• Title/Summary/Keyword: (L, N)-structure

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수정체 광투과에 대응하는 LPE Filter 설계 (Layout of Long-pass-edge Filter Correspond with the Optical Transmission in Crystalline)

  • 김용근
    • 한국안광학회지
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    • 제4권2호
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    • pp.57-63
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    • 1999
  • 소의 수정체의 광투과, 흡수 Spectrum을 Spectrophotometer로 200-800nm 영역에서 측정하였다. 자외선 A-B선 모두 흡수되고 400nm 영역에서 광투과 edge가 나타나고, edge 영역보다 큰 파장에서는 완전투과형 filter가 되었다. 특히 $4^{\circ}C$-$60^{\circ}C$온도에서 광흡수 투과율의 온도조성은 없었다. 박막 설계로부터 long-pass edge filter형인 $n_0/(0.5H)L(LH)^6(0.5H)/n_s$$n_0{\mid}(0.5LH0.5L)^kL/1.25{\mid}4.0$ 박막 구조가 소의 수정체 광투과 Spectrum과 일치함을 알 수 있었다. 인공수정체, 안내렌즈의 설계시 박막구조 설계를 추가함으로써 자외선 차단 역할을 할 수 있다.

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Stereoselective Solvolyses of Activated Esters in the Aggregate System of Imidazole-Containing Copolymeric Surfactants

  • Cho, I-Whan;Lee, Burm-Jong
    • Bulletin of the Korean Chemical Society
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    • 제10권2호
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    • pp.172-177
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    • 1989
  • Stereoselective solvolyses of optically active activated esters in the aggregate system of optically active polymeric surfactants containing imidazole and benzene moieties were performed. The catalyst polymers employed were copolymers of N-methacryloyl-L-histidine methyl ester (MHis) with N,N-dimethyl-N-hexadecyl-N-[10-(p-methacryloylo xyphenoxycarbonyl)-decyl]ammonium bromide(DEMAB). In the solvolyses of N-carbobenzoxy-D- and L-phenylalanine p-nitrophenyl esters (D-NBP and L-NBP) by polymeric catalysts, copoly(MHis-DEMAB) exhibited not only increased catalytic activity but also enhanced enantioselectivity as the mole ${\%}$ of surfactant monomers in the copolymers increased. The polymeric catalysts showed noticeable enantioselective solvolyses toward D- and L-NBP of the substrates employed. As the reaction temperature was lowered for the solvolyses of D- and L-NBP with the catalyst polymer containing 3.5 mole ${\%}$ of MHis, the increased reaction rate and enhanced enantioselectivity were observed. The coaggregative systems of the polymer and monomeric surfactants were also investigated. In the case of coaggregate system consisted of 70 mole ${\%}$ of cetyldimethylethylammonium bromide with polymeric catalyst showed maximum enantioselective catalysis, viz., $k_{cat}(L)/k_{cat}(D)$ = 2.85. The catalyst polymers in the sonicated solvolytic solutions were confirmed to form large aggregate structure by electron microscopic observation.

[Cu(L)](ClO4)2 (L:3,5,10-12-Tetramethyl-1,4,8,11-tetraazacyclotetradecane) 착물의 합성 및 구조 (Synthesis and Structure of [Cu(L)](ClO4)2 (L;3,5,10,12-Tetramethyl-1,4,8,11-tetraazacyclotetradecane))

  • 최기영;홍청표
    • 한국결정학회지
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    • 제9권1호
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    • pp.6-10
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    • 1998
  • [Cu(L)](ClO4)2(1)(L:3,5,10,12-Tetramethyl-1,4,8,11-tetraazacyclotetradecane) 착물을 합성하고 구조를 규명하였다. 이 착물은 단순결정, 공간군 P21/n, a=8.802(2)Å, b=13.339(6) Å, c=10.752(5) Å, β=111.02(4)˚, Z=2로 결정화 되었다. 이착물의구조는 최소자승법으로 정밀화 하였으며, 최종 신뢰도 R(Rw)값은 617개의 회석반점에 대하여 0.073및 0.142이었다. 이 착물의 결정구조는 평면사각구조와 trans-III형태를 갖는다.

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STRUCTURE OF THE SPIRAL GALAXY NGC 300 -1. The generalzation of Toomre's mass model-

  • Rhee, Myung-Hyun;Chun, Mun-Suk
    • Journal of Astronomy and Space Sciences
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    • 제9권1호
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    • pp.11-29
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    • 1992
  • In 1963, Toomre built up classes of mass models for the highly flattened galaxies which have free parameters n, $a_n$ and $C_n$. In order to keep the universal dimension, we adopt parameters $b_n({C_n}^2={a_n}^{2n}+^2{b_n}^2/(n-1)!)$ insteal of $C_n$. Series of the normalized Toomre's mass models (G = $V_{max}$ =$R_{max}$ = 1, n = 1 to 7) are derived and the normalized parameters $a_n$ and $b_n$ are determined by the iteration method. Replacing parameters $a_n$ and $b_n$ to ${a_n}^l(=a_nr_{max})$ and ${b_n}^l(=b_n\cdotV_{max}/r_{max})$, we can get the generalization of Toomre's mass model.

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$Ca_{2-X}-Ln_{x}MnO_{4}$상의 합성과 결정구조 정밀화 {Ln=Gd, Nd, Pr, Sm} (Syntheses and structure refinement of $Ln_{x}MnO_{4}$ {Ln=Gd, Nd, Pr, Sm})

  • 서상일;이재열
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.726-729
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    • 2000
  • Though L $a_{1+x}$S $r_{2-x}$M $n_2$ $O_{7}$ n=2 R-P phases have been well known to have CMR effect, it was generally believed that n=1 phase was insulating. But recently monolayered perovskite $Ca_{2-x}$L $n_{x}$Mn $O_4$phase has been reported to show magnetoresistance. In this study, layered perovskite $Ca_{2-x}$L $n_{x}$Mn $O_4$ (x=0, 0.5, Ln=Pr, Nd, Sm, Gd) phases were synthesized by solid state reaction and their structures were refined by Rietveld method. The space groups of $Ca_2$Mn $O_4$, N $d_{0.5}$C $a_{1.5}$Mn $O_4$phases were refined as C2cb and Fmmm, respectively.y.ely.y.y.y.y.y.y.

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Synthesis of a Di-N-cyanoethylated Tetraaza Macrocycle Containing Eight C-Methyl Groups and Its Nickel(II) Complex: Effects of the Methyl Groups on Their Properties

  • Kang, Shin-Geol;Ryu, Ki-Seok;Kim, Jin-Kwon
    • Bulletin of the Korean Chemical Society
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    • 제23권1호
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    • pp.81-85
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    • 2002
  • A new di-N-cyanoethylated 14-membered tetraaza macrocycle 1,8-bis(2-cyanoethyl)-3,5,7,7,10,12,14,14-octamethyl-1,4,8,11-tetraazacyclotetradecane $(L^2)$ and its nickel(II) complex $[NiL^2(OAc)]^+$ have been prepared. The square-planar complex $[NiL^2](C IO_4)_2$ can be prepared by addition of $HClO_4$ to a hot aqueous solution of $[NiL^2(OAc)]^+$ The Ni-N (tertiary amino group) bond distances $(2.008{\AA})$ of $[NiL^2](C IO_4)_2$ are relatively long, and the complex exhibits a d-d transition band at unusually long wavelength (ca. 515 nm). The complex $[NiL^2](C IO_4)_2$ rapidly reacts with acetate ion or ethylenediamine (en) to produce $[NiL^2(OAc)]^+$ or [Ni(en)_3]^{2+}$, respectively, and is readily decomposed in NaOH (0.01 M) solution. The chemical properties of $[NiL^2]^{2+}$ as well as its synthetic procedure are quite different from those for other related 14-membered tetraaza macrocyclic complexes. Effects of the N-cyanoethyl and C-methyl groups on the properties of $L^2$.

A METHOD OF COMPUTATIONS OF CONGRUENT NUMBERS AND ELLIPTIC CURVES

  • Park, Jong-Youll;Lee, Heon-Soo
    • 호남수학학술지
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    • 제32권1호
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    • pp.177-192
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    • 2010
  • We study the concepts of congruent number problems and elliptic curves. We research the structure of the group of elliptic curves and find out a method of the computation of L($E_n$, 1) and L'($E_n$, 1) by using SAGE program. In this paper, we obtain the first few congruent numbers for n ${\leq}$ 2500.

ON THE STRUCTURE OF MINIMAL SUBMANIFOLDS IN A RIEMANNIAN MANIFOLD OF NON-NEGATIVE CURVATURE

  • Yun, Gab-Jin;Kim, Dong-Ho
    • 대한수학회보
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    • 제46권6호
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    • pp.1213-1219
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    • 2009
  • Let M$^n$ be a complete oriented non-compact minimally immersed submanifold in a complete Riemannian manifold N$^{n+p}$ of nonnegative curvature. We prove that if M is super-stable, then there are no non-trivial L$^2$ harmonic one forms on M. This is a generalization of the main result in [8].

Genetic characterization and population structure of six brown layer pure lines using microsatellite markers

  • Karsli, Taki;Balcioglu, Murat Soner
    • Asian-Australasian Journal of Animal Sciences
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    • 제32권1호
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    • pp.49-57
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    • 2019
  • Objective: The first stage in both breeding and programs for the conservation of genetic resources are the identification of genetic diversity in the relevant population. The aim of the present study is to identify genetic diversity of six brown layer pure chicken lines (Rhode Island Red [RIRI, RIRII], Barred Rock [BARI, BARII], Columbian Rock [COL], and line 54 [L-54]) with microsatellite markers. Furthermore, the study aims to employ its findings to discuss the possibilities for the conservation and sustainable use of these lines that have been bred as closed populations for a long time. Methods: In the present study, a total number of 180 samples belonging to RIRI (n = 30), RIRII (n = 30), BARI (n = 30), BARII (n = 30), L-54 (n = 30), and COL (n = 30) lines were genotyped using 22 microsatellite loci. Microsatellite markers are extremely useful tools in the identification of genetic diversity since they are distributed throughout the eukaryotic genome in multitudes, demonstrate co-dominant inheritance and they feature a high rate of polymorphism and repeatability. Results: In this study, we found all loci to be polymorphic and identified the average number of alleles per locus to be in the range between 4.41 (BARI) and 5.45 (RIRI); the observed heterozygosity to be in the range between 0.31 (RIRII) and 0.50 (BARII); and $F_{IS}$ (inbreeding coefficient) values in the range between 0.16 (L-54) and 0.46 (RIRII). The $F_{IS}$ values obtained in this context points out to a deviation from Hardy-Weinberg equilibrium due to heterozygote deficiency in six different populations. The Neighbour-Joining tree, Factorial Correspondence Analysis and STRUCTURE clustering analyzes showed that six brown layer lines were separated according to their genetic origins. Conclusion: The results obtained from the study indicate a medium level of genetic diversity, high level inbreeding in chicken lines and high level genetic differentiation between chicken lines.

크로스 링크된 단백질 서브시퀀스를 찾는 알고리즘 (Algorithm for identifying cross-linked protein subsequences)

  • 김성권
    • 한국정보과학회논문지:시스템및이론
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    • 제29권9호
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    • pp.514-519
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    • 2002
  • 단백질의 구조를 예측하는 과정에 사용될 수 있는 다음 문제를 고려한다. 길이가 n이고 원소가 모두 양수인 두 배열 A, B와 양수 M이 주어질 때, A[i]+…A[j]+B[k]+…B[ι]=M이 되는 부배열 쌍 A[i]+…A[j],$1{\leq}i{\leq}j{\leq}n$과 B[k], …, B[l], $1{\leq}k{\leq}l{\leq}n$을 모두 찾으시오. 본 논문에서는 이 문제를 $Ο(n^2log n+K)$ 시간에 Ο(n) 메모리를 사용하여 해결하는 알고리즘을 제시한다. 단, K는 찾은 부배열 쌍의 수이다. 기존의 결과는$Ο(n^2log +Klog n)$ 시간과 Ο(n) 메모리였다.