• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.86.1-86.1
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• 2010

예비개질기(Pre-reformer)는 중대형 내부개질형 용융탄산염 연료전지(MCFC) 시스템에서 다양한 연료를 사용하기 위한 필수적인 화학반응기이다. 예비개질기는 스택 전단에 설치함으로서 스택 내부의 열균형을 유지하고, 다양한 원료를 연료로 이용할 수 있도록 하며, 황화물로부터 후단의 개질촉매 및 전극촉매를 보호하여 주개질 반응의 부담을 감소시켜 MCFC 시스템의 내구성 향상의 중요한 역할을 한다. 본 연구는 예비개질 반응기 설계에 CFD 모델링을 적용하기에 앞서 파일롯 반응기 내 농도/ 온도 구배를 측정하고자 하는 목적으로 수행되었다. 반응가스로는 천연가스 내 고차탄화수소(C2 이상) 중 상대적으로 높은 농도를 가진 에탄을 이용하였고, MCFC용 예비개질기의 운전특성을 고려하여 비교적 낮은 온도와 높은 수증기/탄소 비에서 단열반응기로 실험을 진행하였다. 향후 본 실험결과를 이용하여 CFD 모델링에 대한 검증을 수행할 예정이며, 하수처리장부생가스(ADG)/ 매립지 가스(LFG)용 MCFC 시스템을 위한 예비개질기 설계에도 적용을 하고자 한다.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.44 no.4
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• pp.333-342
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• 2016

Liquid rocket propulsion is a system that produces required thrust for satellites and space launch vehicles by using chemical reactions of a liquid fuel and a liquid oxidizer. Monomethylhydrazine/dinitrogen tetroxide, liquid hydrogen/liquid oxygen and RP-1/liquid oxygen are typical combinations of liquid propellants commonly used for the liquid rocket propulsion system. The objective of the present study is to investigate useful design and performance data of liquid rocket engine by conducting a numerical analysis of thermochemical reactions of liquid rocket propellants. For this, final products and chemical compositions of three liquid propellant combinations are calculated using equilibrium constants of major elementary equilibrium reactions when reactants remain in chemical equilibrium state after combustion process. In addition, flame temperature and specific impulse are estimated.

• Journal of the Korea Institute of Building Construction
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• v.15 no.1
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• pp.25-33
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• 2015

In this study, initial crack index was evaluated by FEM analysis to find the crack propagation from hydration heat in precast concrete. As results, as the usage of hardening accelerator increased, initial compressive strength increased and setting time was shortened. Additionally, as amounts of hardening accelerators increased, the central temperature of concrete increased and the time to reach the highest temperature was shortened. It was demonstrated that the hardening accelerators accelerated the hydration reaction of cement, and caused the increase of hydration heat within the short period of time. Furthermore, the crack index for evaluating the heat level was performed by FEM. As results, there was no problem about the cracks, despite of the growth of initial high hydration heat. This is because of the increased tensile strength that is large enough to sustain the thermally induced-stress.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2011.04a
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• pp.457-462
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• 2011

This paper presents a numerical investigation of deflagration to detonation transition (DDT) induced by shock wave and flame interaction in ethylene-air mixtures. Also shows the change of DDT triggering time by wall cooling effect. A model is consisted of the compressible reactive Navier-Stokes equations. And the effect of viscosity, thermal conduction, molecular diffusion, chemical reaction and wall effect are included. Using this model, the generation of hot spot by repeated shock and flame interaction, occurrence of detonation, and wall cooling effect of detonation confining boundaries are studied.

• Clean Technology
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• v.23 no.2
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• pp.140-147
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• 2017

In this study, we performed numerical simulation for the catalyst regeneration process of diesel desulfurization reactor. We analyzed the changes in regeneration process according to purge gas flow rate, catalyst permeability, reactor size, and heat loss of reactor. We have found that the regeneration process is very much affected by temperature changes whereas it is hardly affected by catalyst permeability and porosity. We also estimated the regeneration time according to purge gas flow rate and initial temperatures and have found that increasing purge gas temperature is more effect for fast regeneration. The present results can be utilized to design a regeneration process of diesel desulfurization reactor for a fuel cell used in ships. Furthermore, the present work also can be used to design low sulfur diesel supply in oil refineries and therefore contribute to the development of clean petrochemical technology.

• Proceedings of the Korean Institute of Landscape Architecture Conference
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• 2017.10a
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• pp.147-149
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• 2017

경수 용기재배는 뿌리분의 손상 없이 식재를 할 수 있어 이식 후 활착이 용이하고, 식재시기의 계절적 제약을 적게 받아 부적기 이식 시 하자를 현저히 줄일 수 있다. 용기재배 시 용기 내 토양온도는 토양의 물리화학반응과 식물의 생육 및 물과 양분의 흡수에 영향을 주는 중요한 토양환경요소의 하나이다. 목본성 식물 용기재배의 경우 제한된 근권부의 토양이 외부기온에 의해 불안정할 수 밖에 없다. 재배용기의 유형에 따른 지온의 변화를 측정한 결과 지중재배형의 용기가 단열성능이 큰 것으로 나타났다. 지상재배 방식의 용기 중에서는 Bag in Pot-루트 스커트 형의 용기가 단열성능이 큰 것으로 나타났으며, 이는 지중재배방식의 용기와 유사한 용기 내 지온 안정화 정도를 보이는 것으로 나타났다. 향후 후속 연구에서는 본 연구를 토대로 디자인 개발된 용기의 시제품을 제작하여 테스트하고, 재배농가에 적용가능성을 검토하고자 한다.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.489-492
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• 2008

Adiabatic temperature rise and autogenous shrinkage experiments were performed for three silica-fume included mass concrete mixtures and a reference mixture without silica-fume, in order to investigate the influence of silica-fume on the hydration heat and autogenous shrinkage properties of mass concrete, and to examine applicability of silica-fume to mass concrete. It was revealed from the experiment that, for mass concrete, the rate of hydration was hardly increased while the maximum adiabatic temperature rise decreased about 5$^{\circ}$C by the addition of silica-fume, and the amount of autogenous shrinkage was almost the same regardless of silica-fume replacement. These facts imply that silica-fume can enhance the resistance of mass concrete to temperature cracking as well as the durability.

• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.131.2-131.2
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• 2010

서부 발전 태안화력발전소에 건설 예정인 IGCC Demo plant의 설계 자료를 근거로 석탄 가스화기의 정상 상태 전산모사를 PRO/II를 사용하여 수행하였다. 석탄을 PRO/II가 받아들일 수 있는 성분으로 바꾼 후 가스화기를 버너와 가스화기 본체의 두 부분으로 나누어 모델링하였다. 버너는 단열조건의 Gibbs Reactor로 모델링하였다. 모사 결과 산소가 완전 소진될 때까지 반응이 진행되는 것을 확인하였다. 가스화기는 char gasification 반응은 kinetic reaction equation으로, gas phase reaction은 equilibrium reactor로 모사하는 알고리듬을 개발 하였으나 PRO/II의 기능에 한계가 있어 간단한 Gibbs Reactor로 모사하였다. 가스화기는 membrane wall에 의하여 냉각되는 것을 고려하여 $1550^{\circ}C$의 균일한 온도에서 반응이 일어나는 것으로 고려하였다. 전산 모사 결과 주요 성분의 조성이 실제 syngas의 조성과 5% 정도 오차가 있는 것으로 나타났다.

• Korean Chemical Engineering Research
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• v.57 no.3
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• pp.420-424
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• 2019

In SNG (synthetic natural gas) process by proposed RIST(Research Institute of Industrial Science & Technology)-IAE(Institute for Advanced Engineering) (including three adiabatic reactors and one isothermal reactor), the methanation reaction and water gas shift (WGS) reaction take place simultaneously, and the supply of steam with syngas might control the temperature in catalyst bed and deactivate the catalyst. In this study for development of SNG process, the characteristics of the methanation reaction with a Ni-based catalyst by prepared RIST and using a low $H_2/CO$ mole ratio (including $CO_2$ 22%) are evaluated. The operating conditions ($H_2O/CO$ ratio of the $1^{st}$ adiabatic reactor, operating temperature range of $4^{th}$ isothermal reactor, etc.) were reflected the results from previous studies and in the same condition a pilot scale SNG process is carried out. As a results, the pilot scale SNG process is stable and the CO conversion and $CH_4$ selectivity are 100% and 96.9%, respectively, while the maximum $CH_4$ productivity is $660ml/g_{cat}{\cdot}h$.

• Transactions of the Korean hydrogen and new energy society
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• v.26 no.3
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• pp.271-277
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• 2015

The present paper discusses about noble idea on various reactions including hydrides, hydrogen peroxide and nano-sized metal powders, which do not emit toxic materials as well as carbon dioxide. Here in this paper, the very first-ever concept that heat energy can be generated from the direct reaction between sodium borohydride and hydrogen peroxide is presented. Sodium hydride as fuel can supply hydrogen reacting with oxygen provided by the decomposition of hydrogen peroxide solution. Solid sodium borohydride can be resolved in water and treated as liquid solution for the easy handling and the practical usage although its solid powder can be directly mixed with hydrogen peroxide for the higher reactivity. The thermodynamic analysis was conducted to estimate adiabatic reaction temperatures from these materials. The preliminary experiment on the reactions conducted using sodium borohydride powder and hydrogen peroxide water solution revealed that the self-propagating reaction can occur and that its reactivity increases with an increase of hydrogen peroxide concentration.