• Title/Summary/Keyword: 동 튜브재

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Interfacial Characterization of Mineralized Carbon Nanotubes (광물화된 탄소나노튜브 첨가재의 계면 특성화)

  • Park, Chanwook;Jung, Jiwon;Yun, Gunjin
    • Composites Research
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    • v.31 no.5
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    • pp.282-287
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    • 2018
  • In this paper, we explore interfacial properties of the mineralized CNTs when they are employed as reinforcing fillers in a polymer nanocomposite using molecular dynamics (MD) simulations. Recently, several studies on mineralizing carbon nanotubes (CNTs) with an aid of nitrogen doping to CNTs have been reported. However, there is a lack of studies on the reinforcing effects of the mineralized CNTs when it is employed as a filler of nanocomposites. Silica ($SiO_2$) is used as a mineral material and poly (methyl metacrylate) (PMMA) is used as a polymer matrix. Pull-out simulations are conducted to obtain the interfacial energy and the interfacial shear stress. It was found that the silica mineralized CNTs have higher interfacial interaction with the polymer matrix. In the future, by examining various thermomechanical properties of the mineralized-CNT-filler/polymer nanocomposites, we will search for potential applications of the novel reinforcing filler.

Characterization of CNT/Polymer Nanocomposites using MD-based Multiscale Method (분자동역학에 기반한 멀티스케일 해석을 이용한 탄소나노튜브/고분자 복합재료의 특성 규명)

  • Yu, Su-Young;Yang, Seung-Hwa;Cho, Maeng-Hyo
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2010.04a
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    • pp.554-557
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    • 2010
  • 본 논문에서는 동일한 체적분율 가지는 탄소나노튜브 나노복합재의 기계적 특성을 규명하였다. 동일한 chirality를 가지는 서로 다른 크기의 탄소나노튜브를 이용하여 탄소나노튜브의 크기가 복합재의 물성에 미치는 영향을 규명하였다. 복합재료의 분자동역학의 결과 탄소나노튜브의 길이방향의 물성은 크게 증가하나, 전단특성의 물성 강화효과를 나타나지 않았다. 이는 통해 탄소나노튜브와 기지재료 사이의 상호작용력이 복합재료의 전단력을 전달하고, 변형을 유지할 만큼 강하지 않다는 것을 확인하였다. 이와 같은 분자동역학 결과를 바탕으로 멀티스케일 모델을 개발하여 복합재료에서 나타나는 현상을 묘사하였다. 제안된 멀티스케일 모델을 이용하여 다양한 조건의 복합재료에 대한 특성 예측이 가능하다.

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Molecular Dynamics Study on Mechanical Behavior and Load Transfer of CNT/PET Nanocomposites : the Effects of Covalent Grafting (탄소나노튜브/폴리에스터 복합재의 역학적 거동과 하중전달에 관한 분자 동역학 전산모사 : 그래프팅 가공의 영향)

  • Jin, Juho;Yang, Seunghwa
    • Composites Research
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    • v.30 no.3
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    • pp.193-201
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    • 2017
  • Molecular dynamics simulation and the Mori-Tanaka micromechanics study are performed to investigate the effect of the covalent grafting between CNT and polyester on the mechanical behavior and load transfer of nanocomposites. The transversely isotropic stress-strain curves are determined through the tension and shear simulations according to the covalent grafting. Also, isotropic properties of randomly dispersed nanocomposites are obtained by orientation averaging the transversely isotropic stiffness matrix. By addressing the grafting, the transverse Young's modulus and shear moduli of the nanocomposites are improved, while the longitudinal Young's modulus decreases due to the degradation of the grafted CNT.

Molecular Dynamics and Micromechanics Study on Mechanical Behavior and Interfacial Properties of BNNT/Polymer Nanocomposites (분자동역학 전산모사와 미시역학 모델을 이용한 질화붕소 나노튜브/고분자 복합재의 역학적 물성 및 계면특성 예측)

  • Choi, Seoyeon;Yang, Seunghwa
    • Composites Research
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    • v.30 no.4
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    • pp.247-253
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    • 2017
  • In this study, the mechanical behavior and interface properties of boron nitride nanotube-poly(methyl methacrylate) nanocomposites are predicted using the molecular dynamics simulations and the double inclusion model. After modeling nanocomposite unit cell embedding single-walled nanotube and polymer, the stiffness matrix is determined from uniaxial tension and shear tests. Through the orientation average of the transversely isotropic stiffness matrix, the effective isotropic elastic constants of randomly dispersed microstructure of nanocomposites. Compared with the double inclusion model solution with a perfect interfacial condition, it is found that the interface between boron nitride nanotube and polymer matrix is weak in nature. To characterize the interphase surrounding the nanotube, the two step domain decomposition method incorporating a linear spring model at the interface is adopted. As a result, various combinations of the interfacial compliance and the interphase elastic constants are successfully determined from an inverse analysis.

Dynamic Instability of Submerged Floating Tunnels due to Tendon Slack (긴장재 느슨해짐에 따른 해중 터널의 동적 불안정 거동)

  • Won, Deok Hee;Kim, Seungjun
    • Journal of Korean Society of Steel Construction
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    • v.29 no.6
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    • pp.401-410
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    • 2017
  • This study deals with dynamic instability of a tendon moored submerged floating tunnel (SFT) due to tendon slack. In general, environmental loadings such as wave and current govern SFT design. Especially, the wave force, whose amplitude and direction continuously change, directly induces the dynamic behavior of the SFT. The motion of the floating tube, induced by the wave force, leads dynamic response of the attached tendons and the dynamic change of internal forces of the tendons significantly affects to the fatigue design as well as the structural strength design. When the severe motion of the SFT occurs due to significant waves, tendons might lose their tension and slack so that the floating tube can be transiently instable. In this study, the characteristics of dynamic instability of the SFT due to tendon slack are investigated performing hydrodynamic analysis. In addition, the effects of draft, buoyancy-weight ratio, and tendon inclination on tendon slack and dynamic instability behavior are analytically investigated.

A Study on the Prediction of Elastoplastic Behavior of Carbon Nanotube/Polymer Composites (계면 결합력과 나노튜브의 응집에 따른 나노튜브/고분자 복합재의 탄소성 거동 예측에 대한 연구)

  • Yang, Seunghwa;Yu, Suyoung;Ryu, Junghyun;Cho, Maenghyo
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.26 no.6
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    • pp.423-430
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    • 2013
  • In this research, a paramteric study to account for the effect of interfacial strength and nanotube agglomeration on the elastoplastic behavior of carbon nanotube reinforced polypropylene composites is performed. At first, the elastoplastic behavior of nanocomposites is predicted from molecular dynamics(MD) simulations. By combining the MD simulation results with the nonlinear micromechanics model based on the Mori-Tanaka model, a two-step domain decomposition method is applied to inversely identify the elastoplastic behavior of adsorption interphase zone inside nanocomposites. In nonlinear micromechanics model, the secant moduli method combined with field fluctuation method is used to predict the elastoplastic behavior of nanocomposites. To account for the imperfect material interface between nanotube and matrix polymer, displacement discontinuity condition is applied to the micromechanics model. Using the elastoplastic behavior of the adsorption interphase zone obtained from the present study, stress-strain relation of nanocomposites at various interfacial bonding condition and local nanotube agglomeration is predicted from nonlinear micromechanics model with and without the adsorption interphase zone. As a result, it has been found that local nanotube agglomeration is the most important design factor to maximize reinforcing effect of nanotube in elastic and plastic behavior.

The Network Analysis of the Diffusion on the Disaster Issue Via SNS based on Types of Information, Issue Contractiveness and Diffusion (재난 발생 시 SNS를 통해 확산된 재난 이슈 네트워크 분석: 유튜브의 정보 종류 및 이슈의 집중도·확산성을 중심으로)

  • Hong, Ju-Hyun
    • The Journal of the Korea Contents Association
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    • v.18 no.3
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    • pp.138-147
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    • 2018
  • The network analysis is done to explore what kind if issues are diffused about earthquake and the role of social media. The types of disaster information is classified into formal and informal. The role of actor is classified based on the concentrativeness and the diffusion of issue. Youttube is functioned as a formal channel and an informal channel when disaster happened. In case of government's video, issue contractiveness is high but the diffusion is low. In case of media's video, issue contractiveness and the diffusion are all high. In case of individual channel, issue contractiveness is low, but diffusion is high. In disaster, youtube is a tool to respread the disaster issue. Government needs to try diffusion of government's news actively in disaster.

A Study on the Design of Three-Dimensional Bending Machine (3차원 Bending Machine 설계에 관한 연구)

  • Lee, Choon-Man;Lim, Sang-Heon;Park, Dong-Keun
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.1852-1857
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    • 2003
  • This study is concerned about the development of three-dimensional bending machine for heat exchanger. Recently, three-dimensional bending is required for various heat exchanger. The purpose of this study is design of three-dimensional bending machine by analysis of bending process and structural analysis simulation. The analysis is carried out by FEM simulation using DEFORM and CATIA V5 software. The copper-tube is modeled by shell elements and the machine is modeled by placing proper shell and solid finite elements and fictitious mass properties to represent the real one. The final results of analysis are applied to the design of three-dimensional bending machine and the machine is successfully developed.

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Information Structure of Online Video Platform Focused on Web-Drama Case (온라인 동영상 시청 플랫폼의 정보구조 탐색 - 웹드라마 사례를 중심으로)

  • Cha, Dong-Min;Sung, Junghwan
    • The Journal of the Korea Contents Association
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    • v.19 no.9
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    • pp.135-143
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    • 2019
  • Purpose of this study is enhancing usability of online video platform by analyze link-depth and advertisement frequency. In this study, researcher checked market share of video platform which publishing web-drama, and compare their link-depth and advertisement frequency. As a result, access to the latest content has two to three link-depth. So it does not worsen usability. but, if contents doesn't show on main page or search result, it requires more than five to six steps. Image advertisement show up more than twice on every platform. 'Youtube' and 'Naver TV' show up pre-roll video advertisement in video player before offering contents. In this video platform information structure, directory searching needs high link-depth level and advertisement frequency. It will increase user's bounce rate and decrease return visit rate. So researcher suggests prototype using drop-down menu to reduce link-depth and enhance information structure.

A Study on the Characteristic Analysis and Manufacture of Electrostatic Dissipation PU Foaming Film (정전방전 PU 발포필름의 제조와 특성분석)

  • Kim, Seung-Jin;Park, Jun-Hyeong;Choi, La-Hee;Park, Mi-Ra;Ma, Hye-Young;Kwon, Oh-Kyung
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.58-58
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    • 2011
  • CNT 나노기술을 응용한 IT산업용 적층간지용 ESD(정전방전, Electrostatic Dissipation)PU 발포필름의 제조 가공기술 및 상품화 개발은 전자제품 패키지에 요구되는 쿠션성과 정전방전 기능을 갖는 폴리우레탄 발포 필름의 제조기술을 확립함으로써 가능 할 수 있다. 특히 IT산업용 필름제품이 개발되면 ESD 성능을 발휘하게 됨으로서 정전기 쇼크에 의한 각종 전자제품의 오작동이나 파손 방지가 가능하게 되어 포장재, 자동차, 전자제품의 하우징 등으로 사용될 수 있게 된다. 현재까지 ESD 기능을 부여하기 위해서 사용되는 충전재로는 금속섬유, 금속플레이크, 탄소섬유, 카본블랙 등이 있으며, 최근 탄소나노튜브를 응용한 연구가 많이 진행되고 있는데 탄소나노튜브는 직경이 수십nm, 종횡비 1000이상의 나노섬유형태로 서 전기전도성이 구리수준으로 알려져 있고 소량을 충전할 시 기계적 특성도 오히려 증대하는 장점을 가지고 있으며 전기적 특성으로는 상대적으로 낮은 나노튜브 함량에서는 ESD를 들 수 있고 높은 함량에서는 전자파 차폐성까지 기대되고 있다. 본 연구에서는 우수한 인장강도, 기계적 강도, 열적 안정성, 내약품성을 가지면서 습식 또는 용융공정을 통해 용이하게 시트, 필름, 코팅제를 제조할 수 있는 방수, 투습방수성을 가지는 유연재료인 폴리우레탄(PU) 1액형 PU에 MWNT 함량이 3wt%인 IPA/MWNT 분산용액을 PU 함량 대비 20, 30, 40파트로 함유시켜 $120^{\circ}C$에서 2분 건조시켜 제조한 그라운드 필름에 2액형 PU와 IPA/MWNT 분산용액에 발포제를 첨가하여 발포온도 140, 150, $160^{\circ}C$에서 5분간 건조시켜 시료 필름을 제조하였다. 제조된 필름의 전기전도성 측정은 부피저항과, 표면저항을 각각 측정하여 확인하였으며, 필름의 마찰 대전압은 E.S.T-7 마찰 대전압 시험기를 이용하여 표면 마찰 대전압과 반감기를 측정하여 확인하고, 필름의 물리적 특성은 인장시험기를 이용하여 breaking stress, breaking strain을 구하였다. 필름의 표면 특성은 영상 현미경 시스템을 사용하여 ${\times}1000$ 배율로 측정하여 분산특성과의 연관성을 확인하였다.

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