• KEPCO Journal on Electric Power and Energy
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• v.6 no.1
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• pp.53-58
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• 2020

Korea Electric Power Corporation (KEPCO) uses large amount of SF₆, one of the potent greenhouse gases, in electric equipment for electrical insulation. KEPCO is developing SF₆ recovery and purification technology to minimize the release of SF₆ into the environment, to secure certified emission reduction, and to save purchase cost of new SF₆ by reusing the refined SF₆. A prototype SF₆ purification system using cryogenic solidification technology has been built in demonstration scale. To evaluate the feasibility of the commercialization, the system has been operated to purify large amount of used SF₆ in a long-term operation and the performance has been economically evaluated. The system was stable enough for commercial operation such that it was able to purify 5.4 tons of used SF₆ from power transmission equipment in 2-month operation. Over 99% of the SF₆ was recovered from the used gas and the purity of the purified gas was over 99.7 vol%. The operation cost, which is the cost of refrigerant (liquid nitrogen), electricity and labor, per kilogram of purified SF₆ was 6,526 KRW. Considering the price of new SF₆ in Korea is about 15,000 KRW per kilogram this year, about 56% of the purchase cost can be saved.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.1
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• pp.47-53
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• 2011

$SF_6$ (Sulfur hexafluoride) possesses high GWP (Global Warming Potential) as sepcified by the IPCC (Intergonvernmental Panel of Climate Change). Recently, the recovery-separtion of $SF_6$ research area, including permeation properties studies using various membrane's materials and the practical operation of recovery-separtion using membrane of waste $SF_6$ gas is in the initial state. The separation efficiency of a single $SF_6$ and waste $SF_6$ mixture was evaluated using a PSF (polysulfone), PC (tetra-bromo polycarbonate) and PI (polyimide) hollow fiber membranes. According to the results of single gases permeation properties, PI membrane has the highest permselectivity of $N_2$ gas in $N_2/SF_6$ gas. Under the condition of P=0.5 MPa, the highest concentration of recovered $SF_6$ is 95.6 vol % in the separation experiment of $SF_6/N_2$ mixture gas by PC membrane. Under the operation pressure of P=0.3 MPa at a fixed retentate flow rate fixed of 150 cc/min, the maximum recovery efficiency of $SF_6$ is up to 97.8% by PSF membrane. From the results above, it is thought that the separation and recovery technique of $SF_6$ gas using membrane will be used as the representative eco-technology in the $SF_6$ gas treatment in the future.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.56 no.9
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• pp.1566-1570
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• 2007

[ $SF_6$ ] gas circuit breakers are widely used for short circuit current interruption in EHV(Extra High Voltage) or UHV(Ultra High Voltage) power systems. To develop $SF_6$ gas circuit breakers, the arc resistance value is necessary to compare experimental results to numerical ones. The arc resistance value can be obtained from a breaking test with a $SF_6$ gas circuit breaker. The direct testing or synthetic testing facility is widely used to verify the breaking ability for $SF_6$ gas circuit breakers. We employed the simplified synthetic testing facility to test a $SF_6$ gas circuit breaker prototype. The arc resistance characteristic was measured and calculated under the various experimental conditions. This arc resistance value can be used for verifying the numerical results from arc simulation in a circuit breakers.

• 전기의세계
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• v.28 no.4
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• pp.39-46
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• 1979

The effective ionization coefficient in $SF_{6}$/$N_{2}$ mixtures was attempted to derive from the pure gases. Measurements of static breakdown voltage were made under the uniform field at pressures up to 4 bar in order to compare with the results obtained from this assumption. The relative performance of $SF_{6}$/$N_{2}$ mixtures to pure $SF_{6}$ was also investigated. The effect of surface roughness on discharge thresholds in $SF_{6}$/$N_{2}$ mixtures was calculated employing the simplified model and mesurements of breakdown voltages for a gap with an artificial protrustion were also made. The experimental results show that the effective ionization coefficient in gas mixtures can not be reliably estimated from the values measured for the pure gases. Therefore, basic parameters for $SF_{6}$/$N_{2}$ mixtures must be measured by investigation of the mixtures themselves. The relative performance of mixtures to pure $SF_{6}$ could be considered with the values of pR.

• The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.7 no.1
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• pp.21-29
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• 1993

In this paper, we studied the 50% flashover voltage of lightening impulse which affect the most serious damages on the insulation of the electric power network system. Also its V -t characteristics and corona process phenomena of pure $SF_6, N_2, SF_6-N_2$mixtures under the circumstances of nonuniform field gap are researched. Comparing the characteristics of pure $SF_6$ with that of $SF_6, N_2$mixtures, we discussed that breakdown processes and $SF_6, N_2$ mixture's application to economics.As a results, 50% flashover voltage of $SF_6$ 50% - $N_2$ 50% for impulse voltage is higher then that of 80% of pure SF6, measured data and calculated data by equal area law are almost equal from the points of view of V-t characteristics. Therefore, it has been known that $SF_6$ 50% - $N_2$ 50% mixtures can be used as an economic constitution gas of pure $SF_6$, it is verified that corona processes from Lichtenberg figure.

• Korean Journal of Materials Research
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• v.19 no.2
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• pp.68-72
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• 2009

This study investigated dry etching of acrylic in capacitively coupled $SF_6$, $SF_6/O_2$ and $SF_6/CH_4$ plasma under a low vacuum pressure. The process pressure was 100 mTorr and the total gas flow rate was fixed at 10 sccm. The process variables were the RIE chuck power and the plasma gas composition. The RIE chuck power varied in the range of $25{\sim}150\;W$. $SF_6/O_2$ plasma produced higher etch rates of acrylic than pure $SF_6$ and $O_2$ at a fixed total flow rate. 5 sccm $SF_6$/5 sccm $O_2$ provided $0.11{\mu}m$/min and $1.16{\mu}m$/min at 25W and 150W RIE of chuck power, respectively. The results were nearly 2.9 times higher compared to those at pure $SF_6$ plasma etching. Additionally, mixed plasma of $SF_6/CH_4$ reduced the etch rate of acrylic. 5 sccm $SF_6$/5 sccm $CH_4$ plasma resulted in $0.02{\mu}m$/min and $0.07{\mu}m$/min at 25W and 150W RIE of chuck power. The etch selectivity of acrylic to photoresist was higher in $SF_6/O_2$ plasma than in pure $SF_6$ or $SF_6/CH_4$ plasma. The maximum RMS roughness (7.6 nm) of an etched acrylic surface was found to be 50% $O_2$ in $SF_6/O_2$ plasma. Besides the process regime, the RMS roughness of acrylic was approximately $3{\sim}4\;nm$ at different percentages of $O_2$ with a chuck power of 100W RIE in $SF_6/O_2$ plasma etching.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.122.2-122.2
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• 2011

Sulfur hexafluoride ($SF_6$), one of the most potent greenhouse gases, is known as a hydrate former and has been studied at the high pressure up to 1.3 GPa with gas mixtures and with aqueous surfactant. Since we regard $SF_6$ as a potential promoter molecule that can stabilize hydrate structure more effectively compare to the other promoters, further investigation is required to verify the stabilizing ability of $SF_6$ in the hydrate structure. However, the insoluble nature of $SF_6$ in water or gases hinders fine scale analyses. This work discusses the data obtained by using molecular dynamics simulations of structure II (sII) clathrate hydrates containing $SF_6$ and $H_2$. The simulations were performed using the TIP4P/Ice model for water molecule and a previously reported $SF_6$ molecular model (optimized at the pure $SF_6$ single phase system (Olivet and Vega, 2007)), and a $H_2$ molecular model (adapted from the THF+$H_2$ hydrate system (Alavi et al., 2006)). The simulations are performed to observe the stability of $SF_6$ and $H_2$ in the sII clathrate hydrate system with varying temperature and pressure conditions and occupancies of $SF_6$ and $H_2$, which cannot be easily tuned experimentally. We observe that stability of H2 enclathrated in the hydrate structure more affected by the occupancy of $SF_6$ molecules and temperature than pressure, which ranges from 1 to 100 bar.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.24 no.8
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• pp.142-149
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• 2010

This paper describes dielectric characteristics of $SF_6$ and dry-air gases under lightning impulse voltages in a quasi-uniform electric field. In order to simulate to a quasi-uniform electric field, electric field utilization factor of the used sphere-plane electrode is 71[%]. The gas pressure of $SF_6$ ranges from 0.1 to 0.2[MPa] and that of dry-air ranges from 0.2 to 0.6[MPa]. Electrical breakdown voltages of $SF_6$ and dry-air gases are measured and analyzed as functions of the polarity of lightning impulse voltage and gas pressure. As a result, the electrical breakdown voltage of both gases under the positive lightning impulse voltage is higher than that under the negative one. The electrical breakdown voltage in $SF_6$ is almost higher than 2.67 times compared to dry-air. The results presented in this paper can be used as a useful information to evaluate the capability of alternative insulation gases for $SF_6$ in power distribution equipment with prominent ability against lightning surge.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.29 no.1
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• pp.44-49
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• 2016

Studies on a $SF_6$-mixture and -alternative gas has been in progress to reduce the use of $SF_6$ gas as an insulation material of GIS (gas insulated switchgears). In this paper, we dealt with PD (partial discharge) characteristics in pure $SF_6$ and $N_2$, and their mixtures on aspects of insulation design and risk assessment for GIS. A POC (protrusion on conductor) and a POE (protrusion on enclosure) as the major defects were fabricated to simulate PD. We analyzed the DIV (discharge inception voltage), DEV (discharge extinction voltage), pulse magnitude, counts and phase distribution of PD pulse in $SF_6-N_2$ mixtures ($SF_6$ 100%, $SF_6$ 80%-$N_2$ 20%, $SF_6$ 50%-$N_2$ 50%, $SF_6$ 20%-$N_2$ 80%, and $N_2$ 100%) according to the IEC60270. The DIV, DEV as well as magnitude of PD pulse decreased on the POC as increase of $N_2$ ratio. For the POE, the DIV and DEV in $N_2$ ratio below 50% were the same voltages as those in $SF_6$ 100%. In this experiment, $SF_6$ 80%-$N_2$ 20% mixture could be considered with the equivalent insulation performance to a GIS.

• Membrane Journal
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• v.21 no.3
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• pp.256-262
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• 2011

This study describes the performance of PSF and PC membranes for separation and recovery of $SF_6$ from gas mixtures (10% $SF_6$/70% $N_2$/19% $O_2$/1% $CF_4$) containing low concentration of $SF_6$. The $SF_6$ concentration in retentate, recovery efficiency and selectivity of mixed gases were measured as a function of retentate flow rate and temperature. The concentration of $SF_6$ in the gas recovered from PSF and PC membrane respectively decreased with increase of retentate flow rate and increased with increase of temperature. The values of $SF_6$ concentration in retentate of PSF membrane were higher than those of PC membrane at constant experimental conditions. The maximum value of recovery efficiency of PSF and PC membranes are 95.9% and 67.8%, respectively, under 298.15 K and 150 cc/min of retentate flow rate. With the exception of $CF_4/SF_6$, the real selectivities of $N_2/SF_6$ and $O_2/SF_6$ at PSF membrane were higher than those of PC membrane.