• Title/Summary/Keyword: 내구성 실험

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이중구조 투명전극을 이용한 실리콘 박막 태양전지 효율향상 기법

  • Kim, Hyeon-Yeop;Kim, Min-Geon;Choe, Jae-U;Lee, Jun-Sin;Kim, Jun-Dong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.591-591
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    • 2012
  • 본 연구는 Transparent conducting oxide (TCO, 산화물투명전극)를 이용한 박막태양전지 효율향상에 관한 것으로, 이중의 TCO층(Double-stacked TCO layer)의 효과적인 광학 및 전기적 설계에 관한 것이다. 기존 박막 태양전지에서는 투명전극 TCO layer로서, ITO (Indium-Tin-Oxide), FTO (Fluorine- Tin-Oxide), 및 AZO(Aluminum-doped Zinc Oxide) 등을 사용해 왔다. 각 TCO layer마다 장점이 있지만 단점 또한 존재한다. ITO의 경우 높은 전기적 특성을 가지는 반면 수소 플라즈마에 취약하고 기계적 강도에 취약해 ITO 단일층만으로 박막 태양전지에 적용하는 것에 제한을 받는다. 한편, AZO의 경우 전기적 특성도 우수할 뿐만 아니라 수소 플라즈마에도 내구성이 강한 장점이 있지만, 일함수가 p형 반도체보다 낮아 Schottky junction이 되어, 높은 전위장벽이 형성된다. 이는 정공의 이동을 방해하고, 정공의 축적이 일어나서 순방향 전압을 인가할 때 많은 전류의 감소를 가져온다. 또한, AZO와 p형 반도체 사이의 높은 직렬저항으로 인해 광전압(Voc, Open circuit voltage)와 충실률 (FF, Fill factor)가 떨어진다는 단점이 있다. 본 실험에서는 ITO/AZO 2중구조의 TCO층을 적용하여 상기의 문제점을 해결하고자 한다. 이중 구조 TCO층은 Magnetron sputter system을 이용하여, 단계적으로 증착되었다. 빛이 입사하는 유리에 ITO를 제1전도층으로 증착하였는데, ITO는 입사광의 투과도와 전기전도성이 우수하다. 제2전도층으로는 AZO층을 이용하였으며, 실리콘 반도체층과 접하게 된다. AZO는 실리콘 증착시 발생하는 수소 플라즈마에 안정적이고, 물리적 강도 또한 우수한 장점이 있다. 이중 구조층위에 실리콘 광흡수층(Si absorber)을 증착하였으며, pin 구조를 가진다. 기존, 단일막 TCO층과 2중구조 TCO층을 이용하여, 실리콘 박막 태양전지를 구성하였다. 이때, ITO/AZO의 2중구조를 적용하였을 때 태양 전지 특성이 크게 향상된 결과를 얻을 수가 있었다. 특히, 전류밀도의 경우 ITO, FTO, AZO 각각 14.5 mA/cm2, 11.2 mA/cm2, 8.18 mA/cm2를 나타낸 반면 ITO/AZO 2중구조의 경우 약 17mA/cm2 로 크게 향상 되었고, 태양전지 변환 효율도 각각 7.5%, 6.9%, 4%에서 ITO/AZO 2중 구조의 경우 8.05%로 크게 향상되었다. 본 발표에서는 2중구조 TCO를 이용한 현공정에 적용 가능한 박막태양전지 효율향상 기법에 대해 논의하고자 한다.

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Heat Exchange Performance of Improved Heat Recovery System (개량형 열회수 시스템의 열교환 성능)

  • Suh, Won-Myung;Yoon, Yong-Cheol;Kwon, Jin-Keun
    • Journal of Bio-Environment Control
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    • v.12 no.3
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    • pp.107-113
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    • 2003
  • This study was carried out to improve the performance of pre-developed heat recovery devices attached to exhaust-gas flue connected to combustion chamber of greenhouse heating system. Four different units were compared in the aspect of heat recovery performance; A-, B-, and C-types are exactly the same with the old ones reported in previous studies. D-type newly developed in this experiment is mainly different with the old ones in its heat exchange area and tube thickness. But airflow direction(U-turn) and pipe arrangement are similar with previous three types. The results are summarized as follows; 1. System performances in the aspect of heat recovery efficiency were estimated as 42.2% for A-type, 40.6% for B-type, 54.4% for C-type, and 69.2% for D-type. 2. There was not significant improvement of heat recovering efficiency between two different airflow directions inside the heat exchange system. But considering current technical conditions, straight air flow pattern has more advantage than hair-pin How pattern (U-turn f1ow). 3. The main factors influencing on heat recovery efficiency were presumably verified to be the total area of heat exchange surface, the thickness of ail-flow pipes, and the convective heat transfer coefficient influenced by airflow velocity under the conditions of allowable pipe durability and safety. 4. Desirable blower capacity for each type of heat recovery units were significantly different to each other. Therefore, the optimum airflow capacity should be determined by considering in economic aspect of electricity required together with the optimum heat recovery performance of given heat recovery systems.

Strengths of Rapidly Hardening SBR Cement Mortars as Building Construction Materials According to Admixture Types and Curing Conditions (혼화재 종류 및 양생조건에 따른 속경성 SBR 시멘트 모르타르의 강도)

  • Jo, Young-Kug;Jeong, Seon-Ho;Jang, Duk-Bae
    • Journal of the Korea Institute of Building Construction
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    • v.11 no.6
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    • pp.587-596
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    • 2011
  • Ultra rapid-hardening cement is widely used for latex-modified mortar and concrete as repair and finishing material during urgent work. The purpose of this study is to evaluate the improvements in strength made to SBR cement mortars by the adding of various admixtures and by the use of different curing methods. SBR cement mortar was prepared with various polymer-cement ratios, curing conditions and admixture contents, and tested for flow, flexural and compressive strengths. From the test results, it was determined that the flow of SBR cement mortar increased with an increase in the polymer-cement ratio, and the water reducing ratio also increased. The strength of cement mortar is improved by using SBR emulsion, and is strengthened by adding metakaoline. The strength of SBR cement mortar cured in standard conditions was increased with an increase in the polymer-cement ratio, and attained the maximum strengths at polymer-cement ratios of 15 % and 10 %, respectively. The maximum strengths of SBR cement mortar are about 1.8 and 1.3 times the strengths of plain mortar, respectively. In this study, it is confirmed that the polymer-cement ratio and curing method are important factors for improving the strengths of rapid-hardening SBR cement mortar.

A Study on Chloride Diffusion in Concrete Containing Lightweight Aggregate Using Crushed Stone-powder (폐석분을 활용한 경량골재 콘크리트의 염화물 확산에 관한 연구)

  • Lee, Dae-Hyuk;Yoon, Sang-Chen;Jeong, Yong;Shin, Jae-Kyung;Jee, Nam-Yong
    • Journal of the Korea Concrete Institute
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    • v.22 no.2
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    • pp.255-262
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    • 2010
  • The purpose of this study is to provide preliminary data on chloride diffusion of lightweight aggregate concrete containing crushed stone-powder. Accordingly, the study performed experiments using concrete aggregates of Crushed Aggregate (CG), Single-sized Lightweight Aggregate (SLG), Continuous Graded Lightweight Aggregate (CLG), and using water-binder ratio of 0.4, 0.5, 0.6, and using binder of FA and BFS. The chloride diffusion coefficient is calculated according to the NT BUILD 492. Diffusion coefficient of SLG and CLG were higher than that of CG concrete, but the difference was not significant. Also, chloride diffusion coefficient data indicated that it was highly affected by water-binder ratio, and it decreased with the decrease in waterbinder ratio. The admixture substitution of FA15% was effective in decreasing the diffusion coefficient only with water-binder ratio of 0.4 while admixture substitution of FA10+BFS20% was effective with all levels of water-binder ratio. The result of study shows lightweight aggregate concrete containing crushed stone-powder has slightly higher chloride diffusion coefficient than CG concrete, but the difference is not significant such that it can be overcome by adjusting water-binder ratio and admixture substitution. In addition, the data indicate the chloride diffusion coefficient of lightweight aggregate concrete can be estimated from the strength of lightweight aggregate.

Synthesis of Low Concentration of NaOH Solution using $Na^+$ ion in the Concentrated Water from Membrane Separation Process (분리막 농축수에 포함된 Na를 이용한 저농도 NaOH 용액의 합성)

  • Lee, Yoon-Ji;Park, Youn-Jin;Choi, Jeong-Hak;Shin, Won-Sik;Choi, Sang-June;Chon, Uong
    • Korean Chemical Engineering Research
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    • v.49 no.6
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    • pp.810-815
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    • 2011
  • Concentrated water discharged from seawater desalination process contains a high concentration of $Na^+$ ion. Electrolysis was applied to synthesize NaOH solution from the highly concentrated NaCl solution. The effect of various operating parameters of composited laboratory-scale chlor-alkali (CA) membrane cell was investigated. The operating parameters such as membrane types (CIMS and Nafion membranes), pretreatment of the membrane, flow rate (73 mL/min~200 mL/min), initial $Na^+$ ion concentration (1.5 M, 3M and 5 M) and current (1.5A and 2A) were evaluated. It was observed that synthesis efficiency of NaOH solution with CIMS membrane was higher than that with Nafion membrane, but the durability of CIMS membrane on $Cl_2$ gas was poor. The synthesis efficiency of NaOH solution increased with increasing initial $Na^+$ ion concentration and current, while the efficiency decreased with increasing flow rate using Nafion membrane.

Multiscale Virtual Testing Machines of Concrete and Other Composite Materials: A Review (콘크리트 및 복합재료용 멀티스케일 가상 시험기계에 관한 소고)

  • Haile, Bezawit F.;Park, S.M.;Yang, B.J.;Lee, H.K.
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.31 no.4
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    • pp.173-181
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    • 2018
  • Recently composite materials have dominated most engineering fields, owing to their better performance, increased durability and flexibility to be customized and designed for a specific required property. This has given them unprecedented superiority over conventional materials. With the help of the ever increasing computational capabilities of computers, researchers have been trying to develop accurate material models for the complex and integrated properties of these composites. This has led to advances in virtual testing of composite materials as a supplement or a possible replacement of laboratory experiments to predict the properties and responses of composite materials and structures. This paper presents a review on the complex multi-scale modelling framework of the virtual testing machines, which involve computational mechanics at various length-scales starting with nano-mechanics and ending in structure level computational mechanics, with a homogenization technique used to link the different length scales. In addition, the paper presents the features of some of the biggest integrated virtual testing machines developed for study of concrete, including a multiscale modeling scheme for the simulation of the constitutive properties of nanocomposites. Finally, the current challenges and future development potentials for virtual test machines are discussed.

Load Transfer Characteristics of the 7-wire strand using FBG Sensor Embedded Smart Tendon (FBG센서가 내장된 스마트 텐던을 이용한 7연 강연선의 인발 하중전이 특성)

  • Kim, Young-Sang;Suh, Dong-Nam;Kim, Jae-Min;Sung, Hyun-Jong
    • Journal of the Korean Society of Hazard Mitigation
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    • v.9 no.5
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    • pp.79-86
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    • 2009
  • With the substantial increase of the size of structure, the management of excavation becomes more difficult. Therefore, massive collapses which are related to retaining wall recently increase. However, since the study on measuring and monitoring the pre-stressing force of anchor is insufficient, behavior of anchor may not be predicted and monitored appropriately by the existing strain gauge and load cell type monitoring system. FBG Sensor, which is smaller than strain gauge and has better durability and does not have a noise from electromagnetic waves, is adapted to measure the strain and pre-stressing force of 7-wire strand, so called smart tendon. A series of pullout tests were performed to verify the feasibility of smart tendon and find out the load transfer mechanism around the steel wire tendon fixed to rock with grout. Distribution of measured strains and estimated shear stresses are compared with those predicted by theoretical solutions. It was found that developed smart tendon can be used effectively for measuring strain of 7-wire strand anchor and theoretical solutions underestimate the magnitude of shear stress and load transfer depth.

Development of Environmental Safety Real-Time Monitoring System by Living Area (생활권역별 환경안전 실시간 모니터링 시스템의 개발)

  • Lee, Joo-Hyun;Kim, Joo-Ho;Lee, Seung-Ho
    • Journal of IKEEE
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    • v.23 no.3
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    • pp.1088-1091
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    • 2019
  • In this paper, a real-time monitoring system for environmental safety by living area is proposed. The proposed system is designed to measure radiation, fine dust and basic living information (temperature) using fixed and mobile measuring equipment, and constitutes a web database that stores data received from the equipment. It also develops web programs for displaying received data on PCs and mobile phones. The results of testing the performance of the system by an authorized testing agency showed that the radiation measurement range was measured in the range of $10{\mu}Sv/h$ to 10mSv/h, which is comparable to the world's highest level, and that the accuracy was measured between ${\pm}6.7$ and ${\pm}8.7$ percent of the measurement uncertainty was measured and normal operation at or below the international standard of ${\pm}15$ percent. In addition, the temperature test was conducted on a section of $-20^{\circ}C$ to $50^{\circ}C$ and normal operation was confirmed in response to the temperature change. Stability of radiated electromagnetic waves was ensured by a suitable judgment. The product's testing in general and high and low temperature environments for about four months after the prototype was made confirmed to be more than five years of durability. The measurement range and accuracy of fine dust sensors are compared with those of companies that measure the air environment, and the performance level is similar through the air quality measurement register.

Thermal Energy Capacity of Concrete Blocks Subjected to High-Temperature Thermal Cycling (열사이클을 적용한 고온 조건 콘크리트 블록의 열용량 특성)

  • Yang, In-Hwan;Park, Ji-Hun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.4
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    • pp.571-580
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    • 2020
  • In this study, an experimental study on storage media for thermal energy storage system was conducted. For thermal energy storage medium, concrete has excellent thermal and mechanical properties and also has various advantages due to its low cost. In addition, the ultra-high strength concrete reinforced by steel fibers exhibits excellent durability against exposure to high temperatures due to its high toughness and high strength characteristics. Moreover, the high thermal conductivity of steel fibers has an advantageous effect on heat storage and heat dissipation. Therefore, to investigate the temperature distribution characteristics of ultra-high-strength concrete, concrete blocks were fabricated and a heating test was performed by applying high-temperature thermal cycles. The heat transfer pipe was buried in the center of the concrete block for heat transfer by heat fluid flow. In order to explore the temperature distribution characteristics according to different shapes of the heat transfer pipe, a round pipe and a longitudinal fin pipe were used. The temperature distribution at the differnent thermal cycles were analyzed, and the thermal energy and the cumulated thermal energy over time were calculated and analyzed for comparison based on test results.

Strength and Durability Characteristics of Low-alkali Mortar for Artificial Reefs Produced by 3D Printers (인공어초 3D 프린터 출력을 위한 저알칼리 모르타르의 강도와 내구성능)

  • Lee, Byung-Jae;Kim, Bong-Kyun;Kim, Yun-Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.1
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    • pp.67-72
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    • 2022
  • Concrete prevents corrosion of reinforcing bars due to its strong alkalinity. However, in the sea, strong alkali components with a pH of 12 to 13 are eluted, which adversely affects the ecological environment and growth of marine organisms. In this study, the mechanical properties and durability of the low alkali mortar were evaluated for the development of a low alkali mortar for the 3D printed artificial reefs. As a result of evaluation of strength characteristics, the α-35 mixture, which were produced with fly ash, silica fume and α-hemihydrate gypsum, satisfied the strength requirement 27 MPa in terms of compressive strength. As a result of pH measurement, it was found that mixing with alpha-type hemihydrate gypsum resulted in minimizing pH due to the the formation of calcium sulfate instead of calcium hydroxide production. As a result of the chloride ion penetration resistance test, the α-35 mixture exhibited the best performance, 3844C. As a result of measuring the length change over time, the α-35 mixture showed the shrinkage 33.5% less compared to the Plain mix.