• Title/Summary/Keyword: 다공성입자

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The Auto-adhesion of Fingerprint Powders (지문 분말의 자착성(auto-adhesion)에 관한 연구)

  • Kim, Chae-Won;Cho, Hyeong-Woo;Lee, Sang-A;Song, Dong-Ha;Yu, Je-Seol
    • The Journal of the Korea Contents Association
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    • v.17 no.8
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    • pp.579-585
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    • 2017
  • Powder method is one of the most commonly used techniques for developing latent fingerprints on non-porous surfaces. While fingerprint powders become more diverse, there is no standard for the number of stroking a brush. For this reason, crime scene investigators need to stroke a brush as they try to figure out how much latent fingerprints are developed. Also, results vary from individual to individual. According to the combination of material and manufacturing, there are various results that powder particles hold together. It is called auto-adhesion which means the interaction between powder particles. This study showed auto-adhesion of 13 kinds of fingerprint powders expanding the number of stroking time. Consequently, some fingerprint powders had strong auto-adhesive property and others had weak auto-adhesion. Furthermore, the others did not change.

Effective Diffusion Coefficient in the Porous Media (다공성 미디아에 있어서 유효확산계수)

  • Jeehyeong Khim
    • Journal of Korea Soil Environment Society
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    • v.1 no.2
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    • pp.83-90
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    • 1996
  • A diffusion process is often the main mechanism of soil gas/vapor movement in the vadose zone. The diffusion coefficients in the porous soil media are different from those in the free air phase by the reduction of available area for diffusion, tortuous diffusion path and variable cross section area along the diffusion path. To take account those effects of the diffusion process in the porous media, usually the terms of effective diffusion coefficient and tortuosity are have been used. However, as there are many differents definitions for the tortuosity, when the term of tortuosity is used, it is necessary to examine it throughly. Moreover, there are many different equations for the effective diffusion coefficient according to the investigators and the differences in the values of effective diffusion coefficients between the equations are not insignificant, the selection of the equation should be done with caution. In this paper, the different definitions of effective diffusion coefficient are examined and discussed. As well as definitions, the lots of availabe models for the diffusion coefficient in terms of porosities are compared. Also, the constrictiviy which explains the effect of cross sectional area change over the diffusion path was discussed.

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Synthetic Characteristics of Porous Polymeric Catalyst Support (다공성 고분자촉매 담체의 제조 특성)

  • Kang, Hee-Suk;Lee, Han-Soo;Chung, Hongsuk;Ahn, Do-Hee;Son, Soon-Hwan;Chung, Yang Geun;Song, Myung-Jae
    • Applied Chemistry for Engineering
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    • v.7 no.4
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    • pp.715-725
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    • 1996
  • This study represents the synthetic characteristics of styrene-DVB copolymer which is used as a catalyst support for the removal of tritium in CANDU. To evaluate the effect of solvent on the styrene-DVB polymeric support, the solvating power dependent on various kinds and composition of solvents was calculated. In order to synthesize the macroreticular type polymer bead, the following conditions are needed; solvating power should be higher than 1 for 20% of crosslinkage and higher than 3 for 40% of crosslinkage. Stabilization of organic monomers at about $40^{\circ}C$ for more than 2 hours is prerequisite. Removal of solvent prior to drying is preferred for the post-treatment of the bead. The polymer particle size was increased by lowering concentration of surfactant and stirring speed.

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Separation of Hydrogen-Nitrogen Gases by PTMSP-Borosilicate Composite Membranes (PTMSP-Borosilicate 복합막에 의한 수소-질소 기체 분리에 관한 연구)

  • Lee, Suk Ho;Kang, Tae Beom
    • Membrane Journal
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    • v.24 no.6
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    • pp.438-447
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    • 2014
  • The amorphous and porous borosilicate without any cracks was obtained under the following condition : 0.01~ 0.10 mole ratio of trimethylborate (TMB)/ tetraethylorthosilicate (TEOS) and the temperature of $700{\sim}800^{\circ}C$. According to the BET and SEM measurements, borosilicate heat-treated in between 700 and $800^{\circ}C$ showed the surface area of $251.12{\sim}355.62m^2/g$, the pore diameter of 3.5~4.9 nm, and the particle size of 30~60 nm. According to the TGA measurements, the thermal stability of poly[1-(trimethylsilyl)propyne](PTMSP) membrane was enhanced by inserting borosilicate. SEM observation showed that the size of dispersed borosilicate in the composite membrane was $1{\mu}m$. The results showed that the permeability of $H_2$ and $N_2$ increased and the selectivity of $H_2/N_2$ decreased upon the addition of borosilicate into PTMSP membranes. Addition of borosilicate may possibly increase the free volume, cavity and porosity of membranes indicating that permeation occurred by molecular sieving, surface and Knudsen diffusion rather than solution diffusion of gases.

Studies for Processing Condition Optimization and Physicochemical Property of Resistant Starch (난소화성 전분 제조공정의 최적화 및 이화학적 특성 연구)

  • 한명륜;김우경;강남이;이수정;김명환
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.32 no.8
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    • pp.1193-1199
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    • 2003
  • As a result of resistant starch yield depending on heating temperature, moisture content, storage temperature and heating-cooling cycle with RSM (response surface methodology), high amylose corn starch (46%) was appeared higher than normal corn starch in the yield (22%). At the high amylose corn starch, optimum conditions for resistant starch formation were 6 times of heating-cooling cycle, 108$^{\circ}C$ heating temperature and 67% moisture content at the 2$0^{\circ}C$ storage temperature, which resulted in 25% yield with these experiment conditions. Affecting factor for the resistant starch formation was arranged according to heating -cooling cycle, moisture content, heating temperature and storage temperature. Raw corn starch granule was destructive and appeared a porous reticular structure by the resistant starch formation. Color became dark and increased yellowness by caramelization during heating processing. Heating-cooling processing was the result of decreased hardness, cohesiveness, springiness and gumminess.

Adsorption Capacity and Antibacterial Activity of Porous Feldspar Porphyry (다공성 구조가 발달한 장석반암의 흡착과 항균성 연구)

  • Kim, Sung-Wook;Choi, Eun-Kyeong;Cho, Jinwoo
    • The Journal of the Petrological Society of Korea
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    • v.26 no.2
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    • pp.143-152
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    • 2017
  • As weathering processes, micro-cavities are formed on the surface of rocks, and in particular, the porous structure is increased in feldspar. Adsorption and antibacterial tests were carried out to clarify the environmental function of porous feldspar porphyry. Almost all the heavy metals were adsorbed in the feldspar filter and the adsorption rate could be controlled by changing the filter length. The shake flask method of fabric coated with 5% and 7% feldspar powder showed very high antibacterial activity of 98% and 99.9%, respectively. The cation exchange capacity at a particle size of $10{\mu}m$ was 114.63 meq/100g probably due to the porous structure. The potential value of porous feldspar porphyry as a resource is sufficient based on the results of the experiment.

Development Trend of Nanofiber Filter (나노섬유 필터의 개발 동향)

  • Kang Inn-Kyu;Kim Young-Jin;Byun Hong-Sik
    • Membrane Journal
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    • v.16 no.1
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    • pp.1-8
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    • 2006
  • Nanofiber is a broad phrase generally referring to a fiber with diameter less than 1 micron. Various polymers have been successfully electrospun into nanofibers in recent years. These nanofibers, due to their high surface area and porosity, have a great potential for use as filter medium, adsorption layers in protective clothing, etc. Nanofiber filters will enable new levels of filtration performance in the field of air filtration. In particular, nanofibers provide marked increases in filtration efficiency at relatively small pressure drop in permeability. Therefore, nanofiber filters could be substituted for conventional filter market due to the easy application of process and the possibility of coating to micron-sized non-woven sheets. This review is discussed on the trend of researche and development related to nanofiber filter including future marketability.

Evaluation of NOx Reduction Performance by Photocatalytic (TiO2) Coating of Cement Mortar Mixed with Zeolite and Activate Hwangtoh (제올라이트와 활성 황토를 혼입한 시멘트 모르타르의 광촉매(TiO2) 코팅에 따른 NOx 저감성능평가)

  • Park, Jang-Hyun;Kim, Hyeok-Jung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.4
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    • pp.483-489
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    • 2020
  • Particulate matter is divided into PM10 (particle diameter of 10 ㎛ or less) and PM2.5 (particle diameter of 2.5 ㎛ or less), which are approximately 1/5 of the thickness of the hair. Due to its effect on the human body, lung disease, arteriosclerosis and heart It is known as a carcinogen that causes various diseases such as diseases. It is known that the main cause of such fine dust is nitrogen dioxide (NOx), which is emitted from automobiles in about 57.3% of urban roadsides. Therefore, in this study, as part of the development of functional construction materials to reduce NOx generated from road transport pollutants, comparative evaluation of NOx reduction performance was conducted according to the replacement rate of cement mortar in which cement was replaced with a porous material. In addition, the NOx reduction performance of cement mortar according to the photocatalyst application method and the number of applications was compared an d evaluated. As a result of the experiment, when activated ocher was substituted by 30%, it showed a reduction effect of about 32.7%, showing the best reduction performance.

Separation of $H_2$/$N_2$ Gas Mixture by SiO$_2$-B$_2$O$_3$ Membrane (SiO$_2$-B$_2$O$_3$ 막에 의한 수소/질소 혼합기체 분리)

  • Kang Tae-Bum;Park Jin-Ho
    • Membrane Journal
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    • v.14 no.4
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    • pp.312-319
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    • 2004
  • The porous SiO$_2$-B$_2$O$_3$ membrane was prepared from Si(OC$_2$$H_5$)$_4$-($CH_3$O)$_3$B-C$_2$$H_5$OH-$H_2O$ system by sol-gel method. In order to investigate the characteristics of this membrane, we examined that using BET, IR spectrophotometer, X-ray diffractometer, SEM and TEM. At $700^{\circ}C$, the surface area of SiO$_2$-B$_2$O$_3$ membrane was 354.398 $m^2$/, the median pore diameter was 0.0048 ${\mu}{\textrm}{m}$, and the particle size of SiO$_2$-B$_2$O$_3$ membrane was 7 nm. The separation properties of the gas mixture ($H_2$/$N_2$) through the SiO$_2$-B$_2$O$_3$ membrane was studied as a function of pressure. The real separation factor($\alpha$) of SiO$_2$-B$_2$O$_3$ membrane for $H_2$/$N_2$ gas mixture was 4.68 at 155.15 cmHg and $25^{\circ}C$. The real separation factor($\alpha$), head separation factor($\beta$) and tail separation factor((equation omitted)) were increased as the pressure of permeation cell increased.

Manufacturing Method and Characteristics of the Dongrok(copper chloride) pigments (동록(염화동) 안료의 제조방법 및 특성에 관한 연구)

  • KANG Yeongseok;PARK Juhyun;MUN Seongwoo;HWANG Gahyun;KIM Myoungnam;LEE Sunmyung
    • Korean Journal of Heritage: History & Science
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    • v.56 no.2
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    • pp.148-169
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    • 2023
  • Hayeob pigment is known as one of the traditional dark green pigments, but the color, raw material, and manufacturing method have not been clearly identified. However, comparing the analysis results of the particle shape and constituent minerals of Hayeob pigments revealed through pigment analysis studies of colored cultural properties such as Dancheong, Gwaebul, and paintings, Hayeob pigments appear to be the same as Dongrok pigments produced by salt corrosion. Therefore, in order to restore Hayeob pigment, the manufacturing method of Dongrok pigment was studied based on the records of old literature. The Dongrok pigment manufacturing method confirmed in the old literature records is a natural corrosion method in which copper powder and a caustic are mixed and then left in a humid condition to corrode. Based on this, artificial corrosion using a corrosion tester was adopted to corrode the copper powder more efficiently, and an appropriate mixing ratio was selected by analyzing the state of corrosion products according to the mixing ratio of the caustic agent. In addition, the manufacturing method of Dongrok pigment was established by adding a salt removal process to remove residual caustic agents and a purification process to increase chroma during pigment coloring. The prepared Dongrok pigments have a bluish green or green color, show an elliptical particle shape and a form in which small particles are aggregated, and a porous surface is observed. The main constituent elements are copper(Cu) and chlorine(Cl), and the main constituent mineral is identified as atacamite [Cu2Cl(OH)3]. As a result of an accelerated weathering test to evaluate the stability of the prepared Dongrok pigments, it was found that the greenness partially decreased and the yellowness significantly increased as deterioration progressed. Before deterioration, the Dongrok pigments had lower yellowness compared to the Hayeob pigments of the old Dancheong, but after deterioration, yellowness increased significantly, and it was found to have a similar chromaticity range as Dancheong's Hayeob pigments. As a result, the prepared Dongrok pigments were confirmed to be similar to Dancheong's Hayeob pigments in terms of color as well as particle shape and constituent minerals.