• 제목/요약/키워드: 광물학적 연구

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Heavy Metal Retention by Secondary Minerals in Mine Waste Rocks at the Abandoned Seobo Mine (서보광산 폐광석 내 2차 광물에 의한 중금속 고정화)

  • 이평구;강민주;최상훈;신성천
    • Economic and Environmental Geology
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    • v.36 no.3
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    • pp.177-189
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    • 2003
  • The main purposes of this study are to utilize mineralogical studies such as optical microscope, XRD and SEM/EDS analyses to characterize the oxidation of sulfide minerals and the mechanisms controlling the movement of dissolved metals from waste rocks at the abandoned Seobo mine. Mineralogical research of the waste rocks confirms the presence of anglesite, covellite, goethite, native sulfur and nsutite as secondary minerals, suggesting that these phases control the dissolved concentrations of As, Cu, Fe, Mn, Pb and Zn. The dissolved metals are precipitated, adsorbed and/or coprecipitated with(or within) Fe(Mn)-hydroxides and Mn(Fe)-hydroxides. The main phases of secondary mineral, Fe-hydroxide, can be classified as amorphous or poorly crystalline and more crystallized phases(e.g. goethite) by crystallinity. Amorphous or poorly crystalline Fe-hydroxide has relatively high As contents(9-24 wt.%). This poorly crystalline Fe-hydroxide changes toward more crystallized phase(e.g. goethite) which contains relatively low As(0.6-7.7 wt.%). These results are mainly due to the progressive release of As with the crystallization evolution of the As-trapping poorly crystalline Fe-hydroxides. It is also attributed to the differences of specific surface areas between the poorly crystalline Fe-hydroxides and well crystallized phases. The dissolved metals from waste rocks at Seobo mine area are naturally attenuated by a series of precipitation(as Fe, Mn, Cu, Pb), coprecipitation(Fe, Mn) and adsorption(As, Cu, Pb, An) reactions. The results of mineralogical researches permit to assess the environmental impacts of mine waste rocks in the areas, and can be used as a useful data to lay available mine restoration plan.

A Study on the Making Properties of Natural Pigments based on Substance Characteristics for Hwangto in Korea (국내 산출되는 황토의 특징에 따른 천연(제조)안료 특성연구)

  • Mun, Seong Woo;Kang, Yeong Seok;Park, Ju Hyun;Han, Min Su;Jeong, Hye Young
    • Journal of Conservation Science
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    • v.35 no.6
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    • pp.600-611
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    • 2019
  • Yellow to reddish brown soil is generally referred to as hwangto and is used in various industries in Korea. Despite the fact that it is used as an inorganic pigment in dancheong, limited studies have been conducted on the properties of pigments associated with soil and on the mineralogical characteristics of hwangto. This study examines how the pedological and mineralogical features of hwangto affect pigment properties. Results indicate that reddish and yellowish soils have differences in terms of soil texture, mineral composition, oil absorption and stability under light. Reddish soil is mostly found in clay regions, whereas Ulleungdo hwangto is found in loam regions. Yellowish soil is mostly present in the clay loam to loam zones. whereas Haenam hwangto exists in the sandy clay loam zone. As a result of a mineralogical analysis, reddish soil is classified into the feldspar group and clay soil. The major minerals in the yellowish soils are similar however these soils differ in terms of clay mineral compositions. results of the characteristics of pigments prepared by the traditional method revealed that the average particle size is in the range of 10-20 ㎛, reddish soil has an average of 20 ml/100 g higher oil absorption than yellowish soil. In addition, reddish soil is more susceptible to discoloration and deterioration under light than yellowish soil. This study confirms that the soil and mineral characteristics of hwangto affect the physical properties and stability of produced pigments. These result can be used as basic data in future studies natural inorganic pigments using hwangto.

Introduction of Numerical Analysis Method for Calculation of Diffusion Property in Interlayer Water of Expansible Clay Mineral (팽창성 점토광물 내 층간수의 확산특성분석을 위한 수치해석학적 방법)

  • Choi, Jung-Hae;Chae, Byung-Gon;Chon, Chul-Min
    • Journal of the Mineralogical Society of Korea
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    • v.25 no.4
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    • pp.211-220
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    • 2012
  • The numerical modeling and simulation have been used increasingly as tools for examining and interpreting the bulk structure and properties of materials. The use of molecular dynamics (MD) simulations to model the structure of materials is now both widespread and reasonably well understood. In this research, we introduced the numerical method to calculate the physico-chemical properties such as a diffusion coefficient and a viscosity of clay mineral. In this research, a series of MD calculations were performed for clay mineral and clay-water systems, appropriate to a saturated deep geological setting. Then, by using homogenization analysis (HA), the diffusion coefficients are calculated for conditions of the spatial distribution of the water viscosity associated with some configuration of clay minerals. This result of numerical analysis is quite similar to the previous experimental results. It means that the introduced numerical method is very useful to calculate the physico-chemical properties of clay minerals under various environmental conditions.

The Oxidation of Chalcopyrite and Geochemical Behavior of Heavy Metals in the Manjang Cu Mine (만장광산에서 산출되는 황동석의 산화과정과 중금속 거동 특성)

  • 이평구;이인경;최상훈;김지수
    • Economic and Environmental Geology
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    • v.37 no.3
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    • pp.291-301
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    • 2004
  • In order to charaterize weathering of chalcopyrite and behavior of dissolved metal ions in waste rocks from Manjang Cu mine, mineralogical studies such as refractive microscope, XRD and SEM/EDS analyses carried out. The weathering was mainly occurred in fractures and edge of the chalcopyrite within the mine waste rocks. The weathering process can be seen to reflect four stages based on the weathering degree of chalcopyrite. The main secondary minerals are goethite, covellite, azurite, malachite and brochantite. Dissolved Cu and As were mainly adsorbed Fe-hydroxide. Poorly crystalline Fe-oxide contains relatively high As contents. In oxdizing condition, the weathering of chalcopyrite mainly occurs along the fracture, while the replacement of chalcopyrite observed mainly in the grain and produced covellite and brochantite. The dissolved metals (Cu, Fe, As) in waste rocks from the abandoned Manjang mine area could attenuate naturally by precipitation, adsorption and replacement reaction.

Mineralogical Characteristics and Removal of Heavy Metals from Gum-poong Mine Tailings (금풍광산(鑛山) 광물(鑛物)찌꺼기의 광물(鑛物)학적 특성(特性) 및 중금속(重金屬) 제거(除去))

  • Cha, Jongmun;Park, Jayhyun;Kang, Heon Chan
    • Resources Recycling
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    • v.21 no.6
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    • pp.51-57
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    • 2012
  • The objective of this study was to research the mineralogical characteristics and removal of heavy metals of tailings from Gum-poong mine. From the result of mineralogical analysis, there are several sulphide minerals such as chalcocite, aresenopyrite, pyrite, sphalerite and galena. Cd and Zn have a good positive correlation from the statistical relation between Cd and other heavy metals(Cu, Pb, Zn). Residual heavy metals(As, Cd, Cu, Pb, Zn) from the Gum-poong tailings were removed under the warning criteria from the result of froth flotation with K.A.X.(Potassium Amyl Xanthate) and Aerofloat 211.