• 제목/요약/키워드: 고체 표면

검색결과 511건 처리시간 0.022초

Validation of Factors Effect on Pretreatment of Brown Algae, Undaria, Using Response Surface Methodology and Prospect of Lactic Acid Production (반응표면분석법을 이용한 갈조류, 미역의 전처리 인자 영향 파악 및 젖산 생산성 검토)

  • Min, Chang Ha;Lee, Doo-Geun;Um, Byung Hwan;Yoon, Jeong-Jun
    • Korean Chemical Engineering Research
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    • 제56권4호
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    • pp.453-460
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    • 2018
  • Owing to rising oil prices and anthropogenic global warming, focused attempts are being made toward production of industrially important compounds by using renewable biomass. In this context, algal biomass as third-generation biomass is important because it doesn't compatible with food resource, has high yield, and helps abate greenhouse gases. Here, we investigate whether Undaria has the highest sugar content, which would make it the most suitable biomass for lactic acid production among the four algal biomasses tested. For effective pretreatment of Undaria, the response surface methodology was used. The amount of solid loaded and catalyst concentration were related to the extraction rate of total sugar. Lactic acid was produced by pretreatment of Undaria by using four Lactobacilli, and L. alimentarius and L. brevis were found to be suitable for lactic acid production.

Characteristics of Kinetic Energy Transfer in Collisions Between Fragile Nanoparticle and Rigid Particle on Surface (승화성 나노 탄환입자와 표면위의 나노 고체입자의 충돌에서의 운동에너지 전달 특성)

  • Choi, Min Seok;Lee, Jin Won
    • Transactions of the Korean Society of Mechanical Engineers B
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    • 제38권7호
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    • pp.595-600
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    • 2014
  • The characteristics of kinetic energy transfer during a collision between a rigid target particle on a surface and a fragile bullet particle moving at a high velocity were analyzed using molecular dynamics simulation. Bullet particles made of $CO_2$ were considered and their size, temperature, and velocity were varied over a wide range. The fraction of kinetic energy transferred from the bullet particle to the target particle was almost independent of the former's size or velocity; however, it was sensitively dependent on its temperature, which can be attributed to the change in the bullet rigidity with temperature. This fraction was nearly twice as high for $CO_2$ bullets as for Ar bullets. This result explains the reason for the more superior cleaning performance of $CO_2$ bullets than Ar bullets with regard to contaminants in the 10 nm size range.

Spreading Dynamics of an Ellipsoidal Drop Impacting on a Heated Substrate (고온으로 가열된 고체 표면과 충돌하는 타원형 액적의 퍼짐 거동)

  • Yun, Sungchan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • 제41권3호
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    • pp.205-209
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    • 2017
  • Unlike spherical drop impact, ellipsoidal drop impact can control the bouncing height on a heated surface by significantly altering impact behavior. To scrutinize the effect of the aspect ratio (AR) of the drop on the bounce suppression, in this study, non-axisymmetric spreading behaviors are observed from two side views and characterized based on the spreading width of the drop for horizontal principal axes. In addition, the maximum spreading width is investigated for various ARs. The results show that as the AR increases, the maximum spreading width of the minor axis increases, whereas that of the major axis shows no significant variation. In the regime of high AR and high impact velocity, liquid fragmentations by three parts are observed during bouncing. These fragmentations are discussed in this work. The hydrodynamic features of ellipsoidal drop impact will help understand bouncing control on non-wetting surfaces for several applications, such as self-cleaning and spray cooling.

Oscillation Characteristics of Turbulent Channel Flow with Wall Blowing (채널유동에서 질량분사에 의한 표면유동의 진동 특성)

  • Na, Yang;Lee, Chang-Jin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • 제37권1호
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    • pp.62-68
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    • 2009
  • The interaction between wall blowing and oxidizer flow can generate a very complicated flow characteristics in combustion chamber of hybrid rockets. LES analysis was conducted with an in-house CFD code to investigate the features of turbulent flow without chemical reactions. The numerical results reveal that the flow oscillations at a certain frequency exists on the fuel surface, which is analogous to those observed in the solid propellant combustion. However, the observation of oscillating flow at a certain frequency is only limited to a very thin layer adjacent to wall surface and the strength of the oscillation is not strong enough to induce the drastic change in temperature gradient on the surface. The visualization of fluctuating pressure components shows the periodic appearance of relatively high and low pressure regions along the axial direction. This subsequently results in the oscillation of flow at a certain fixed frequency. This implies that the resonance phenomenon would be possible if the external disturbances such as acoustic excitation could be imposed to the oscillating flow in the combustion chamber.

Axial and Radial Distributions of Bubble Holdup in a Slurry Bubble Column with Pilot Plant Scale (파일럿규모 슬러리 기포탑에서 기포체류량의 축방향, 반경방향 분포)

  • Lim, Dae-Ho;Jang, Ji-Hwa;Kang, Yong;Jun, Ki-Won
    • Korean Chemical Engineering Research
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    • 제49권2호
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    • pp.200-205
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    • 2011
  • Axial and radial distributions of bubble holdup were investigated in a slurry bubble column with pilot plant scale(D=1.0 m). Effects of gas velocity, surface tension of continuous liquid medium and solid fraction in the slurry phase on the axial and radial distributions of bubble holdup were examined. The bubble holdup decreased with increasing radial dimensionless distance from the center of the column, while it increased with increasing dimensionless distance in the axial direction from the distributor, in all the cases studied. The radial non-uniformity of bubble holdup increased with increasing gas velocity but decreasing surface tension of liquid medium, while it was not dependent upon the solid fraction in the slurry phase. The axial non-uniformity of bubble holdup increased with increasing gas velocity, but it does not change considerably with variations of liquid surface tension or solid fraction in the slurry phase . The axial and radial distributions of bubble holdup were well correlated in terms of operating variables within this experimental conditions.

Friction Force Microscopy Analysis of Diamond-like Carbon Films (다이아몬드상 카본 박막의 Friction Force Microscopy 분석)

  • Choi, Won-Seok;Lee, Jong-Hwan;Song, Beom-Young;Heo, Jin-Hee;You, Jin-Soo;Hong, Byung-You
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.181-181
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    • 2008
  • DLC (Diamond-like Carbon) 박막은 높은 내마모성과 낮은 마찰 계수, 화학적 안정성 및 적외선 영역에서의 높은 투과율과 낮은 광 반사도, 높은 전기저항과 낮은 유전율, 전계방출특성 등 여러 가지 장점을 가진 물질이다[1]. 최근에는 DLC 박막의 여러 장점들과 산과 염기 유기용매에 대한 화학적 안정성으로 인하여 인조관절에서 인공심장의 판막에 이르기까지 의공학 관련 부품소재로 응용되고 있으며 내구성과 안정성에 있어서 탁월한 성능을 보여주고 있다. 또한 DLC 박막의 높은 경도와 낮은 마찰 계수, 부드러운 박막 표면 (수nm의 RMS 거칠기)의 장점을 살려 마그네틱 미디어와 하드디스크의 슬라이딩 표면에 사용되어지고, MEMS (Micro-Electro Mechanical System) 소자와 MMAs (Moving Mechanical Assemblies)의 고체윤활코팅으로 활용하여 미세기계의 내구성과 성능 향상을 도모할 수 있다. 이와 같이 DLC 박막은 다양한 분야에 응용되고 있으며, 박막이 지닌 여러 가지 장점들로 인하여 더 많은 분야에 응용될 가능성을 지닌 물질이다. 그러나 수 ${\mu}m$이상의 두께에서 박막이 높은 잔류응력 (residual stress)을 가지고, 열에 취약하여 이의 개선에 관한 연구들이 진행되어 지고 있다 [2]. 따라서 사용되는 목적에 따라 용도에 맞는 양질의 DLC 박막을 합성하기 위해선 합성 장치의 개발과 다양한 실험을 통한 최적의 합성조건 도출 등의 노력이 요구된다. 또한 DLC 박막 합성시의 여러 가지 증착 방법에 따른 박막 물성에 대한 재현성 확보 및 박막 증착에 관한 명확한 메커니즘 규명이 아직까지는 불분명하여 이에 관한 연구가 시급하다. 따라서 본 연구에서는 MEMS 소자와 MMAs의 고체윤활코팅으로 사용가능한 DLC 박막을 RF PECVD (Plasma Enhanced Vapor Deposition) 방식으로 합성하고 후열처리 온도에 따른 DLC 박막의 마찰계수 변화를 박막에 훼손을 주지 않는 FFM (Friction Force Microscopy) 방식을 사용하여 분석하였다.

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Precise Static Contact Angle Measurements Using Pythagolas Rule (피타고라스 원리를 이용한 정적 접촉각 정밀 각도 측정방법)

  • Choi, Jin-Yeong;Kwon, Dong-Jun;Wang, Zuo-Jia;Shin, Pyeong-Su;Park, Joung-Man
    • Journal of Adhesion and Interface
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    • 제15권2호
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    • pp.57-62
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    • 2014
  • Pythagolas rule was used for investigation of static contact angle in particular figures. Static contact angle measurement was important to evaluate the wettability between solid and liquid. Optimum measurement method and standardization of calculation for static contact angle were investigated for practical application. Optimum diameter of droplet for static contact angle measurement was confirmed as 1 mm. Contact angle measurement using Pythagolas rule was also used to calculate advancing, receding angle and wettability of different surface condition. At last, it was concluded that the Pythagolas rule method was more accurate than general lineation method for static contact angle measurement.

Dehydration of D-Xylose into Furfural Using Propylsulfonic Acid Modified Mesoporous Silica (황산 표면개질 메조다공 실리카를 이용한 푸르푸랄 제조에 관한 연구)

  • Kim, Eun-Gyu;Kim, Saet-Byul;Park, Eun-Duck;Kim, Sang-Wook
    • Clean Technology
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    • 제16권2호
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    • pp.95-102
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    • 2010
  • Sulfonic acid (-SO3H) functionalized mesoporous silica containing HMS, SBA 15(S15), MCM 41(M41) were synthesized by post-synthesis and co-condensation method. Their catalytic performance is tested by dehydration reaction of D-xylose to furfural. As a result, good conversion and selectivity was obtained using water as an environmentally friendly solvent. Additionally, increased amounts of sulfuric acid in catalysts resulted in improved conversion of D-xylose. All of the acid-functionalized mesoporous silica showed higher selectivity than other solid acids such as ${\gamma}-Al_{2}O_{3}$ and zeolite.

A Study on the Output Performance of Solid-solid Triboelectric Energy Harvesting Depending on the Surface Morphology and Thickness of AAO (AAO 두께 및 표면 형상에 따른 고체-고체 마찰 대전 기반 에너지 하베스팅 발전 성능에 관한 연구)

  • Kwangseok Lee;Woonbong Hwang
    • Composites Research
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    • 제36권3호
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    • pp.224-229
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    • 2023
  • Due to the increasing demand for wearable devices and miniaturization of various electronic devices, the trend of nanofabrication in IT devices is underway. In order to overcome the limitations of battery size and capacity, there has been a lot of research interest in energy harvesting technology, also known as triboelectric nanogenerator. AAO(Anodic Aluminum oxide) coated with fluoride is a structure that includes an anode layer with high properties in the triboelectric series, an dielectric layer that helps transfer the triboelectrically generated charges to the electrode without loss, and the electrode. For these reasons, AAO has been a lot of research on its application to frictional energy harvesting nanogenerators. In this work, we analyzed the correlation of AAO between the surface morphology and thickness of the insulating layer by utilizing aluminum oxide, which is advantageous for the application of triboelectric nanogenerators, and adjusting the thickness of the insulating layer.

Relationship Between Mass Transfer and Degradation of Sorbed Phenanthrene in Goethite Catalyzed Fenton-like Oxidation Using Non-ionic/anionic Surfactant (Phenanthrene 의 goethite 촉매에 의한 Fenton 산화에 있어서 음이온/비이온 계면활성제의 영향)

  • Kim, Jeong-Hwan;Choi, Won-Ho;Kim, Jung-Hwan;Park, Joo-Yang
    • KSCE Journal of Civil and Environmental Engineering Research
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    • 제29권2B호
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    • pp.207-212
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    • 2009
  • Surfactants were used as representative anionic and non ionic surfactants to investigate the effect of mass transfer on the mineral-catalyzed Fenton-like oxidation of sorbed phenanthrene. Mass transfer of phenanthrene on the oxide surface or interlayer between aqueous and solid phases was generated by surfactant addition. Apparent solubility of phenanthrene was increased as surfactant concentration increasesd. In tests using Tween 80, oxidation of phenanthrene decreased as apparent solubility increased. High apparent solubility was not responsible for oxidation of sorbed phenanthrene in the sand due to the surfactant acted as a scavenger of degradation. In tests with SDS, $H_{2}O_{2}$ decomposition rate in Fenton-like oxidation was decreased by complexation between goethite and SDS. However, in tests using 32 mM of SDS, efficiency of phenanthrene treatment increased compared to the test without SDS addition. Therefore, suitable amount of SDS addition could provide optimum condition for phenanthrene oxidation on the oxide surface or interlayer between aqueous and solid phase, and decrease $H_{2}O_{2}$ decomposition, and as a result, phenanthrene removal efficiency can be improved.