• The Korean Journal of Pesticide Science
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• v.12 no.4
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• pp.403-413
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• 2008

This study was conducted to select excellent tank mix combinations of pesticides for aerial application by manned helicopter. Among 209 pesticide combinations of 3-way tank-mixing for aerial application, a total of 93 recommendable combinations including tricyclazole SC+validamycin-A SL+imidacloprid SL were finally selected for the simultaneous control of key pests on paddy rice such as blast, sheath blight, brown planthopper and moth. The selected combinations were not phytotoxic to rice plants and nearby non-target crops, and excellent in physicochemical properties of ultra low volume (ULV) spray solutions. The efficacies on sheath blight, brown planthoppers and white-backed planthoppers of pesticides sprayed by aerial application were similar to those of pesticides by conventional spraying. Total cost of aerial application in paddy rice was very economical as one fourth level of that of conventional spraying.

• The Korean Journal of Pesticide Science
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• v.18 no.4
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• pp.236-246
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• 2014

Pesticide is used to protect the crops, but also become a cause of polluting the environment. Perform a risk assessment using physical and chemical properties, environmental fate and toxicity data in order to determine the pesticide registration. The aquatic model estimates pesticide concentrations in water bodies that result from pesticide applications to rice paddies and apple orchard. The used models are the PRZM, EXAMS and AGRO shell (PA5), Rice Water Quality Model (RICEWQ) and Screening Concentration In GROund Water (SCI-GROW). The residual concentration of water body was estimated using meteorological data, crop calendar and soil series of Korea. The chosen pesticides were butachlor, carbofuran, iprobenfos and tebuconazole. It has shown the potential that the RICEWQ is possible to predict residue level in water of butachlor and iprobenfos, because the maximum value in water monitoring data is lower than the peak concentration of the model, and the minimum value is lower than the average annual concentration of the model. But RICEWQ was insufficient to predict exposure concentrations in ground water. The estimated exposure concentrations of carbofuran in ground water is very higher than in surface water because of its low soil adsorption coefficient. Although tebuconazole were not detected in the water monitoring that means very low concentration, it is possible that the PA5 can be used to predict residue level in water.

• The Korean Journal of Pesticide Science
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• v.7 no.1
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• pp.58-65
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• 2003

Various physicochemical parameters for the active ingredients of 245 herbicides were calculated to develope a diagnosis and estimation system for utility as herbicide. The range of physico-chemical parameters for each inhibitors of photo system II (H1), acetolactate synthase (ALS) (H2) and herbicides were confirmed. The distribution ranges of 85% dependence for each physicochemical parameters were Obs.logP :$-0.90\sim4.50$, dipol moment: $1.80\sim12.22$ (debye), molecular refractivity: $53.0\sim104.0(cm^3/mol)$, polarizability: $19.0\sim37.0(\AA^3)$, HOMO energy: $-9.98\sim-7.34$ (eV), LUMO energy:$-2.76\sim0.40$ (eV), Van der Waals molecular volumes: $558.0\sim995.0(cm^3)$, molecular weight: $202.0\sim430.0$ (amu) and surface areas (Grids): $194.0\sim356.0(\AA^2)$, hydration energy: $-10.16\sim114.7$ Kcal/mol, respectively. It is suggested that MR and polarizability constants will be able to distinguish between herbicides and medicinal drugs. Results revealed that various compounds based on the range of physicochemical parameters of herbicides could be diagnosed and estimated.

• The Bimonthly Magazine for Agrochemicals and Plant Protection
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• v.13 no.1 s.106
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• pp.88-95
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• 1992

하우스재배에서 수량이나 품질을 낮추는 주요한 원인 가운데에는 시설내에서 발생하는 병해나 생리장해가 있다. 우리나라는 아직 선진국과 같이 시설이 대형화되고 중장비화(重裝備化)되지는 않았지만 현재에도 하우스 재배가 전업화되고 단지화됨에 따라 자연 연작하지 않을 수 없게 되어 연작장해가 일어나고 있는 실정이다. 즉 하우스 재배에서는 단위면적당 수량을 높이기 위해서 밀식하는 경향인데 비해 하우스내는 고온이고 노지보다 시비량이나 관수량도 많아 비료성분인 염류(鹽類)가 쌓이고 토양 병원균도 많아지고 토양물리성이 나빠져 토양병해나 생리장해가 많이 발생하고 있다. 이 글에서는 하우스 작물의 연작장해의 원인과 실태조사 결과를 분석해보고 다음호에서는 그 대책에 대해 알아본다.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2000.11a
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• pp.245-246
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• 2000

산업의 발달로 인하여 유해폐기물의 양과 종류가 날로 증가하고 있다. 특히 본 연구에서 사용한 $CCl_4$는 염화탄화수소(chlorinated hydrocarbons, CHCs)(Elizabeth 와 Catherine) 계통의 대표적인 유해폐기물이며 플라스틱제조업, 제초제와 살충제를 제조하는 농약제조업, 유기용제 제조업 등에서 다량 배출되며 해마다 발생량이 증가하는 추세이다. 최근까지 대부분의 유해폐기물을 처리가격의 저렴성과 기술적으로 어려움이 적은 매립 및 밀봉등의 방법과 물리화학적 방법으로 처리하였으나 앞으로는 소각에 의한 처리방법이 증가되리라 예상된다. (중략)

• Applied Biological Chemistry
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• v.33 no.4
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• pp.315-318
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• 1990

After technical pesticides and dispersants were dissolved in a volatile organic solvent, the wettable powders(WP's) were formulated by adsorbing the pesticide-dispersant solution to finely powdered porous synthetic silica without milling process. The median sizes of 11 WP'S were smaller than $8{\mu}m$, 9 of which had more than 80% suspensibility after 2 hours. It was possible In formulate 50% WP for liquid of fly technical pesticides. The pesticidal efficacies of WP's tested were comparable In commercial formulations regardless of suspensibilities of WP's.

• Journal of Food Hygiene and Safety
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• v.26 no.3
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• pp.273-282
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• 2011

This study established hazards which may cause risk to human at farm during cultivation stage of paprika. Samples of plants (paprika, leaf, stem), cultivation environments (water, soil), personal hygiene (hand, glove, clothes), work utensils (carpet, basket, box) and airborne bacteria were collected from three paprika farms (A, B, C) located in Western Gyeongnam, Korea. The collected samples were assessed for biological (sanitary indications and major foodborne pathogens), chemical (heavy metals, pesticide residues) and physical hazards. In biological hazards, total bacteria and coliform were detected at the levels of 1.9~6.6 and 0.0~4.610g CFU/g, leaf, mL, hand or 100 $cm^2$, while Escherichia coli was not detected in all samples. In major pathogens, only Bacillus cereus were detected at levels of ${\leq}$ 1.5 log CFU/g, mL, hand or 100 $cm^2$, while Staphylococuus aureus, Listeria monocytogenes, E. coli O157 and Salmonella spp. were not detected in all samples. Heavy metal and pesticide residue as chemical hazards were detected at levels below the regulation limit, physical hazard factors, such as insects, pieces of metal and glasses, were also found in paprika farms. Proper management is needed to prevent biological hazards due to cross-contamination while physical and chemical hazards were appropriate GAP criteria.

• The Korean Journal of Pesticide Science
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• v.12 no.4
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• pp.421-428
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• 2008

This study was carried out to elucidate the effects of adjuvants on physicochemical properties and pest control efficacy of pesticide spray solution. Spray droplet sizes of pesticide solution decreased by addition of adjuvants even though its effect varied according to the pesticides. The adhesive effect of pesticides sprayed on target crops by addition of adjuvants varied according to the properties, the application methods, and the spray volume of pesticides. Wash-off of the deposited amount of active ingredients of the solution of tricyclazole WP and fenobucarb EC by simulated rainfall after spraying on rice plants dramatically reduced by adding adjuvants. The retained amount of active ingredients of the pesticides were $1.5{\sim}4.1$ times higher than those without adjuvants when subjected to simulated rainfall 6 hours after spraying. Addition of adjuvants to the propanil EC spray solution enhanced the control efficacy in barnyard grass, Echinocloa crus-galli Beauv. by $8{\sim}30%$, which showed a potential to reduce pesticide use.

• Proceedings of the Korean Society of Postharvest Science and Technology of Agricultural Products Conference
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• 2003.10a
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• pp.143.1-143
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• 2003

본 논문은 브랜드 쌀 구매에 영향을 미치는 요인(factor)들이 소비자 특성에 따라 차이가 있는지를 분석하기 위한 목적으로 수행되었다. 분석을 위하여 서울시에 1,000명의 주부를 대상으로 설문조사를 실시하였으며, 그 주요 내용은 다음과 같다. 먼저 주부들이 쌀 구매에 영향을 미치는 11개 항목을 5점 리커르트 척도를 이용하여 분석하였다. 그 결과 소비자들이 가장 높은 점수를 부여하는 것은 쌀의 잔류 농약 정도로서 4.12점이 나왔으며, 영양가 높은 쌀(4.01점), 쌀알의 모양(3.96점) 및 쌀의 생산지(3.88점) 등의 순위가 높았다. 요인분석을 위해 고유치(eigen value) 값이 0.8 이상인 경우를 기준으로 요인 수를 분석한 결과 다섯가지의 요인이 추출되었으며, 그 특징은 유형적 차원과 무형적 차원으로 구분되었다. 전자인 유형적차원은 물리적 속성(완전미 여부, 도정일자, 잔류농약), 지역성(생산지), 외관성(크기, 모양) 및 가격성등의 가시적 차원으로 소비자가 쉽게 판단하거나 쌀간의 비교가 용이한 특성이며, 후자는 심리적 속성이나 상징성을 의미하는 것으로서 브랜드 상표와 품질 인증 마크가 가지는 신뢰성 등이 영향을 미치는 것으로 분석되었다. 무형적 차원인 식품의 안전성이 도시주부간 쌀 구매에 미치는 차별성을 알아보기 위하여 정규성 검정 결과에 따라 독립표본 T-검정을 실시하였다. 분석에서 도시주부가 특성별로 두 집단으로 구분되는 기준은 자의적 분류보다는 공통적인 기준을 이용하고자 평균값(나이, 학력, 소득, 동거가족 수)을 기준으로, 그 외의 경우는 더미변수(주부직업 유무, 주거형태 및 거주지역)를 이용하여 구분하였다. 식품의 안전성으로 추출된 요인 값의 평균에 대해 두 집단간 차이를 검정하였으며, 분석 결과 주거형태가 1％ 유의수준에서, 주부취업 여부 및 거주지역이 각각 5%유의수준에서 통계적 유의성이 있는 것으로 분석되었다. 반면 주부간 나이, 학력, 소득수준 및 동거가족 수에서는 유의미한 결과가 추정되지 못하였다. 본 연구결과를 볼 때, 식품의 안전성을 고려한 쌀의 마케팅 전략은 취업주부, 아파트 거주자 및 강남지역 주부들을 대상으로 한 판매활동 강화가 필요하다. 아울러 통계적으로 유의미한 결과를 나타내는 도시 주부의 특성 변수들을 세밀하게 구분해서 연구·분석하는 시장세분화 연구가 필요하다.

• Korean Journal of Environment and Ecology
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• v.33 no.2
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• pp.178-186
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• 2019

This study used the probit analysis to evaluate the toxicity of three chemicals - benomyl (Germicide), carbofuran (insecticide), and thiobencarb (herbicide) - with the FETAX (Frog Embryo Teratogenesis Assay-Xenopus) protocol using the incubated embryos of tree frog, Hyla japonica. The results showed that the larval body length decreased while the mortality and malformation rates increased as the concentrations of benomyl, carbofuran, and thiobencarb increased. The teratogenic concentration ($EC_{50}$) of benomyl, carbofuran, and thiobencarb were 1.00, 0.58, 4.75 mg/L, respectively, indicating that the malformation of larvae was the most sensitive to carbofuran. The embryo lethal concentration ($LC_{50}$) was 7.04, 28.71, and 16.12mg/L, respectively, indicating that benomyl showed the lowest embryo lethal concentration. The teratogenic index (TI) was 7.04 in Benomyl, 49.50 in Carbofuran, and 3.39 in Thiobencarb, indicating that the TI values were above 1.5, which is the criterion of teratogenicity, for all three chemicals. All three pesticides examined by this study were considered to be the most teratogenic substances, and the carbofuran was the most potent teratogen.