• Title/Summary/Keyword: 기공복합체

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Sintering characteristics of the mixed body of clay and flyash containing unburnt carbon (미연탄소 함유 석탄회 복합체의 소결 특성)

  • 허승환;한정환;김유택;이기강;김석범
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.1
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    • pp.86-90
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    • 2000
  • The mixed body of clay and flyash containing unburnt carbon was examined at various sintering conditions in order to recycle flyash as environment-affinitive construction materials. Experimental results can be summarized as follows : when large aggregate of 2.54 cm dia. was sintered at a heating rate of $20^{\circ}C$/min, heterogeneous phase with bulgings, inner pores, and cracks were observed at the sintering temperature of $1200^{\circ}C$. Accordingly, heating patterns for the complete removal of the heterogeneous phase were proposed as countermeasures. The compressive strength of finally obtained aggregate was 670~870kg/$\textrm{cm}^2$, which is over two and a half times stronger than the minimum requirement of 200kg/$\textrm{cm}^2$.

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Synthesis of highly crystalline nanoporous titanium dioxide at room temperature (상온에서 고결정성 나노기공 이산화티탄 제조기술)

  • Chung, Pyung Jin;Kwon, Yong Seok
    • Journal of Energy Engineering
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    • v.25 no.2
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    • pp.65-78
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    • 2016
  • Initial studies of the photocatalyst has been developed from the field relating to the conversion and storage of solar energy. Recently, the study of the various organic decomposition compound and the water purification and waste water treatment by ultraviolet irradiation in the presence of light or a photocatalyst are being actively investigated. In addition, the oxidized material-carbon nanotubes, graphene-nanocomposites have been studied. Such a complex is suitable as a material constituting the solar cells and photolysis nanoelectronics, including the flexible element due to thermal and chemical stability.

Leaf epidermal structure of the Allium L. and its taxonomic significance (부추속(Allium L.) 잎 표피의 구조와 이의 분류학적 중요성)

  • Choi, Hyeok-Jae;Jang, Chang-Gee;Ko, Sung-Chul;Oh, Byoung-Un
    • Korean Journal of Plant Taxonomy
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    • v.34 no.2
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    • pp.97-118
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    • 2004
  • A comparative anatomical and ultrastructural study was undertaken to investigare on the leaf epidermis by light microscopy (LM) and scanning electron microscopy (SEM). On the basis of results from this study, it was grasped major characters of taxa and variation range of each character on the level of species, section and subgenus respectively. The shape of leaf epidermal cell was oblong to linear, which was varied by each taxon. Epidermal cell of taxa in sects. Microscordum, Anguinum, and Rhizirideum, which had wide leaf blade, oblong instead of linear shape in others examined taxa in this study. The leaf of taxa in sect. Anguinum was hypostomatic, while the rest of taxa had amphistomatic leaf. This was also one of characters which could discriminate taxa of sect. Anguinum from others. The guard cell in investigated taxa had not so much variation in the respect of its size. The number of stomata per unit area reduced by increasing size of epidermal cell, the fewest number of stomata per unit area was found in the taxa of sect. Anguinum. The type of stomatal apparatus of observed all taxa was anomocytic. It was found to know ultrastructural variation in the epidermal cell, like as patterns of sculpture on the cell wall, and features of deposition of wax by SEM. There were no depositions of wax in the taxa of sect. Microscordum and Anguinum, but fine thread-like structures which were parallel or cross to axis was found on the surface of epidermal cell respectively. The patterns of sculpture on the cell were prominent straight in sects. Recticulato-bulbosa and Rhizirideum, discontinuous line in the sect. Oreiprason. The epicuticular wax had been deposited on the surface of its epidermal cell in all taxa except sects. Microscordum and Anguinum.

A taxonomic study on genus Rhynchospora Vahl in Korea (한국산 골풀아재비속 3종의 분류학적 검토)

  • Oh, Yong Cha;Lee, Chang Shook
    • Korean Journal of Plant Taxonomy
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    • v.33 no.4
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    • pp.393-409
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    • 2003
  • Morphological and anatomical characters of selected 3 taxa of Rhynchospora were reexamined. The epidermal patterns of achene and leaf were investigated using a scanning electron microscope (SEM) and a light microscope (LM). Morphological characters such as length and width of bract, spikelet, scale, achene, stem, leaf and leaf sheath, and shape of inflorescence, spikelet, scale, apex of scale, perigynium and achene, and number of stigma and anatomical characters (transectional shape of the stem, and leaf: vascular bundles in stem and leaf epidermal patterns: shape of fundamental epidermal cell and cell wall, type of silica body, subsidiary cell shape, size and frequency of stomatal complex of leaf) were useful for the identification. Keys based on data were presented here.

Effect of Glass Composition on the Properties of Glass-Infiltrated Alumina (II) : Effect of La2O3 (유리침투 알루미나 복합체의 물성에 미치는 유리조성의 영향 (II) : La2O3의 영향)

  • Lee, Jae-Hee;Kim, Cheol-Young
    • Journal of the Korean Ceramic Society
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    • v.41 no.12 s.271
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    • pp.939-945
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    • 2004
  • Glasses of $SiO_2-B_{2}O_3-Al_{2}O_3-CaO-La_{2}O_3$ with various amounts of $La_{2}O_3$ were infiltrated into a porous alumina to make an alumina-glass composite. The infiltration characterization and bending strength of the composite were examined in terms of glass composition. $La_{2}O_3$ in the glass decreased the high temperature viscosity and this enhanced the wetting behaviour of this glass to alumina, and made glass infiltration easier. The infiltrated glass dissolved the alumina skeleton, and $Al_{2}O_3$ component in the glass melt reprecipitated on the alumina. The grain growth occurred to a specific crystal direction. The glass containing $20mole\%$ of $La_{2}O_3$ was crystallized after infiltration, and this enhanced the bending strength of the composite.

Effects of Silane-treated Silica on the Cure Temperature and Mechanical Properties of Elastomeric Epoxy (실란 커플링제로 처리된 실리카가 탄성에폭시의 경화온도 및 기계적 물성에 미치는 영향)

  • Choi, Sun-Mi;Lee, Eun-Kyoung;Choi, Seo-Young
    • Elastomers and Composites
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    • v.43 no.3
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    • pp.147-156
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    • 2008
  • In this work, epoxy/carboxyl-terminated butadiene acrylonitirile (EP/CTBN) composites were prepared by employing a reinforcing filler, silica treated with silane coupling agent in different ratio by dry and wet method. Their curing characteristics, surface free energy, interface morphologies and mechanical properties such as tensile strength and impact resistance were carefully investigated. Differential scanning calorimetry(DSC) results showed that curing temperature was lowered with the increase of silane coupling agent because of the increase of relative curing agent cotent by filling the pores of silica. Wet method was proved to be more effective for lowering curing temperature of EP/CTBN composite. In general, surface free energy and impact resistance were increased with the increase of silane coupling agent in this work. Tensile strength, however, was observed to be decreased at 4 wt% of silane coupling agent. It was found that the dry method was proved to be preferable for pretreatment of silica with coupling agent.

The Study on the Improvement of the Strength and the Thermal Shock Resistance of $Al_2O_3-ZrO_2$ Composites ($Al_2O_3-ZrO_2$ 복합체의 강도 및 열충격 저항의 향상에 관한 연구)

  • Hwang, K.H.;Bae, W.T.;Choi, M.D.;Oh, K.D.;Kim, K.U.;Kim, H.
    • Journal of the Korean Ceramic Society
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    • v.25 no.3
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    • pp.225-230
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    • 1988
  • The strength and thermal shock resistance of $Al_2O_3-ZrO_2$ composites have been studied. The tetragonal $ZrO_2$ powder containing 1 mol.% $Y_2O_3$ and monoclinic $ZrO_2$ powder were prepared by coprecipitation method and subsequently mixed with $Al_2O_3$ powder and granulated by sieving. Duplex composites were prepared by dry mixing matrix agglomerate with 15 to 30 vol.% of dispersion agglomerate, followed by pressing and sintering at 1$600^{\circ}C$ for1 hr. These $Al_2O_3-ZrO_2$ 2 composites having heterogeneous structure showed improved thermal shock behaviors because of the microcracking and pores in dispersed granules, and compressive stresses around dispersed granules resulting from $ZrO_2$ transformation.

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Synthesis of Fe3O4/porous Carbon Composite for Efficient Cu2+ Ions Removal (효과적인 Cu2+ 이온 제거를 위한 산화철(Fe3O4)/다공성 탄소 복합체 합성)

  • Seok, Dohyeong;Kim, Younghun;Sohn, Hiesang
    • Membrane Journal
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    • v.29 no.6
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    • pp.308-313
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    • 2019
  • In this study, the Fe3O4/porous carbon composite was synthesized by hydrothermal method for removal of Cu2+ ions and the characteristic of Cu2+ ions removal was performed. The Fe3O4/porous carbon composite was investigated via using SEM, XRD for its morphology and structure. BET analysis was conducted to conform a specific area and pore size distribution of the composite. For the investigation of the performance for removal of Cu2+ ions in the solution, UV-vis spectrometer was used. It suggests that a synergetic effect between magnetic Fe3O4 and porous carbon shows an improvement for removal of Cu2+ ions.

Microstructure and annealing effect on fracture behavior in the dental glass-infiltrated alumina (치아용 유리침윤 알루미나에서 파괴거동에 미치는 미세구조 및 어닐링 효과)

  • 정종원;최성철
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.4
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    • pp.330-336
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    • 2000
  • Effects of microstructure and indentation stress on fracture behavior of glass-infiltrated alumina composite for dental restorative application were investigated by the Hertzian and Vickers indentation method. Indentation stress-strain curve of glass-infiltrated alumina has showed the quasi-plastic behavior - deviation from linearity at high stress and the classical Hertzian cone crack, which could be confirmed the subsurface damage micrographs using bonded-interface specimen technique. The indentation stress-strain curves for the starting preforms are strongly dependent on porosity and microstructure of the preforms. On the other hand, the curves for the infiltrated composites are relatively insensitive to these factors. The failure of composite is originated at quasi-plastic deformation region. Damage and fracture behavior due to Hertzian stress field is theoretically examined, so that the indentation stress field plays a great role in material degradation. After Hertzian indentation annealing processing changes fracture behavior of alumina composite, so that stress field in material is healed through annealing.

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A taxonomic study on six sections Ischnostachyae, Anomalae, Capitellatae, Debiles, Capillares and Molliculae of Carex L. in Korea (Cyperaceae) (한국산 사초속 사초아속 (Carex subgen. Carex) 6절 식물의 분류학적 연구)

  • Oh, Yong Cha;Lee, Chang Shook;Yoon, Ja Young
    • Korean Journal of Plant Taxonomy
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    • v.34 no.4
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    • pp.297-319
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    • 2004
  • Morphological characters of 14 taxa in 6 sections Ischnostachya(one taxon), Anomalae(one taxon), Capitellatae (five taxa), Debiles (one taxon), Capillares (one taxon) and Molliculae (five taxa) of genus Carex (Cyperaceae) were reexamined. The epidermal patterns of perigynium, achene and leaf were investigated using by using a scanning eletron microscope (SEM) and a light microscope (LM). Morphological characters such as rhizome, spike, width of leaf, leaf sheath, involucre, involucre sheath, beak of perigynium, perigynium shape, and leaf epidermal patterns were useful for the identification of observed fourteen taxa. The number of spike, arrangement of psitillate or staminate spike and presence of bract were very useful characters to divide the treated 14 taxa into two groups. A key based on data was presented here.