• Applied Chemistry for Engineering
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• v.32 no.2
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• pp.174-179
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• 2021

The coal tar pitch and phenol resins are used as binders in artificial graphite manufacture, but there are differences in the initial carbon compound structure. According to the carbonization temperature, it can be expected that there are differences in thermal decomposition behavior, microstructure, and crystallinity change. These properties of the coal tar pitch and phenol resins were compared to each other. As the carbonization temperature of coal tar pitch and phenol resin increases, crystallinity tends to increase. The coal tar pitch went through the carbonization process through the liquid, and it was confirmed that the crystallinity changed rapidly in the temperature range of 500 and 600 ℃, where the microstructure changed quickly. These results confirmed the close correlation between microstructure and crystallinity.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.291.1-291.1
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• 2014

산화아연 박막은 아연이 코팅된 테프론 기판 위에 졸-겔 스핀코팅 방법을 이용하여 각기 다른 후열처리 온도에서 제작되었다. 산화아연 박막의 후열처리 온도에 따른 구조적, 광학적 특성은 field emission scanning electron microscopy (FE-SEM), X-ray diffractometer, and photoluminescence spectroscope를 이용하여 분석하였다. 후열처리 온도를 달리하여 성장한 모든 산화아연 박막은 수지상(dendrite) 구조를 가지고 있으며, 이 수지상 구조 위에 약 20 nm의 산화아연 입자들이 성장되었다. 후열처리 온도가 증가함에 따라 c-축 배향성이 우세하게 나타났으며, 인장응력도 증가하였다. 후열처리 온도 $400^{\circ}C$에서 Near-band-edge emission (NBE) 피크는 적색편이(red-shift) 하였고, 후열처리 온도가 증가함에 따라 deep-level emission (DLE) 피크의 세기는 감소하였다. 또한 $400^{\circ}C$의 후열처리 온도에서 NBE 피크의 반치폭(FWHM)이 가장 작았으며, INBE/IDLE의 비율이 가장 높았다. 따라서 $400^{\circ}C$의 후열처리 공정에 의해 결정성 및 광학적 특성이 가장 우수한 산화아연 박막을 얻을 수 있었다.

• Applied Chemistry for Engineering
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• v.1 no.2
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• pp.232-239
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• 1990

${\gamma}$-Glycidoxy propyl trimethoxy slilane, CTBN rubber(carboxyl terminated butadiene acrylonitrile rubber) and GMA(glycidyl methacrylate) were reacted with the surface of silica one by one in existence of TEA(triethylamine) or BPO(benzoyl peroxide). The amount of reactant was 2.5~5.8% of treated silica weight. The treated silica was mixed with epoxy resin and MTHPA(methyltetrahydrophthalic anhydride) in the range of 0~60% (wt. %) of total component. The flexural and thermal properties were tested for cured products. In filler content 35~55%, the using of silica treated with silane/rubber or silane/rubber/vinyl represented 25% higher flexural strength, 5% lower flexural modulus and 13% higher than mixing liquid rubber 3% with epoxy resin containing untreated silica.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.1
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• pp.35-42
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• 2015

Injection molding is a high efficient manufacturing technology for producing plastic parts. On the other hand, the warpage of molded plastic parts is an ubiquitous problem in the injection molding process. The main objective of this study was to minimize the amount of warpage occurring in the injection molding process of a hopper of ATDPS made of crystalline polymer (PP) instead of amorphous polymer (ABS). The moldflow CAE simulation was conducted for the molding process of the hopper to clarify the injection moldability, shear rate, shear stress, warpage by changing the gate shape and the number of ribs installed on the top of the hopper flange. The wide gate shape of runner system and multiple rib installation were found to be useful for minimizing the warpage of the hopper. The validity of the CAE simulations was supported by the injection molding experiment for the optimized design case.

• Journal of the Korean Chemical Society
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• v.31 no.1
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• pp.45-54
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• 1987

Dowex 1-X8 resin ion exchanged with calcon carboxylic acid (CCA-Dowex 1-X8) and 2-methyl-8-hydroxyquinoline(MHQ) impregnated-Amberlite XAD-4 resin (MHQ-XAD-4) were examined for the separation and preconcentration of ferric ion from the various matrices. The stabilities of these resins were investigated, and their capacities on ferric ion were also measured. The effect of pH on the adsorption of ferric ion and matrix ions, such as Al(Ⅲ) and Ca(Ⅱ), was investigated to determine the optimun pH ranges. Separation and preconcentration of iron in aluminium foil and mineral water samples were studied by elution method with these resin columns. The recovered ions by 10ml of 2F nitric acid was determined by flame atomic spectrophotometry. SP-Sephadex C-25 column was used to separate ferrous and ferric ion in mineral water by stepwise elution with ferrozine and 1 % ascorbic acid-ferrozine solution. The concentrated and separated each ion could be determined spectrophotometrically at the analytical wavelenth of Fe(Ⅱ)-ferrozine complex (562nm).

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 1997.04a
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• pp.223-231
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• 1997

내열성복합재료와 Steel 구조물 사이의 좁고 긴 원통형 공간을 내열성 폴리우레탄 재료로 충전하는 연구를 수행하였다. 충전재료를 결정하기 위하여 3종의 폴리우레탄과 에폭시수지를 선정, 시험하여 내열성, 흐름성, 접착성, 경도측정 등을 통하여 최종 결정하였으며 선정된 폴리우레탄을 충전하기 위하여 Resin Transfer Molding(RTM) 방법을 사용하였다. 충전 공정의 적용여부를 판단하기 위하여 아크릴을 이용한 RTM치구를 설계, 제작하여 시험하였다. 충전된 조립체는 비파괴 검사를 통하여 접착, 기공 등을 검사하였으며 지상연소시험을 통하여 내열성능을 평가하였다.

• Journal of the Korean Chemical Society
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• v.28 no.6
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• pp.403-411
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• 1984

Amberlite XAD-7 and XAD-4 resins impregnated with DXHQ (5,7-dihalo-8-hydroxyquinoline) were prepared for the adsorption, separation and recovery of heavy metal ions from aqueous solutions. The characteristics of the impregnated resins, DXHQ (X : Cl, Br, I)-XAD were studied to find out the proper pairs of resin and DXHQ for the adsorption of metal ions. The increasing order of the impregnated amount of DXHQ onto XAD-7 resin was as follows: DCHQ < DBHQ < DIHQ. It was observed from the plot of log $K_d$ vs. pH that the optimum pH range for the adsorption of DIHQ onto XAD-4 resin was from 3.0 to 7.0. The stabilities of the DXHQ-XAD resins were investigated by measuring the amount of DXHQ remained on the XAD resin after shaking the DXHQ-XAD resins in various solutions of pH ranging from 2 to 12 and hydrochloric acid solutions. The impregnated resins were considerably stable in both acidic and neutral solutions. The amount of DIHQ leached from DIHQ-XAD-4 resin by eluting with various HCl solutions (1 ∼ 5M) was negligible, but in the case of XAD-7 resin it increases as the concentration of HCl solution increases. The optimum pH ranges, absorption mole ratio (M : DXHQ) and adsorption capacities (mmol metal per gram of resin) for the adsorption of metal ions onto the DXHQ-XAD resins were determined respectively. The stability of metal ion absorbed by the DXHQ-XAD resins was observed as the following order: M-DCHQ-XAD-7 < M-DBHQ-XAD-7 < M-DIHQ-XAD-7. The adsorbed metal ions were quantitatively recovered by eluting with HCl (0.5 ∼ 5M) and DXHQ-XAD resins could be reused over 5 times without re-impregnation of DXHQ.

• Proceedings of the Korea Water Resources Association Conference
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• 2016.05a
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• pp.109-109
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• 2016

유역의 물수지는 기상인자, 지형, 토양, 식생 등 여러 가지 인자들에 의해 결정된다. 물수지 분포를 평가하기 위해 수문모형의 모의 시 필요한 수문요소 조건들을 정보화하게 되며, 동시에 토양수분의 특성, 강우 입력자료, 유역의 지형학적 특성들은 불확실성에 기인하는 요소로 작용한다. 이러한 수문모형 모의 시 불확실성을 제거하기 위해 모형 초기조건에 대한 다각적인 분석이 선행이 필요하다. 특히 토양수분은 대기와 지표 사이의 상호작용에 작용하는 중요한 수문기상학적 인자로 평가되고 있다. 토양수분 데이터 자료를 이용하여 강우-유출모형의 입력자료를 구축하여 실제 토양수분의 변동성을 파악하는 연구가 활발히 진행되고 있으며, 유역기반의 유출현황을 산정하기 위해 매우 유용한 초기조건으로 그 역할이 기대된다. 현장에서 관측하는 토양수분 데이터는 넓은 유역의 토양수분을 대표하는 자료로 사용되기에는 한계점이 있으며, 위성기반 토양수분 데이터는 원격탐사를 통해 획득되기 때문에 토양수분의 시 공간적인 변동성 파악에 용의하며 경제성 또한 높다. 이에 따라, 본 연구에서는 유역의 수문순환 분석을 하고, 위성기반 토양수분의 적용 가능성을 평가하기 위해 Aqua위성에 탑재된 Advanced Mircowave Scanning Radiometer Earth Observing System(AMSR-E)와 Metop-A의 Advanced SCATterometer(ASCAT)의 토양수분 데이터를 이용하여 강우-유출모델의 초기조건을 산정하였다. 또한, 이에 대한 검증을 위해 기존 강우인자 초기조건 및 지점에서 관측된 토양수분 초기조건 등을 비교하여 통계분석을 실시하였다.

• International Area Studies Review
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• v.15 no.2
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• pp.331-350
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• 2011

This paper analyzes balance of goods for a panel data of 56 industry classification in the MTI from 1980 to 2009. This study also develops the equilibrium adjustment process, which is a trade-off between the adjustment costs towards equilibrium costs for balance of goods and the cost of being in disequilibrium. In this framework, the GMM estimation procedure is used to estimate this dynamic panel model consistently. It is found that equilibrium balances of goods in Korean adjust to the speed is very slow to 0.0389. because of this is necessary to adjust the equilibrium goods balance as the cost of goods balance deficit is larger than by the cost. In addition, the real income elasticity for goods balance of resin in Japan and Korea, the real income elasticity 4.38168 and -0.835225, respectively, the marks were consistent with economic theory. The exchange rate elasticity of goods balance in japan to 0.478435 were found in the inelastic.

• Polymer(Korea)
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• v.39 no.1
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• pp.114-121
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• 2015

Mutli-walled carbon nanotubes (MWCNTs) were surface-modified by a hydrofluoric acid solution to remove impurities and improve interfacial bonding and dispersion of nanotubes in an epoxy matrix. The crystallinity on the surface of treated MWCNTs was investigated by X-ray photoelectron spectroscopy and Raman spectroscopy. The mechanical properties were characterized by tensile test, and the enhancement of mechanical properties of the modified MWCNTs/epoxy composites was indicated by a 33% increase in tensile strength. The electromagnetic interference shielding effectiveness (EMI-SE) of modified MWCNTs/epoxy composites was improved with an increase in concentration of hydrofluoric solution, and EMI-SE showed the maximum increase with 25% HF. However, mechanical and EMI-SE properties didn't show further increase with over 50% HF concentration because the properties of MWCNTs were influenced by degradation of crystallinity and intrinsic properties of MWCNTs. The mechanical and electrical property enhancements of the polymer composites are attributed to the modification of MWCNTs which improve crystallinity of MWCNTs and dispersion in the epoxy resin.