• Title/Summary/Keyword: 고온·고압

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Characteristics of $TiH_2$ under High Pressure (고압하에서 $TiH_2$의 특성화 연구)

  • Kim, Young-Ho
    • Journal of the Mineralogical Society of Korea
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    • v.5 no.2
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    • pp.72-78
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    • 1992
  • The Earth outer core accomodates moderately considerable amount of lighter elements than pure iron itself. Hydrogen is one of the possible candidates of minor constituents in the outer core. It would be worth while to extend for the pressure effect on the solubility of hydrogen in the metal-hydrides including iron hydride. In view of hydrogen being one of the potential substitutes for petroleum, searching a more efficient way for storing hydrogen in the form of hydrides is of considerable value. For two purposes, $TiH_2$was selected among lot of hydrides for its characteristics under pressure and temperature. There have been two kinds of experiment carried out on $TiH_2$ under different experimental conditions. As one of these attempts, polycrystalline $TiH_2$ was loaded up to 15 GPa stepwise at the constant temperature 500${\circ}$ using a piston-cylinder diamond anvil cell equipped with a miniature furnace of an electric power supply. The X-ra diffraction technique was employed on the quenched samples after the simultaneous high pressure and temperature treatments. During these high pressure-temperature runs, and irreversible phase of $TiH_2$ has been observed at the pressures higher than 11.3 GPa, which would be assigned to the orthorhombic crystal system as one of the new phase(s) of $TiH_2$. Molar volume change on this phase transition is ∼10%.

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Development of Commercial-scaled Pervaporation Hollow Fiber Membrane System for High Pressure and High Temperature Applications (고온 고압용 상업적 규모의 중공사 투과증발 막시스템 개발)

  • Yeom, Choong Kyun;Kang, Kyeong Log;Kim, Joo Yeol;Ahn, Hyo Sung;Kwon, Konho
    • Membrane Journal
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    • v.23 no.4
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    • pp.257-266
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    • 2013
  • The main purpose of this study is to develop a commercial scale of pervaporative process equipped with hollow fiber membrane modules, being able to effectually purify organic solvent at high temperature well over its boiling point under high vapor pressure. Three constituent technologies have been developed; 1) to fabricate braid-reinforced hollow fiber membrane stable in high pressure and high temperature application, 2) to design and fabricate a commercial scale of hollow fiber membrane module, and 3) to design and fabricate a pilot scale of pervaporation equipment system. The developed hollow fiber membrane possesses a membrane performance superior to the membrane of Sulzer (Germany) which is the most-well known for pervaporation process, and the membrane module equips hollow fiber membranes of $4.6m^2$ and the pervaporation system can treat organic liquid at 200 L/h, which is based on the dehydration of 95 wt% isopropyl alcohol (IPA). Since the membrane module is designed to flow in and pass through the inside of individual hollow fiber membrane, not to involve both the formation of feed's dead volume observed in flat-sheet membrane module and the channeling of feed occurring inside hollow fiber bundle which lower membrane performance seriously, it showed excellent separation efficiency. In particular, the module is inexpensive and has less heat loss into its surrounding, in compared with flat-sheet membrane module. In addition, permeant can be removed effectively from the outer surface of hollow fiber membrane because the applied vacuum is conveyed uniformly through space between fibers into respective fiber, even into one in the middle of the hollow fiber bundle in which the space between fibers is uniform in distance. Since the hollow fiber membrane pervaporation system is the first one ever developed in the world, our own unique proprietary technology can be secured, preoccupying technical superiority in export competitive challenges.

An experimental study on the evaporation of paraffin family fuel droplet under high temperature and high pressure (고온 고압기류중을 비행하는 파라핀계 연료액적의 증발에 관한 연구)

  • ;川口修
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.15 no.6
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    • pp.2125-2131
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    • 1991
  • Evaporation rate constant, obtained by in this experimental study, of freely falling liquid fuel droplet on the condition of hot and pressurized environment are converted to critical evaporation constant according to Eq. of Ranz and Marshall. Critical evaporation constant, on constant environment pressuire, actively increase almost linearly with environment temperature increasing, but, on constant temperature, increases more or less with pressure increasing. Multycomponent droplet mixed with the fine fuel having a different of boiling point evaporate in order to boiling point, and each evaporation rate constant of mixed fuel equal to each fuel.

Product distribution of rapid devolatilization of pulverized coal (미분탄의 고속열분해시 생성물 분포해석)

  • Park, Hoyoung
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.76.2-76.2
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    • 2011
  • 석탄의 탄종별 열분해 생성물은 석탄가스화기의 뮬레이션 기법의 첫 번째 단계이며 이러한 탄종별 생성물 예측은 가스화기의 성능, 즉 가스화기 출구 가스조성, 탄소전환율, 냉가스 전환율등을 예측하는데 있어 가장 기본적이고 중요한 절차이다. 본 논문에서는 석탄가스화기내 열분해 과정을 모사할 수 있도록 석탄 성상과 가스화기 운전압력에 따라 탄종별 고온고압 열분해시의 생성물을 정량적으로 계산하는 방법을 제시하였다. Merrick(1983)의 방법을 기반으로 석탄의 성상(공업/원소분석치), 가스화기 운전압력과 몇가지 상관관계식으로부터 고온고압하 열분해 생성물을 계산하는 방법이며 이를 프로그램화하여 가스화기 시뮬레이터용 모듈로 구성할 수 있도록 하였다. 또한, 국내 수입 5개 탄종에 대하여 열분해 생성물의 조성을 구하였으며 이를 상용 열분해모델의 결과와 서로 비교하였다. 열분해 생성물 조성의 분포는 다른 상용 프로그램 결과와 부합하였으며 생성물의 발열량도 원탄의 발열량과 적합한 결과를 보여주었다.

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Foaming Characteristics of Autoclaved Aerated Concrete with Different C/S Molar Ratios and Aluminum Powder Contents (C/S 몰비 및 알루미늄 분말 첨가율 변화에 따른 고온·고압 기포 콘크리트의 발포특성)

  • Yoon, Hyun-Sub;Pakr, Jong-Beom;Lee, Kwang-Il;Yang, Keun-Hyeok
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.220-221
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    • 2018
  • Test results showed that foaming ratio of autoclaved aerated concrete significantly affected by the CaO/Si2O (C/S) molar ratio of the component materials, indicating the greatest foaming ratio of 202% when the C/S ratio was 0.9.

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Analysis of Grid Spring Characteristic of Fuel Assembly in High Temperature and High Pressure Environment (고온고압조건하에서의 핵연료 피복관 지지스프링의 하중-변위 특성 분석)

  • Lee, Young-Ho;Kim, Hyung-Kyu;Jung, Youn-Ho
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.2146-2150
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    • 2004
  • To evaluate the variation of spring stiffness in nuclear plant operating condition, load-displacement tests ($P-{\delta}$ test) were performed using two kinds of space grid springs in high temperature and high pressure water. With increasing temperature, stiffness of each spring gradually decreased except $100{\sim}150^{\circ}C$. It is apparently showed that spring with convex shape had a relatively high stability of spring stiffness at high temperature compared with I-shaped spring. It is suggested that the variation of spring stiffness with temperature and spring shape should be considered as an important variable in the design and analysis of the fuel assembly.

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Transient State Analysis of Nozzle Ablation under High Temperature and High Pressure Plasma (고온 고압 플라즈마 하에서의 과도상태 노즐용삭 해석 기술)

  • Lee, B.Y.;Song, K.D.;Park, K.Y.
    • Proceedings of the KIEE Conference
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    • 2003.07b
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    • pp.982-984
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    • 2003
  • 본 논문에서는 계통에서 사고에 의해 발생한 고장전류를 차단할 때, 가스차단부에서 발생하는 고온 고압의 아크플라즈마 하에서 노즐용삭에 의해 PTFE와 같은 노즐 물질이 $SF_6$가스에 혼입하는 경우에 노즐 재질이 아크플라즈마의 차단특성에 미치는 영향을 평가하기 위해 요구되는 과도상태 노즐용삭 해석기술에 대하여 정리한다. 그리고 노즐용삭 해석기술을 계통에서 고장이 발생한 경우에 흐르는 고장전류를 차단하는 과정에서 발생하는 아크플라즈마에 적용하여 용삭된 PTFE의 농도를 계산하고 그 결과를 제시한다.

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Study on Softening Characteristics of 9Cr-1Mo Steel Weldments for High Temperature and Pressure Vessels Application (고온고압장치 적용을 위한 9Cr-1Mo강 용접부의 연화특성에 관한 연구)

  • 이영호;이규천;윤의박;김기철
    • Journal of Welding and Joining
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    • v.10 no.3
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    • pp.40-53
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    • 1992
  • 고온고압장치(High Temperature and Pressure Vessels)의 적용을 위한 기초연구로서 9Cr-1Mo강 용접부의 연화특성에 대하여 검토하였다. 9Cr-1Mo 강재에 Bead-on-Plate용접을 실시한 후, 용접부의 기계적 성질과 그 현미경조직관찰 및 미세경도를 측정한 결과, As-Welded 및 용접 후열처리(PWHT)등의 조건에 관계없이 용접열향부의 변태역과 템퍼링역의 경계에서 모재의 경 도보다 낮은 경도값(연화역)을 나타내었으며 이러한 원인은 결정립계(Grain boundary)에 석출 되는 탄화물의 형성에 의한 뜨임 현상임이 판명되었다.

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Degradation Evaluation of High Pressure Reactor Vessel in field Using Electrical Resistivity Method (전기비저항법을 이용한 고압반응기 열화도 현장평가)

  • Park, Jong-Seo;Baek, Un-Bong;Nahm, Seung-Hoon;Han, Sang-In
    • Journal of the Korean Society for Nondestructive Testing
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    • v.25 no.5
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    • pp.377-383
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    • 2005
  • Because explosive fluid is used at high temperature or under high pressure in petrochemistry and refined oil equipment, the interest about safety of equipments is intensive. Specially, the safety of high pressure reactor vessel is required among them. The material selected in this study is 2.25Cr-1Mo steel that is widely used for high pressure reactor vessel material of petrochemical plant. Eight kinds of artificially aged specimens were prepared by differing from aging periods under three different temperatures. The material was iso-thermally heat treated at higher temperatures than $391^{\circ}C$ that is the operating temperature of high pressure reactor vessel. Vickers hardness properties and electrical resistivity properties about artificially aged material as well as un-aged material were measured, and master curves were made out from the correlation with larson-Miller parameter. And electrical resistivity properties as well as Victors hardness properties measured at high pressure reactor vessel of the field were compared with master curves made out in a laboratory. Degradation evaluation possibility in the field of high pressure reactor vessel by using electrical resistivity method was examined. Electrical resistivity property measured in the field is similar with that of artificially aged material in similar aging level.

증기터빈의 성능향상 기술 동향

  • Jeong, Mun-Su
    • Journal of the KSME
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    • v.49 no.9
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    • pp.52-57
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    • 2009
  • 이 글에서는 차세대 증기터빈 개발에 대해서 먼저 소개하고 이에 따른 증기터빈의 고온 고압화, 긴 블레이드의 개발 그리고 이에 수반되는 내부효율 향상을 소개하고자 한다.

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