• Title/Summary/Keyword: 근적상

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Growth of HgCdTe thin film by the hot-wall epitaxy method (Hot-wall epitaxy 방법에 의한 HgCdTe 박막 성장)

  • 최규상;정태수
    • Journal of the Korean Vacuum Society
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    • v.9 no.4
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    • pp.406-410
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    • 2000
  • Using the hot-wall epitaxy method, we grew a $Hg_{1-x}Cd_xTe$ (MCT) thin film in-situ after growing (111) CdTe of 9 $mu \textrm{m}$ as a buffer layer. The value of FWHM of double crystal x-ray diffraction rocking curve was 125 arcsec and the surface morphology was clean with a small roughness of 10 nm. From measuring the photocurrent of the grown MCT thin film, the maximum peak wavelength and the cut-off wavelength were 1.1050 $\mu\textrm{m}$ (1.1220 eV) and 1.2632 $\mu\textrm{m}$ (0.9815 eV), respectively. This peak wavelength corresponds to the peak of the band gap due to the intrinsic transition of the photoconductor. Therefore, the MCT thin film could be used as the photoconducting detector sensing a near-IR wavelength band from 1.0 to 1.6 $\mu\textrm{m}$.

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Performance evaluation of Terrestrial Laser Scanner over Calibration Baseline (표준거리측정 시설을 이용한 지상라이다 성능 평가)

  • Lee, In-Su;Lee, Jae-One
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.28 no.3
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    • pp.329-336
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    • 2010
  • This study deals with the measurement of reflectivity as well as the distance accuracy with Terrestrial Laser Scanner(TLS) using time of flight methods and near infrared wave length, for a variety of user-made targets. Especially, point clouds' reflection to several targets was measured with Gretag Macbeth il spectrophotometer in the office. And the distance accuracy in comparison to reference distance for TLS performance evaluation, was tested after scanning the user-made targets and measuring the inter-pillars distances over the precise EDM calibration baseline. The results of test was shown that except white resin objects, with approx. 10m and 170m inter-pillar distances, other targets achieved the distance accuracy of several millimeters(mm) with respect to standard distances. Future work should be concentrate on a few parameters influencing on the distance accuracy such as atmospheric correction, instrument correction, the additive constant or zero/index correction, etc.

은 도핑 효과를 이용한 그래핀 투명 전도성 필름의 전기적 특성 향상

  • Jeong, Sang-Hui;Lee, Su-Il;Kim, Yu-Seok;Song, U-Seok;Kim, Seong-Hwan;Cha, Myeong-Jun;Park, Sang-Eun;Min, Gyeong-Im;Park, Jong-Yun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.566-566
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    • 2012
  • 그래핀(Graphene)은 모든 탄소 동소체의 기본구성 요소로 2 차원 결정구조를 가지며, 양자홀 효과(quantum Hall effect), 뛰어난 열 전도도, 고 탄성, 광학적 투과성 등과 같은 탁월한 물리적 성질을 보이는 물질이다. 이러한 그래핀의 우수한 특성은 전계 효과 트랜지스터(field effect transistor), 화학/바이오 센서, 투명 전극(transparent electrode) 등의 다양한 전자소자를 개발하는 응용 가능하다. 그 중, 그래핀 투명전극의 제조는 가장 응용가능성이 높은 분야이다. 현재 투명전극 물질로는 인듐-주석 산화물(indium tin oxide; ITO)가 널리 이용되고 있으나, 인듐의 고갈로 인한 공급부족 문제 및 고 생산비용, 휘어지지 않는 취성 등의 단점을 지니고 있다. 따라서, 우수한 광학적 투과성과 전기전도성을 지닌 그래핀이 ITO의 대체 물질로서 각광받고 있다.[1-5] 본 연구에서는 그래핀의 투명전도필름의 응용을 위해 면저항을 낮추기 위한 방법으로 화학적 도핑(doping)을 이용하였다. 그래핀은 구리(copper; Cu) 호일을 촉매로 사용하여 열 화학증착법(Thermal Chemical Vapor Deposition)을 이용하여 합성하였다. 합성된 그래핀은 PMMA(Poly(methyl methacrylate)) 전사법을 이용하여 산화실리콘(SiO2) 기판에 전사 후, 염화은(AgCl)과 클로로벤젠(C6H5Cl)으로 만든 콜로이드(colloid) 용액에 디핑(dipping)하여 그래핀에 은 입자를 도핑 하였다. 그 결과, 은 입자 도핑 농도에 따라 면저항이 감소하는 양상을 보였다. 제작된 그래핀 투명전도성 필름의 투과도는 자외선-가시광선-근적외선 분광법(UV-Vis-NIR spectroscopy)를 이용하여 측정하였고, 라만 분광법(Raman spectroscopy)을 통해 그래핀 필름의 질적 우수성과 성장 균일도를 조사하였다.

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Determination of Diazepam in Intact Diazepam Tablets Using Near Infrared Spectroscopy (근적외선 분광법을 이용한 디아제팜정에서 디아제팜의 정량)

  • Choi, Hyun Cheol;Kang, Shin Jung;Youn, Mi Ok;Lee, Su Jung;Kim, Ho Jung;Kim, Ji Yeon;Cha, Ki Won
    • Analytical Science and Technology
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    • v.15 no.3
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    • pp.243-247
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    • 2002
  • A rapid and simple determination of diazepam in intact diazepam tablets has been investigated using the near infrared spectroscopy(NIRS) combined with partial least squares regession. The separate calibration curves of 2 mg and 5 mg diazepam tablets were studied, as well as the linearity, concentration range and reproducibility of those calibration curves were evaluated. The correlation coefficients of calibration curves of 2 mg and 5 mg diazepam tablets are 0.9416 and 0.9159, respectively and the standard errors of calibration curves(SEC) are 0.018% and 0.032%, respectively.

Changes of Volatile Components in Extracts of Bovine Bone Using an Electronic Nose and Fourier Transform-Near Infrared Spectrometer (전자코와 푸리에 변환 근적외선 분광기를 사용한 사골 추출물의 향기 성분 변화 분석)

  • Jang, Nak-Hoon;Cho, Yon Soo;Park, Su Won;Dong, Hyemin;Han, Hyun Jung;Noh, Bong-Soo
    • Korean Journal of Food Science and Technology
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    • v.46 no.6
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    • pp.734-738
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    • 2014
  • This study was conducted to investigate whether four hot-water extraction steps could effectively remove off-flavor from bovine bone extracts and produce compounds with pleasant aroma. Experiments were performed using a mass spectrometry-electronic nose and Fourier transform-near infrared spectrometer (FT-NIR). Off-flavor compounds were removed by washing and extraction with hot water. Steaming treatment produced compounds with a better aroma, such as 4-methylthiazole. In addition, a change in flavor compounds was observed in treated samples.

Infrared Absorption and Reflection Properties of Silver Nanoparticles Synthesized by Liquid Reduction Method (액상환원법을 이용하여 합성된 은 나노입자의 적외선 흡수 및 반사 특성)

  • Hong, Min Ji;Park, Min Ji;Kim, Jong Hwa;Rokade, Ashish A.;Jin, Young Eup;Lee, Gun-Dae;Park, Seong Soo
    • Applied Chemistry for Engineering
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    • v.28 no.5
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    • pp.587-592
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    • 2017
  • Uniform and optimum sized silver nanoplates were synthesized through the liquid phase reduction method by using silver nitrate solution as a starting chemical, dimethylformmide (DMF) as a reducing solvent, and polyvinylpyrrolidone (PVP) as reducing and surfactant agents. Synthesized and also film samples were characterized by using SEM, TEM, UV-Vis-NIR spectroscopy, particle size analyzer (PSA), and XRD. Triangle nanoplates with the size of 100~200 nm were found from the sample synthesized at $70^{\circ}C$ for 72 h using silver nitrate, DMF and 26 wt% PVP. The sample could reflect near-infrared light because it showed the maximum absorbing peak at about 1,000 nm. When the content or particle size of silver nanoplates increased in coating solutions, the transmittance decreased and the reflectance increased in film samples.

The Effect of Representative Dataset Selection on Prediction of Chemical Composition for Corn kernel by Near-Infrared Reflectance Spectroscopy (예측알고리즘 적용을 위한 데이터세트 구성이 근적외선 분광광도계를 이용한 옥수수 품질평가에 미치는 영향)

  • Choi, Sung-Won;Lee, Chang-Sug;Park, Chang-Hee;Kim, Dong-Hee;Park, Sung-Kwon;Kim, Beob-Gyun;Moon, Sang-Ho
    • Journal of Animal Environmental Science
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    • v.20 no.3
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    • pp.117-124
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    • 2014
  • The objectives were to assess the use of near-infrared reflectance spectroscopy (NIRS) as a tool for estimating nutrient compositions of corn kernel, and to apply an NIRS-based indium gallium arsenide array detector to the system for collecting spectra and analyzing calibration equations using equipments designed for field application. Partial Least Squares Regression (PLSR) was employed to develop calibration equations based on representative data sets. The kennard-stone algorithm was applied to induce a calibration set and a validation set. As a result, the method for structuring a calibration set significantly affected prediction accuracy. The prediction of chemical composition of corn kernel resulted in the following (kennard-stone algorithm: relative) moisture ($R^2=0.82$, RMSEP=0.183), crude protein ($R^2=0.80$, RMSEP=0.142), crude fat ($R^2=0.84$, RMSEP=0.098), crude fiber ($R^2=0.74$, RMSEP=0.098), and crude ash ($R^2=0.81$, RMSEP=0.048). Result of this experiment showed the potential of NIRS to predict the chemical composition of corn kernel.

Quantification of Melanin Density at Epidermal Basal Layer by Using Confocal Scanning Laser Microscope (CSLM) (Confocal Scanning Laser Microscope (CSLM)을 이용한 피부 기저층 멜라닌 밀도의 정량화)

  • Kim, Dong Hyun;Lee, Sung Ho;Oh, Myoung Jin;Choi, Go Woon;Yang, Woo Chul;Park, Chang Seo
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.40 no.3
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    • pp.259-268
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    • 2014
  • Non-invasive technologies in skin research have enabled to use a live image of living skin without a biopsy or histologic processing of tissue. Confocal scanning laser microscope (CSLM) operated at a near-infrared wavelength of 830 nm allows visualization of inner structure of skin as a non-invasive manner. According to previous researches using CSLM, melanin cap and papillary ring were clearly observed in pigmented areas between stratum basale and papillary dermis. In this study, conversional analysis of CSLM digital images into numerical estimation using scanning probe image processor (SPIP) software was attempted for the first time. It is concluded that a quantification of CSLM images can pave way to expand the field of applications of CSLM.

Hydrogen Bonding between Thioamides and Dimethylsulfoxide (DMSO) in $CCl_4$ ($CCl_4$속에서 Thioamides 와 Dimethyl Sulfoxide (DMSO) 사이의 수소 결합에 대한 연구)

  • Young-Lac Do;Seon-Jin Kim;Chang-Ju Yun;Young-Sang Choi
    • Journal of the Korean Chemical Society
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    • v.36 no.2
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    • pp.185-190
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    • 1992
  • Near-IR spectra for $ν_{\alpha}$+ Amide Ⅱ combination band of thioamides, and very dilute thioamide-DMSO solution in CCl4 were recorded in the temperature range of $5^{\circ}C$ to $55^{\circ}C$. This combination band was resolved by the computer program into two Lorentzian-Gaussian product function which have been identified with monomeric thioamide and thioamide-DMSO 1 : 1 complex. Equilibrium constants and thermodynamic parameters for the thioamide-DMSO hydrogen bonding were elucidated by the analysis of conce ntration and temperature dependent spectra. The hydrogen bonding strength between thioacetamide (TA) and DMSO in $CCl_4$ is stronger than that between thiopropionamide (TPA) and DMSO in CCl4. The ${\Delta}H^{\circ}$ for the TA-DMSO and TPA-DMSO 1 : 1 complex in CCl4 were -15.3 kJ${\cdot}$$mol^{-1}$ and -14.2 kj${\cdot}$$mol^{-1}$, respectively.

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A Study on the Thermochromic properties of Ti-doped Vanadium Dioxide (티타늄이 도핑된 이산화 바나듐의 열변색 특성에 관한 연구)

  • Park, Jin Wook;Park, Seong-Soo;Ahn, Byung Hyun;Hong, Seong-Soo;Lee, Gun Dae
    • Clean Technology
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    • v.21 no.4
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    • pp.235-240
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    • 2015
  • In this study, vanadium dioxide was doped with titanium (0~0.5 at %) to improve thermochromic properties. The titanium doped vanadium dioxide (Ti-VO2) particles were prepared via thermolysis process using vanadyl sulfate, ammonium bicarbonate and titianium chloride as precursors. The crystal structure, morphology, chemical bonding and thermochromic properties were investigated by using XRD, FE-SEM, XPS, DSC and UV-Vis-NIR spectroscopy. It was found that titanium was successfully doped into the crystal lattice of VO2 and the obtained Ti-VO2 particles have monoclinic structure. With increasing Ti concentration, the particle size and phase transition temperature of Ti-VO2 particles decreased and NIR switching efficiency increased.