• Title/Summary/Keyword: 과잉 사용

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TEM and Raman Spectrum Characterization of 3C-SiC/Si(001) Heterostructure Grown by Chemical Vapor Deposition (화학증착 방법으로 Si(001)기판 상에 성장된 3C-SiC 이종접합 박막의 투과전자현미경 및 라만 특성분석)

  • Kim, Dong-Geun;Lee, Byeong-Taek;Mun, Chan-Gi;Kim, Jae-Geun;Jang, Seong-Ju
    • Korean Journal of Materials Research
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    • v.7 no.8
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    • pp.654-659
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    • 1997
  • HMDS[Si$_{2}$(CH$_{3}$)$_{6}$]단일 선구체를 이용하여 화학증착 방법으로 성장된 3C-SiC/Si(001) 이종접합박막의 특성을 XRD, 라만 스펙트럼 및 투과전자현미경(TEM)등을 이용하여 조사하였으며 시판되고 있는 상용 3C-SiC/Si 시편을 같은 방법으로 분석하여 특성을 비교검토하였다. $C_{3}$H$_{8}$-SiH$_{4}$-H$_{2}$혼합가스를 선구체로 이용하여 5$\mu\textrm{m}$두께로 성장된 상용 3C-SiC/Si 이종접합박막 시료의 XRD스펙트럼에서는 강한 3C-SiC(002)피크 만이 관찰되었으며, 라만 스펙트럼의 LO피크는 970nm$^{-1}$ 정도에서 강하게 나타났다. TEM 관찰 결과 다수의 전위, 쌍정, 적층결함 및 APB와 같은 결정결함들이 3C-SiC/Si 계면 근처에 집중적으로 분포되어 있었으며 성장된 박막은 단결정임을 확인할 수 있었다. 선구체로 HMDS를 사용하여 0.3$\mu\textrm{m}$ 및 2$\mu\textrm{m}$ 두께로 성장시킨 3C-SiC/Si 박막 시료의 XRD 스펙트럼은 다소 완만한 3C-SiC(002) 피크와 함께 3C-SiC(111)피크가 관찰되었으며, TEM으로 확인한 결과 소경각 결정립들이 약 5˚-10˚ 정도 방위차를 가지고 성장하여 기둥구조(columnar structure)를 이루고 있기 때문임을 알 수 있었다. 라만 스펙트럼 분석 결과 박막의 LO 피크가 967-969nm$^{-1}$정도로 다소 낮은 wavenumber쪽으로 이동되어 박막 내에 상당한 응력이 존재함을 확인할 수 있었다. 이와 같은 HMDS 3C-SiC박막의 특성은 성장 온도가 낮고 박막 성장용 가스로 사용한 HMDS 선구체에서 탄소가 과잉으로 공급되기 때문으로 제안되었다.다.

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Numerical Analysis for Consolidation of Compressible Soils (압축성 모의 압밀에 대한 수치해석 -다층토를 중심으로-)

  • Kim, Pal-Gyu;Song, Yong-Hui;Lee, Hwan-Gi
    • Geotechnical Engineering
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    • v.1 no.1
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    • pp.5-12
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    • 1985
  • Ocassionally it is used for simple extensions of Terzahgi's theory to account for time-depend- tint loading but there is little evidence of application in more complicated consolidation theories that take into account such effects as nonlinear stress.strain, layered systems or large strains. The purpose of this paper provides an efficient computer algorthm based on numerical analysis using finite difference method which account for multi-layered soils to determine the degree of consolidation and excess pore pressures relative to time and positions more realistically. The explicitly scheme of solving the consolidation equations has been investigated from the point of view of the stability conditions and the convergence with variance of the operator as well as to obtain an optimal divided depth ratios of total depth. A comparison of the settlement predictions with both the classical analysis and the algorithm based on numerical analysis indicates that the new algorithm scheme is found to be superior to the classical theory in the layered soils.

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Environmental Stress Strategies for Stimulating Lipid Production from Microalgae for Biodiesel (바이오디젤용 지질 생산을 위한 미세조류 배양에서 환경 스트레스 조건의 활용 전략)

  • Kim, Garam;Mujtaba, Ghulam;Rizwan, Muhammad;Lee, Kisay
    • Applied Chemistry for Engineering
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    • v.25 no.6
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    • pp.553-558
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    • 2014
  • Microalgae are a promising alternative feedstock for biodiesel production because their growth rates and oil contents are higher than those of conventional energy crops. Microalgal lipid is mainly triacylglyceride that can be converted to biodiesel as fatty acid methyl esters through trans-esterification. In this paper, the influence of several important lipid inducing factors such as nutrient limitation and changes in salinity and metallic components in microalgae and their potential strategies to be used for biodiesel production are reviewed. Depending upon strains/species that we use, microalgae react to stresses by producing different amount of triacylglyceride and/or by altering their fatty acids composition. Although the most widely applied method is the nitrogen starvation, other potential factors, including nutrient surplus conditions and changes in salinity, pH, temperature and metal concentrations, should be considered to increase biodiesel productivity.

Effect of Injector Cooling on Ignition of Cryogenic Spray (분사기 냉각이 초저온 분무의 점화에 미치는 영향)

  • Kim, Do-Hun;Lee, Jin-Hyuk;Koo, Ja-Ye
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.40 no.3
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    • pp.222-229
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    • 2012
  • The cooling of a injector effects on the vapor pressure of cryogenic oxidizer spray, and it decides the phase transition point at the ignition process, when the combustion chamber pressure increases drastically. The phase transition of oxidizer spray affects the ignition characteristics, and several ignition tests with the LOx/$GCH_4$ uni-element coaxial swirl injector was performed in the different initial temperatures of oxidizer injector, in order to investigate the effect of injector cooling on the ignition transient characteristics. At the transition point of oxidizer phase, where the combustion chamber pressure increased over the LOx vapor pressure, the temporary quenching phenomenon of the flame occurred. The lower temperature of chilled down injector and tubing tends to move up the phase transition earlier.

Numerical Modeling of Soil Liquefaction at Slope Site (사면에서 발생하는 액상화 수치해석)

  • Park, Sungsik
    • Journal of the Korean GEO-environmental Society
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    • v.7 no.6
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    • pp.133-143
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    • 2006
  • A fully coupled effective stress dynamic analysis procedure for modeling seismic liquefaction on slope is presented. An elasto-plastic formulation is used for the constitutive model UBCSAND in which the yield loci are radial lines of constant stress ratio and the flow rule is non-associated. This is incorporated into the 2D version of Fast Lagrangian Analysis of Continua (FLAC) by modifying the existing Mohr-Coulomb model. This numerical procedure is used to simulate centrifuge test data from the Rensselaer Polytechnic Institute (RPI). UBCSAND is first calibrated to cyclic direct simple shear tests performed on Nevada sand. Both pre- and post-liquefaction behaviour is captured. The centrifuge test is then modeled and the predicted accelerations, excess porewater pressures, and displacements are compared with the measurements. The results are shown to be in general agreement. The procedure is currently being used in the design of liquefaction remediation measures for a number of dam, bridge, tunnel, and pipeline projects in Western Canada.

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Design of Water Gas Shift Reactor for Rapid Start-Up in 200 W Portable Fuel Cell System (200 W급 휴대용 연료전지 시스템의 빠른 기동 특성을 위한 수성 가스 반응기 설계)

  • Choi, Jong-Rock;Lee, Sungchul
    • Korean Chemical Engineering Research
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    • v.51 no.4
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    • pp.455-459
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    • 2013
  • The fuel processor for the portable fuel cell includes multi-step processes consisting of hydrogen generator, heat generator and several CO clean-up stages. One of requirements of the fuel processor for portable fuel cell system is a rapid start-up time. Especially, the warm-up time for WGS reactor is crucial factors for total start-up time. In this paper, active heating protocol, which is the heating protocol of WGS reactor supplied by the oxidation of CO rich reformate in the initial stage, is used for a rapid start-up. The air stream fed to the inlet of WGS reactor rapidly oxidize the CO rich reformate in the WGS reactor. Therefore, CO concentration in reformate quickly stabilized at the desired concentration without CO surges.

The System Reliability Analysis of Web Frame by Plastic Strength Analysis (소성 강도 해석에 의한 Web Frame의 시스템 신뢰성 해석)

  • Y.S. Yang;S.J. Yim
    • Journal of the Society of Naval Architects of Korea
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    • v.28 no.2
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    • pp.251-267
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    • 1991
  • Plastic strength analysis using plastic failure mode as a limit state is adopted instead of a conventional elastic structural analysis to predict the ultimate strength of Web frame idealized by a plane frame. Linear programming arid Compact procedure are developed for determining the collapse load factor. It is found that the final results are good agreement with the results of Elasto-plastic analysis. Besides, the redundant structures like Web frame is known to have multiple failure modes. Web frame may collapse under any of the possible failure modes. Thus, the identification of these possible failure modes is necessary and very important in the reliability analysis of Web frame. In order to deal with multiple failure modes, automatic generation method of all failure modes and basic failure modes is used for selecting the dominant failure modes. The probability of failure pastic collapse of Web frame is calculated using these dominant failure modes. The safety of Web frame is asscssed and compared by performing the deterministic and probabilistic analysis.

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Dielectric and Piezoelectric Properties of Low Temperature Sintering PZN-PZT Ceramics with a variation of $Li_2CO_3$ Addition ($Li_2CO_3$ 첨가에 따른 저온소결 PZN-PZT 세라믹스의 유전 및 압전특성)

  • Lee, Yu-Hyong;Lee, Sang-Ho;Yoo, Ju-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.307-307
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    • 2007
  • 압전액츄에이터 및 초음파진동자는 전자제품의 소형화 및 경량화, 의료기기, 모바일기기 및 소형로붓의 발전에 힘입어 그 활용범위가 넓게 확장되고 있다. 1960년 Smolenski등에 의해 $A(B_1,B_2)O_3$형 복합 페로브스카이트 구조를 갖는 강유전성 세라믹스에 대한 연구가 시작된 이래 $Pb(Co,Nb)O_3-Pb(Zr,Ti)O_3$, $Pb(Zn,Nb)O_3-Pb(Zr,Ti)O_3$, $Pb(Mg,Nb)O_3-Pb(Zr,Ti)O_3$ 등 3성분계 세라믹스의 유전, 압전 및 강유전 특성에 대한 많은 연구가 진행되어 왔다. 그러나 압전성이 우수한 세라믹스들은 Pb가 포함되어 있기 때문에 $1000^{\circ}C$ 이상에서 PbO가 급격하게 휘발되는 성질에 따라서 조성의 변동이 생겨 재현성이 어려우며 이를 방지하기 위하여 과잉 PbO를 첨가시키기 때문에 환경오염뿐만 아니라, 경제적인 측면에서도 많은 문제점을 가지고 있다. 소결조제를 이용한 산화물 첨가법은 PbO의 휘발을 억제하는 저온소결 방법중 가장 효과적인 방법으로 알려져 있다. 따라서, 본 연구에서는 적층형 압전액츄에이터로 사용하기위한 저온소결 압전세라믹스를 개발하기 위하여 PZN-PZT세라믹스에 $Li_2CO_3$, $Bi_2O_3$, CuO 를 소결조제로 사용하여 $Li_2CO_3$의 첨가량 변화에 따른 압전 및 유전 특성을 관찰하였다.

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Ferroelectric Properties $\textrm{SrBi}_{2}\textrm{Ta}_{2}\textrm{O}_{9}$ Thin Films Deposited by RF Magnetron Sputtering Technique (RF magnetron sputtering법에 의해 제조된 $\textrm{SrBi}_{2}\textrm{Ta}_{2}\textrm{O}_{9}$박막의 강유전 특성에 관한 연구)

  • Park, Sang-Sik;Yang, Cheol-Hun;Yun, Sun-Gil
    • Korean Journal of Materials Research
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    • v.7 no.6
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    • pp.505-509
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    • 1997
  • FRAM(Ferroelectric Random Access memory)에의 응용을 위해 rf magnetron sputtering법을 이용하여 SrB $i_{2}$T $a_{2}$ $O_{9}$(SBT)박막을 증착하였다. 사용된 기판은 Pt/Ti/Si $o_{2}$Si이었으며 50$0^{\circ}C$에서 증착한 후 80$0^{\circ}C$의 산소 분위기 하에서 1시간 동안 열처리하였다. 증착시 증착 압력을 변화시켜 가면서 이에 따른 특성의 변화를 고찰하였다. 박막내의 Bi와 Sr의 부족을 보상하기 위해 20mole%의 Bi $O_{2}$와 30mole%의 SrC $O_{3}$를 과잉으로 넣어 타겟을 제조후 사용하였고 박막들의 두께는 300nm의 두께를 가지며 증착압력에 따라 다른 미세 구조르 보였다. 10mtorr에서 증착한 박막의 조성은 S $r_{0.6}$B $i_{3.8}$Ta/ sub 2.0/ $O_{9.0}$이었다. 이 SBT 박막의 잔류 분극(2 $P_{r}$)과 보전계(2 $E_{c}$)값은 각각 인가 전압 5V에서 18.5 $\mu%C/$\textrm{cm}^2$과 150kV/cm이었고, signal/noise비는 3V에서 4.6을 나타내었다. 5V의 bipolar pulse하에서 $10^{10}$cycle까지 피로 현상이 나타나지 않았으며, 누설 전류 밀도는 133kV/cm에서 약 1x$10^{-7A}$$\textrm{cm}^2$의 값을 보였다.을 보였다.

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Labor Investment Efficiency and Value Relevance of Accounting Information (노동투자효율성이 회계정보의 가치관련성에 미치는 영향)

  • Cho, Jungeun
    • The Journal of the Korea Contents Association
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    • v.20 no.12
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    • pp.136-144
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    • 2020
  • Previous studies report that labor investment inefficiency occurs as the information asymmetry becomes severe and the agency problem between managers and external investors increases. Therefore, it is highly likely that managers will make opportunistic decisions that can damage corporate value in companies with high labor investment inefficiency. This study examines whether the value relevance of accounting information decreases as labor investment inefficiency increases as it is less likely that investors in the market use the accounting information of companies in which labor investment decisions are made inefficiently. Labor investment efficiency is measured as the difference between the actual level of labor investment and the expected level of optimal labor investment. Larger difference between the actual level of labor investment and the expected level of optimal labor investment is considered as higher inefficiency in labor investment. Using data of firms listed on the Korea Stock Exchange from 2002 to 2018, empirical results show that the value relevance of earnings decreases as the inefficiency of labor investment increases. This research provides empirical evidence on whether investment inefficiency in labor, which is an important factor in the competitiveness of a company, reduces the information usefulness of reported earnings.