• Fire Science and Engineering
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• v.23 no.3
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• pp.103-109
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• 2009

The thermal degradation of concrete results mainly from two mechanisms. The first one is related to phase transformations of constituents at different temperatures. The initial constituents transform to other phases due to elevated temperature. The second mechanism is related to the temperature sensitivity of the mechanical properties of the constituents in concrete. Therefore, the degradation of concrete under high temperatures must be studied from both mechanical and chemical points of view. This study was performed as a basic study to propose the material models of concrete exposed to high temperatures considering above two mechanisms. This study presents a prediction model on the porosity of hardened cement paste considering phase changes according to temperature increase.

• Journal of the Korea institute for structural maintenance and inspection
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• v.18 no.1
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• pp.84-92
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• 2014

The purpose of study is to analyze mechanism with early high portland cement and hardening accelerator. As the result, it was concluded that hardening accelerator makes accelerates appearance of $Ca(OH)_2$ through experiment using TG-DTA when it hydrates with cement. On the result of compressive strength, as increasing the amount of hardening accelerator used, early compressive strength was improved. Also, as a result of hydration heat, hardening accelerator accelerates hydration of $C_3S$ that is cement's component. On the result of XRD's analyzation, hydration product for each age could be check and it was shown that as increasing the amount of hardening accelerator used, peak point of hydration product was recorded high. As the result of SEM, appearance of C-S-H was shown as the amount of $Ca(OH)_2$'s appearance and each age according to additive contents of hardening accelerator. Therefore hardening accelerator used on this study is effective on getting early compressive strength.

• Korean Journal of Materials Research
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• v.9 no.5
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• pp.467-472
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• 1999

The isothermal cure behavior of diglycidyl ether of bisphenol A(DGEBA) 4,4'-methylene dianiline(MDA) system with various contents of neopentyl glycol(NPG) has been analyzed by differential scanning calorimetry(DSC). TO increase the cure rate of DGEBA/MDA system, NPG was introduced as an accelerator. Regardless of the NPG content, the shape of the conversion curves showed sigmoid indication that DGEBA/MDA/NPG system followed autocatalytic cure reaction. The cure reaction of DGEBA/MDA system increased with the increment of NPG content and it was due to the catalytic role of hydroxyl groups of NPG.

• Composites Research
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• v.31 no.6
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• pp.404-411
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• 2018

As the autoclave process progresses in a given cure cycle, residual stress in the composite product is induced by cure shrinkage of the resin. As a result, It generates the thermal deformation such as spring-in and warpage, and the inaccuracy of the final product increases. It is important to predict thermal deformation in aerospace parts which require precise fabrication. The research has been done on predicting and grasping curing process of composite material. In this study, the cure mechanism of composite materials according to the process is predicted through finite element analysis, and the effect of cure shrinkage on thermal deformation generated by the process is analyzed.

• Journal of the Korea Concrete Institute
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• v.18 no.4 s.94
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• pp.449-458
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• 2006

The discharge of fly ash that is produced by coal-fired electric power plants is rapidly increasing in Korea. The utilization of fly ash in the raw materials would contribute to the elimination of an environmental problem and to the development of new high-performance materials. So it is needed to study the binder obtained by chemically activation of pozzolanic materials by means of a substitute for the cement. Fly ash consists of a glass phase. As it is produced from high temperature, it is a chemically stable material. Fly ash mostly consists of $SiO_2\;and\;Al_2O_3$, and it assumes the form of an oxide in the inside of fly ash. Because this reaction has not broken out by itself, it is need to supply it with additional $OH^-$ through alkali activators. Alkali activators were used for supplying it with additional $OH^-$. This paper concentrated on the strength development according to the kind of chemical activators, the curing temperature, the heat curing time. Also, according to scanning electron microscopy and X-Ray diffraction, the main reaction product in the alkali activated fly ash mortar is Zeolite of $Na_6-(AlO_2)_6-(SiO_2)_{10}-12H_2O$ type.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.31 no.3A
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• pp.251-260
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• 2011

In this study, the effect of natural jute fiber volume fraction on the bond characteristics of polyolefin based macro fiber in natural jute fiber reinforced cement composites, including bond strength, interface toughness, and microstructure analysis are presented. The experimental results on polyolefin based macro fiber pullout test of different conditions are reported. Natural jute fiber volume fractions ranging from 0.1% to 0.2% are used in the mix proportions. Pullout tests are conducted to measure the bond characteristics of polyolefin based macro fiber from natural jute fiber reinforced cement composites. Test results are found that the incorporation of natural jute fiber can effectively enhance the polyolefin based macro fiber-cement matrix interfacial properties. The bond strength and interface toughness between polyolefin based macro fiber and natural jute fiber reinforced cement composites increases with the volume fraction of natural jute fiber. The microstructural observation confirms the findings on the interface bond mechanism drawn from the fiber pullout test results.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.4
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• pp.443-450
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• 2021

The effects of blast furnace slag(BFS) and desulfurized gypsum(FDG) on the compressive strength of CFBA, and self-hydration of CFBA were studied. CFBA has self-hydrating and hardening properties, and it can be seen that the compressive strength of CFBA can be improved by using appropriate amounts of BFS and FDG. In addition, the self-hardening properties of CFBA are similar to the hydration reaction of 4CaO·Al₂O₃·Fe₂O₃ (C₄AF), a cement clinker mineral, and when free-CaO, CaSO₄ and CaCO₃ coexist, Compressive strength of CFBA is expressed by the formation of calcium carbo compounds and hydrates of ettringite, calcium silicate, and calcium aluminate.

• Journal of the Korean Society of Propulsion Engineers
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• v.11 no.6
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• pp.18-25
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• 2007

In a plastic metal forming of thermally rate-sensitive material, the localized shear band stems from evolution of a narrow region in which intensive plastic flow occurs. And it give rise to fatal fracture with plastic instability. The objectives of this study are to investigate the localization behavior by using numerical method and predict the failure for WHA(Tungsten Heavy Alloy). In this work, the implicit finite difference scheme is used because of the advantage about convergence and the numerical stability. This study is based on an analysed material with hardening as well as thermally softening behavior which includes isotropic strain hardening and observed the extension of localization within shear band according to material properties.

• Journal of the Korean Chemical Society
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• v.41 no.6
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• pp.299-303
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• 1997

The rate constants($k_{OH}$) for the alkaline hydrolysis of the 4-substituted phenyl ethyl benzylphosphonates were determined in various buffer solutions by UV(Vis spectrophotometer. The activation entropies of the title reactions show negative values and this result is not consistent with a dissociative mechanism (EA) for which a positive or slightly negative value of the entropy of activation should be expected. An associative mechanism(AE) is favorable because the negligible negative charge is generated on the leaving group in the rate determining step from a good Hammett relationship(ρ=1.89). By the results of a kinetic study, we conclude that a dissociative mechanism is not proceeded in the title reactions.

• Journal of the Korean GEO-environmental Society
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• v.12 no.10
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• pp.5-12
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• 2011

Recently, NDS(Natural and Durable Stabilizer)method and other similar methods are composed of inorganic accelerating agent and the ultra-super fine cement have been studied as the ground improvement material in Korea. However, in the existing research, the chemical changing process of NDS in the strength development mechanism with the elapsed curing time and the principles of strength development did not give an explanation. For the popularization of the inorganic grout material, it determined that the mechanism verifying of the curing process had to be clearly preceded. Therefore, unconfined compression test, SEM and XRD analysis were performed by the elapsed curing time and were analyzed. In addition, the same trial for SGR method, that is the representative example of the water glass grout material, was selected as comparative target in order to distinguish properties of NDS more clearly. The result of experiment, the strength development mechanism of NDS could be investigated through the close correlation of the unconfined compression strength - SEM - XRD analysis, and excellence of a performance was confirmed.