• 제목/요약/키워드: ($(Gd\

검색결과 1,150건 처리시간 0.029초

반도체형 열중성자 선량 측정센서 개발 (The development of a thermal neutron dosimetry using a semiconductor)

  • 이남호;김양모
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2003년도 학술회의 논문집 정보 및 제어부문 B
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    • pp.789-792
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    • 2003
  • pMOSFET having 10 ${\mu}um$ thickness Gd layer has been tested to be used as a slow neutron sensor. The total thermal neutron cross section for the Gd is 47,000 barns and the cross section value drops rapidly with increasing neutron energy. When slow neutrons are incident to the Gd layer, the conversion electrons are emitted by the neutron absorption process. The conversion electrons generate electron-hole pairs in the $SiO_2$ layer of the pMOSFET. The holes are easily trapped in Oxide and act as positive charge centers in the $SiO_2$ layer. Due to the induced positive charges, the threshold turn-on voltage of the pMOSFET is changed. We have found that the voltage change is proportional to the accumulated slow neutron dose, therefore the pMOSFET having a Gd nuclear reaction layer can be used for a slow neutron dosimeter. The Gd-pMOSFET were tested at HANARO neutron beam port and $^{60}CO$ irradiation facility to investigate slow neutron response and gamma response respectively. Also the pMOSFET without Gd layer were tested at same conditions to compare the characteristics to the Gd-pMOSFET. From the result, we have concluded that the Gd-pMOSFET is very sensitive to the slow neutron and can be used as a slow neutron dosimeter. It can also be used in a mixed radiation field by subtracting the voltage change value of a pMOSFET without Gd from the value of the Gd-pMOSFET.

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가로 가둠을 통한 자성층간 결합 기여도 조절 (Tailoring Magnetic Interlayer Coupling Contribution via Lateral Confinement)

  • 이동렬
    • 한국자기학회지
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    • 제26권5호
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    • pp.149-153
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    • 2016
  • Fe/Gd 다층박막 내 자성층간 결합에 미치는 패턴의 영향을 연구하였다. 이를 위하여 하나의 다층박막 시료를 나누어서 패턴한 것과 패턴하지 않은 것으로 제작하여 비교하였다. X선 자기 원편광 이색성(X-ray magnetic circular dichrosim: XMCD)을 이용하여 Gd 원소에 선택적인 자화 벡터의 온도 변화를 비교한 결과, 패턴 시료의 경우 Gd 자화 벡터의 온도의존성이 패턴 전에 비해 뚜렷하게 변화했음을 관측하였다. 이는 패턴 효과와 반강자성의 층간 결합 효과가 서로 경쟁하여 나타난 결과이다.

Gd effect on microstructure and properties of the Modified-690 alloy for function structure integrated thermal neutron shielding

  • Cheng Zhang;Jie Pan;Zixie Wang;Zhaoyu Wu;Qiliang Mei;Qianxue Ding;Jing Gao;Xueshan Xiao
    • Nuclear Engineering and Technology
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    • 제55권5호
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    • pp.1541-1558
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    • 2023
  • The new Modified-690Gd alloy, namely as Ni-30Cr-(10-x) Fe-xGd (x = 0.5, 1.0, 1.5,2.0, 3.0 wt%) for function structure integrated thermal neutron shielding has been prepared and characterized. The Modified-690Gd alloy was mainly composed of γ austenite matrix and (Ni, Cr, Fe)5Gd precipitated along grain boundaries. The new Modified-690Gd alloy had great mechanical properties, which had the tensile strength exceeding 620 MPa and the elongation being above 50%. Meanwhile, this alloy had excellent weldability and good corrosion resistance in boric acid. The new Modified-690Gd alloy is expected to be a kind of high efficiency thermal neutron shielding materials.

나노 크기의 Gd2O3:Eu3+ 적색형광체가 코팅된 판상 Mica의 제조 및 형광특성 (Preparation of Nanosized Gd2O3:Eu3+ Red Phosphor Coated on Mica Flake and Its Luminescent Property)

  • 반세민;박정민;정경열;최병기;강광중;강명창;김대성
    • 한국분말재료학회지
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    • 제24권6호
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    • pp.457-463
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    • 2017
  • Nanosized $Gd_2O_3:Eu^{3+}$ red phosphor is prepared using a template method from metal salt impregnated into a crystalline cellulose and is dispersed using a bead mill wet process. The driving force of the surface coating between $Gd_2O_3:Eu^{3+}$ and mica is induced by the Coulomb force. The red phosphor nanosol is effectively coated on mica flakes by the electrostatic interaction between positively charged $Gd_2O_3:Eu^{3+}$ and negatively charged mica above pH 6. To prepare $Gd_2O_3:Eu^{3+}$-coated mica ($Gd_2O_3:Eu/mica$), the coating conditions are optimized, including the stirring temperature, pH, calcination temperature, and coating amount (wt%) of $Gd_2O_3:Eu^{3+}$. In spite of the low luminescence of the $Gd_2O_3:Eu/mica$, the luminescent property is recovered after calcination above $600^{\circ}C$ and is enhanced by increasing the $Gd_2O_3:Eu^{3+}$ coating amount. The $Gd_2O_3:Eu/mica$ is characterized using X-ray diffraction, field emission scanning electron microscopy, zeta potential measurements, and fluorescence spectrometer analysis.

$Tb^{3+}$$Eu^{3+}$로 활성화된 $Al_3GdB_4O_{12}$ 형광체의 발광특성 (Photoluminance Properties of $Al_3GdB_4O_{12}$ Phosphors Activated by $Tb^{3+}$and $Eu^{3+}$)

  • 김기운;김성우;이임렬
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 추계학술대회 논문집
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    • pp.594-597
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    • 1999
  • The new green and red phosphors for PDP application activated by T $b^{3+}$ and E $u^{3+}$ were synthesized, and their photoluminance properties were investigated. It was found that the brightness of $Al_3$Gd $B_4$ $O_{12}$ :T $b^{3+}$ green phosphor under 147nm VUV irradiation was higher than that of commercial Z $n_2$ $SiO_4$:M $n^{2+}$ phosphor. But the emitting intensity of A1$_3$Gd $B_4$ $O^{12}$ :E $u^{3+}$ red phosphor was inferior to the commercial (Y,Gd)B $O_3$:E $u^{3+}$. $Al_3$Gd $B_4$ $O_{12}$ Phosphor had a strong excitation band at 160nm associated with the host absorption, and also the photoluminance excitation intensity of $Al_3$Gd $B_4$ $O_{12}$ :T $b^{3+}$ was higher than that of Z $n_2$ $SiO_4$:M $n^{2+}$, but the intensity of $Al_3$Gd $B_4$ $O_{12}$ :E $u^{3+}$ phosphor was smaller than (Y,Gd)B $O_3$:E $u^{3+}$ phosphor In the VUV range. C $e^{3+}$ co-doping in A1$_3$Gd $B_4$ $O^{12}$ :E $u^{3+}$ and substitution of $Al^{3+}$ by G $a^{3+}$ A1$_3$Gd $B_4$ $O^{12}$ :E $u^{3+}$ phosphor were tried, but they did not improved the optical property .d the optical property .ty .

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종자 결정 성장법으로 제조된 $GdBa_2Cu_3O_{7-y}$ 벌크 초전도체의 자기적 특성 (Magnetic Properties of $GdBa_2Cu_3O_{7-y}$ Bulk Superconductors Fabricated by a Top-seeded Melt Growth Process)

  • 김광모;박순동;전병혁;고태국;김찬중
    • Progress in Superconductivity
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    • 제14권1호
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    • pp.39-44
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    • 2012
  • The fabrications condition and superconducting properties of top-seeded melt growth (TSMG) processed $GdBa_2Cu_3O_{7-y}$ (Gd123) bulk superconductors were studied. Processing parameters (a maximum temperature ($T_{max}$), a temperature for crystal growth ($T_G$) and a cooling rate ($R_G$) through a peritectic temperature ($T_P$) for the fabrication of single grain Gd123 superconductors were optimized. The magnetic levitation forces, trapped magnetic fields, superconducting transition temperature ($T_c$) and critical current density ($J_c$) of the Gd123 bulks superconductors were estimated. Single grain Gd123 bulk superconductors were successfully fabricated at the optimized processing condition. The $T_c$ of a TSMG processed Gd123 sample was 92.5 K and the $J_c$ at 77 K and 0 T was approximately $50kA/cm^2$. The trapped magnetic field contour and magnetic levitation forces were dependent on the top surface morphology of TSMG processed Gd123 samples. The single grain Gd123 samples, field-cooled at 77 K using a Nd-B-Fe permanent magnet with 5.27 kG and 30 mm dia., showed the trapped magnetic field contour of a single grain with a maximum of 4 kG at the sample center. The maximum magnetic levitation forces of the single grain Gd123 sample, field-cooled or zero field-cooled, were 40 N and 107 N, respectively.

염산용액(鹽酸溶液)에서 PC88A와 비누화 PC88A에 의한 Gd와 Nd의 분리추출(分離抽出) (Solvent Extraction for the Separation of Gd and Nd from Chloride Solution with PC88A and Saponified PC88A)

  • 이만승;이진영;김준수
    • 자원리싸이클링
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    • 제17권1호
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    • pp.12-19
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    • 2008
  • Gd와 Nd이 혼합된 염산용액에서 PC88A와 비누화 PC88A에 의한 용매추출실험을 하였다. 본 연구에서 수행한 실험조건에서 H88A에 의해 Gd이 Nd보다 추출이 잘 되었으며, 40% 비누화된 H88A를 사용하여 Gd와 Nd의 분배계수가 증가하였다. PC88A와 비누화 PC88A에 의한 추출시 초기추출조건으로부터 Gd와 Nd의 분배계수를 예측할 수 있는 모델을 개발하였다. 본 연구에서 개발된 모델을 초기추출조건에 적용하여 예측한 Gd와 Nd의 분배계수는 실험으로 측정한 값과 서로 잘 일치하였다

Effect of $UO_2$ Powder Property and Oxygen Potential on Sintering Characteristics of $UO_2-Gd_2O_3$ Fuel

  • Song, Kun-Woo;Kim, Keon-Sik;Yoo, Ho-Sik;Jung, Youn-Ho
    • Nuclear Engineering and Technology
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    • 제30권2호
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    • pp.128-139
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    • 1998
  • The effect of UO$_2$ powder property and oxygen potential on characteristics of sintered UO$_2$-Gd$_2$O$_3$ fuel pellets has been investigated. Two types of powder, mixture of AUC-UO$_2$ and Gd$_2$O$_3$powders (type I) and mixture of ADU-UO$_2$ and Gd$_2$O$_3$powders (type II), have been prepared, pressed, and sintered at 168$0^{\circ}C$ for 4 hours. Four sintering atmospheres with different mixing ratios of $CO_2$to H$_2$ gas ranging from 0 to 0.3 have been used. UO$_2$-Gd$_2$O$_3$ fuel has lower sintered density than UO$_2$ fuel, and the density drop is larger for powder type I than for powder type II. As the oxygen potential increases, the sintered density of UO$_2$-2wt% Gd$_2$O$_3$pellets increases but that of UO$_2$-10wt% Gd$_2$O$_3$ pellets decreases. It is found that pores are newly formed in UO$_2$-10wt% Gd$_2$O$_3$ pellets in accordance with the decrease in density. The grain size of UO$_2$-Gd$_2$O$_3$ fuel increases and a short range G4 distribution becomes homogeneous as the oxygen potential increases. A long range ed distribution and grain structure are inhomogeneous for powder type II. The lattice parameter of (U,Gd)O$_2$solid solution decreases linearly with Gd$_2$O$_3$ content. The dependence of UO$_2$-Gd$_2$O$_3$fuel characteristics on powder type and sintering atmosphere have been discussed.

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The superconductivity and pinning properties of Y2O3-doped GdBa2Cu3O7-δ films prepared by pulsed laser deposition

  • Oh, Won-Jae;Park, Insung;Yoo, Sang-Im
    • 한국초전도ㆍ저온공학회논문지
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    • 제20권4호
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    • pp.41-45
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    • 2018
  • We have investigated the effect of $Y_2O_3$ nanoparticles on the pinning properties of $Y_2O_3$-doped $GdBa_2Cu_3O_{7-{\delta}}$ (GdBCO) films. Both undoped and $Y_2O_3$-doped GdBCO films were grown on $CeO_2$-buffered MgO (100) single crystal substrates by pulsed laser deposition (PLD) using KrF (${\lambda}=248nm$) laser. The $Y_2O_3$ doping contents were controlled up to ~ 2.5 area% by varying the internal angles of $Y_2O_3$ sectors put on the top surface of GdBCO target. Compared with the $Gd_2O_3$-doped GdBCO films previously reported by our group [1], the $Y_2O_3$-doped GdBCO films exhibited less severe critical temperature ($T_c$) drop and thus slightly enhanced critical current densities ($J_c$) and pinning force densities ($F_p$) at 65 K for the applied field parallel to the c-axis of the GdBCO matrix (B//c) with increasing the doping content. Below 40 K, the in-field $J_c$ and $F_p$ values of all $Y_2O_3$-doped GdBCO films exhibited higher than those of undoped GdBCO film, suggesting that $Y_2O_3$ inclusions might act as effective pinning centers.

고체산화물 연료전지의 양극재료로서 Gd1-xSrxMnO3의 합성 및 특성평가 (Synthesis and Characterization of Gd1-xSrxMnO3 as Cathodic Material for Solid Oxide Fuel Cell)

  • 윤희성;최승우;김병호
    • 한국세라믹학회지
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    • 제36권2호
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    • pp.145-150
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    • 1999
  • 고체산화물 연료전지의 양극재료로서 Gd1-xSrxMnO3을 구연산법으로 합성하였으며, 이의 결정구조, 전기전도도 및 열팽창률을 조사하였다. 또한 합성한 Gd1-xSrxMnO3을 8mol% yttria stabilized zirconia(8YSZ) 혹은 Ce0.8Gd0.2O1.9(CGO) 전해질과의 반응성을 조사하였다. Gd1-xSrxMnO3의 결정구조는 Sr함량이 증가함에 따라 orthorhombic (0$\leq$X$\leq$0.3)에서 cubic(0.4$\leq$X$\leq$0.5)을 거쳐 tetragonal (X=0.6)로 변하였다. Sr 함량이 증가함에 따라 Gd1-xSrxMnO3의 전기전도도는 증가하였다. 열팽창률은 Sr 함량이 30mol% 이상인 경우 함량이 증가함에 따라 증가하는 경향을 보이는 8YSZ, CGO와 비슷한 거동을 보였다. 8YSZ 및 CGO와의 반응성을 보기 위하여 Gd1-xSrxMnO3과 이들을 각각 혼합하여 130$0^{\circ}C$에서 48시간 동안 열처리했을 경우 8YSZ와는 SrZrO3의 반응물을 형성하였으나 CGO와는 반응을 하지 않았다.

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