• Title/Summary/Keyword: 결정소성

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A Numerical and Experimental Study on Structural Performance of Noncomposite and Composite Eco-Arch Structures subjected to Concentrated Loads (집중하중을 받는 비합성.합성 생태아치구조물의 성능평가를 위한 수치해석 및 모형실험 연구)

  • Kim, Yong-Hee;Park, Jong-Sup;Lee, Young-Ho;Oh, Min-Su
    • Journal of Korean Society of Steel Construction
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    • v.22 no.2
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    • pp.173-183
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    • 2010
  • In this study, noncomposite and composite eco-arch structures with I-beams and precast concrete(PC) decks were investigated. Four finite-element models(a steel-girder model, a steel-girder-and-several-PC-panels model, a three-steel-girder model, and a three-steel-girder-and-several-PC-panels model) using a general finite-element program, ABAQUS, were reviewed to predict the strength of the noncomposite and composite arch structures. Based on the results of the finite- element analysis, the behaviors of the four models were investigated, and deflection and strain gauges for the experimental specimen consisting of three steel girders and several PC panels were set up to obtain the ultimate strength. The ultimate strength of the specimen was estimated to be 1,961kN. The ultimate strength was much larger than the 1,380-kN load calculated using AASHTO LRFD Bridge Design Specifications(2007). The noncomposite and composite arch bridges were found to have enough strength for safety.

Analytical Study on Hybrid Precast Concrete Beam-Column Connections (하이브리드 프리캐스트 보-기둥 접합부의 해석적 연구)

  • Choi, Chang-Sik;Kim, Seung-Hyun;Choi, Yun-Cheul;Choi, Hyun-Ki
    • Journal of the Korea Concrete Institute
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    • v.25 no.6
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    • pp.631-639
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    • 2013
  • Non-linear finite element analysis for newly developed precast concrete details for beam-to-column connection which can be used in moderate seismic region was carried out in this study. Developed precast system is based on composite structure and which have steel tube in column and steel plate in beam. Improving cracking strength of joint under reversed cyclic loading, joint area was casted with ECC (Engineering Cementitious Composites). Since this newly developed precast system have complex sectional properties and newly developed material, new analysis method should be developed. Using embedded elements and models of non-linear finite element analysis program ABAQUS previously tested specimens were successfully analyzed. Analysis results show comparatively accurate and conservative prediction. Using finite element model, effect of axial load magnitude and flexural strength ratio were investigated. Developed connection have optimized performance under axial load of 10~20% of compressive strength of column. Plastic hinge was successfully developed with flexural strength ratio greater than 1.2.

Analysis of the Stability and Behavior of a Calcareous Rock Slope During Construction of a Tunnel Entrance (터널출입구 시공에 따른 석회암 사면의 안정성 및 거동 분석)

  • Song, Young-Suk;Yun, Jung-Mann
    • The Journal of Engineering Geology
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    • v.23 no.3
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    • pp.283-292
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    • 2013
  • A calcareous rock slope failed during excavation of the slope for construction of a tunnel entrance. The slope is located at the construction site for widening highway in Yeongwol, Korea. Field surveys, laboratory tests, and numerical analyses were performed to determine the reason for the slope failure. The numerical analysis revealed that the safety factor of the slope before construction of the entrance was less than 1, and that this decreased after construction. After construction of the entrance, the sliding zone of the slope increased and slope stability decreased because the shear strain and plastic zone in the slope over the tunnel entrance showed an increase relative to the lower part of the slope. To enhance the stability of the slope for construction of the tunnel entrance, countermeasures such as rock bolts, rock anchors, and FRP (Fiber glass Reinforced Plastic) grouting were adopted in light of the field conditions. Serial field monitoring performed to confirm the reinforcing effects of the adopted countermeasures revealed a small amount of horizontal deformation of the slope soils, most of the elastic deformation that can regain its former value. In addition, the axial forces of the rock bolt and anchor were more strongly affected by slope excavation during construction of the tunnel entrance than by tunnel excavation or the rainy season, and the axial forces tended to converge after excavation of the tunnel. Therefore, we can confirm that the slope is currently safe.

Effect of Ni on Pt/$Ce_{(1-x)}Zr_{(x)}O_2$ catalysts for water gas shift reaction (WGS 반응용 Pt/$Ce_{(1-x)}Zr_{(x)}O_2$ 촉매에 Ni 첨가에 따른 영향)

  • Jeong, Dae-Woon;Kim, Ki-Sun;Eum, Ic-Hwan;Lee, Sung-Hun;Koo, Kee-Young;Yoon, Wang-Lai;Roh, Hyun-Seog
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.232-232
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    • 2009
  • 최근 WGS반응용 Pt 촉매의 성능 향상을 위한 다양한 담체 및 조촉매(Promotor) 개발에 대한 연구가 활발하게 진행되고 있다. 선행 연구결과, 입방(Cubic)구조를 가지는 $Ce_{0.8}Zr_{0.2}O_2$ 담체는 정방 입계(Tetragonal)구조를 가지는 $Ce_{0.2}Zr_{0.8}O_2$ 담체 또는 혼합산화물(Mixed oxide)구조를 가지는 $Ce_{0.5}Zr_{0.5}O_2$ 담체 보다 높은 활성과 안전성을 가진다. 이것은 촉매의 성능 향상이 Ce-$ZrO_2$의 결정구조에 의존한다는 것을 나타낸다. 따라서 WGS 반응에서 Ce/Zr 비에 따라 변화된 담체 특성이 Pt 촉매의 활성에 영향이 있을 것으로 예상되며 실험결과 1% Pt/$CeO_2$ 촉매가 가장 높은 활성을 나타내었다. 따라서 Pt/Ce-$ZrO_2$ 촉매의 성능 향상을 위해 Ce-$ZrO_2$ 담체에 조촉매인 Ni을 첨가하여 촉매적 활성을 비교하여 보았다. 촉매는 2%의 Pt과 15%의 Ni로 고정하였고 Ce/Zr 비를 제조변수로 하였다. 제조된 모든 담체는 공침법(Co-precipitation)을 사용하여 제조하였으며 $500^{\circ}C$에서 6시간 소성하였다. Pt 촉매는 함침법 (Incipient wetness impregnation)으로 담지 시켰다. 2% Pt/Ce-$ZrO_2$ 촉매와 2% Pt/15% Ni-Ce-$ZrO_2$ 촉매는 저온영역($200^{\circ}{\sim}320^{\circ}C$)에서 비슷한 CO 전환율을 나타내었으나 고온영역($360^{\circ}C{\sim}400^{\circ}C$)에서는 2% Pt/15% Ni-Ce-$ZrO_2$ 촉매가 더 높은 CO의 전환율을 나타내었다. 이것은 Ni의 영향으로 고온에서 부반응인 메탄화 반응(Methanation reaction)이 생긴 것으로 판단되어 메탄($CH_4$)의 선택도를 살펴본 결과 2% Pt/15% Ni-Ce-$ZrO_2$ 촉매가 고온영역($360^{\circ}{\sim}400^{\circ}C$)에서 급격하게 증가하는 것으로 나타나 메탄화 반응이 일어난 사실을 증명한다.

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Archaeomagnetic Study on Roof Tile Kilns of Goryeo Period in Gyeonggi Region (경기지역 고려시대 기와가마에 대한 고고지자기학적 연구)

  • Sung, Hyong Mi
    • Journal of Conservation Science
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    • v.32 no.1
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    • pp.1-10
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    • 2016
  • At the archaeological site, there are a variety of fired soil remains with which archaeomagnetic dating is measured, and there are also different kinds of kilns equipped with favorable plasticity conditions, so quality data can be gained. Among them, roof tile kilns indicate fairly great results of archaeomagnetic measuring. This should be associated with the properties of soil consisting of the kilns. With a lot of experimental results, it has been found that the fired soil samples of roof tile kilns have formed very stable residual magnetization. This author conducted archaeomagnetic research to present archaeomagnetic results of measuring about roof tile kilns from Goryeo in Gyeonggi. With the archaeomagnetic data of measuring 21 samples, this researcher tried to estimate the archaeomagnetic dating of roof tile kilns from Goryeo in Gyeonggi and divided them into three groups, group A (A.D.900~1150), group B (A.D.1150~1250), and group C (A.D.1300~1400) to figure out their relative order and arrange them in order. Through this kind of archaeomagnetic research, it will be possible to identify the dating of 21 roof tile kilns from Goryeo in Gyeonggi and also contribute considerably to chronological research on roof tile kilns from Goryeo. In the body, the remains and kilns belonging to each group are presented in detail.

Growth of $CdS_{0.67}Se_{0.33}$ single crystal by sublimation method and their photoconductive characteristics (승화법에 의한 $CdS_{0.67}Se_{0.33}$ 단결정 성장과 광전도 특성)

  • Hong, K.J.;Lee, S.Y.
    • Journal of Sensor Science and Technology
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    • v.7 no.2
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    • pp.131-139
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    • 1998
  • $CdS_{0.67}Se_{0.33}$ single crystal was grown by vertical sublimation method of closed tube physical vapour deposition. The (0001) growth plane of oriented single crystals was confirmed from the back-ref1ection Laue patterns. From the Hall effects by van der Pauw method, the as-grown $CdS_{0.67}Se_{0.33}$ single crystals were found to be n-type semiconductors. The mobility appeared to be decreased by lattice scattering at temperature range from 150K to 293K and by impurity scattering at temperatures ranging from 30K to 150K In order to explore its applicability in photoconductive cells, we measured the ratio of photo-current to dark-current (pc/dc), maximum allowable power dissipation (MAPD), spectral response and response time respectively. The results indicated that for the samples annealed in Cu vapour the photoconductive characteristics are best. We obtained sensitivity of 0.99, the value of pc/de of $1.84{\times}10^{7}$, the MAPD of 323mW and the rise and decay time of 9.3 ms and 9.7 ms, respectively.

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Estimation of Shear Strength Along Concrete Construction Joints Considering the Variation of Concrete Cohesion and Coefficient of Friction (콘크리트 시공줄눈 면에서 점착력 및 마찰계수의 변화를 고려한 전단내력 평가)

  • Yang, Keun-Hyeok;Kwon, Hyuck-Jin;Park, Jong-Beom
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.6
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    • pp.106-112
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    • 2017
  • This paper presents a mathematical model derived from the upper-bound theorem of concrete plasticity to rationally evaluate the shear friction strength of concrete interfaces with a construction joint. The upper limit of the shear friction strength was formulated from the limit state of concrete crushing failure on the strut-and-tie action along the construction joints to avoid overestimating the shear transfer capacity of a transverse reinforcement with a high clamping force. The present model approach proposed that the cohesion and coefficient of friction of concrete can be set to be $0.27(f_{ck})^{0.65}$ and 0.95, respectively, for rough construction joints and $0.11(f_{ck})^{0.65}$ and 0.64, respectively, for smooth ones, where $f_{ck}$ is the compressive strength of concrete. From the comparisons with 155 data compiled from the available literature, the proposed model gave lower values of standard deviation and coefficient of variation of the ratios between predictions and experiments than AASHTO and fib 2010 equations, indicating that the proposed model has consistent trends with test results, unlike the significant underestimation results of such code equations in evaluating the shear friction strength.

Analysis of Contact Properties by Varying the Firing Condition of AgAl Electrode for n-type Crystalline Silicon Solar Cell (AgAl 전극 고온 소성 조건 가변에 따른 N-형 결정질 실리콘 태양전지의 접촉 특성 분석)

  • Oh, Dong-Hyun;Chung, Sung-Youn;Jeon, Min-Han;Kang, Ji-Woon;Shim, Gyeong-Bae;Park, Cheol-Min;Kim, Hyun-Hoo;Yi, Jun-Sin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.8
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    • pp.461-465
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    • 2016
  • n-type silicon shows the better tolerance towards metal impurities with a higher minority carrier lifetime compared to p-type silicon substrate. Due to better lifetime stability as compared to p-type during illumination made the photovoltaic community to switch toward n-type wafers for high efficiency silicon solar cells. We fabricated the front electrode of the n-type solar cell with AgAl paste. The electrodes characteristics of the AgAl paste depend on the contact junction depth that is closely related to the firing temperature. Metal contact depth with p+ emitter, with optimized depth is important as it influence the resistance. In this study, we optimize the firing condition for the effective formation of the metal depth by varying the firing condition. The firing was carried out at temperatures below $670^{\circ}C$ with low contact depth and high contact resistance. It was noted that the contact resistance was reduced with the increase of firing temperature. The contact resistance of $5.99m{\Omega}cm^2$ was shown for the optimum firing temperature of $865^{\circ}C$. Over $900^{\circ}C$, contact junction is bonded to the Si through the emitter, resulting the contact resistance to shunt. we obtained photovoltaic parameter such as fill factor of 76.68%, short-circuit current of $40.2mA/cm^2$, open-circuit voltage of 620 mV and convert efficiency of 19.11%.

Research on the Microstructure and Features of Pottery Excavated from Gijang-gun, Busan, South Korea (기장군출토 도자기의 미세구조 및 특성에 관한 연구)

  • Hong, Jong Ouk;Han, Min Su
    • 보존과학연구
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    • s.33
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    • pp.109-124
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    • 2012
  • Jangan-eup, located in Busan, South Korea,is a famous pottery-producing area in the Joseon Dynasty period. The aim of this paper was to determine the correlation of the pottery from each kiln site of Jangan-eup by analyzing the ingredients of clay as well as its production technique and firing condition. The materials that were used for the study were fragments of inlaid celadon, white porcelain, and white porcelain painted with underglazed iron excavated from six kiln sites of Jangan-eup:Sil-li, Daeryong-li, Hajangan-li, Sangjangan-li, Yongso-li, and Dumyeong-li. In each of the samples from the six kilns, cristobalite, mullite, and quats were found. The firing temperature distinguished from the crystal structure was higher in the following order: Dumyeongli>Sangjangan-li>Daeryong-li>Hajangan-li>Yongso-li>Sil-li. The samples were divided into four groups based on the ingredients of the clayfound therein: the Sil-li andDaeryong-li group, the Hajangan-li and Sangjangan-li group, the Yongso-li group, and the Dumyeong-li group. It was also found that the sample of Dumyeong-li was made using the most homogeneous clay compared with the other samples. The pottery of Jangan-eup had $40-400{\mu}m$ glaze, had bubbles in their bodies, and had $10-150{\mu}m$ sizes.

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Physicochemical Properties of Oxidized Rice Flour and Effects of Added Oxidized Rice Flour on the Textural Properties of Julpyun(Korean traditional rice cake) during Storage (TEMPO를 이용하여 산화시킨 쌀가루의 이화학적 특성 및 산화 쌀가루를 첨가한 절편의 저장 중 텍스처 특성)

  • Kim, Moon-Soo;Suh, Dong-Soon;Chang, Pahn-Shick;Kim, Kwang-Ok
    • Korean Journal of Food Science and Technology
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    • v.33 no.2
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    • pp.209-215
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    • 2001
  • This study was conducted to examine the effects of 2,2,6,6-tetramethyl-1-piperidine oxoammonium ion(TEMPO) and sodium bromide(NaBr) for the selective oxidation on primary alcohol groups of rice starch molecules in rice flour and to use oxidized rice flour in Julpyun to extend its shelf life. Reaction time decreased with higher levels of TEMPO and NaBr. Yield and selectivity decreased with increased NaBr levels. TEMPO increased yield until certain levels, but decreased thereafter. The levels of TEMPO and NaBr for the preparation of oxidized rice flour were determined as 0.9 and 44 mM/100 mM anhydroglucose unit, respectively. Water and oil binding capacities, and viscosity increased significantly by the oxidation of rice flour. The partial replacement of rice flour with oxidized rice flour increased peak viscosity and decreased setback. Oxidized rice flour with the increased amount of water showed positive effect on the textural properties of Julpyun during storage.

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