여러 가지 산출요소의 가중평균의 비율로 표시하며, 특정 의사결정단위의 효율성 정도는 유사한 투입 산출구조를 가지는 준거집단과 비교하여 상대적으로 측정하고자 하는 방법이다. 본 논문에서는 DEA모형의 구조와 이론적 근거, 그리고 적용상의 장단점에 대해 알아 본 뒤 국내 일선우체국의 운영자료를 토대로 하여 공공적인 성격을 띠는 기관의 운영효율성 측정에의 적용사례를 제시하였다. 투입자료로는 '98년 우정사업자료를 중심으로 공통영업비, 우편영업비, 금융영업비, 직원수, 관할가구수, 관할면적, 고정자산 등 7개 변수와 우편영업수익, 금융영업수익, 보험수지차, 배달 및 중계 우편물량, 현금출납 취급건수, 연평잔실적의 6개 변수를 각각 투입물과 산출물 변수로 설정하여 모형을 구축하였다. 분석대상으로 삼은 64개 우체국 전체의 효율성 평균은 82.14%으로 나타났으며 DEA모형의 효율성결과와 기존에 이미 발표된 정보통신부 평가결과와의 상관관계는 0.46291로 강하지는 않지만 두 변수간에는 정(正)의 상관관계가 있음을 알 수 있었다.

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Prediction of the Added Mass of a 50-meter Class Airship with Empennage (꼬리날개를 고려한 50m급 비행선의 부가 질량 예측)

  • Ok Honam;Lew Jae-Moon;Lee Yung-Gyo;Lee Jinwoo
    • Proceedings of the KSME Conference
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    • 2002.08a
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    • pp.799-802
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    • 2002
  • Korea Aerospace Research Institute has been developing a 50-meter class airship to demonstrate the technology to be used in the development of a stratospheric airship, and importance of accurate prediction of the dynamic behavior of an airship before flight test is widely conceived. The added mass has large impact on the dynamic characteristics of an airship unlike for an airplane and the added mass of the airship with empennage is predicted in this paper. At first, the usability of the strip theory is examined which integrates the analytic two dimensional results in the cross section along the longitudinal axis. A panel method with the surface distribution of sources is developed and its validity is also examined. Finally, the panel method with both source and doublet distributions is implemented, and it is validated and applied for the calculation of the added mass of a 50-meter class airship. Using the methods developed, the influence of empennage and control surface deflection on the added mass property of the airship is studied.

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Synthesis and Characterization of Square Planar Mixed-Ligand Complexes (Ⅰ) : Synthesis and Spectroscopic Property of M(S-S)(N-N) Type Complexes with Ni (Ⅱ), Pd (Ⅱ), and Pt (Ⅱ) (평면사각형 혼합 리간드 착물의 합성과 그 특성 (제 1 보) : Ni (Ⅱ), Pd (Ⅱ) 및 Pt (Ⅱ) 의 M(S-S)(N-N) 형 착물의 합성과 분광학적 성질)

  • O, Sang O;Jeong, Deok Yeong
    • Journal of the Korean Chemical Society
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    • v.34 no.6
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    • pp.593-599
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    • 1990
  • A series of new, square planar, and mixed-ligand complexes of Ni(Ⅱ), Pd(Ⅱ), and Pt(Ⅱ) have been prepared. From the observation of electronic spectrum for the variation of the ligand substituents, the very intense absorption band in the visible range is by the electronic transition of dithiolene to diimine ligand, HOMO to LUMO. In the various solvent systems the IT band shows the similar behavior to IT transition of mixed-valence dinuclear complexes followed with Hush theory, happens rto dominently by the inner sphere charge transfer transition. The negative solvatochromism represents that the excited-state electric dipole is reduced or reversed by the electronic transition.

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Magnetism and Electronic Structure of Tc Half-monolayer on Pd(oo1) Surface (Pd(001) 위에 올려진 Tc 0.5 웃층의 자성과 전자구조)

  • 김동철;이재일
    • Journal of the Korean Magnetics Society
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    • v.9 no.5
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    • pp.223-226
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    • 1999
  • We have investigated the magnetic properties and the electronic structures of Tc half-monolayer (0.5-ML) on Pd(001) using the full-potential linearized augmented plane wave(FLAPW) energy band method. We calculated the total energies for ferromagnetic and paramagnetic states to determine the stable magnetic state. The calculated results show that the total energy of the ferromagnetic state is lower than that of the paramagnetic one. The overlayer Tc 0.5-ML has considerably large magnetic moment $(2.09\;{\mu}_B)$, while the substrate Pd layers have been negatively polarized. The calculated density of states and total electrons inside the muffin-tin (MT) sphere are presented and discussed in relation with the magnetic properties.

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First-principles Study on the Magnetism of VRu(001) Surface (VRu(001) 표면의 자성에 대한 제일원리 연구)

  • Jang, Y.R.;Song, Ki-Myung;Lee, J.I.
    • Journal of the Korean Magnetics Society
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    • v.17 no.3
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    • pp.109-113
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    • 2007
  • We investigated the magnetic properties of VRu(001) surface by using the all electron full-potenial linearized augmented planewave (FLAPW) energy band method within the GGA. We consider two different configurations, V and Ru surface layers, respectively. The V atoms in surface layer was calculated to have large magnetic moment of $1.71_{{\mu}_B}$ while the Ru surface layer to have nearly nonmagnetic state. The calculated spin-polarized density of states. spin density contour, and charge density were discussed in relation to the magnetic properties of VRu(001) surface.

Conceptual Domain of Organizational Citizenship Behavior : the Application of Q-Methodology (조직시민행동의 개념적 영역 탐구 : Q방법론의 적용)

  • Kim, Kyoung Seok;Lee, Jei Young
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.8
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    • pp.94-104
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    • 2018
  • This purpose of this study is to extract the perceptual types of Organizational Citizenship Behavior(OCB) conceptual domain. OCB is a employee behavior that goes above and beyond the call of duty, that is discretionary and not explicitly recognized by the employing organization's formal reward system, and that contributes to organizational effectiveness. But, as is generally known, OCB is such a fuzzy concept that many researchers have been questioning the exact conceptual domain of OCB. In this context, we try to applicate Q-methodology to find more effective way of explaining the conceptual domain of OCB. Q-sample was constructed by a thorough review on the relevant literature, and P-sample is 14 employees of an manufacturing company. In conclusion, we find three types of the conceptual domain of OCB, that is coworker-oriented, organization-orienteded, and work-orienteed type. The paper ends with suggestions for future research directions.

Half-metallicity and Magnetism of Co2ZrSi/ZnTe(001) Interface: A First-principles Study (Co2ZrSi/ZnTe(001)계면의 자성과 반쪽금속성에 대한 제일원리 연구)

  • Jin, Y.J.;Lee, J.I.
    • Journal of the Korean Magnetics Society
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    • v.17 no.4
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    • pp.147-151
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    • 2007
  • We have investigated the half-metallicity and magnetism for the Heusler ferromagnet $Co_2$ZrSi interfaced with semiconductor ZnTe along the (001) plane by using the full-potential linearized augmented plane wave (FLAPW) method. We considered low types of possible interfaces: ZrSi/Zn, ZrSi/Te, Co/Zn, and Co/Te, respectively. From the calculated density of states, it was found that the half-metallicity was lost at all the interfaces, however for the Co/Te system the value of minority spin density of states was close to zero at the Fermi level. These facts are due to the interface states, appeared in the minority spin gap in bulk $Co_2$ZrSi, caused by the changes of the coordination and symmetry and the hybridizations between the interface atoms. At the Co/Te interface, the magnetic moments of Co atoms are 0.68 and $0.78{\mu}_B$ for the "bridge" and "antibridge" sites, respectively, which are much reduced with respect to that ($1.15{\mu}_B$) of the bulk $Co_2$ZrSi. In the case of Co/Zn, Co atoms at the "bridge" and "antibridge" sites have magnetic moments of 1.16 and $0.93{\mu}_B$, respectively, which are almost same or slightly decreased compared to that of the bulk $Co_2$ZrSi. On the other hand, for the ZrSi/Zn and ZrSi/Te systems, the magnetic moments of Co atoms at the sub-interface layers are in the range of $1.13{\sim}1.30\;{\mu}_B$, which are almost same or slightly increased than that of the bulk $Co_2$ZrSi.

Comparison of Delay Estimates for Signalized Intersection (신호교차로 지체 산정 비교)

  • Jo, Jun-Han;Jo, Yong-Chan;Kim, Seong-Ho
    • Journal of Korean Society of Transportation
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    • v.23 no.1
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    • pp.67-80
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    • 2005
  • In this paper, the primary objective of the research are to review the methods currently avaliable for estimating the delay incurred by vehicles at signalized intersections. The paper compares the delay estimates from a deterministic queueing model, a model based on shock wave theory , the steady-state Webster model, the queue-based models defined in the 1994 and 2001 version of the High way Capacity Manual, in addition to the delays estimated from the TRANSYT-7F macroscopic simulation and NETSIM microscopic simulation. More especially, this paper is to compare the delay estimates obtained using macroscopic and microscopic simulation tools against state-of-the practice analytical models that are derived from deterministic queueing and shock wave analysis theory. The results of the comparisons indicate that all delay models produce relatively similar results for signalized intersections with low traffic demand, but that increasing differences occur as the traffic demand approaches saturation. In particular, when the TRANSYT-7F and NETSIM are compared, it is highly differences as approach for traffic condition to over-saturation. Also, the NETSIM microscopic simulation is the lowest estimates among the various models.

A Comprehensive Groundwater Modeling using Multicomponent Multiphase Theory: 1. Development of a Multidimensional Finite Element Model (다중 다상이론을 이용한 통합적 지하수 모델링: 1. 다차원 유한요소 모형의 개발)

  • Joon Hyun Kim
    • Journal of Korea Soil Environment Society
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    • v.1 no.1
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    • pp.89-102
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    • 1996
  • An integrated model is presented to describe underground flow and mass transport, using a multicomponent multiphase approach. The comprehensive governing equation is derived considering mass and force balances of chemical species over four phases(water, oil, air, and soil) in a schematic elementary volume. Compact and systemati notations of relevant variables and equations are introduced to facilitate the inclusion of complex migration and transformation processes, and variable spatial dimensions. The resulting nonlinear system is solved by a multidimensional finite element code. The developed code with dynamic array allocation, is sufficiently flexible to work across a wide spectrum of computers, including an IBM ES 9000/900 vector facility, SP2 cluster machine, Unix workstations and PCs, for one-, two and three-dimensional problems. To reduce the computation time and storage requirements, the system equations are decoupled and solved using a banded global matrix solver, with the vector and parallel processing on the IBM 9000. To avoide the numerical oscillations of the nonlinear problems in the case of convective dominant transport, the techniques of upstream weighting, mass lumping, and elementary-wise parameter evaluation are applied. The instability and convergence criteria of the nonlinear problems are studied for the one-dimensional analogue of FEM and FDM. Modeling capacity is presented in the simulation of three dimensional composite multiphase TCE migration. Comprehesive simulation feature of the code is presented in a companion paper of this issue for the specific groundwater or flow and contamination problems.

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