• Title/Summary/Keyword: 대안선정

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Degradation of Sulfonamide Antibiotic Substances by Ozonation: An Experimental and Computational Approach (설폰아미드계 항생물질의 오존산화분해에 대한 계산화학적 해석 및 실험적 검증)

  • Won, Jung Sik;Lim, Dong Hee;Seo, Gyu Tae
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.6
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    • pp.442-450
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    • 2014
  • Concern has grown over a presence of micropollutants in natural water since sulfonamide antibiotic substances such as sulfamethazine, sulfamethoxazole, sulfathiazole have been frequently detected in Nakdong River, Korea. The current work investigates the degradation of the three sulfonamide substances by using quantum chemistry calculations of density functional theory (DFT) and experimental measurement techniques of Fourier transform infrared spectroscopy (FT-IR) and ultraviolet-visible spectrophotometer (UV-VIS). DFT calculations demonstrate that the lowest energy gap between the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbitals (LUMO) lies in sulfanilamide functional group of sulfonamide, implying that the sulfanilamide functional group would be the most active site for ozone oxidation. Also, UV-VIS spectra and FT-IR analysis reveal that 260 nm band originated from sulfanilamide group was absent after ozone oxidation, indicating that a functional group of amine (N-H) was removed from sulfanilamide. Both theoretical and experimental observations agree well with each other, demonstrating the DFT calculation tool can be an alternative tool for the prediction of chemical reactions in purification treatment processes.

Simulating Carbon Storage Dynamics of Trees on the Artificial Ground (시뮬레이션을 통한 인공지반 교목의 탄소저장량 변화)

  • You, Soo-Jin;Song, Ki-Hwan;Park, Samuel;Kim, Se-Young;Chon, Jin-Hyung
    • Journal of the Korean Institute of Landscape Architecture
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    • v.45 no.2
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    • pp.11-22
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    • 2017
  • To successfully create a low-carbon landscape in order to become a low-carbon city, it is necessary to understand the dynamics of artificial greening's resources on a multi-scale. Additionally, the effects of carbon storage should be quantitatively evaluated. The purpose of this study is to simulate and evaluate the changes in carbon storages of artificial ground trees using system dynamics throughout a long-term period. The process consisted of analyzing the dynamics of the multi-scale carbon cycle by using a casual loop diagram as well as simulating carbon storage changes in the green roof of the Gangnam-gu office building in 2008, 2018, 2028, and 2038. Results of the study are as follows. First, the causal loop diagram representing the relationship between the carbon storage of the artificial ground trees and the urban carbon cycle demonstrates that the carbon storage of the trees possess mutual cross-scale dynamics. Second, the main variables for the simulation model collected 'Biomass,' 'Carbon storage,' 'Dead organic matter,' and 'Carbon absorption,'and validated a high coefficient of determination, the value being ($R^2$=0.725, p<0.05). Third, as a result of the simulation model, we found that the variation in ranking of tree species was changing over time. This study also suggested the specific species of tree-such as Acer palmatum var. amoenum, Pinus densiflora, and Betula platyphylla-are used to improve the carbon storage in the green roof of the Gangnam-gu office building. This study can help contribute to developing quantitative and scientific criteria when designing, managing, and developing programs on low-carbon landscapes.

Analyzing the effect of LID(Low Impact Development) using the CAT(Catchment hydrologic cycle Assessment Tool) (CAT을 이용한 LID(Low Impact Development) 효과 분석)

  • Jang, Cheol-Hee;Kim, Hyeon-Jun
    • Proceedings of the Korea Water Resources Association Conference
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    • 2012.05a
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    • pp.278-278
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    • 2012
  • 최근 녹색도시를 지향하면서 도시 내에서의 물의 순환에 대한 관심이 높아지고 있으며 도시계획 단계에서부터 물의 순환을 고려하려는 시도가 이루어지고 있다. 국토해양부, 환경부, 소방방재청 및 지방자치단체들은 법령, 기준, 지침 및 조례 등을 제정하여 물순환을 도시개발 이전의 상태가 될 수 있도록 시설 설치를 유도하고 있다. 그러나, 개별시설들의 조합이 유역규모의 물순환에 미치는 영향 평가는 이루어지고 있지 못한 실정이다. 종래에는 홍수저감을 목적으로 홍수저류지와 침투시설에 대하여 설계하고 시공을 하였으나 장기적인 관점에서 LID 시설의 효과를 평가하여 도시 계획 단계에서 반영하지는 못하였다. 그리고 이들 개별 LID 시설(침투, 저류 등)에 대한 단위 시설의 규모 설계에 그치고 있어 개선 시설이 다중으로 조합되어 분산 계획되었을 경우, 유역 규모에서 물순환의 긍정적인 변화를 판단하기는 어려운 형편이다. 도시지역에서의 LID(Low Impact Development) 효과 분석과 연계된 유역 물순환 해석을 위하여 독일, 호주 및 미국에서는 STORM, Urban Developer, SUSTAIN(System for Urban Stromwater Treatment, and Analysis INtegratration) 및 SWMM LID(Storm Wastewater Management Model LID) 등의 모형을 출시하고 실무에 적용하고 있다. 그러나, 해외에서 개발된 기술은 국내의 유역 환경을 충분히 반영하기 어렵다. 저수지 혹은 하천에서의 취수 등과 같이 국내의 복잡한 물순환 형태를 반영하는데 한계가 있으며, 기존의 물순환 해석모형에 의한 LID 시설을 계획하는 방법은 홍수저감에 국한되어 있고, 하천 유량이나 지하수위 측정 자료가 부족한 대상지역에 대한 장기적인 유역 물순환 및 도시 개발과 같은 토지이용 변화가 물순환에 미치는 영향을 해석하는데 있어 제한이 있고, 개별적으로 설치된 LID 시설들이 유역의 물순환을 개선하는 효과를 종합적, 정량적으로 구현하는데 한계가 있다. 본 연구에서는 도시 개발 지역의 장기간에 걸친 물순환의 변화를 예측하고 물순환을 개선시키는 대안 시설의 효과를 사전에 평가하는 것을 목표로 김현준 등(한국건설기술연구원, 2011)이 개발한 유역 물순환 해석 모형인 CAT(Catchment hydrologic cycle Assessment Tool)을 이용하였다. 특히, CAT은 사용자의 목적에 맞는 다양한 물순환 개선시설(침투시설, 저류지, 습지, 빗물저장 시설, 리사이클 및 외부급수 등)의 구현 및 모의가 가능하도록 개발되었다. 대상유역으로는 경기도 Y지구를 선정하였으며 도시개발 시나리오(전원도시 및 산업도시 등)에 따른 LID 효과 분석을 실시하였다. 대상지역에 대한 도시유형별 개발계획에 따른 개발 전 후 물순환 변화량 분석 및 LID 시설 계획에 의한 물순환 개선효과를 살펴보면 1998년부터 2007년까지의 평균 강우량을 1,271mm라고 할 때 산업도시의 경우 도시 개발 전의 증발산, 직접유출 및 기저유출은 각각 53%, 29%, 19%로 나타났으며 도시 개발 후 35%, 54%, 12%로 직접유출이 개발 전에 비해 86%나 증가하여 개발에 따른 영향이 큰 것으로 나타났다. 따라서, 이러한 개발에 따른 영향을 최소화하기 위하여 LID 시설을 계획하여 효과를 분석한 결과 증발산, 직접유출, 기저유출이 44%, 34%, 13%로 나타나 도시 개발 후의 왜곡된 물순환 체계가 개발전의 수준과 근접하게 나타나 LID 시설의 긍정적인 효과를 검토할 수 있었다. 이상에서와 같이 CAT 모형을 사용하여 도시유역의 물순환 체계를 진단하고, LID 시설의 효과를 평가할 수 있게 됨으로써 향후 도시유역에 대한 물순환 정상화를 실현하기 위한 정책 수립에 기초자료를 제공하고, 설계 실무에 활용될 수 있을 것이다.

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Impact Analysis for Transit Oriented Street Design (A Case Study for Kangnam Street in Seoul) (대중교통우선가로제 시행방안 및 기대효과 분석 (강남대로 중앙버스전용차로 도입을 중심으로))

  • 황기연;이조영
    • Journal of Korean Society of Transportation
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    • v.21 no.3
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    • pp.47-56
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    • 2003
  • Considering the high density developments along the major traffic corridors in Seoul, transit-oriented street designs will be a very effective to control traffic congestion along the corridors. For testing the effectiveness, we selected. for our case study, Kangnam Street, which is one of the most highly developed corridors in Seoul The traffic study on Kangnam street in 2000 shows that the daily average bus speed is 11.73km/h, which is 5km/h lower than the auto speed. The Central Bus Lane system was applied on the Kangnam street to test impact on bus speed as well as auto speed. Simulation results show that with Central Bus Lane have been improved the travel speeds of bus as well as auto on Kangnam street from 14.4km/hr to 35.0km/hr and from 25.1km/hr to 26.1km/hr, respectively. The bus market share increases about 6-8 percentages. Especially, 13.4% of bus users are increased for long-distance trips.

Case Analysis on Application of Project Delay Analysis Method in Domestic Construction Project (국내 건설공사에서 공기지연 분석방법 적용 사례 분석)

  • Kim, Seon-Gyoo;Kwon, Soonwook
    • Korean Journal of Construction Engineering and Management
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    • v.20 no.6
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    • pp.98-106
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    • 2019
  • Recently, the number of project delay-related claims and disputes in Korean construction projects has been increasing rapidly. This suggests that the domestic construction contract practice, which has traditionally been superior to the client, is changing into a mutually balanced relationship among the contracting parties. The project delay analysis selects the application method according to the type of schedule approved at the start of the construction and how the schedule management was performed during the construction. The most important prerequisite for project delay analysis is that a complete CPM schedule agreed at the beginning of the construction is prepared and the actual progress of such schedule is well documented. This study is about applying the project delay analysis methodology of a case where a contractor claims damages to a client while constructing a large new private building construction project. In this study, it is determined whether the application of the as-planned analysis method is appropriate to the incomplete CPM schedule and then proposes the as-planned vs. as-built analysis method based on the new standard as an alternative. Next, apply the as-planned vs. as-built analysis method to the schedule in the case project, and then compare it with the result of the as-planned analysis method. The purpose of this study is to suggest a project delay analysis method suitable for the domestic schedule management practices, so that it can be used as a meaningful reference in project delay disputes and litigations of domestic construction projects.

Evaluation of the Effect of Agricultural Activity on Stream Water Quality by Watershed Modeling (유역모형을 이용한 농업활동이 수질에 미치는 영향평가)

  • Jung, KwangWook;Jung, Inkyun;Kang, SooMan;Kwon, Jinwook
    • Proceedings of the Korea Water Resources Association Conference
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    • 2016.05a
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    • pp.510-510
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    • 2016
  • 농업 비점오염원의 영향을 분석하고 여러 가지 대안(관리정책)이 수계의 수질에 미치는 영향을 평가하기 위해서 유역모형의 적용이 필요하다. 이러한 유역모형에는 모형의 복합성, 계산시간 등에 따라 simple method, mid-range model, detail model로 나눌 수 있다. Simple methods는 요구되는 자료가 작으나 그 결과의 정확성은 떨어진다. 반면에 detail model는 정확한 결과를 획득할 수 있으나 그만큼 방대한 자료와 모니터링을 요구하며, 보정 및 검증에 많은 시간과 노력을 필요로 한다. 특히, 복잡한 유역특성 및 축산오염원을 포함한 복잡한 특성들을 고려해서 모델링하기 위해서는 detail model이 필요하며 본 연구에서는 HSPF모델을 이용해서 그 영향을 분석하고자 하였다. 따라서 본 연구에서는 농업에 미치는 영향을 평가하기 위해서 청미천 유역 및 덕천천 유역을 대상유역으로 선정하여 그 영향을 분석하였다. 농업에 미치는 영향을 평가하기 위해서 유역내 투입된 비료사용량을 통계청 자료를 활용하여 산정후 적용하였으며, 축산 부산물중 자원화되는 축산 액비 및 퇴비량을 산정하여 그 영향에 대해 분석하였다. 또한 기존에 광범위하게 활용되고 있는 수질오염총량관리제도에서 산정되는 배출부하량에 유달율을 고려하여 점오염으로 입력하였으며, 직접방류되는 하수처리장도 함게 고려하여 구축하였다. 청미천 유역의 청미천1 지점의 BOD, T-N, T-P에 대한 보정기간의 평균 관측값은 4.205mg/L, 3.844mg/L, 0.137mg/L이며 검정기간의 관측값은 2.741mg/L, 4.638mg/L, 0.144mg/L로 나타났다. BOD, T-N, T-P에 대한 보정기간의 NSE는 -0.58, -0.20, -0.33이며, 검정기간의 NSE는 -0.26, -1.35, -3.54로 분석되었다. BOD, T-N, T-P에 대한 보정기간의 RMSE는 2.65, 1.63, 0.12이며, 검정기간의 RMSE는 1.36, 1.64, 0.07로 나타났다. 덕천천 유역의 경우 국가관측망이 없어 동진강의 제일 말단 지점인 동진강3 지점의 BOD, T-N, T-P에 대한 보정기간 평균관측값은 2.891mg/L, 3.455mg/L, 0.096mg/L이며, 검정기간의 관측값은 2.293mg/L, 3.223mg/L, 0.104mg/L로 나타났다. BOD, T-N, T-P에 대한 보정기간의 NSE는 -0.20, -0.56, -0.49이며, 검정기간의 NSE는 0.24, -0.06, -0.19으로 분석되었다. BOD, T-N, T-P에 대한 보정기간의 RMSE는 1.53, 2.12, 0.05이며, 검정기간의 RMSE는 1.05, 0.98, 0.06으로 나타났다. 본 연구의 분석결과는 점오염원, 축산계비점오염, 토지계비점오염, 시비량, 배경부하로 구분하여 분석을 실시하였으며 분석결과 청미천 유역의 비점오염 기여율이 약 65%를 차지하고 있는 것으로 평가되었으며, 덕천천 말단에서는 약 37.7%의 비점오염물질이 하천수질에 영향을 미치는 것으로 나타났다. 또한, 기존 수질오염 총량관리제도에서 점오염의 감소에 의한 비점오염비중이 커지는 것으로 평가되었으며, 그 중 축산이 차지하는 비중이 상대적으로 높은 것으로 평가되고 있지만, 본 연구의 결과에서는 그보다 적은 수준이 수계에 영향을 미치는 것으로 분석되었다.

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Study of the Strategy of Establishment and Expansion of Green Port - the Case of Incheon Port - (녹색항만의 구축과 활성화 방안 -인천항의 사례를 중심으로-)

  • Kim, Hong-Seop
    • Journal of Korea Port Economic Association
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    • v.34 no.4
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    • pp.161-180
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    • 2018
  • Environmental value is essential to the survival and development of humans. Environmental value and its importance are being emphasized, and related disputes are being expanded. The concept of green logistics is understood to be the same as that of the environment. As a way to preserve nature and engage in sustainable development, green logistics includes all logistical activities for protecting nature and minimizing or reducing behaviors that harm the environment for all processes, including using and reusing products and abolishing the search for resources by final users. All areas of human activity, such as the political, economic, social, and cultural sectors, strive to protect and preserve the environment and nature. In particular, the preservation of the environment shall be stressed in the economic activities that produce various products and expand the value added, and similarly for the social aspects. Green (environment) logistics aims to protect the environment and expand the prevention of environmental destruction and minimization on Earth. Some important cases and experiences that were introduced and applied in major countries are summarized. This research reviewed previous studies and the concepts of green logistics, including at ports, which represent a key sector of logistical activities. In this paper, air and water pollution at Incheon Port were investigated, and alternatives and system figures related to improving environmental logistics regarding three dimensions-country, company, and civil society-are recommended.

A Study on Price Competitiveness for LNG Bunkering in the Busan Port (부산항의 LNG 벙커링 가격 경쟁력 확보 방안)

  • KIM, Geun-Sub
    • Journal of Korea Port Economic Association
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    • v.32 no.1
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    • pp.123-133
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    • 2016
  • LNG(Liquefied Natural Gas) bunkering has become an important issue with the enforcement of environment regulations in shipping industry required by the International Maritime Organization (IMO). With increased attention on LNG bunkering, many studies that focus on safety, regulation, demand forecasting, and the feasibility of LNG fueled ships have been carried out. However, most of the existing research has not included considerations of the price of LNG bunkering and its competitiveness. This paper, therefore, suggests ways to increase price competitiveness in the LNG bunkering market in the Busan Port. This paper analyzes the LNG bunkering supply mechanism by investigating various LNG bunkering terminal business in the LNG supply market. Factors that determine LNG bunkering price and its elasticity are also identified. Market players who want to operate LNG bunkering terminals in the Busan Port should introduce a merchandising trade method that is able to exclude the "Korea premium" in order to increase price competitiveness. This paper also suggests adoptable strategies such as the use of TPS (Terminal to Ship via Pipeline) type of bunkering service and the importance of location for minimizing initial investment cost.

A Study on Priorities of the Key Competence of Port Logistics Enterprise using AHP Method (AHP 기법을 활용한 항만물류기업의 직업기초능력 우선순위 분석)

  • Park, Doojin
    • Journal of Korea Port Economic Association
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    • v.30 no.1
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    • pp.159-173
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    • 2014
  • This study is key competence port logistics companies analyze the priorities of evaluation factors. key competence index of NCS(National competency standard) was designed on the basis of the research model. The priorities of evaluation factors were analyzed using AHP method. The results of the analysis of 1 layer's key competence priorities are as follows: Interpersonal skills(0.217), communication skills(0.153), ability to develop problem(0.148), ability to understand the organization(0.103), and resource management skills(0.090), self-development ability and professional ethics(0.070), information skills(0.065), technical skills(0.049), numeracy skills(0.035).

Analysis on Response System against International Maritime Terrorism : Using Analytic Hierarchy Process(AHP) Method (국제해상테러 대응체계의 우선순위 분석 : 계층적 의사결정기법(AHP)을 이용하여)

  • Oh, Tae Kon
    • International Area Studies Review
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    • v.17 no.4
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    • pp.181-202
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    • 2013
  • After the Cold War, international terrorism and related issues have been the most urgent problems. However, Korea hasn't recognized this seriousness due to relatively slight damage. Yet the interest about the international maritime terrorism and related issues is increasing as the maritime terrorism issues emerged. This is because Korea is located next to three oceans and majority of international trades depend largely on international maritime transportation due to its scarce natural resources. Therefore this study has the purpose that it reviews the advanced researches and documents, analyzes the priority about response system against international maritime terrorism, suggests the practical solutions. For these purposes, it conducted Delphi technique to international maritime terrorism experts with response system factors selected among the advanced researches and documents. As the result of analysis, this study figured out that legal and institutional countermeasures are needed as international measures, strategic countermeasures are needed as domestic measures to set up the response system against international maritime terrorism. Synthetically, for the efficient and practical counteract against international maritime terrorism, the response institute against international maritime terrorism and the awareness of relevant experts are preferentially necessary.