• Title/Summary/Keyword: 계면온도

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A Study of the Single Crystal Growth of $Ag_2S$ Mixed Conductor and it$s Characteristics (혼합 반도체 $Ag_2S$의 단결정 성장 및 특성에 관한 연구)

  • 김병국;신명균;윤종규
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.2 no.1
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    • pp.76-85
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    • 1992
  • ${\beta}-$Ag_2S$(high temperature phase) was grown by solid/vapour reaction growth based on solid -state electrochemisty. In S/V growth, one of the reactants, silver ion, is supplied to the growth surface through the solid $Ag_2S$ from one side and the other reactants, surfur, is transported in the phase of vapour from the other side. With the sufficient supply of S vapour, the growth rate increased as increasing $T_d$(decomposition temperature of $Ag_2S$) and ${\Delta}T$ between $T_d$ and $T_g$(temperature of growth surface). At low S vapour pressure, growth rate decreased with decreased vapour pressure and ${\beta}-$Ag_2S$ was grown in the form of whisker, when Ag+ion is sufficiently supplied. The measured values of electronic conductivity of ${\beta}-$Ag_2S$ showed that electronic conductivity of the poly crystal was larger than that of single crystal.

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Optimum Condition of Pencil Drawing Paper Sensor(PDPS) for Temperature Detecting (온도 감지용 연필 선 종이 센서 최적화 연구)

  • Kwon, Dong-Jun;Shin, Pyeong-Su;Kim, Jong-Hyun;Beak, Young-Min;Park, Ha-Sung;Park, Joung-Man
    • Journal of Adhesion and Interface
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    • v.18 no.1
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    • pp.1-7
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    • 2017
  • This study is about basic sensor experiment using PDPS by common pencil. 20 mm length, 3 mm thickness of line using 4B pencil is optimum condition. In order to be stable at point of contact between pencil line and copper wire, silver paste is needed. At using the PDPS, thermal detecting is able and thermal properties is inversely proportional to electrical resistance in the based on empirical formula. The sensor can be also used in the composites mold via the empirical formula by the relationship between thermal impact and electrical resistance. The change of electrical resistance relates the interfacial property of composites. It leads to expectation of properties.

Characterization of interfacial electrical properties in InSb MIS structure (InSb MIS구조에서의 계면의 전기적 특성 평가)

  • Lee, Jae-Gon;Choi, Sie-Young
    • Journal of Sensor Science and Technology
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    • v.5 no.6
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    • pp.60-67
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    • 1996
  • The interfacial electrical properties of InSb MIS structure with low temperature remote PECVD $SiO_{2}$ have been characterized. The interlace-state density at mid-bandgap of the MIS structure was about $1{\sim}2{\times}10^{11}\;cm^{-2}eV^{-1}$, when the $SiO_{2}$ film was deposited at $105^{\circ}C$. However, large amount of interlace states and trap states were observed in the MIS structure fabricated at temperatures above $105^{\circ}C$. The time constant of $10^{-4}{\sim}10^{-5}\;sec$ of interface states was extracted from G- V measurement. As the deposition temperature increased, the hysteresis of C- V curves were increased due to the high trap density.

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Effect of surfactants and Environmental Factors on the Bioremediation of Phenanthrene (토양내 Phenanthrene의 생물학적분해에 미치는 계면활성제와 환경변수의 영향)

  • 류두현;최상일;김광수
    • Journal of Korea Soil Environment Society
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    • v.3 no.2
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    • pp.115-125
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    • 1998
  • The biodegradation of ($C^{14}$)phenanthrene was studied in water and soil-water systems with nonionic surfactants and biosurfactant : polyoxyethylene alkyl ester($C_{17}$$H_33$COO($C_2$$H_4$O)nH) and sophorolipid. The extents of so1ubilization and biodegradation were monitored by radiotracer technique. Experimental results showed that surfactant concentrations above the critical micelle concentration were toxic to the phenanthrene-degrading bacteria in soil or active sludge and the presence of surfactant micelles inhibited mineralization of PAHs. Solubility and bioavailibility of phenanthrene in water and soil-water system were enhanced by mixed surfactants system. The optimum water content and hydrogen concentration were 30% (w/v) , pH 7, respectively.

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Interfacial Reactions of Co/Ti Multilayer System (Co/Ti 다층 박막 구조 시스템에서의 계면 반응에 관한 연구)

  • Lee, Sang-Hoon;Park, Se-Jun;Ko, Dae-Hong
    • Applied Microscopy
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    • v.29 no.2
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    • pp.255-263
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    • 1999
  • We have investigated the interfacial reactions in Co/Ti multilayer thin films prepared by DC Magnetron sputtering system. We observed that the amorphous Co-Ti phase formed by SSAR (Solid State Amorphization Reaction) upon annealing at $200^{\circ}C$. Upon annealing treatments at $300^{\circ}C\;and\;400^{\circ}C$, a crystalline phase of CoTi formed at the Co/Ti interface. The sheet resistance of Co/Ti multilayer thin film increased by the formation of the amorphous phase at the Co/Ti interface, which decreased by the formation of new crystalline compound CoTi.

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Dynamic Behavior Study Using Videomicroscopy in Systems Containing Polar Oils and Nonionic Surfactant (극성 오일, 비이온성 계면활성제를 포함한 계에서의 Videomicroscopy를 이용한 동적 거동에 관한 연구)

  • Lim, Jong-Choo
    • Applied Chemistry for Engineering
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    • v.8 no.3
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    • pp.473-481
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    • 1997
  • Enhanced videomicroscopy was used to observe the dynamic behavior which occurred when water containing pure nonionic surfactant was carefully contacted with equal volumes of polar oils such as oleyl alcohol and oleic acid at various temperatures. A key component of the system is a vertical-stage microscope which provides for stable interfaces by locating the oil above the denser aqueous phase. This arrangement allowed intermediate phases formed at the surface of contact to be clearly observed, as well as any spontaneous emulsification which developed. Contacting experiments with $C_{12}E_5$ as the surfactant and with pure oleyl alcohol and oleic acid soils showed little activity below the cloud point but vigorous activity at higher temperatures including formation of an intermediate lamellar liquid crystalline phase. Diffusion path theory, which allows prediction of spontaneous emulsification resulting from diffusion and of intermediate phase formation during contacting processes, was used to understand the dynamic behavior seen during contacting experiments. Tentative diffusion paths for the contacting experiments with pure oleyl alcohol were presented with the aid of a partial phase diagram of the oleyl alcohol-water-$C_{12}E_5$ system.

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Solution Behaviour of Nonionic Surfactants with Polyolic Group as Hydrophilic Portion (폴리올류를 친수부로 한 비이온성 계면활성제의 용액거동)

  • Kim, S.C.;Kim, T.Y.;Lee, S.Y.;Roh, S.H;Nam, K.D.
    • Applied Chemistry for Engineering
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    • v.5 no.4
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    • pp.573-579
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    • 1994
  • 1-O-oleoyl glycerol, 2-O-oleoyl myo-inositol and methyl 2-O-oleoyl-${\alpha}$-D-glucopyranoside were used as surfactants in this study. The solution properties and solubilization process of those nonionic surfactants were examined by the phase equilibria. As a result of this study, we have found that phase behavior of two component systems of surfactants/$H_2O$/cyclohexane depends on temperature respectively. The three phase regions of three component systems appeared in the temperature range of $27^{\circ}C{\sim}32^{\circ}C$, $36^{\circ}C{\sim}45^{\circ}C$ and $38^{\circ}C{\sim}52^{\circ}C$ and solubilization of water and oil was high in those three phase ranged As the temperature was varied in the two component systems, liquid crystals of hexagonal were observed to in the case of 1-O-oleoyl glycerol, and liquid crystal of lamella types were observed in the case of 2-O-oleoyl myo-inositol and methyl 2-O-oleoyl-${\alpha}$-D-glucopyranoside.

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A Study on the Optimum Condition and GMB Addition in Emulsifying (에멀젼화의 퇴적조건과 예감제 첨가에 관한 연구)

  • 안명석;조명찬;김종현
    • Explosives and Blasting
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    • v.22 no.1
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    • pp.1-4
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    • 2004
  • The gelatine dynamite, which has been traditionally used in Korea as the 2nd generation explosive, is now being rapidly replaced by an emulsion explosive because of the change in life environment economic schemes, and safety reasons. However, there has been lack of study in the surfactant which is an important factor in manufacturing technology of emulsion explosives, and especially GMB technology has not been used in Korea. In this study, effective usage of surfactant with optimum dosage and optimum mixing temperature of GMB was investigated to increase safety and effectiveness.

Marangoni Convection Effects on Crystal Growth (결정 성장에서 Marangoni 대류의 영향)

  • 강승민;최종건;오근호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.2 no.2
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    • pp.77-82
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    • 1992
  • When a crystal is grown by FZ process, the melt zone is located at between the solid of upper and lower side and is kept by the solid-liquid interface tension. On the surface of the melt zone, a surface tension gradient is occured by the difference of temperature and solute concentration, it is the driving force of marangoni flow. The crystal even in the steady state growth can become imperfect for the dislocation distribution and the solute concentration in the peripheral region of the crystal are higher than those in the inner part and the probability of the formation of the defects such as voids, bubble penetration, secondary phase creation and crack is high near the solid-liquid interface. This is because the solid -liquid interface becomes irregular because of the local variation of temperature in that region due to marangoni convection.

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InAs/GaAs 양자점 태양전지에서 양자점 크기 및 온도에 따른 Photovoltage 효과

  • Yun, Su-Jin;So, Mo-Geun;Son, Chang-Won;Han, Im-Sik;No, Sam-Gyu;Lee, Sang-Jun;Kim, Jong-Su
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.228.1-228.1
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    • 2013
  • Photoreflectance (PR) 분광법은 비접촉, 비파괴적인 변조분광법으로서 반도체 표면 및 계면의 광학적 특성 연구에 많이 이용되고 있다. PR 신호의 Franz-Keldysh oscillation (FKO)으로부터 Molecular Beam Epitaxy (MBE) 방법으로 성장한 InAs/GaAs 양자점 태양전지 접합계면의 전기장을 조사하였다. InAs 양자점의 크기는 각각 1.7, 2.0, 2.5, 3.0 monolayer이며, p+-n-n+ 태양전지 구조의 표면으로부터 1.8 ${\mu}m$, 활성영역으로부터 약 1.1 ${\mu}m$ 위치에 삽입되어 있다. 여기광 세기가 큰 영역(1~200 $mW/cm^2$)에서 접합계면의 전기장으로부터 관측한 photovoltage 효과는 로그 스케일에서 대체로 선형적인 분포를 보였으며, 이를 계산결과와 비교 분석하였다. 또한, 양자점 크기 및 온도에 따른 photovoltage 효과는 활성영역에서 여기된 운반자의 양 및 양자점에 의한 전하트랩의 영향과 관련하여 비교 분석하였다.

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