Abstract
Near-IR spectra for $ν_{\alpha}$+ Amide Ⅱ combination band of thioamides, and very dilute thioamide-DMSO solution in CCl4 were recorded in the temperature range of $5^{\circ}C$ to $55^{\circ}C$. This combination band was resolved by the computer program into two Lorentzian-Gaussian product function which have been identified with monomeric thioamide and thioamide-DMSO 1 : 1 complex. Equilibrium constants and thermodynamic parameters for the thioamide-DMSO hydrogen bonding were elucidated by the analysis of conce ntration and temperature dependent spectra. The hydrogen bonding strength between thioacetamide (TA) and DMSO in $CCl_4$ is stronger than that between thiopropionamide (TPA) and DMSO in CCl4. The ${\Delta}H^{\circ}$ for the TA-DMSO and TPA-DMSO 1 : 1 complex in CCl4 were -15.3 kJ${\cdot}$$mol^{-1}$ and -14.2 kj${\cdot}$$mol^{-1}$, respectively.
사염화탄소 속에서 대단히 묽은 티오아미드 및 티오아미드-DMSO 용액의 $ν_{\alpha}$ + Amide II 조합띠에 대한 근적외선 스펙트럼을 $5^{\circ}C$ 와 $55^{\circ}C$ 사이에서 얻었다. 이 조합띠는 두 개의 Lorentzian-Gaussian product 함수로 분해되며, 각각은 단체 티오아미드 및 1 : 1 티오아미드-DMSO 복합체로 확인되었다. 티오아세트아미드(TA)와 DMSO 사이의 수소결합은 티오프로피온 아미드(TPA)와 DMSO 사이의 수소결합보다 약간 강하며 $CCl_4$ 속에서 TA-DMSO와 TPA-DMSO 1: 1 복합체에 대한 ${\Delta}H^{\circ}$는 각각 -15.3 kJ${\cdot}$$mol^{-1}$ 및 -14.2 kj${\cdot}$$mol^{-1}$이었다.