• Title/Summary/Keyword: 기계적혼합층

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Gradient Structures and Surface Composition of Polypropylene/Ethylene-Propylene Rubber Blends (폴리프로필렌/에틸렌-프로필렌 고무 블렌드 경사구조 및 표면조성)

  • Kim, Seog Je;Lee, Sung-Goo;Lee, Jae Heung;Choi, Kil-Yeong
    • Journal of Adhesion and Interface
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    • v.2 no.4
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    • pp.24-31
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    • 2001
  • Polypropylenes(PP) with different melt index values were mixed with ethylene-propylene rubber(EPR) or ethylene-propylene diene monomer rubber(EPDM) and an ethylene copolymer containing carboxylic acid group in a twin screw extruder. Then test specimens were prepared from the pellets of the blends with an injection molding machine. The mechanical properties and morphology of fractured surfaces were measured. Relative peak intensities of carboxylic acid group on the specimen surface were measured with an attennuated total reflection infrared spectrometer (ATR-IR) and compared with each other. The blend specimens were found to have the gradient morphology of rubber domains in PP matrix in the core region and PP skin layer. The blends containing PP of higher melt index showed greater content of ethylene copolymer containing carboxylic acid on the surface when the relative peak intensities of ATR-IR for carboxylic acid were compared. As the melt index values were increased, the decrease tendency in mechanical propeties such as tensile strength and impact strength was more significant for PP/EPR blends than PP/EPDM blends.

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A Study on Physical and Mechanical Properties of Sawdustboards combined with Polypropylene Chip and Oriented Thread (폴리프로필렌사(絲)칩과 배향사(配向絲)를 결체(結締)한 톱밥보드의 물리적(物理的) 및 기계적(機械的) 성질(性質)에 관(關)한 연구(硏究))

  • Suh, Jin-Suk;Lee, Phil-Woo
    • Journal of the Korean Wood Science and Technology
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    • v.16 no.2
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    • pp.1-41
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    • 1988
  • For the purpose of utilizing the sawdust having poor combining properties as board raw material and resulting in dimensional instability of board, polypropylene chip (abbreviated below as PP chip) or oriented PP thread was combined with sawdust particle from white meranti(Shorea sp.). The PP chip was prepared from PP thread in length of 0.25, 0.5, 1.0 and 1.5 cm for conventional blending application. Thereafter, the PP chip cut as above was combined with the sawdust particle by 3, 6, 9, 12 and 15% on the weight basis of board. Oriented PP threads were aligned with spacing of 0.5, 1.0 and 1.5cm along transverse direction of board. The physical and mechanical properties on one, two and three layer boards manufactured with the above combining conditions were investigated. The conclusions obtained at this study were summarized as follows: 1. In thickness swelling, all one layer boards combined with PP chips showed lower values than control sawdustboard, and gradually clear decreasing tendendy with the increase of PP chip composition. Two layer board showed higher swelling value than one layer board, but the majority of boards lower values than control sawdustboard. All three layer boards showed lower swelling values than control sawdustboard. 2. In the PP chip and oriented thread combining board, the swelling values of boards combining 0.5cm spacing oriented thread with 1.0 or 1.5cm long PP chip in 12 and 15% by board weight were much lower than the lowest of one or three layer. 3. In specific gravity of 0.51, modulus of rupture of one layer board combined with 3% PP chip showed higher value than control sawdustboard. However, moduli of rupture of the boards with every PP chip composition did not exceed 80kgf/cm2, the low limit value of type 100 board, Korean Industrial Standard KS F 3104 Particleboards. Moduli of rupture of 6%, 1.5cm-long and 3% PP chip combined boards in specific gravity of 0.63 as well as PP chip combined board in specific gravity of 0.72 exceeded 80kgf/$cm^2$ on KS F 3104. Two layer boards combined with every PI' chip composition showed lower values than control sawdustboard and one layer board. Three layer boards combined with.1.5cm long PP chip in 3, 6 and 9% combination level showed higher values than control sawdustboard, and exceeded 80kgf/$cm^2$ on KS F 3104. 4. In modulus of rupture of PP thread oriented sawdustboard, 0.5cm spacing oriented board showed the highest value, and 1.0 and 1.5cm spacing oriented boards lower values than the 0.5cm. However, all PP thread oriented sawdustboards showed higher values than control saw-dustboard. 5. Moduli of rupture in the majority of PP chip and oriented thread combining boards were higher than 80kgf/$cm^2$ on KS F 3104. Moduli of rupture in the boards combining longer PP chip with narrower 0.5cm spacing oriented thread showed high values. In accordance with the spacing increase of oriented thread, moduli of rupture in the PP chip and oriented thread combining boards showed increasing tendency compared with oriented sawdustboard. 6. Moduli of elasticity in one, two and three layer boards were lower than those of control sawdustboard, however, moduli of elasticity of oriented sawdustboards with 0.5, 1.0 and 1.5cm spacing increased 20, 18 and 10% compared with control sawdustboard, respectively. 7. Moduli of elasticity in the majority of PP chip and oriented thread combining boards in 0.5, 1.0 and 1.5cm oriented spacing showed much higher values than control sawdustboard. On the whole, moduli of elasticity in the oriented boards combined with 9% or less combination level and 0.5cm or more length of PP chip showed higher values than oriented sawdustboard. The increasing effect on modulus of elasticity was shown by the PP chip composition in oriented board with narrow spacing. 8. Internal bond strengths of all one layer PP chip combined boards showed lower values than control sawdust board, however, the PP chip combined boards in specific gravity of 0.63 and 0.72 exceeded 1.5kgf/$cm^2$, the low limit value of type 100 board and 3kgf/$cm^2$, type 200 board on KS F 3104, respectively. And also most of all two, three layer-and oriented boards exceeded 3kgf/$cm^2$ on KS F. 9. In general, screw holding strength of one layer board combined with PP chip showed lower value than control sawdustboard, however, that of two or three layer board combined with PP chip did no decreased tendency, and even screw holding strength with the increase of PP chip composition. In the PP chip and oriented PP thread combining boards, most of the boards showed higher values than control sawdustboard in 9% or less PP chip composition.

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Study of Ignition Characteristics of CH4/Hot Air Diffusion Flame Using a Flame-Controlling Continuation Method (화염제어 연속계산법을 이용한 CH4-고온공기 확산화염의 점화특성 연구)

  • Song, Keum-Mi;Oh, Chang-Bo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.6
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    • pp.625-632
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    • 2011
  • The ignition characteristics of a $CH_4$/hot air counterflow diffusion flame were investigated numerically using a flame-controlling continuation method. For the chemical reactions, the GRI-v1.2 reaction mechanism was used in the simulation. The maximum flame temperature was presented in the space of the inverse global strain rate, and showed S-curve-type behavior. The flame temperatures and velocities of the upper and middle branches were compared for different global strain rates. In addition, the global strain rate was compared with the local strain rates defined at the flame surface and the boundaries of the fuel and oxidizer sides of the fuel/air mixing layer. These local strain rates correlated well with the global strain rate.

Large-scale structure of circular jet in transitional region at reynolds number of ${10}^{4}$ (Reynolds수 ${10}^{4}$일때 천이영역에서의 왼형제트의 Large-Scale 구조에 관한 연구)

  • 이택식;최은수
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.10 no.6
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    • pp.823-829
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    • 1986
  • The Large-scale structure of the circular jet in the transition region, which influences the subsequent flow in the turbulent region, was studied experimentally. Measuring equipments are composed of the two channel hot-wire anemometer, the computer controlled two-directional traverse mechanism, the data acquisition system, and FFT-analyzer. The circular jet has 50mm diameter. The mean velocity distribution, the velocity fluctuation, the auto 'cross correlations and the power spectra were acquired at moderate Reynolds number of 10$^{4}$. And the VITA method was used to measure the convection velocity of Large-scale eddy. The phase of u'is in advance of that of v'in all regions. .over bar. $R_{u}$(.tau.=0) is approximately zero in the potential core region, but a small regular deviation is observed. At a position in the mixing layer region the convection velocity is different along the part of the eddy, and in this experiment the convection velocity of the inner region is larger than the outer region. The averge convection velocity of the eddy along y/D=0 was approximately constant in the transition region.D=0 was approximately constant in the transition region.

Study on Elevator Induced Structural Vibration Reduction Performance Using Polymer Concrete (폴리머 콘크리트를 이용한 엘리베이터 기인 구조 진동저감 성능 연구)

  • Yeom, Jihye;Kim, Jeong-Jin;Park, Junhong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.25 no.6
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    • pp.90-94
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    • 2021
  • With the increased interest on quiescent place for residential place, the noise generation from facilities needs to be minimized. One important noise source include sounds from operation of elevators. The elevator operates between floors and generates significantly annoying sounds to the nearby living spaces. It is recognized as the significant contributor inducing noise annoyance to residents. Elevator is supported to the building structure at several locations for movements between floors. In this study, the vibration reduction by use of polymer concrete on the support location was demonstrated. By measuring and comparing the vibration generation when supported on cement and polymer concrete, the noise reduction performance was evaluated. The polymer concrete was made in the form of being inserted into the wall that imitates the hoistway. The impact vibration was induced to the bracket and vibration transfer magnitude was measured. The damping ratio was evaluated through normalization and curve fitting of transient response, and comparison was performed for each resin mixing ratio. By use of polymer concrete, it was possible to reduce the vibration generation in an effect manner without sacrifice on the structural rigidity.

Fabrication of Resistive Switching Memory based on Solution Processed AlOx - PMMA Blended Thin Film

  • Sin, Jung-Won;Baek, Il-Jin;Jo, Won-Ju
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.181.1-181.1
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    • 2015
  • 용액 공정을 이용한 Resistive random access memory (ReRAM)은 간단한 공정 과정, 대면적화, 저렴한 가격 등의 장점으로 인해 큰 관심을 받고 있으며, HfOx, TiOx, AlOx 등의 산화물이 ReRAM 절연 막으로 주로 연구되고 있다. 더 나아가 최근에는 organic 물질을 메모리 소자로 사용한 연구가 보고되고 있다. 이는 경제적이며, wearable 또는 flexible system에 적용이 용이하다. 그럼에도 불구하고, organic 물질을 갖는 메모리 소자는 기존의 산화물 소자에 비해 열에 취약하며 전기적인 특성과 신뢰성이 우수하지 못하다는 단점을 가지고 있다. 이를 위한 방안으로 본 연구에서는 AlOx - polymethylmethacrylate (PMMA) blended thin film ReRAM을 제안하였다. 이는 organic물질의 전기적 특성을 개선시킬 뿐 아니라, inorganic 물질을 wearable 소자에 적용했을 때 발생하는 crack과 같은 기계적 물리적 결함을 해결할 수 있는 새로운 방법이다. 먼저, P-type Si 위에 습식산화를 통하여 SiO2 300 nm 성장시킨 기판을 사용하여 electron beam evaporation으로 10 nm의 Ti, 100 nm의 Pt 층을 차례로 증착하였다. 그리고 PMMA 용액과 AlOx 용액을 초음파를 이용하여 혼합한 뒤, 이 용액을 Pt 하부 전극 상에서 spin coating방법으로 1000 rpm 10초, 5000 rpm 30초의 조건으로 증착하였다. Solvent 및 불순물 제거를 위하여 150, 180, $210^{\circ}C$의 온도로 30 분 동안 열처리를 진행하였고, shadow mask를 이용하여 상부 전극인 Ti를 sputtering 방식으로 100 nm 증착하였다. 150, 180, $210^{\circ}C$로 각각 열처리한 AlOx - PMMA blended ReRAM의 전기적 특성은 HP 4156B semiconductor parameter analyzer를 이용하여 측정하였다. 측정 결과 제작된 소자 전부에서 2 V이하의 낮은 동작전압, 안정된 DC endurance (>150cycles), 102 이상의 높은 on/off ratio를 확인하였고, 그 중 $180^{\circ}C$에서 열처리한 ReRAM은 더 높은 on/off ratio를 갖는 것을 확인하였다. 결론적으로 baking 온도를 최적화하였으며 AlOx - PMMA blended film ReRAM의 우수한 메모리 특성을 확인하였다. AlOx-PMMA blended film ReRAM은 organic과 inorganic의 장점을 갖는 wearable 및 system용 비휘발성 메모리소자에 적용이 가능한 경제적인 기술로 판단된다.

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Electrodeposition of Copper on Porous Reticular Cathode (II) - Effect of PEG and MPS on throwing Power- (다공성 그물구조 음극을 이용한 구리 전착에 관한 연구 (II) -유기첨가제 PEG, MPS의 영향 -)

  • Lee Kwan Hyi;Lee Hwa Young;Jeung Won Young
    • Journal of the Korean Electrochemical Society
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    • v.4 no.2
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    • pp.41-46
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    • 2001
  • The effect of organic additives such as PEG ind MPS on throwing power have been studied in the fabrication of porous reticular metal by electrodeposition using the mixture of cupric sulfate and sulfuric acid as electrolyte. Both the polarization test and the electrodeposition on the stacked electrodes, mean pore diameter of which was $250{\mu}m$, were performed to illustrate the behavior of throwing power quantitatively. As far as PEG was concerned, it lowered throwing power of electrodeposition on the porous electrode used in this work while the addition of MPS up to 500 ppm in electrolyte enhanced throwing power monotonously. When both MPS and PEG were added in electrolyte, the effect of MPS on throwing power was superior to that of PEG. However, the excess addition of MPS was found to cause the defect in mechanical strength of deposit layer. From the result of SEM observation, it could be concluded that less than 50 ppm of MPS in electrolyte was appropriate to avoid the breakage of deposit layer.

Thermal and Mechanical Evaluation of Environmental Barrier Coatings for SiCf-SiC Composites (SiCf-SiC 복합재료의 내환경 코팅 및 열, 기계적 내구성 평가)

  • Chae, Yeon-Hwa;Moon, Heung Soo;Kim, Seyoung;Woo, Sang Kuk;Park, Ji-Yeon;Lee, Kee Sung
    • Composites Research
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    • v.30 no.2
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    • pp.84-93
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    • 2017
  • This study investigates thermal and mechanical characterization of environmental barrier coating on the $SiC_f-SiC$ composites. The spherical environmental barrier coating (EBC) powders are prepared using a spray drying process for flowing easily during coating process. The powders consisting of mullite and 12 wt% of Ytterbium silicate are air plasma sprayed on the Si bondcoat on the LSI SiC fiber reinforced SiC composite substrate for protecting the composites from oxidation and water vapor reaction. We vary the process parameter of spray distance during air plasma spray of powders, 100, 120 and 140 mm. After that, we performed the thermal durability tests by thermal annealing test at $1100^{\circ}C$ for 100hr and thermal shock test from $1200^{\circ}C$ for 3000 cycles. As a result, the interface delamination of EBC never occur during thermal durability tests while stable cracks are prominent on the coating layer. The crack density and crack length depend on the spray distance during coating. The post indentation test indicates thermal tests influence on the indentation load-displacement mechanical behavior.

Questions and Solutions on Repair of Lime-Soil Consolidation in Traditional Buildings (전통 건축물 석회다짐층 보수 시공시의 문제점 및 개선 방안)

  • Kim, Jin-Man;Kwak, Eun-Gu;Suh, Man-Cheol;Cho, Heon-Young
    • 한국문화재보존과학회:학술대회논문집
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    • 2002.02a
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    • pp.21-31
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    • 2002
  • Lime-soil consolidations are very important as structural material, bonding material, waterproofing material, and finishing material in korea traditional buildings. In this study, we investigated site application trouble in korea traditional buildings being repaired or restored, and propose following solutions. 1) To diminish quality variation occurred by slaking quick-lime in site, it is desirable to use slaked-lime for lime-soil consolidation. 2) For uniform construction of lime-soil consolidation, we would recommend builders to use mixer to be uniform mixture, premixed type materials and compacting machine in field, 3) and to use rigid suitable temporary construction as scaffold for preventing traditional buildings from additional damage occurred in demolition and construction of a layer of lime-soil consolidation of a roofing. 4) For suitable repair of traditional buildings, it is necessary to specify definitely materials and construction methods suggested by the standard specifications for repair of the cultural property.

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Development of 400 kV Oil-filled Power Cable and Joints Insulated with Polypropylene Laminated Paper (400 kV급 반합성지 전력케이블 및 접속함 개발)

  • Youn, B.H.;Kim, D.W.;Kim, J.N.;Kim, Seong-Yun;Lee, S.J.;Kim, J.S.;Shin, H.Y.;Lee, I.H.;Lim, C.H.;Park, W.K.
    • Proceedings of the KIEE Conference
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    • 2006.10a
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    • pp.155-157
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    • 2006
  • 송전전압이 점차 초고압화되면서 절연체의 유전특성을 개선하여 송전용량을 향상시키고, 절연내력을 높여 케이블 외경을 저감시키려는 시도에 따라 우수한 유전특성 및 절연내력을 갖는 폴리머 절연층과 기계적 특성, 절연유와의 적합성이 우수한 크라프트지의 장점을 혼합시킨 반합성지가 개발되어 전력케이블의 주절연재료로 사용되고 있다. 본 논문은 LS전선이 국내최초로 개발한 400 kV급 반합성지 전력케이블 및 접속함 개발과정 및 이와 관련된 요소기술에 대해 기술하였다. 송전시스템에서 요구되는 유전특성의 반합성지를 설계 제작하여, 기존 크라프트 절연지 대비 유전손실은 50% 수준, 절연내력은 125%이상의 반합성지를 개발하였고, 반합성지 고유의 특성인 팽윤율을 조절하여 케이블을 제조하였다. 반합성지 절연 케이블에 필요한 접속함에서는 보강절연재로 케이블과 동일한 반합성지를 사용하여 전체적인 3기를 감소시키고, 열저항성을 줄이고자 노력하였다. 또한, 접속함 조립공정에 필요한 저온연공법을 개발하여 반합성지에 열적 스트레스를 최소화하였다. 상기 관련기술의 개발 결과로, IEC 60141, AEIC CS2-97 및 NGTS 3.5.1에 근거하여 400 kV급 반합성지 OF 케이블 및 접속함에 대해 국제 공인기관인 KEMA의부터 Type Test을 인증받았다.

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