• Title/Summary/Keyword: 다공성입자

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Development of Adsorptive Permeation Membrane (APM) and Process for Separation of $CO_2$ from gas mixtures (이산화탄소 분리를 위한 흡착투과막 및 공정 개발)

  • Yeom, Choong Kyun;Ahn, Hyo Sung;Kang, Kyeong Rok;Kim, Joo Yul;Han, Jin-Soo;Kwon, Keun-Oh
    • Membrane Journal
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    • v.23 no.6
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    • pp.409-417
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    • 2013
  • Adsorptive permeation hollow fiber membrane (APM) has been developed for effectively separating $CO_2$ from gas mixture. Inside the APM, zeolite 13X particles were uniformly dispersed without covering their surfaces by a symmetric porous structure of polypropylene lattice. In this study, $CO_2/N_2$ mixture was used as a simulated gas mixture. Separation was achieved by adsorbing $CO_2$ on the zeolite particles in the APM and then permeating $N_2$ into permeate side in passing all the feed gas through the APM. Adsorptive permeation tests were carried out with a set of APM modules, and the adsorptive permeation performances of the modules were analyzed from the test results. After saturation of the adsorbent with $CO_2$, the APM was regenerated by desorption of $CO_2$ from it through vacuuming both inside of outside of the APM hollow fiber, and the regeneration process of the APM by vacuuming was discussed in terms of regeneration efficiency and energy consumption.

Effect of Strontium Carbonate Inorganic Binder Addition on Ceramic Candle Filter Matrix (세라믹 캔들 필터 지지체의 스트론튬 카보네이트 무기결합재 첨가 영향)

  • Han, Insub;Seo, Doowon;Hong, Kiseog;Kim, Seyoung;Yu, Jihang;Woo, Sangkuk
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.109.2-109.2
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    • 2010
  • 세라믹 필터는 여러 종류의 분진제거 시스템에서 연소 배가스 정제를 위한 가장 적절한 소재로 알려져 있다. 현재까지 다양한 형태의 세라믹 필터가 개발되고 있는데, 캔들 타입(candle type), 튜브 타입(tubular type), 평판 타입(parallel flow type) 등이 그 예이다. 통상적으로 세라믹 캔들 필터는 가압유동층복합발전(PFBC, Pressurize Fluidized-Bed Combustion), 석탄가스화복합발전(IGCC, Integrated coal Gasification Combined Cycle), 석탄가스화연료전지복합발전(IGFC, Integrated coal Gasification Fuel cell Combined cycle)에서 고온 배가스 정제용으로 사용되고 있다. 일반적으로 IGCC나 CTL 합성가스 정제시스템의 경우에는 높은 고압(약 25기압)과 미세분진이 함유되어 있는 분위기에서 운전된다. 그러므로 이때 사용되는 초청정용 세라믹 집진필터는 고온, 고압 및 부식 환경에서 50 MPa 이상을 갖는 높은 강도와 내식성을 갖도록 개발되어야 하기 때문에 SiC(Silicon Carbide)가 가장 적절한 캔들 필터 소재로 적용되고 있다. 이에 따라 집진용 SiC 세라믹 캔들 필터를 개발하기 위해서는 고온에서 내산화성이 우수하고, 부피팽창에 의한 균열이 발생하지 않는 무기결합재의 선정 및 이를 통한 소재의 특성 최적화가 가장 중요한 부분이라 할 수 있다. 본 연구에서는 IGCC나 CTL 공정에 적용하기 위한 SiC 캔들 필터 소재 개발을 위해 래밍성형 공정으로 1m급의 탄화규소 캔들 필터 시작품을 제작하여 SiC 출발입자 크기와 무기계 결합재인 스트론튬 카보네이트의 첨가량 변화에 따른 필터 소재의 특성 평가를 수행하였다.

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Characterization of fine lightweight aggregates sintered at floating state using by vertical furnace (수직로에서 부유 소성된 경량 세골재의 특성)

  • Kang, Seung-Gu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.18 no.6
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    • pp.258-263
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    • 2008
  • The fine aggregates of below 2 mm size was fabricated using by the vertical furnace in which the aggregates could be sintered at floating state and its physical properties were analyzed. The liquid formed at the surface of specimens sintered at $1200{\sim}l300^{\circ}C$ induced a gas in core to expand so the denser shell and porous core could be produced. The C series specimen fabricated by crushing an extruded body had an irregular shape and sharp edges but those became spheroidized by bloating due to gas expansion inside. The fine aggregates fabricated in this study was as light as floating in the water and had an apparent density of $0.68{\sim}1.08$. The absorption rate was proportioned to a porosity showing that the pores in core was not closed completely. The properties of fine aggregates fabricated in vertical furnace were similar with those of in an electric muffle furnace but the sticking-together phenomenon by surface fusion was not occurred in the vertical furnace. The aggregates fabricated in this study had a little lower impact resistance than that of natural aggregate but satisfied the unit volume weight standard specified in KS.

Evaluation of the adsorptive capacity of spent coffee powder for the removal of aqueous organic pollutants (액상 유기오염물질에 대한 폐커피가루의 흡착능력 평가)

  • Kim, Seulgi;Na, Seungmin;Son, Younggyu
    • Journal of Wetlands Research
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    • v.18 no.1
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    • pp.39-44
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    • 2016
  • The reuse of spent coffee powder has been researched for environmental engineering applications such as adsorbents of organic/inorganic pollutants. In this study adsorption equilibrium tests and adsorption kinetics tests for the removal of aqueous organic pollutant (methylene blue) were conducted using spent coffee powder, granular activated carbon, and powdered activated carbon. It was found that the maximum adsorption capacity of three adsorbents followed the order of powdered activated carbon (178.6 mg/g) > spent coffee powder (60.6 mg/g) > granular activated carbon (15.6 mg/g). The results of adsorption kinetics tests also indicated that spent coffee powder had higher kinetic parameters than granular activated carbon for pseudo 1st and 2nd order kinetics. The high performance of spent coffee powder might be due to its porous surface like those of granular and powdered activated carbons and smaller particle size comparing with granular activated carbon.

Strength, Absorption and Interfacial Properties of Mortar Using Waste Shells as Fine Aggregates (잔골재를 패각으로 치환한 모르터의 강도, 흡수율 및 계면 결합형태)

  • Moon, Hoon;Kim, Ji-Hyun;Lee, Jae-Yong;Chung, Chul-Woo
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.6
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    • pp.523-529
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    • 2014
  • Large amounts of waste shells have been produced each year from shellfish raising industries located in Korean costal areas. Due to the limited space for the waste shell disposal, the related environmental problem has been a serious issue. It is believed that using the waste shells as a source of aggregate for mortar, concrete or bricks can be a good solution. In this research, possibility of utilizing waste shells as an aggregate of mortar is investigated. Waste shells of manila clam, cockle, clam, sea mussel, and oyster were properly crushed, sieved, and sorted to meet the requirements of the grading of standard fine aggregate. After that, the waste shells were used as partial and total replacement of the fine aggregate, and their absorption and 28-day compressive strengths of mortar were measured. In general, replacement of waste shells increased the absorption and decreased the strength. However, one specimen with cockle increased compressive strength as replacement ratio increased. Mortar with cockle of 50% and 100% replacement showed higher compressive strength than that of control mortar. This increase of compressive strength was found to be affected by the strong interfacial bonding properties of the cockle and a cement matrix.

The Synthesis of Nano-sphere Titanium-oxide and Cosmetic Applications (광반사체로 사용되는 $TiO_2$ 나노구형체의 합성과 화장품으로의 적용 연구)

  • Lee, Ji Hye;Kim, Joon Woo;Kim, Ji Man;Choung, Suk-Jin
    • Applied Chemistry for Engineering
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    • v.24 no.3
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    • pp.231-238
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    • 2013
  • In this study, the $TiO_2$ nano spheres were synthesized by Sol-gel method to give an excellent UV-blocking effect and increase waste adsorption. The pH value was adjusted to obtain a superb UV-blocking effect and adsorption capacity due to the high surface area which is the characteristics of porosity. Base treated $TiO_2$ showed outstanding characteristics. The adsorption of gycerine onto the $TiO_2$ sample using TGA resulted in a high surface area of 1.16 mg/mg. This also showed a high reflectance in the UV-A region. In order to find the optimum dispersion, inorganic powder particles were maintained their sizes as 180 nm for about 6 months. The size of particles were measured using ester oil and silicon oil. Overall, the results reveal that $TiO_2$ has an excellent capability sunscreen in the UV-A region and skin waste adsorption.

Bio-inspired Cr2O3 and Co3O4 Nanoparticles Loaded Electrospun WO3 Nanofiber Chemical Sensor for Early Diagnosis of Halitosis (고분산성 Cr2O3 및 Co3O4 전이금속 나노입자 촉매가 기능화된 다공성 WO3 나노섬유를 이용한 구취진단용 화학센서)

  • Jang, Ji-Soo;Kim, Sang-Joon;Choi, Seon-Jin;Koo, Won-Tae;Kim, Il-Doo
    • Journal of Sensor Science and Technology
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    • v.25 no.3
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    • pp.223-228
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    • 2016
  • In this work, we prepared porous WO3 nanofibers (NFs) functionalized by bio-inspired catalytic $Cr_2O_3$ and $Co_3O_4$ nanoparticles as highly sensitive and selective $H_2S$ gas sensing layers. Highly porous 3-dimensional (3D) NFs networks decorated by well-dispersed catalyst NPs exhibited superior $H_2S$ gas response ($R_{air}/R_{gas}$ = 46 at 5 ppm) in high humidity environment (95 %RH). In particular, the sensors showed outstanding $H_2S$ selectivity against other interfering analytes (such as acetone, toluene, CO, $H_2$, ethanol). Exhaled breath sensors using $Cr_2O_3$ and $Co_3O_4$ catalysts-loaded $WO_3$ NFs are highly promising for the accurate detection of halitosis.

A Comparison Study on Acorn and Chestnut Starch Gels (도토리와 밤전분 gel의 물리적 특성 비교)

  • 이혜성;이혜수
    • Korean journal of food and cookery science
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    • v.7 no.1
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    • pp.11-14
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    • 1991
  • The physical properties of acorn and chestnut gels by various heating temperature were investigated. In microsturcture analysis by SEM, acorn starch gels of 9$0^{\circ}C$$90^{\circ}C$ showed regular three dimensional network structure and chestnut starch gels had finer porous network from $70^{\circ}C$. X-ray diffraction patterns of two starch gels showed very weak peak at 8~$10^{\circ}C$ and 16~$19^{\circ}C$. Hardness had the highest value at $90^{\circ}C$ and $98^{\circ}C$ for acorn gels, and $80^{\circ}C$ for chestnut gels. But cohesiveness increased with heating temperature in both of two starch gels.

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Development of Electrospun Cellulose Acetate Membranes using Carbon Nanotubes for Filtration of Particulate Matter in the Air (전기방사를 이용한 탄소나노튜브 폴리머 공기정화 멤브레인 개발)

  • Park, Soyeon;Kim, Jaehyuk;Han, Sangil
    • Korean Chemical Engineering Research
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    • v.55 no.1
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    • pp.68-73
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    • 2017
  • The removal of particulate matter ranging from $0.01{\mu}m{\sim}10{\mu}m$ can be performed by using membrane filters composed of fibers. Electrospinning techniques offer the production of very thin fibers with a uniform fiber diameter over conventional techniques including template synthesis, melt-blown, phase separation, etc. Air filtration will be improved with electrospun membranes due to the open pore structures, high porosity, and large surface area of the membranes. In the present study, filtration efficiency increased with pore size decrease and fiber density increase induced by carbon nanotube and the increased CA (cellulose acetate) concentration during electrospinning process.

Effect of Gelatin Particles on Cell Proliferation in Polymer Scaffolds Made Using Particulate Leaching Technique. (Particulate Leaching 기법을 사용한 Polymer Scaffold 상의 세포증식에 있어서 젤라틴 입자의 효과)

  • 서수원;신지연;김진훈;김진국;길광현
    • Journal of Biomedical Engineering Research
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    • v.25 no.1
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    • pp.1-4
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    • 2004
  • On the background of general idea and technique of bioscience, medicine and engineering, tissue engineering aim at maintenance, improvement and repair of human body function through manufacturing and transplantation of artificial tissue and organ exchangeable human body. Basic material used in the area is scaffold that aid tissue and organ formation. Making scaffold, solvent-casting and particulate leaching technique is widely used in manufacturing of porous polymer scaffold. There are many types of particle including salt and gelatin. Salt is a most commonly used particulate because it is easily available and very easy to handle and gelatin particle is another candidate for this method because it is known as a material, which enhances cell attachment and proliferation. But there is no comparative study of two kinds of materials. In this study we compared the biocompatibility of the two scaffolds made from salt(salt scaffold) and gelatin particle (gelatin scaffold). These results demonstrated that gelatin scaffold showed better attachment of cells at the initial stage and better proliferation of cells. The better performance of gelatin scaffold is contributed to the better connection of pores in the same porosity.