• Title/Summary/Keyword: 내구강도

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Effect of SUS316L Bipolar Plate Corrosion on Contact Resistance and PEMFC Performance (SUS316L 분리판 부식에 의한 접촉저항 및 고분자전해질 연료전지 성능에 미치는 영향)

  • Kim, Junseob;Kim, Junbom
    • Applied Chemistry for Engineering
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    • v.32 no.6
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    • pp.664-670
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    • 2021
  • Stainless steel was applied as bipolar plate (BP) of polymer electrolyte membrane fuel cell (PEMFC) due to high mechanical strength, electrical conductivity, and good machinability. However, stainless steel was corroded and increased contact resistance resulting PEMFC performance decrease. Although the corrosion resistance could be improved by surface treatment such as noble metal coating, there is a disadvantage of cost increase. The stainless steel corrosion behavior and passive layer influence on PEMFC performance should be studied to improve durability and economics of metal bipolar plate. In this study, SUS316L bipolar plate of 25 cm2 active area was manufactured, and experiments were conducted for corrosion behavior at an anode and cathode. The influence of SUS316L BP corrosion on fuel cell performance was measured using the polarization curve, impedance, and contact resistance. The metal ion concentration in drained water was analyzed during fuel cell operation with SUS316L BP. It was confirmed that the corrosion occurs more severely at the anode than at the cathode for SUS316L BP. The contact resistance was increased due to the passivation of SUS316L during fuel cell operation, and metal ions continuously dissolved even after the passive layer formation.

Recycling of Coal Ash and Related Environmental Issues in Australia (호주의 석탄재 재활용 사례와 석탄재 재활용과 관련된 환경 문제)

  • Park, Jin Hee;Ji, Sang-Woo;Shin, Hee-Young;Jo, Hwanju;Ahn, Ji-Whan
    • Resources Recycling
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    • v.28 no.4
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    • pp.15-22
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    • 2019
  • Coal combustion products are generated during coal combustion and can be grouped into fly ash and bottom ash depending on collection methods. Fly ash and bottom ash can be recycled for various purposes based on their characteristics. Australia is the fourth largest coal production country in the world and reuses coal ash as cement, concrete, mine filler, and agricultural soil amendment. When fly ash is used as a supplement for cement and concrete, strength of the cement and the durability of the concrete can be improved. Use of coal combustion product for mine backfill stabilizes underground mine voids and stores a large amount of coal ash in the voids. Because of alkalinity of coal combustion products, it can neutralize acid mine drainage when used for mine backfill. In addition, it can be used as an agricultural soil amendment to improve acidity and physical properties of the soil and to supply plant nutrients. Recycling of fly ash in Australia will be further expanded because of its low trace element contents that can be toxic to plants and low radioactive element contents existing within soil background concentrations. The characteristics of coal combustion products are related to the characteristics of the coal used for combustion, and since Korea imports coal from Australia, Korean coal combustion products also can be recycled for various purposes.

Evaluation of Chloride Diffusion Characteristics in Concrete with Fly Ash Cured for 2 Years (2년 양생된 Fly Ash 콘크리트의 염화물 확산 특성 평가)

  • Yoon, Yong-Sik;Hwang, Sang-Hyeon;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.1
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    • pp.8-15
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    • 2019
  • When RC(Reinforced Concrete) structures are exposed to harsh environment, deterioration phenomenon occurs, and the corrosion in rebar due to chloride intrusion is known as representative deterioration, so called chloride attack. In this paper, chloride resistance performance of 2 years aged concrete is evaluated considering 3 levels of water to binder ratio(0.37, 0.42, and 0.47) and 2 levels of substitution ratio of fly ash(0% and 30%). Accelerated chloride diffusion coefficient tests referred to Tang's method, total passed charge tests referred to ASTM C 1202, and compressive strength tests referred to KS F 2405 are performed. With adaptation of the previous test results and the results from this study, time-dependent chloride diffusion characteristics are analyzed for each concrete. The FA(Fly Ash) concrete has higher chloride resistance performance than OPC(Ordinary Portland Cement) concrete. According to the evaluation standard of ASTM C 1202, the FA concrete has "Moderate" grade after 49 days while OPC concrete does "Moderate" grade after 365 days. As the results of time-parameter for chloride diffusion, OPC concrete and FA concrete show the decreasing behavior of time-parameters with increasing water to binder ratio. Also, FA concrete has 1.57~2.74 times of time-parameter than OPC concrete. That's cause is thought that the time-parameter indicates the gradient of decreasing of diffusion coefficient. FA concrete has higher time-parameters than OPC concrete by pozzolanic reaction of FA.

Development of an Open-Typed Optimal Trolley Model for Cable-Based Retractable Membrane Roof (케이블 기반 개폐 막 지붕의 오픈형 최적 트롤리 모델 개발)

  • Lee, Donwoo;Shon, Sudeok;Choi, Bongyoung;Lee, Seungjae
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.22 no.1
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    • pp.719-727
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    • 2021
  • In the field of architecture, retractable devices capable of responding flexibly to the environment have been applied widely to large structures. Among these devices, the aesthetically pleasing retractable membrane is lightweight so that the membrane can be opened easily using only a traction device. On the other hand, because the towed membrane moves as it is connected to the main cable by a trolley, the number of trolleys needed increases in proportion to the roof's area. This study proposes an optimal model for an open-type trolley (OTT), which is used widely in these devices, using topology optimization. The analysis used the ANSYS program. A new model was proposed based on the results and reviewed through the feedback. Through this process, it was possible to develop a prototype with increased durability and reduced weight. For OTT, optimization was performed based on static analysis and the boundary conditions, so three prototypes were designed. A comparison of the proposed trolley with the conventional one under the same conditions revealed an up to 71.04% decrease in volume while the yield-strength reached 8.67 to 11.43%. In conclusion, the optimal trolley proposed was found to be reliable in terms of economy and stability.

The Prediction of Durability Performance for Chloride Ingress in Fly Ash Concrete by Artificial Neural Network Algorithm (인공 신경망 알고리즘을 활용한 플라이애시 콘크리트의 염해 내구성능 예측)

  • Kwon, Seung-Jun;Yoon, Yong-Sik
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.5
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    • pp.127-134
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    • 2022
  • In this study, RCPTs (Rapid Chloride Penetration Test) were performed for fly ash concrete with curing age of 4 ~ 6 years. The concrete mixtures were prepared with 3 levels of water to binder ratio (0.37, 0.42, and 0.47) and 2 levels of substitution ratio of fly ash (0 and 30%), and the improved passed charges of chloride ion behavior were quantitatively analyzed. Additionally, the results were trained through the univariate time series models consisted of GRU (Gated Recurrent Unit) algorithm and those from the models were evaluated. As the result of the RCPT, fly ash concrete showed the reduced passed charges with period and an more improved resistance to chloride penetration than OPC concrete. At the final evaluation period (6 years), fly ash concrete showed 'Very low' grade in all W/B (water to binder) ratio, however OPC concrete showed 'Moderate' grade in the condition with the highest W/B ratio (0.47). The adopted algorithm of GRU for this study can analyze time series data and has the advantage like operation efficiency. The deep learning model with 4 hidden layers was designed, and it provided a reasonable prediction results of passed charge. The deep learning model from this study has a limitation of single consideration of a univariate time series characteristic, but it is in the developing process of providing various characteristics of concrete like strength and diffusion coefficient through additional studies.

A Study on the Error Rate of Non-destructive Rebar Detection Under Different Environmental Factors (환경적 요인에 따른 비파괴 철근 탐사의 오차율에 관한 연구)

  • Kang, Beom-Ju;Kim, Young-Hwan;Kim, Young-Min;Park, Kyung-Han;Oh, Hong-Seob
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.506-513
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    • 2021
  • The durability and safety of reinforced concrete structures significantly depend on the reinforcement conditions, concrete cover thickness, cracks, and concrete strength. There are two ways to accurately determine the information on reinforcing bars embedded in concrete - the local destructive method and the non-destructive rebar detection test. In general, the non-destructive rebar detection tests, such as the electromagnetic wave radar method, electromagnetic induction method, and radiation method, are adopted to avoid damage to the structural elements. The moisture content and temperature of concrete affect the dielectric constant, which is the electrical property of concrete, and cause interference in the non-destructive rebar detection test results. Therefore, in this study, the effects of the electromagnetic wave radar method and electromagnetic induction method have been analyzed according to the temperature and surface moisture content of concrete. Due to the technological advancement and development of equipment, the average error rate was less than 5% in the specimens at 24℃, irrespective of their operating principles. Among the tested methods, the electromagnetic induction method showed very high accuracy. The electromagnetic wave radar method indicated a relatively small error rate in the dry state than in the wet state, and exhibited a relatively high error rate at high temperatures. It was confirmed that the error could be reduced by applying the electromagnetic wave radar method when the temperature of the probe was low and in a dry state, and by using the electromagnetic induction method when the probe was in a wet state or at a high temperature.

Effect of Repeated Wet/Dry Cycles of Salt Solution on Flexural Performance of Steel Fiber Reinforced Concrete (반복적 염수침지가 강섬유 혼입 콘크리트의 휨성능에 미치는 영향)

  • Kim, Ji-Hyun;Choi, Yu-Jin;Chung, Chul-Woo
    • Journal of the Korea Institute of Building Construction
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    • v.22 no.6
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    • pp.553-564
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    • 2022
  • Concrete is a representative composite material that shows excellent performance in the construction field. However, it is a brittle and nonhomogeneous material and exhibits weak behavior against bending and tensile forces. To compensate for such weakens, fiber reinforcement has been utilized, and steel fiber has been recognized as one of the best material for such purpose. However, steel fiber can seriously affect the durability of concrete exposed to the marine environment due to the corrosion caused by chlorine ions. This study intended to evaluate the mechanical performance of steel fiber reinforce concrete during and after repeated wet/dry cycles in salt solution. According to the experimental results, there was no reduction in the relative dynamic modulus of concrete during the repeated wet/dry cycles in salt solution for 37 weeks. Flexural strength was not decreased after completion of repeated wet/dry cycles in salt solution. There was no sign of corrosion in steel fibers after visual observation of fractured surface. However, the flexural toughness was decreased, and this is because about half of the concrete specimen showed failure before reaching the maximum displacement of 3 mm. Although repeated wet/dry cycles in salt solution did not cause cracks in concrete through corrosion of steel fibers, specific attention is required because it can reduce flexural toughness of steel fiber reinforced concrete.

Types and Characteristics of Landslides in Danyang Geopark (단양 지질공원 내의 산사태 유형과 특징)

  • Seong-Woo Moon;Ho-Geun Kim;Yong-Seok Seo
    • The Journal of Engineering Geology
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    • v.33 no.3
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    • pp.427-438
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    • 2023
  • We carried out a geological survey to classify the types of mass movement in Danyang Geopark (where various rock types are distributed) and analyzed the mechanical and hydraulic characteristics of landslide materials using a series of laboratory tests. Debris flows occurred in areas of limestone/marble, shale, and porphyroblastic gneiss, and limestone/marble landslides were distinguished from the others through the presence of karren topography. Soil tests showed that soil derived from weathered gneiss, which has a higher proportion of coarse grains, has a higher friction angle, lower cohesion, and larger hydraulic conductivity than soils from areas of limestone/marble, and shale. Rock failure mass movements occurred in areas of phyllite, sandstone, and conglomerate and were subdivided into plane failure, block-fall, and boulder-fall types in areas of phyllite, sandstone, and conglomerate, respectively. The shear strength of phyllite is much lower than that of the other types of rock, which have similar rock quality. The slake durability index of the conglomerate is similar to that of the other rock types, which have similar degrees of weathering, but differential weathering of the matrix and clasts was clearly observed when comparing the samples before and after the test. This study can help establish appropriate reinforcement and disaster prevention measures, which depend on the type of mass movement expected given the geological characteristics of an area.

Injection Characteristics Evaluation of Conductive Grout Material According to Carbon Fiber Mixing Ratio (탄소섬유 배합비에 따른 전도성 그라우트 재료의 주입특성평가)

  • Hyojun Choi;Wanjei Cho;Hyungseok Heo;Teawan Bang;Chanyoung Yune
    • Journal of the Korean GEO-environmental Society
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    • v.24 no.1
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    • pp.15-23
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    • 2023
  • The grouting method is a method of construction for the purpose of waterproofing and reinforcing soft ground. When grout is injected into the ground, there are various types of penetration and diffusion of grout depending on the shape of the ground, the size of soil, the porosity, and the presence or absence of groundwater. the current situation. Therefore, in this study, to investigate the penetration performance of the grouting to conductive material, laboratory tests were performed on the addition of the conductive material. In the injection test, 0%, 3%, and 5% of the mixed water were added as conductive materials to the grout, and the original ground condition was composed of various types of ground composed of gravel and silica sand. Conductive grout is injected by pressure into the model ground using a dedicated injection device, and the injection time (t), pressure (p), flow rate (v) and injection amount (q) are measured, and the hardened body injected in the model ground is collected. Penetration performance was evaluated. In the results of the grout injection experiment, the amount of conductive material used and the grout injection rate showed an inverse relationship, and it was confirmed that the penetration pattern was changed according to the size of the soil particles in the model ground. The grout containing the conductive material has relatively good penetration into the ground and excellent strength and durability of the hardened body, so it was judged that it could be used as an additive for measuring the penetration range of the grout.

The Effect of Rainfall on the Stability of Mudstone Slope in Consideration of Collapse Record (이암 절취사면의 붕괴이력을 고려한 강우침투에 따른 안정성 분석)

  • Jeon, Byeong-Chu;Lee, Su-Gon;Kim, Young-Muk;Chung, Sung-Rae
    • Journal of the Korean Geotechnical Society
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    • v.25 no.2
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    • pp.55-66
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    • 2009
  • At the mudstone slope located on the roadside of the Seokri area in Donghae-myeon, Pohang, Gyeongsangbuk-do, this study was performed to analyze the effects of rainfall on the stability of slope through seepage analysis according to the precipitation type of the mudstone slope, referring to the actual case of slope failure. For this, precise geological survey, geophysical exploration and drilling survey for the slope where the failure occurred were performed and followed by analysis of detailed soil layer. For the section where failure surface located, the durability reduction of rocks was measured through slaking/swelling tests and the permeability was measured through in-situ permeability tests for each soil layer. In addition, the change of strength parameter and process of instability were analyzed by back analysis, using Talren 97 and Slope/W programs, in the slope. By applying different precipitation conditions to the geographical conditions of the slope that had actual failure records, the slope stability was analyzed by seepage analysis according to duration of rainfall and rise of groundwater level resulting from the flow of rainfall caused by development of geological structures and the slope surface condition.