• 제목/요약/키워드: 나노 재료

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카본나노튜브가 프린즈 필드 스위칭 액정 셀의 전기 광학적 특성에 미치는 영향 (Effects of carbon nanotubes on electro-optic characteristics of fringe-field switching liquid crystal cell)

  • 최정훈;조은미;김미영;;이승희;배정준;이규;이영희;이희규;이승은
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.435-436
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    • 2008
  • In this paper, the electro-optical characteristics of carbon nano tubes (CNTs) doped liquid crystal (LC), in fringe-field switching cell have been investigated and compared with pure LC. The electro-optical characteristics of CNTs doped LC were found to be improved than that of pure LC. The CNTs doped LC exhibits faster response time and lower driving voltage than that of pure LC.

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다양한 계면활성제를 이용한 고순도 단일벽 탄소나노튜브의 수계 분산 (Dispersion of Highly Pure Single-Walled Carbon Nanotube in Aqueous Solution of Various Surfactants)

  • 곽정춘;김명수;이내성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.153-153
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    • 2008
  • Practical application of single-walled carbon nanotubes (SWCNTs) qualified as a promising material has been limited by either poor dispersion or their insolubility in aqueous or organic media due to formation of bundling by relatively high surface energy. Thus, major attention to overcome this issue has been paid at surface modification of CNTs by functionalization, but this introduces defects to the sidewall of CNTs, consequently perturbing the inherent electronic and optical properties. Therefore, using surfactants is a general approach to disperse SWCNTs with lower damages by which bundled nanotubes could be dispersed up to the level of individuals or small bundles. Here, we have investigated various surfactants for their efficiency in dissolving purified SWCNTs produced by arc discharge in deionized water. To compare the surfactants respectively, we have determined the least amount of each surfactant to suspend the nanotubes under optimized experimental conditions(CNT amount, sonication power, and centrifugation speed, etc.) set on the basis of the most common surfactant (sodium dodecyl sulfate, SDS) and discussed the qualitative and quantitative characterization of SWCNT dispersions by UV-Vis absorption spectroscopy. Quantitative aspect about nanotube dispersion was that in particular N-methyl-2-pyrrolidone (NMP) and sodium dodecylbenzene sulfonate (NaDDBS) were found to be effective in dispersing individual tubes.

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$TiO_2$ 나노파이버를 첨가한 광전극용 $TiO_2$ 페이스트가 염료감응 태양전지의 광전변환 특성에 미치는 영향 (Effect of performance in $TiO_2$ paste for Dye-Sensitized Solar Cells by $TiO_2$ nanofiber)

  • 백형열;이호;김은미;박경희;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.358-359
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    • 2008
  • Solar cell based on dye-sensitized photoelectric conversion was studied by investigating the effects of the amount of $TiO_2$ nanofiber added to the $TiO_2$ paste, on surface morphology, good electric of the $TiO_2$ films and on the solar cell performance. Energy conversion efficiency was found to increased with $TiO_2$ nanofiber addition up to 7wt% in $TiO_2$ films. Maximum increase upto 15% in the efficiently was observed at 7 wt. % of $TiO_2$ nanofiber in $TiO_2$ electrode.

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혼합 연마제가 TEOS 막에 미치는 영향 (Effect of Mixed Abrasive Slurry (MAS) on the Tetra-Ethyl Ortho-Silicate (TEOS) Film)

  • 이영균;한상준;박성우;서용진;이우선
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.541-541
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    • 2008
  • 반도체 소자가 차세대 초미세 공정 기술 도입의 가속화를 통해 고속화 및 고집적화 되어 감에 따라 나노(Nano) 크기의 회로 선폭 미세화를 극복하고자 최적의 CMP (Chemical Mechanical Polishing) 공정이 요구되어지고 있다. 이처럼 CMP 공정이 반도체 제조 공정에 적용됨으로써 공정 마진 확보에 진일보 하였으나 CMP 장비의 공정 조건, 슬러리의 종류, 연마패드의 종류 등에 의해 CMP 성능이 결정된다. 특히 슬러리는 연마 공정의 성능에 중요한 영향을 미치는 요인이다. 고가의 슬러리가 차지하는 비중이 40% 이상을 넘고 있어 슬러리 원액의 소모량을 줄이기 위한 연구들이 현재 활발히 진행되고 있다. 본 연구에서는 새로운 연마제의 특성을 알아보기 위해 탈이온수(De-ionized water; DIW) 에 $CeO_2$, 연마제를 첨가한 후 분산시간에 따른 연마 특성과 AFM, EDX, XRD, TEM분석을 통해 그 가능성을 알아보았다.

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나노크기의 비가시 무기형광체 제조와 발광특성 (Preparation and Luminescene properties with invisible inoranic phosphors of nano size)

  • 정재훈;윤현;장규환;신상식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.461-462
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    • 2008
  • $BaMgAl_{10}O_{17}$:Mn, $Eu^{2+}$ green phosphors has been synthesized by the solid state reaction. Green phosphors of nano-size were manufactured in short time by shake method. which were easily manufactured respectively general method. Green phosphors of nano size were control additive, size of $ZrO_3$ ball, shake time and weight of ball in toluene. In result that green phosphors were obtained particle size of 140nm~150nm. The characteristics of fired samples were obtained by 365nm and 380nm excitation source under ultraviolet. In result that the highest PL intensity were observed in wavelength of 365nm.

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증착조건에 따른 ZnO 나노와이어의 성장 및 photoluminescence 특성 (Growth and photoluminescence characteristics of ZnO nanowire depending on deposition condition)

  • 오원석;장건익
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.172-172
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    • 2008
  • By thermal evaporation method, well-aligned ZnO nanowires were synthesized on sapphire substrate at $1000^{\circ}C$ with different oxygen flow rate by using pure ZnO powder (99.999 %). The as-synthesized ZnO nanowires were characterized by field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM). The well-aligned nanowires are single crystalline in nature and perpendicularly grown along the c-axis. Also the growth rate of nanowires, such as diameter and length, had a tendency to increase as oxygen flow rate increased. Based on the PL measurement of ZnO nanowires, we found that the near band edge of emission redshifted with the increasing intensity of the defect-related green emission in proportion to the increase of oxygen flow rate. "This research was supported by the Korea Research Foundation Grant funded by the Korean Government(MOEHRD)" (The Regional Research Universities Program/Chungbuk BIT Research-Oriented University Consortium).

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직류 바이어스를 이용한 나노결정 실리콘의 구조 및 광학적 특성 (Characterization of hydrogenated nanocrystalline silicon thin films prepared with various negative DC biases)

  • 심재현;조남희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.37-37
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    • 2008
  • Hydrogenated nanocrystalline Si (nc-Si:H) thin films were prepared by plasma enhanced chemical vapor deposition (PECVD). The films were deposited with a radio frequency power of 100 W, while substrates were exposed to direct current (DC) biases in the range from 0 to -400 V. The effects of the DC bias on the formation of nanoscale Si crystallites in the films and on their optical characteristics were investigated. The size of the Si crystallites in the films ranges from ~ 1.9 to ~ 4.1 nm. The relative fraction of the crystallites in the films reached up ~ 56.5 % when the DC bias of -400 V was applied. Based on the variation in the structural, chemical, and optical features of the films with DC bias voltages, a model for the formation of nanostructures of the nc-Si:H films prepared by PECVD was suggested. This model can be utilized to understand the evolution in the size and relative fraction of the nanocrystallites as well as the amorphous matrix in the nc-Si:H films.

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성장시간에 따른 ZnO 나노로드의 구조적 및 광학적 특성 변화 (Variation of Structural and Optical Properties of ZnO Nanorods with Growing Time)

  • 마대영
    • 한국전기전자재료학회논문지
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    • 제29권12호
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    • pp.841-846
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    • 2016
  • ZnO nanorods were grown on $SiO_2$ coated Si wafers and glass by the hydrothermal method. The structural and optical properties variation of ZnO nanorods as a function of growing time was studied. ~10 nm-thick ZnO thin films deposited on substrates by rf magnetron sputtering were employed as seed layers. Zinc nitrate hexahydrate (0.05 M) and hexamethylenetetramine (0.05 M) mixed in DI water were used as a reaction solution. ZnO nanorods were respectively grown for 30 min, 1 h, 2 h, 3 h, and 4 h by maintaining the reactor at $90^{\circ}C$. Crystallinity of ZnO nanorods was analyzed by X-ray diffraction, and the morphology of nanorods was observed by a field emission scanning electron microscope. Transmittance and absorbance were measured by a UV-Vis spectrophotometer, and energy band gap and urbach energy were obtained from the data. Photoluminescence measurements were carried out using Nd-Yag laser (266 nm).

Pulsed Laser Deposition 방법으로 증착된 Fe3O4 나노선의 성장과 특성 (Fabrication and Properties of Fe3O4 Nanowires Using Pulsed Laser Deposition)

  • 윤종구;김진아;윤순길
    • 한국전기전자재료학회논문지
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    • 제26권1호
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    • pp.64-67
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    • 2013
  • $Fe_3O_4$(magnetite) having half metallic property attracts great attention material with high curie temperature in spintronics. $Fe_3O_4$ thin films and nanowires were grown onto c-$Al_2O_3$(0001) at various substrate temperatures. $Fe_3O_4$ films deposited from 300 to $600^{\circ}C$ are influenced by thermal stress induced from mismatch of thermal expansion coefficient between $Fe_3O_4$ and $Al_2O_3$ (0001) substrate. The $Fe_3O_4$ nanowires grown at $640^{\circ}C$ showed a diameter of 130 nm and a length of $2-10{\mu}m$. The nanowire arrays fabricated by pulsed laser deposition technique have high coercivity($H_c$) of 608 Oe and Squareness($M_r/M_s$) of 0.68 in perpendicular direction.

알루미늄 하부층이 탄소나노튜브의 성장 및 전계방출 특성에 미치는 영향 (Effect of an AI underlayer on the Growth of Carbon Nanotubes and Their Field Emission Characteristics)

  • 이승환;곽정춘;이한성;이내성
    • 한국전기전자재료학회논문지
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    • 제21권2호
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    • pp.162-172
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    • 2008
  • We studied the effect of an Al underlayer on the growth of carbon nanotubes (CNTs) and their field emission characteristics, First of all, CNTs were grown on the Invar catalyst layers with different thickness of 1 to 10 nm, showing that the CNT length was saturated for the catalyst 5 nm or thicker. The CNTs grown on the 5-nm-thick catalyst were ${\sim}10{\mu}m$ long and ${\sim}30nm$ in diameter. Second, an Al underlayer was applied between the catalyst layer and the Ti diffusion barrier to reduce the diameters of CNTs for better field emission properties by forming spherical Al oxide particles on which smaller catalyst nanoparticles would occur. The optimal thickness of an Al underlayer underneath the 5-nm-thick catalyst was ${\sim}15nm$, producing the CNTs with the length of ${\sim}15{\mu}m$ and the diameter of ${\sim}15nm$. The field emission measurements, following the tape activation, showed that the thinner and longer CNTs gave rise to better field emission performance with the lower turn-on and threshold electric fields.