• Title/Summary/Keyword: 나노벽

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Noncovalent Titania Wrapping of Single-Walled Carbon Nanotubes for Environmentally Stable Transparent Conductive Thin Films (환경신뢰성이 확보된 투명전도성 필름을 위한 비공유 결합에 의한 단일벽 탄소나노튜브의 $TiO_2$ 코팅)

  • Han, Joong-Tark;Kim, Jun-Suk;Jeong, Hee-Jin;Jeong, Seung-Yol;Lee, Geon-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.279-279
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    • 2010
  • We present a simple process for the fabrication of high performance transparent conducting films that contain single-walled carbon nanotubes (SWCNTs) noncovalently coated with an ultrathin titania layer. The hydrophobic interactions between nanotube surfaces and the acetylacetone (acac) ligands used to stabilize the $TiO_2$ precursor provide an interesting alternative method for noncovalently coating the SWCNTs with a titania layer. The ultrathin titania layer on SWCNTs prevented the oxidation of functionalized SWCNTs at high temperatures, and protected against water molecule absorption.

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Observation of SWCNT Stretching in homogeneously aligned nematic liquid Crystal medium (수평 배향된 양의 액정 내에서의 단일벽 탄소 나노튜브 Stretching 관찰)

  • Yang, Gyu-Hyung;Kang, Byeong-Gyun;Lee, Seung-Hee;Lee, Kyu;Lee, Young-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.170-170
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    • 2010
  • In this paper, we observed stretching of single-wall carbon nanotubes (SWCNTs) aggregates driven by the in-plane field in a homogeneously aligned nematic liquid crystal (LC) medium. Aggregates of SWCNTs started to stretch above the 0.5 V/${\mu}m$ and stretched up to $1.83\;{\mu}m$ from original size with $0.74\;{\mu}m$ at 3.5 V/${\mu}m$.

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Titania-assisted dispersion of carboxylated single-walled carbon nanotubes in ZnO sol for transprent conducting films with high thermal stability ($TiO_2$ 도입에 따른 ZnO 졸에서의 단일벽 탄소나노튜브의 분산안정성 및 그 투명전도성 필름의 고온 안정성)

  • Kim, Bo-Gyeong;Han, Joong-Tark;Jeong, Hae-Deuk;Jeong, Hae-Deuk;Jeong, Seung-Yol;Lee, Geon-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.03b
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    • pp.41-41
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    • 2010
  • We present facile chemical route stabilizing dispersion of carboxylated single-walled carbon nanotubes (SWCNTs) in ZnOsol prepared by using diethanolamine as a stabilizer. The dispersion was stabilized via capping of carboxyl groups on the SWCNT surface by a titania layer. We also demonstrated that the conductivity of the films prepared P3/$TiO_2$/ZnO as enhanced by therml treatment, and thethermal stbility of the film improved hybridization with ZnO sol pristine P3, P3/$SiO_2$ and P3/$TiO_2$ hybrid films.

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Fabrication and Electromagnetic Characteristics of Multi-walled Carbon nanotube/Epoxy Composites (다중벽 나노튜브/에폭시 복합재의 제작과 전자기적 특성)

  • 이상의;박기연;이원준;김천곤;한재흥
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.10a
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    • pp.107-110
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    • 2003
  • The electromagnetic intereference(EMI) shielding is very essential for commercial and military purposes. We fabricated multi-walled carbon nanoube(MWNT)/epoxy composites and studied the electromagnetic characteristics of the composites before we study the characteristics of MWNT-filled glass fiber-reinforced composites. After setting up the fabrication process, we measured the permittivities of MWNT/epoxy composites with process variables and MWNT concentrations in X-band(8.2GHz- 12.4GHz). Process variables changed the degree of dispersion, which influenced permittivities and permittivities increased rapidly from 0.5wt% to 1.0wt%.

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The Physical Property of MWNT/PU Composite Films (다중벽 탄소나노튜브와 폴리우레탄 복합화 필름의 물성특성)

  • Kim, Jeong-Hyun;Park, Jun-Hyeong;Kim, Seung-Jin
    • Textile Coloration and Finishing
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    • v.22 no.3
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    • pp.246-256
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    • 2010
  • This study studies on the physical property of MWNT/PU composite film for electrostatic dissipation (ESD) function by dispersing multi-wall carbon nanotubes (MWNT) in dimethylformamide (DMF) and by combining it with polyurethane(PU). For this purpose, four kinds of MWNT were selected and the composite films were made by dispersion processing, and their physical properties were measured and investigated in terms of electrical conductivity. For dispersion parameters, four MWNT contents(0.5, 1, 2, 5wt%) and two dispersion times(30min, 120min) were selected. The dispersion property and the electrical conductivity of MWNT/PU film was measured using a UV-Vis spectrometer and conductivity measuring apparatus. Finally, their physical properties according to the dispersion conditions were analyzed and discussed with various processing conditions.

Type conversion of single walled carbon nanotube field effect transistor using stable n-type dopants

  • Yun, Jang-Yeol;Ha, Jeong-Suk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.268-268
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    • 2010
  • 단일벽 탄소 나노튜브(SWCNT)는 그 뛰어난 전기적, 물리적 특성 때문에 반도체 공정에 있어서 중요한 p-type 채널 물질로 꼽히고 있다. 본 연구에서는 SWCNT를 성장하여 이를 이용한 전계효과 트랜지스터를 제작하고 또한, 부분적인 폴리머의 코팅으로 타입을 변화하는 연구를 보이고자 한다. Ferritin용액을 DI-water에 2000배 희석하여 SiO2 기판 위에 뿌린 뒤 Methanol을 이용하여 기판 표면에 촉매가 붙어있게 한다. 이 기판을 $900^{\circ}C$로 가열하여 유기물질을 제거한 뒤 화학 기상 증착(Chemical Vapor Deposition)방법으로 SWCNT를 성장하게 된다. 이렇게 성장된 SWCNT는 촉매의 농도에 비례하는 밀도를 가지게 되며 이 위에 전극을 증착하고 back-gate를 설치하여 FET를 제작한다. 메탈릭한 SWCNT는 breakdown 공정을 통하여 제거한 뒤, 전자 농도가 높은 NADH를 전체적으로 코팅을 한다. NADH는 기존의 다른 폴리머(polyethyleneimine: PEI)에 비교하여 코팅 후 전자 제공 효과가 크며 그 성질의 재현성이 높고 공기 중에서 안정성을 유지하는 능력이 있다. 이러한 NADH의 코팅으로 n-type으로의 SWCNT FET를 제작하였으며 type conversion 현상을 이용하면 국부적인 NADH의 코팅으로 homojunction-diode의 제작 등 다양한 소자의 제작에 적용될 것으로 예상한다.

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Synthesis and Microstructure of Single-Walled Carbon Nanotubes by Catalytic Chemical Vapor Deposition Method (촉매화학기상증착법에 의한 단일벽 탄소나노튜브의 합성과 미세구조)

  • Kim, Jong-Sik;Kim, Gwan-Ha;Kim, Chang-Il
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.55 no.7
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    • pp.359-363
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    • 2006
  • Single-walled carbon nanotubes (SWCNTs) with few defects and very small amount of amorphous carbon coating have been synthesized by catalytic decomposition of methane in $H_2$ over well-dispersed metal particles supported on MgO. The yield of SWCNTs was estimated to be 88.5% and the purities of SWCNTs thus obtained were more than 90%. Peak of the radial breathing mode in the Raman spectrum demonstrated that the diameters of synthesized CNTs are in the range 0.4-2.0 nm. Our results also indicated that MgO support materials are useful to a large-scale synthesis of high-quality SWCNTs. Increasing temperature could remarkably increase the yield and also improve the quality of SWCNTs from catalytic decomposition of methane. The morphologies and microstructures of the synthesized carbon materials were characterized by scanning electron microscopy (SEM), Thermogravimetric analysis (TGA), Raman spectroscopy, and X-ray diffraction (XRD).

Torsion of Hypothetical Single-Wall Silicon Nanotubes (가상의 단일벽 실리콘 나노튜브의 비틀림)

  • 변기량;강정원;이준하;권오근;황호정
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.12S
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    • pp.1165-1174
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    • 2003
  • The responses of hypothetical silicon nanotubes under torsion have been investigated using an atomistic simulation based on the Tersoff potential. A torque, proportional to the deformation within Hooke's law, resulted in the ribbon-like flattened shapes and eventually led to a breaking of hypothetical silicon nanotubes. Each shape change of hypothetical silicon nanotubcs corresponded to an abrupt energy change and a singularity in the strain energy curve as a function of the external tangential force, torque, or twisted angle. The dynamics o silicon nanotubes under torsion can be modelled in the continuum elasticity theory.

Encapsulation of Fullerenes in Single-walled Carbon Nanotubes and their Characteristic Analysis by Raman Spectroscopy (단일벽 탄소나노튜브의 플러렌 캡슐화 및 라만분광 분석)

  • Goak, Jeung-Choon;Lee, Nae-Sung
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.2
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    • pp.118-125
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    • 2008
  • Single walled carbon nanotubes (SWCNTs) can be modified to produce a new concept of hybrid materials by introducing atoms or molecules inside their cylindrical empty space. Such an endohedral doping of the SWCNTs is expected to decisively alter their electronic transport and mechanical properties, In this study, we purified SWCNTs by three-step purification processes and formed the peapod structure by introducing $C_{60}$ fullerenes inside the SWCNTs. $C_{60}$ molecules were observed to be regularly arranged by transmission electron microscopy. In Raman spectra, the radial breathing mode (RBM) rather than the other modes was significantly affected by the endohedral injection of $C_{60}$. The RBM intensity was more greatly reduced in the large-diameter SWCNTs than the small-diameter ones, Raman spectroscopy is expected to be a key technique for analyzing $C_{60}$-encapsulated SWCNTs.

Microstructure and Electromagnetic Property of MWNT-added Glass Fabric/Epoxy Composites (다중벽 나노튜브가 첨가된 유리 직물 복합재료의 미세구조 및 전자기적 물성)

  • Lee sang-Eui;Lee Won-Jun;Kim Chun-Gon
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.04a
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    • pp.169-172
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    • 2004
  • We fabricated MWNT-added glass fabric/epoxy composites. We observed the distribution of MWNTs in the composites using scanning electron microscopy and conformed that most of MWNTs exist in matrix rich region and interface between yams in warp and fill directions. We also investigated the change of permittivities with MWNT concentrations. Only $1wt\%$ MWNTs leads to high permittivity and electromagnetic waves are impossible to be transmitted to more than $3wt\%$ MWNT-added composites, which means the characteristics of these composites are comparable to those of metals or carbon fiber-reinforced composites.

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