• Title/Summary/Keyword: 경계반응

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Computational Modeling of Cyclic Voltammetry on Multi-electron Electrode Reaction using Diffusion Model (확산모델을 이용한 다중전자 전극반응에 대한 순환전위법의 전산모델링)

  • Cho, Ha-Na;Yoon, Do-Young
    • Journal of the Korean Electrochemical Society
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    • v.15 no.3
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    • pp.165-171
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    • 2012
  • Here is implemented MATLAB program to analyze the characteristic curves of cyclic voltammetry which involves the multi-electron electrode reaction considered as key processes in electrochemical systems. For the electrochemical mass-transfer system, Fick's concentration equation subject to semi-infinite diffusion model for the boundary condition was discretized and solved by the explicit finite difference method. The resulting concentration values were converted into currents at each node by using Butler-Volmer equation. Based on the good agreement between the present numerical solution and the existing experimental results, effects of kinetic constants and CV scan rates on the reaction mechanism in multi-electron transfer processes were investigated effectively.

Subsurface Imaging using Headwave Stacking (선두파 중합을 이용한 천부지층의 영상화)

  • Park Jung-Jae;Ko Seung-Won;Shin Chang-Soo;Suh Jung-Hee
    • Geophysics and Geophysical Exploration
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    • v.5 no.3
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    • pp.178-184
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    • 2002
  • For economy and convenience, seismic refraction survey is widely used in surveying for large civil engineering work. The purpose of this study is to obtain the numerical responses of various models using Kirchhoff migration, and to analyze its application to the real data processing. Synthetic traveltime curve was calculated by vidale's algorithm, and various models such as 2 or 3 layer model and irregular topography model are tested to simulate the response of real structure. In order to compare the effect of initial velocity model, true velocity models, inversion results by tomography, smooth velocity models are used as an initial guess. The responses of model data show that the algorithm of this study is more sensitive to initial velocity model than the reflection survey, so choosing a suitable initial velocity model will be the most important thing in real data processing.

Development of Turbidity Backward Tracking Scheme Using Py_STPS Model and Monitoring Data (Py_STPS모형과 관측자료를 활용한 탁도역추적기법 개발)

  • Hong Koo Yeo;Namjoo Lee
    • Ecology and Resilient Infrastructure
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    • v.10 no.4
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    • pp.125-134
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    • 2023
  • In order to develop a backtracking technique for turbidity measurement data without discriminatory characteristics, three turbidity backtracking techniques for predicting inflow turbidity of a stream were compared using real-time turbidity data measured at automatic water quality measurement points located upstream and downstream of the stream and the Py_STPS model. Three turbidity backtracking techniques were applied: 1) simple preservation method of turbidity load considering flow time, 2) a method of using the flow rate at the upstream boundary considering the flow time as the flow rate at the downstream boundary, 3) method of introducing internal reaction rate to reflect the behavior characteristics of turbidity-causing substances. As a result of applying the three backtracking models, it was confirmed that the backtracking technique that introduced the internal reaction rate had the best results.

A Study on the Unstable behavior according to Lode and boundary condition of shelled space frame structure (쉘형 스페이스 프레임 구조물의 하중 및 경계조건에 따른 불안정 거동에 관한 연구)

  • Kim, Nam-Seok;Shon, Su-Deog;Kim, Seung-Deog
    • Proceeding of KASS Symposium
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    • 2008.05a
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    • pp.80-85
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    • 2008
  • This paper investigate the structure instability properties of the shelled space frame structure. The large structure must have thin thickness for build the large space structure there fore structure instability review is important when we do structural design. The structure instability of the shelled structure accept it sensitively by varied conditions. This come to a nonlinear problem with be concomitant large deformation. In this study, it is compared unstable behavior according to lode and boundary condition of the shelled space frame structure through numerical method which considered geometrical nonlinear and grasped influence for the instability phenomenon and investigated the fundamental collapse mechanism.

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항내 정온계산 위한 BOUSS-2D 모형의 반사특성 검토

  • Ha, Chang-Sik;Kim, Tak-Gyeom;Kim, Jong-Hun;Yu, Ha-Sang
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2018.05a
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    • pp.65-66
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    • 2018
  • 국내 항만의 건설 및 확장 보수를 위한 설계 단계에서의 평면배치 검토시 항내측으로 내습하는 파랑변형특성에 대한 정밀한 평가는 필수적이다. 이에 따라 많은 수학적 모델들이 연안역과 항만에서의 파랑전파와 변형에 대해 개발되어 왔다. 특히 항내정온도의 해석은 항만 사용성 측면에서 매우 중요하며 실제 해상의 파랑상태와 유사한 불규칙파로의 해석이 요구되어 지고 있다. 항내정온도 해석에 있어서 항내파랑장 형성에 크게 영향을 미치는 구조물의 반사율을 효과적으로 적용하는 것은 매우 중요하다. 하지만, 구조물의 반사율은 이론계산이 어렵고, 일반적으로는 모형실험 혹은 현지관측에 의해 추정된다. 따라서, 일반적인 경우 비용 및 시간상의 제약으로 인해 평면 파랑모형으로 정온도 해석시 반사율의 적용은 구조형식별로 연구자들에 의해 개략 제시된 반사율을 적용하고 있다. 특히, 다방향 불규칙파의 적용시에 경계조건으로는 다방향 불규칙파를 효과적으로 제어할 수 있는 부분반사 경계면과 계산영역 밖으로 나가는 파랑에 대해서 인공적인 흡수층 또는 감쇠층(artificial damping layer)을 설정하여 반사를 제어하는 기법을 많이 적용하고 있다. 이때 항만구조물의 부분반사는 파랑제원에 따른 damping layer의 parameter의 조정에 의해 구조물의 구조형식별 반사율을 적절히 재현할 필요성이 있다. 본 연구에서는 불규칙파를 대상으로 damping layer의 parameter(무차원 감쇠계수, 감쇠층의 두께)등의 변화에 따른 반사율의 변화특성을 고찰하고, 향후 부분반사 경계면으로 damping layer가 적용되는 평면 파랑모형의 정온도 해석시 부분반사의 적용에 대한 기초자료를 제공하고자 한다.

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A Study on the Heat Storage System for Chemical Heat Pump Using Inorganic Hydrates (II) -Numerical Analysis of Heat Transfer in CaO Hydration Packed Bed- (화학열펌프에 있어서의 무기수화물계 축열시스템에 관한 연구(II) -CaO 수화반응층의 전열해석-)

  • Park, Young-Hae;Chung, Soo-Yull;Kim, Jong-Shik
    • Applied Chemistry for Engineering
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    • v.7 no.3
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    • pp.518-529
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    • 1996
  • To develope chemical heat pump using available energy sources such as solar heat and many kinds of waste thermal energy we have studied the enhancement effect of inserted fins in cylindical packed bed reactor. Two dimensionnal(radial and circumferential) partial differential eqaetions, concerning heat and masstransfer in CaO packed bad, are solved numerically to describe the characteristics of the reaction of fins inserted reactor and heat transfer. The results obtained by numerical analysis about two dimensional profiles of temperature and conversion in the reactant in the packed bed and exothermic heat amount released from the reactor are follows; -. The insertion of fins in reactor can redue the reaction completion time by half. -. The rate of thermochemical reaction depends of the temperature and concentration and it is also governed by the boundary conditions and heat transfer rate in the particle packed bed.

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A Study on the Heat Storage System for Chemical Heat Pump Using Inorganic Hydrates (III) -Numerical Analysis of Heat Transfer in Ca(OH)2 Dehydration Packed Bed- (화학열펌프에 있어서의 무기수화물계 축열시스템에 관한 연구(III) -Ca(OH)2 탈수반응층의 전열해석-)

  • Park, Young-Hae;Lee, Young-Sei;Kim, Jong-Shlk
    • Applied Chemistry for Engineering
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    • v.7 no.6
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    • pp.1181-1191
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    • 1996
  • To develope chemical heat pump, which is operated by heat of high temperature using available energy sources such as solar heat and many kinds of waste thermal energy we have studied theoretically the enhancement effects of inserted fins on the rate of heat transfer and reaction in cylinderical $Ca(OH)_2$ packed bed reactor. The results obtained by numerical analysis about profiles of temperature, completion time of reaction and exothermic heat amount released from the reactor read as the inserted copper fins in reator reduce the completion time of dehydration reaction in packed bed by half, and the rate of thermochemical reaction depends on the temperature and concentration, and it is also governed by the boundary conditions and the rate of heat transfer in the particle packed bed.

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Fluid flow control using animated B-Spline surface (움직이는 B-Spline 곡면을 이용한 유체 흐름의 제어)

  • Hwang, Chul-Hyun;Kyung, Min-Ho
    • Journal of the Korea Computer Graphics Society
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    • v.10 no.2
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    • pp.35-41
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    • 2004
  • 유체 시뮬레이션은 Navier-Stoke 방정식의 해를 구하는 과정으로 볼 수 있는데, 이 방정식은 초기 조건 및 주변 환경에 따라 매우 민감하게 반응하기 때문에 사용자가 원하는 형태로 제어하는 것이 매우 어려운 일이다. 본 논문에서는 유체의 움직임을 실제 공간에 임베드된 smooth manifold 위로 제한하고, 유체의 움직임을 manifold의 모양에 의해 직관적으로 제어하는 방법을 제안한다. 제어 manifold 안의 유체의 흐름을 자연스럽게 유지하기 위하여 경계에 가상의 중력장을 설정하여 유체가 경계면에서 자연스럽게 내부로 유도되도록 하였다. 본 논문의 유체 제어 방법은 제어 manifold의 모양을 키프레임 보간함으로써 간접적으로 유체 애니메이션의 키프레임 애니메이션으로 만드는 것도 가능하다. 이 과정에서 제어 manifold의 변형에 의한 유체정보를 재구성이 필요한데, 본 연구에서는 그리드의 재샘플링을 통해 해결하는 방법을 제시하였다.

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Response of Spatially Developing Turbulent Boundary Layer to Spanwise Oscillating Electromagnetic Force (횡 방향 진동하는 전자기력에 대한 공간 발달하는 난류 경계층의 반응)

  • Lee, Joung-Ho;Sung, Hyung Jin
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.11 s.242
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    • pp.1189-1198
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    • 2005
  • Direct numerical simulations were performed to investigate the physics of a spatially developing turbulent boundary layer flow subjected to spanwise oscillating electromagnetic forces in the near wall region. A fully implicit fractional step method was employed to simulate the flow. The mean flow properties and the Reynolds stresses were obtained to analyze the near-wall turbulent structure. It is found that skin friction and turbulent kinetic energy can be reduced by the electromagnetic forces. The decrease in production is responsible fur the reduction of turbulent kinetic energy. Instantaneous flow visualization techniques were used to observe the response of streamwise vortices and streak structures to spanwise oscillating forces. The near-wall vortical structures are affected by spanwise oscillating electromagnetic forces. Following the stopping of the electromagnetic force, the flow eventually relaxes back to a two-dimensional equilibrium boundary layer.

Development of the coating materials consisting of Zr-Al-Cu for nano structured coating and investigation of their friction behavior (Zr-Al-Cu계 나노구조 코팅재 설계개발 및 윤활마찰거동 조사)

  • Sin, Seung-Yong;Mun, Gyeong-Il;Seon, Ju-Hyeon
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.17-18
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    • 2014
  • 최근 자동차 성능 및 연비향상을 위해서 엔진의 고출력화 및 소형화 경향이 뚜렷해지고 있으며, 이로 인해 엔진내부의 부품이 받는 환경은 더욱 가혹해 지고 있다. 즉, 자동차 엔진 구동부품은 금속간의 접촉가능성이 매우 높은 경계윤활조건에 놓이게 되며, 또한 배기가스 규제로 인한 첨가제를 최소화 하려는 경향에 따라 경계윤활 환경에서 더욱 심한 마모문제에 직면할 것으로 예상되어 내구성 및 내마모성이 높은 코팅기술에 대한 요구가 더욱 증가하고 있다. 본 연구에서는 Zr기지의 비정질 형성능을 갖는 합금계를 이용하여 아르곤 및 질소분위기에서 스퍼터링 함으로써 고경도의 ZrN상과 엔진오일과 반응하여 저마찰 트라이보 필름을 형성시킬 수 있는 금소계 원소가 Tissue phase로 존재하는 질화물 나노박막합성기술을 개발한 후 자동차 구동부품인 벨브트레인계 및 피스톤링/라이너 부품에 적용하여 마찰특성을 평가하였다.

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