• Journal of Korea Water Resources Association
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• v.31 no.4
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• pp.363-373
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• 1998

In this study, random flow field in a nonstationary porous formation is characterized through cross covariances of the velocity with the log conductivity and the head. The hydraulic head and the velocity in saturated aquifers are found through stochastic analysis of a steady, two-dimensional flow field without recharge. Expression for these cross covariances are obtained in quasi-analytic forms all in terms of the parameters which characterize the nonstationary conductivity field and the average head gradient. The cross covariances with a Gaussian correlation function for the log conductivity are presented for two particular cases where the trend is either parallel or perpendicular to the mean head gradient and for separation distances along and across the mean flow direction. The results may be of particular importance in transport predictions and conditioning on field measurements when the log conductivity field is suspected to be nonstationary and also serve as a benchmark for testing nonstationary numerical codes. Keywords : cross covariance, nonstationary conductivity field, saturated aquifer, stochastic analysis.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.697-700
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• 2008

The object of this paper is to propose a logical prediction model of a concrete creep using rheology. Rheology is the study on the flow and stress relationship of matter under the influence of an applied stress. It is also estimated as an effective theory to describe concrete long-term deformations. According to a time dependency and a mechanism of occurrence, the proposed creep model was divided into four components, such as an elastic deformation, a long-term creep, a time dependent short-term creep and a time independent short-term creep. Evaluation on an actual creep deformation pattern by time passage confirmed these classification. In order to approve a rationality of the proposed model, most coefficients of each components were derived by the microprestresssolidification theory and design codes. Numerical approaches were also used when it was restricted within narrow limits. Finally, the proposed rheolgical model was verified by actual creep test results and compared with common methods.

• Korean Chemical Engineering Research
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• v.51 no.5
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• pp.615-621
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• 2013

Membrane characterization methods for aqueous redox flow batteries aqueous RFBs were modified for non-aqueous RFBs. The modified characterization methods, such as ion exchange capacity, transport number, permeability and single cell test, were carried out to evaluate commercial membranes in non-aqueous electrolyte. It was found that columbic efficiency and energy efficiency in a single cell test were dependent on the ion selectivity of commercial anion exchange membranes. Neosepta AHA anion exchange membrane showed the anion transport number of 0.81, which is a relatively low ion selectivity in non-aqueous electrolyte, however, exhibited 92% of coulombic efficiency and 86% of energy efficiency in a single cell test. It was also found that a porous membrane without ion selectivity is suitable for a non-aqueous redox flow battery at a high current density.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.30 no.2
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• pp.207-210
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• 2004

Glycyrrhiza uralensis (licorice root) is very useful medicinal herb because of strong anti-inflammatory and anti-wrinkle effect. Therefore, it is widely used in functional cosmetics. However, it is insoluble and easily decomposed by light, heat, oxygen, etc. In this study, we first prepared NanoSolve-Licorice (30-50nm) using Glycyrrhiza uralensis and propylene glycol! hydrogenated lecithin/caprylic/capric triglyceride/glycerin/water system with microfluidizer. And then, NanoSolve-Licorice and porous PMMA are dispersed in ethanol. Finally, we could get a stabilized system with high-pressure homogenizer (1,000 Bar, 3 passes). According to HPLC measurement for glabridin content, our system is more stable compared with general liposome ones. Capsulated licorice has an enhanced anti-inflammatory effect on account of excellent skin penetration. We also evaluated our final product through image analyzer, particle size analyzer, FF-TEM and chromameter.

• Clean Technology
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• v.18 no.4
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• pp.331-340
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• 2012

Synthetic methods of colloids have been significantly developed in industry due to their significant demand for preparation of functional particles. Recently, dynamic/static microfluidic system has emerged as a promising route to the synthesis of the particles, providing precise control of physical and chemical properties such as size, shape, porosity, surface roughness, and surface functionality. These formed particles can be potentially used in various applications including medical diagnostics, photonic device, and biological industry. In addition, these particles provide a novel route to create new materials via their directed self-assembly, and it enable to study and predict the natural phenomenon by mimicking of the nature. Therefore, we describe recent progress for functional colloid particles and its applications.

• Journal of Korean Association for Spatial Structures
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• v.7 no.5
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• pp.67-74
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• 2007

The unsymmetrically layered artificial material model is consistently introduced to find the optimum topologies of the plate structures. Reissner-Mindlin (RM) plate theory is adopted to formulate the present 9-node plate element considering the first-order shear deformation of the plates. In the topology optimization process, the strain energy to be minimized is employed as the objective function and the initial volume of structures is adopted as the constraint function. In addition, the resizing algorithm based on the optimality criteria is used to update the hole size introduced in the proposed artificial material model. Several numerical examples are rallied out to investigate the performance of the proposed technique. From numerical results, the proposed topology optimization techniques are found to be very effective to produce the optimum topology of plate structures. In particular, the proposed unsymmetric stiffening layer model make it possible to produce more realistic stiffener design of the plate structures.

• Membrane Journal
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• v.6 no.1
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• pp.53-57
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• 1996

Polysulfone ultrafiltration membrane was coated with polyisobutylene(PIB) as a top layer to separate chlorinated hydrocarbons. The solubility parameter differences between PIB, water and perchloroethylene(PCE) or trichloroethylene(TCE) show that the solubility parameter difference between PIB and TCE or PCE is similar while that between PIB and water is far less, indicating that PIB is selective to chlorinated hydrocarbons. The pervaporation separation of TCE and PCE shows that TCE is concentrated more than four times, by PIB composite membrane, while PCE is concentrated more than thirteen times. This result shows that PIB composite membrane in this study seems to be an appropriate selective layer for the separation of TCE and PCE from aqueous organic solutions.

• Resources Recycling
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• v.21 no.1
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• pp.75-81
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• 2012

Porous pellets for immobilizing heavy metals were manufactured from coal tailings and iron oxide powder. Coal tailings was pulverized and mixed with iron oxide powder. The mixed powder was granulated into spherical pellets and roasted. Over $1100^{\circ}C$, residual coal in coal tailings reduced iron oxide to ZVI(Zero-Valent Iron). The pellets have 34.63% of porosity, 1.31 g/mL of bulk density, and 9.82.urn median pore diameter. The pellets were reacted with synthetic solutions containing each heavy metals: arsenic(V), copper(II), chrome(VI), and cadmium(II), respectively. On the test of immobilizing heavy metal, the pellets made at $1100^{\circ}C$ were superior to the other pellets made under $1000^{\circ}C$. Immobilizing over 99.9% of 10ppm heavy metal solutions required I hour for arsenic, 2 hours for chrome, and 4 hours for copper. However, immobilizing capacity of cadmium was inferior to that of the other metals and it was decreased in reversely proportion to initial concentration of the solutions.

• Applied Chemistry for Engineering
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• v.33 no.1
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• pp.96-102
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• 2022

Reactants of PEMFC are hydrogen and oxygen in gas phases and fuel cell overpotential could be reduced when reactants are smoothly transported. Numerous studies to modify cathode flow field design have been conducted because oxygen mass transfer in high current density region is dominant voltage loss factor. Among those cathode flow field designs, a block in flow field is used to forced supply reactant gas to porous gas diffusion layer. In this study, the block was installed on a simple fuel cell model. Using computational fluid dynamics (CFD), effects of forced convection due to blocks on a polarization curve and local current density contour were studied when different air flow rates were supplied. The high current density could be achieved even with low air supply rate due to forced convection to a gas diffusion layer and also with multiple blocks in series compared to a single block due to an increase of forced convection effect.

• Applied Chemistry for Engineering
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• v.33 no.5
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• pp.488-495
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• 2022

Activated carbon (AC) and carbon molecular sieve (CMS) have attracted attention as porous materials for recovery and separation of greenhouse gases. The carbon molecular sieve having uniform pores is used for collecting and separating gases because it may selectively adsorb a specific gas. The size and uniformity of pores determine the performance of the CMS, and chemical vapor deposition (CVD) is widely used to coat the surface with a predetermined thickness in order to control the CMS's micropores. This CVD method can be used to control the size of pores in CMS manufacturing, but it must be optimized because of its various experimental variables. Therefore, in order to produce AC and CMS for gas adsorption and separation, this review focuses on various activation processes and pore control technologies by CVD and surface treatment.