• Title/Summary/Keyword: 과잉 사용

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Isobaric Vapor-Liquid Equilibrium of Toluene and Cresol Systems (톨루엔-크레졸의 정압 기-액 평형)

  • Kang, Dong-Yuk;Jang, Hoi-Gu;Han, Chang-Nam;Rho, Seon-Gyun;Cho, Dong Lyun;Kang, Choon-Hyoung
    • Korean Chemical Engineering Research
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    • v.47 no.6
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    • pp.755-761
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    • 2009
  • To a first approximation, phase behavior of a system becomes increasingly skew in proportion to the boiling point difference of system-forming constituents. Therefore, phase behavior data of a system of a large boiling point difference are to be experimentally measured for thorough understanding of the thermodynamic characteristics of such system. In this work, isobaric vapor-liquid equilibrium of a mixture consisting of toluene and cresol, which shows a large boiling point difference of nearly $100^{\circ}C$ and is consequently expected to be considerably nonideal, was measured by using a recirculating equilibrium cell at various subatmospheric pressures ranging from 10 kPa to 60 kPa. The measured VLE data were correlated with NRTL and UNIQUAC models in a satisfactory manner and the accompanying thermodynamic consistency test represented soundness of the measurements. In addition, the excess molar volume of the mixture was also measured with a vibrating densitometer and correlated with a Redlich-Kister polynomial. A negative excess volume prevailed over the whole concentration range, which indicates a favorable attraction between toluene and cresol isomers and results in an extensive miscibility.

Biological Activities of Rosaceae Plants Extracts (장미과 식물 추출물의 생물학적 활성)

  • Seo Jeong Min;Ahn Jeung-Youb
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.30 no.4 s.48
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    • pp.499-502
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    • 2004
  • DPPH radical-generating system was used to evaluate the antioxidant properties of the Rosaceae. The inhibitory effects of ethanolic extracts from Rosaceae plants were investigated on melanin biosynthesis which is closely related to hyperpigmentation. Of the Rosaceae extracts, Prunus sargentii, Rubus coreanus, Chaenomeles sinensis, Photinia glabra and Pyrus pyrifolia showed a potent inhibition of tyrosinase, the enzyme which converts 3-(3,4-dihydroxyphenyl) alanine (dopa) to dopachrome in the melanin biosynthetic process. Furthermore, MMT assay was used to check the cytotoxicity of extracts on the human foreskin fibroblast cell line, Hs68. Among the Rosaceae, bark of Prunus sargentii, bark wood of Photinia glabra and all parts or Chaenomeles sinensis showed more than $50\%$ inhibition of mushroom tyrosinase activity at 100 ug/mL and more than $80\%$ of strong DPPH radical-scavenging activity at 10 ug/mL. In audition to, they had no cytotoxic activity on Hs68. These results suggest that these extracts might be except a controler in pigmentation.

Isolation and Quantitative Analysis of Flavonoids with Peroxynitritescavenging Effect from the Young Leaves of Heracleum moellendorffii (어수리 어린 잎으로부터 Peroxynitrite 소거활성을 나타내는 플라보노이드 성분의 분리 및 함량분석)

  • Park, Hee-Juhn;Nugroho, Agung;Jung, Bo-Ram;Won, Yu-Hwa;Jung, Youn-Ju;Kim, Won-Bae;Choi, Jae-Sue
    • Korean Journal of Plant Resources
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    • v.23 no.5
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    • pp.393-398
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    • 2010
  • Naturally occurring substances which strongly scavenge peroxynitrite(ONOO-) are evaluated to be beneficial for cardiovascular, diabetic, hypercholesterolemic and obese disease. To search for bioactive substances with peroxynitritescavenging activity from the young leaves of Heracleum moellendorffii(Umbelliferae) used for a mountainous vegetable, the experiment on peroxynitrite-scavenging assay, phytochemical isolation and HPLC analysis were undertaken. Activity-guided fractionation led to the separation of astragalin and hyperoside which were identified by physicochemical and spectroscopic data. The $IC_{50}$ values of astragalin and hyperoside were shown as $5.80{\pm}0.62$ and $0.560{\pm}0.26\;{\mu}M$, respectively, in the assay. The HPLC analysis led to the quantitative determination of astragalin and hyperoside by $30.0{\pm}0.01$ and $17.0{\pm}0.02\;mg/g$ dried weight, respectively.

Relationship between Internet Game Addiction and Psychiatric Symptoms in a Child and Adolescent Psychiatric Clinic (일 대학병원 소아청소년 정신건강클리닉에 내원한 청소년에서 인터넷게임중독과 정신과적 증상의 관계)

  • Oh, Eun-Jeong;Choi, Sam-Wook;Lee, Hae-Kook;Park, Jang-Ho;Ahn, Joon-Ho;Choi, Ji-Eun;Bhang, Soo-Young
    • Journal of the Korean Academy of Child and Adolescent Psychiatry
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    • v.25 no.3
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    • pp.136-141
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    • 2014
  • Objectives : The aim of this study was to examine the relationship between internet game addiction and psychiatric symptoms. Methods : A total of 447 adolescents who were recruited from a child and adolescent psychiatric clinic of university hospital completed a self-report questionnaire consisting of Korean Internet Addiction Self-scale (K-scale), Beck Depression Inventory (BDI), Beck Anxiety Inventory (BAI), Korean-Attention-Deficit Hyperactivity Disorder Rating Scale (K-ARS), and Adolescent Happiness Index (AHI). They were classified into three internet user groups, non-addicted group (below or equal to 94), potential risk group (95 to 107) and high risk group (above or equal to 108) according to K-scale total score. Results : Significant mean differences in BDI, BAI, K-ARS, and AHI scores were observed among the three groups. The BDI, BAI and K-ARS scores showed positive correlation with K-score. The AHI score showed negative correlation with K-score. Conclusion : Findings of this study suggest that depression, anxiety, inattention, hyperactivity/impulsivity, and happiness are associated with internet game addiction.

Microscopy Study for the Batch Fabrication of Silicon Diaphragms (실리콘 Diaphragm의 일괄 제조공정을 위한 Microscopy Study)

  • 하병주;주병권;차균현;오명환;김철주
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.29A no.1
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    • pp.33-40
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    • 1992
  • Several etching phenomena were observed and analyzed in diaphragm process performed on 4-inch (100) Si wafers for sensor application. In case of deep etching to above 300$\mu$m depth, the etch-defects appeared at etched surface could be classified into three categories such as hillocks, reaction products, and white residues. It was known that the hillock had a pyramidal shape or trapizoidal hexahedron structure depending on the density and size of the reaction products. The IR spectra showed that the white residue, which was due to the local over-saturation of Si dissolved in solution, was mostly Si-N-O compounds mixed with a small amount of H and C etc. Also, the difference in both the existence of etch-defects and etch rate distribution over a whole wafer was investigated when the etched surfaces were downward, upward horizontally and erective in etching solutions. The obtained data were analyzed through flow pattern in the etching bath. As the results, the downward and erective postures were favorable in the etch rate uniformity and the etch-defect removal, respectively.

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Selective Catalytic Reduction of NOx with Ammonia over Cu and Fe Promoted Zeolite Catalysts (구리 제올라이트와 철 제올라이트 촉매에 의한 질소산화물의 암모니아 선택적 촉매환원반응 특성)

  • Ha, Ho-Jung;Hong, Ju-Hwan;Choi, Joon-Hwan;Han, Jong-Dae
    • Clean Technology
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    • v.19 no.3
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    • pp.287-294
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    • 2013
  • The $NH_3$-selective catalytic reduction (SCR) reaction of NO with excess of oxygen were systematically investigated over Cu-zeolite and Fe-zeolite catalysts. Cu-zeolite and Fe-zeolite catatysts to adapt the SCR technology for mobile diesel engines were prepared by liquid ion exchange and incipient wetness impregnation of $NH_4$-BEA and $NH_4$-ZSM-5 zeolites. The catalysts were characterized by BET, XRD, FE-TEM (field emission transmission electron microscopy) and SEM/EDS. The SCR examinations performed under stationary conditions showed that the Cu-exchanged BEA catalyst revealed pronounced performance at low temperatures of $200{\sim}250^{\circ}C$. With respect to the Fe-zeolite catalyst, the Cu-zeolite catalyst showed a higher activity in the SCR reaction at low temperatures below $250^{\circ}C$. BEA zeolite based catalyst exhibited good activity in comparison with ZSM-5 zeolite based catalyst at low temperatures below $250^{\circ}C$.

Development of Power Supply for Voltage-Adaptable Converter to Drive Linear Amplifiers with Variable Loads (가변부하를 갖는 선형 증폭기를 구동하기 위한 전압적응 변환기용 전력공급기 개발)

  • Um, Kee-Hong
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.14 no.6
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    • pp.251-257
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    • 2014
  • An actuator system is a type of motor designed to control a mechanism operated by a source of energy, in the form of an electric current by converting energy into some kind of motion. As audio actuators, transforming electric voltage signal into audio signal, speakers and amplifiers are commonly used. In applications of industry, high output power systems are required. For these systems to generate high-quality output, it is essential to control output impedance of audio systems. We have developed an adaptable power supply for driving active amplifier systems with variable loads. Depending on the changing values of resistance of the speaker which produces audible sound by transforming electric voltage signal, the power supply source of the active amplifier can generate the maximum power delivered to the speaker by an adaptable change of loads. The amplifier is well protected from the abrupt increment of peak current and an excess of current flow.

Determination of Consolidation Characteristics of Clayey Soils from the Self-boring Pressuremeter Test (자가굴착식 프레셔미터 시험을 이용한 점성토의 압밀특성 산정)

  • 장인성;정충기;김명모;조성민
    • Journal of the Korean Geotechnical Society
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    • v.18 no.2
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    • pp.87-96
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    • 2002
  • The strain holding test(SHT) or the sell-boring pressuremeter test(SBPT) has been effectively utilized to determine the horizontal coefficient of consolidation$(c_h)$ of clayey soils. However, a commonly used procedure proposed by Clarke et al.(1979) can lead to an erroneous estimation of $(c_h)$ because of its simplified assumptions. This paper deals with numerical analyses based on realistic test conditions of the generally accepted testing procedure, and .using the most commonly used type of pressuremeter. The effects of pressuremeter geometry, partial drainage during cavity expansion, and the cavity strain level for the holding test are investigated with the radial distributions of the initial excess pore pressure and their dissipation rate. Based on the results of the numerical analyses, the curve of the time factor for the 50% degree of consolidation($T_{50}$) needed to estimate $(c_h)$ is proposed. Comparisons are made between $(c_h)$ values estimated from the SHT or the SBPT and those obtained from other in situ and laboratory tests performed at two sites in Korea. These results suggest the improved capability of the $T_{50}$ curve proposed herein.

Deuterium Ion Implantation for The Suppression of Defect Generation in Gate Oxide of MOSFET (MOSFET 게이트 산화막내 결함 생성 억제를 위한 효과적인 중수소 이온 주입)

  • Lee, Jae-Sung;Do, Seung-Woo;Lee, Yong-Hyun
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.45 no.7
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    • pp.23-31
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    • 2008
  • Experiment results are presented for gate oxide degradation under the constant voltage stress conditions using MOSFETs with 3-nm-thick gate oxides that are treated by deuterium gas. Two kinds of methods, annealing and implantation, are suggested for the effective deuterium incorporation. Annealing process was rather difficult to control the concentration of deuterium. Because the excess deuterium in gate oxide could be a precursor for the wear-out of gate oxide film, we found annealing process did not show improved characteristics in device reliability, compared to conventional process. However, deuterium implantation at the back-end process was effective method for the deuterated gate oxide. Device parameter variations as well as the gate leakage current depend on the deuterium concentration and are improved by low-energy deuterium implantation, compared to those of conventional process. Especially, we found that PMOSFET experienced the high voltage stress shows a giant isotope effect. This is likely because the reaction between "hot" hole and deuterium is involved in the generation of oxide trap.

Optimal Associative Neighborhood Mining using Representative Attribute (대표 속성을 이용한 최적 연관 이웃 마이닝)

  • Jung Kyung-Yong
    • Journal of the Institute of Electronics Engineers of Korea CI
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    • v.43 no.4 s.310
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    • pp.50-57
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    • 2006
  • In Electronic Commerce, the latest most of the personalized recommender systems have applied to the collaborative filtering technique. This method calculates the weight of similarity among users who have a similar preference degree in order to predict and recommend the item which hits to propensity of users. In this case, we commonly use Pearson Correlation Coefficient. However, this method is feasible to calculate a correlation if only there are the items that two users evaluated a preference degree in common. Accordingly, the accuracy of prediction falls. The weight of similarity can affect not only the case which predicts the item which hits to propensity of users, but also the performance of the personalized recommender system. In this study, we verify the improvement of the prediction accuracy through an experiment after observing the rule of the weight of similarity applying Vector similarity, Entropy, Inverse user frequency, and Default voting of Information Retrieval field. The result shows that the method combining the weight of similarity using the Entropy with Default voting got the most efficient performance.