• Title/Summary/Keyword: 고분자전해질 연료전지

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Fabrication and Properties Analysis of MEA for PEMFC (고분자전해질 연료전지용 MEA 제조 및 특성평가)

  • Cho Y.H.;Cho Y.H.;Park I.S.;Sung Y.E.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.230-234
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    • 2005
  • Fabrication of MEA is important factor for proton exchange membrane fuel cell (PEMFC). MEA of PEMFC with hot pressing and direct coating method were prepared, and performances were evaluated and compared each other. The effect of MEA preparation methods, hot pressing methods and direct coating methods, on the cell performance was analyzed by impedance spectroscopy and SEM. The performance of PEMFC with direct coating method was better than with hot pressing method because membrane internal resistance and membrane-interfacial resistance were reduced by elimination of hot pressing process in MEA fabrication. In addition the micro structure of MEA with direct coating method reveals uniform interface between membrane and catalyst layer.

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Modeling of a PEM Fuel Cell Stack using Partial Least Squares and Artificial Neural Networks (부분최소자승법과 인공신경망을 이용한 고분자전해질 연료전지 스택의 모델링)

  • Han, In-Su;Shin, Hyun Khil
    • Korean Chemical Engineering Research
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    • v.53 no.2
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    • pp.236-242
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    • 2015
  • We present two data-driven modeling methods, partial least square (PLS) and artificial neural network (ANN), to predict the major operating and performance variables of a polymer electrolyte membrane (PEM) fuel cell stack. PLS and ANN models were constructed using the experimental data obtained from the testing of a 30 kW-class PEM fuel cell stack, and then were compared with each other in terms of their prediction and computational performances. To reduce the complexity of the models, we combined a variables importance on PLS projection (VIP) as a variable selection method into the modeling procedure in which the predictor variables are selected from a set of input operation variables. The modeling results showed that the ANN models outperformed the PLS models in predicting the average cell voltage and cathode outlet temperature of the fuel cell stack. However, the PLS models also offered satisfactory prediction performances although they can only capture linear correlations between the predictor and output variables. Depending on the degree of modeling accuracy and speed, both ANN and PLS models can be employed for performance predictions, offline and online optimizations, controls, and fault diagnoses in the field of PEM fuel cell designs and operations.

The Performance Analysis of Polymer Electrolyte Membrane Fuel Cells for Mobile Devices using CFD (CFD를 이용한 모바일기기용 고분자전해질 연료전지 성능해석)

  • Kim B.H.;Choi J.P.;Kang D.C.;Jeon B.H.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.553-554
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    • 2006
  • This paper presents the effects of different operating parameters on the performance of a proton exchange membrane (PEM) fuel cell by a three-dimensional computational fluid dynamics (CFD) model. The effects of different operating parameters on the performance of PEM fuel cell studied using pure hydrogen on the anode side and air on the cathode side. The various parameters are temperatures, pressures, humidification of the gas steams and various combinations of these parameters. In addition, geometrical and material parameters such as the gas diffusion layer (GDL) thickness and porosity as well as the ratio between the channel width and the land area were investigated.

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State of Solid oxide fuel cell (고체산화물 연료전지 기술 현황)

  • Song, Rak-Hyun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05c
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    • pp.1-5
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    • 2002
  • 고체산화물 연료전지는 무공해 고효율의 에너지 발전 장치이다. 연료전지는 형태는 1 세대 알카리형 연료 전지부터 인산형, 고분자전해질형, 직접메탄올형, 용융탄산염형 그리고 3세대인 고체산화물형 연료전지들이 있다. 고체산화물 연료전지는 음극 및 양극 그리고 고온에서 작동되기 때문에 전해질 및 내부연결재 등이 많이 연구 개발되고 있다. 고체산화물 연료전지는 이동형으로부터 소형발전 시스템 및 대형 복합발전시스템에 걸쳐 많이 개발이 이루어지고 있다.

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Effect of Nafion Membrane Etching for Proton Exchange Membrane Fuel Cell (고분자전해질형 연료전지에서 Nafion막 에칭의 영향)

  • Park Kwon Pil;Cho Gyou Jin;Lee Gun Jik;Chun Hai Soo
    • Journal of the Korean Electrochemical Society
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    • v.2 no.4
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    • pp.190-194
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    • 1999
  • Etched Nafion membrane and electrode assemblies were fabricated and those performances were observed in PEMFC. Adhesion of membrane to electrode increased with abrasion of membrane surface. Membrane surface ething results in reduction of hot pressing temperature, as a consequence, in improving of cell performance. It was found that Nafion etching was effective in painting method. The optimum content of electrode catalyst should be selected according to etching intensity.

Comparison of Cell Performance with Physical Properties of Gas Diffusion Layers in PEMFCs (고분자전해질 연료전지에서 다양한 기체확산층의 물리적 특성과 연료전지 성능 비교)

  • Lee, Ji-Jung;Kim, In-Tae;Zhang, Yan;Lee, Hong-Ki;Shim, Joong-Pyo
    • Journal of the Korean Electrochemical Society
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    • v.10 no.4
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    • pp.270-278
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    • 2007
  • PEMFC electrodes with various gas diffusion layers (GDL) were characterized to find out the effect of GDL on fuel cell performance. The physical properties of GDL such as electric conductivity, porosity, air permeability, water flux, PTFE content, etc had close relationship each other and affected on the variation of the cell performance. It was observed that the micro-porous layer (MPL) on carbon paper or cloth changed the physical properties of GDL and changed the cell performance. The variation of cell performance as a function of the physical properties of GDL showed different behaviors according to the amount of current density.

Time-Dependent Modeling of Performance Degradation for PEMFC Single Cell System to Evaluate the Cell Performance and Durability: Effects of CO Poisoning (고분자전해질 연료전지의 성능과 안정성 시험을 위한 단위전지의 시간 경과에 따른 모델링: 일산화탄소 피독현상에 의한 효과)

  • Kim, Jong-Sik;Kim, Pil;Joo, Ji-Bong;Kim, Woo-Young;Yi, Jong-Heop
    • Clean Technology
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    • v.14 no.1
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    • pp.61-68
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    • 2008
  • There have been great attentions on polymer electrolyte membrane fuel cell (PEMFC) due to their advantageous characteristics such as zero emission of hazardous pollutant and high energy density. In this work, we evaluated degradation phenomena and stability of single cell performance via one dimensional single cell modeling. Here, CO poisoning on anode on anode was considered for cell performance degradation. Modeling results showed that the performance and stability were highly degraded with CO concentration in fuel gas. In addition, cell performance was reduced by slow oxygen reduction on cathode in long term operation. In order to overcome, it is required to increase ratio o#hydrogen in the fuel gas of anode and high Pt loading contained in the cathodic catalyst layer.

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An Experimental Study on Measurement of Oxygen Concentration in the Cathode Channel of PEMFC by Using GC (GC를 이용한 고분자전해질형 연료전지의 공기극 채널 내 산소 농도 분포에 관한 실험적 연구)

  • Ha Taehun;Kim Han-Sang;Min Kyoungdoug
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.384-387
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    • 2005
  • Fuel cell has been well known as a clean alternative power for vehicles. Recently, an experimental technique has been developed measurement of species and distributions by using gas chromatograph. In this study, cathode channel oxygen distributions as various conditions were investigated using gas chromatograph and cell visualization. And discussed relation between flooding and oxygen concentrations. As a result of experiment, oxygen consumpt ion is affected wi th flooding. Flooding is observed in channel near hydrogen inlet, and oxygen consumption is low at that region.

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TA Study on the Performance and the Efficiency in Polymer Electrolyte embrane Fuel Cell (고분자전해질형 연료전지의 성능해석 및 효율에 관한 연구)

  • Kim Hong-Gun;Kim Yoo-Shin;Yang Sung-Mo;Nah Seok-Chan
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.14 no.4
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    • pp.75-80
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    • 2005
  • An experimental study is carried out to investigate the performance and the efficiency humidifying Membrane Electrolyte Assembly and having the double-tied catalyst layers in a fuel cell system which is taken into account the physical and thermal concept. Subsequently, an electric output produced by PEMFC(Polymer Electrolyte Membrane Fuel Cell) is measured to assess the performance of a stack, and the efficiency is also evaluated according to the different situation in which unit cell is placed with and without the humidification of the MEA. It is found that the measured values of stack voltage and current are influenced by the stack temperature, humidification, and the double-tied catalyst layers which give more enhanced values to be applied to electric units.

Numerical Study of Droplet Dynamics in a PEMFC Air Flow Channel (고분자전해질형 연료전지의 공기 채널 내에서의 액적 거동에 대한 수치적 연구)

  • Choi, Ji-Young;Son, Gi-Hun
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.2390-2395
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    • 2008
  • The water droplet motion in an air flow microchannel with pores through which water emerges is studied numerically by solving the equations governing the conservation of mass and momentum. The gas-liquid interface is tracked by a level set method which is based on a sharp-interface representation for accurately imposing the matching conditions at the interface and is modified to implement the contact angle conditions on the wall and pores. The numerical results show that the droplet growth and detachment pattern depend significantly on the contact angle and inlet air velocity. Also, the dynamic interaction between the droplets growing on multiple pores is investigated. The pore arrangement subject to droplet merging is found to be not effective for water removal.

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