• Title/Summary/Keyword: $Y_H$

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Semiempirical Estimation of Standard Enthalpy of Formation for Halogen Substituted Hydrocarbons (할로겐화합물의 표준생성열의 계산)

  • Kwang Yul Choo;Pil Heui Lee
    • Journal of the Korean Chemical Society
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    • v.24 no.2
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    • pp.108-114
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    • 1980
  • By using electrostatic model and simple bond additivity scheme a reasonable and simple method was developed for the estimation of standard enthalpy of formation $({\Delta}H_f\;^{\circ})$ of very polar compounds. The bond contributions to the enthalpy of formation for halomethanes were; ${\Delta}H_f\;^{\circ}(C-F)=-36.44\;kcal/mole,\;{\Delta}H_f\;^{\circ}(C-Cl)=-2.57\;kcal/mole,\;{\Delta}H_f\;^{\circ}(C-Br)=5.32\;kcal/mole,\;{\Delta}H_f\;^{\circ}(C-I)=19.18\;kcal/mole,\;and\;{\Delta}H_f\;^{\circ}(C-H)=-3.61\;kcal/mole$, respectively. Using these values and calculated electrostatic energies, the estimated ${\Delta}H_f\;^{\circ}$ values were estimated and found to be in good agreement with observed values.

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Esophageal pH and Combined Impedance-pH Monitoring in Children

  • Shin, Myung Seok
    • Pediatric Gastroenterology, Hepatology & Nutrition
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    • v.17 no.1
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    • pp.13-22
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    • 2014
  • Esophageal pH monitoring is considered the gold standard for the diagnosis of gastroesophageal reflux disease because of the normal ranges across the pediatric age range. However, this method can only detect acid reflux. Multichannel intraluminal impedance-pH (MII-pH) monitoring has recently been used for the detection of bolus reflux in infants and children. This method allows for the detection of liquid, gas or mixed reflux in addition to acid, weakly acidic or weakly alkaline reflux. MII-pH monitoring can record the direction of flow and the height of reflux, which are useful parameters to identify an association between symptoms and reflux. However, the technique is limited by its high cost and the lack of normative data of MII-pH in the pediatric population. Despite certain limitations, MII-pH monitoring will become more common and gradually replace pH monitoring in the future, because pH monitoring is part of MII-pH.

A Synthesis for Robust Servo System Based on Mixed $H_2/H_{\infty}$ Control

  • Park, Yeon-Wook;Lee, Kum-Won
    • 제어로봇시스템학회:학술대회논문집
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    • 1999.10a
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    • pp.88-91
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    • 1999
  • The purpose of this paper is to propose an approach to design a robust servo controller based on the Mixed H$_2$/H$\sub$$\infty$/ theory. In order to do this, we first modify the generalized plant for the usual H$\sub$$\infty$/ servo problem to a structure of the Mixed H$_2$/H$\sub$$\infty$/ minimization problem by virtue of the internal model principle. By doing this, we can divide specifications adopted for robust servo system design into H$_2$and H$\sub$$\infty$/ performance criteria, respectively. Then, the mixed H$_2$/H$\sub$$\infty$/ problem is solved in order to find the best solution, by which we can minimize H$_2$-norm of the transfer function under the condition of H$\sub$$\infty$/-norm value, through Linear Matrix Equality (LMI).

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Biodegradation of Formaldehyde by Peudomonas Putida H-5 (Peudomonas putida H-5에 의한 포름알데히드의 생분해)

  • 류병호;임복규
    • KSBB Journal
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    • v.8 no.1
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    • pp.36-41
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    • 1993
  • This study was designed to reveal the characteristics of the strains degrading formaldehyde isolated from mud of waste water. A strain H-5 showed the highest ability of formaldehyde biodegradation among isolated strains. According to identification, the strain H-5 was ascribed to be Peudomonas putida H-5. The optimal conditions of Peudomonas putida H-5 were $30^{\circ}C$ and pH 7.0. The highest level of formaldehyde degradation was demonstrated at the concentration of 0.02~0.04% in a glucose containing medium. Formaldehyde biodegradation by Peudomonas putida H-5 indicated that this reaction was converted to the methanol and formic acid. However, methanol and formic acid did not show any effect on the growth of viable cells.

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Mixed $H_2/H_{\infty}$ Controller Design Considering Minimum Entropy (최소 엔트로피를 고려한 혼합 $H_2/H_{\infty}$ 제어기 구성)

  • Lee, Sang-Hyuk;Seo, Jin-H.
    • Proceedings of the KIEE Conference
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    • 1996.07b
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    • pp.999-1001
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    • 1996
  • In this paper, we represented the relation of minimum entropy/$H_{\infty}$-controller and mixed $H_2/H_{\infty}$-controller. An $H_2$ controller design problem involving a constraint on $H_{\infty}$ disturbance attenuation is considered. By the equivalence of the mixed $H_2/H_{\infty}$ control problem and the minimum entropy/$H_{\infty}$-control problem, we presented the controller state-space realization. Decentralized case was illustrated briefly.

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Changes of the Antioxidant Enzymes and Histopathological Changes of Liver and Kidney According to the Administered Dosage of Bambusae Caulis in Liquamen in Mice (죽력 (Bambusae Caulis in Liquamen)의 투여량에 따른 생쥐의 항산화효소 활성과 간과 신장의 조직병리학적 변화)

  • Kim, Jeong-Sang
    • Applied Microscopy
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    • v.32 no.4
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    • pp.399-410
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    • 2002
  • This study was performed to investigate the effects of Bambusae Caulis in Liquamen (bamboo extract) on the changes of antioxidant enzymes and histopathological changes of liver and kidney in mice when administered in different dosages. The experimental groups were divided into four. For control group, 0.9% NaCl (0.2 ml/25 g B.W.) and for experimental groups, 5% (H1 group), 10% (H2 group), and 20%(H3 group) bamboo extract diluted with 0.9% NaCl, were administered (0.2 ml/25 g B.W.) respectively for 28 days at an interval of 48 hours. MnSOD activities were increased in H1 group (46%, P<0.05), H2 group (40%, P<0.05), and H3 group (34%, P<0.05) as compared to the control group. CuZnSOD activities were increased in H1 group (11%, P<0.05), but were decreased in H3 group (13%, P<0.05). The activities of catalase were decreased in H1 group (39%, P<0.05), H2 group (34%, P<0.05), and H3 group (31%, P<0.05) as compared to the control group. Histopathological observation revealed ballooned hepatocytes in the pericentral and periportal veins of H1 group. More ballooned and injured hepatocytes than in H1 group were observed in the H2 and H3 groups. Detachment of endothelial cells of the central vein was observed in the H2 and H3 groups. These results indicated that bamboo extract developed dose-dependent changes in antioxidant enzyme activities and developed histopathological changes of liver and kidney.

Effect of pH Adjustment by CO2 on Coagulation and Aluminum Elution in Water Treatment (CO2 주입에 의한 pH 조정이 정수장 응집효율 및 알루미늄 용출에 미치는 영향)

  • Lee, Gil-Seong;Kim, Min-Chai;Kwon, Jae-Kook;Seo, Gyu-Tae
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.1
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    • pp.17-22
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    • 2013
  • In this study, a pH control method by carbon dioxide ($CO_2$) was applied to coagulation process in water treatment plant (WTP) to investigate the coagulation efficiency and residual dissolved aluminum when high pH raw water is flowing into the plant during algal blooming. Existing coagulant dose (1 mg/L in raw water) resulted in the pH reduction of 0.0384 by LAS, 0.0254 by PAC, 0.0201 by A-PAC, and 0.0135 by PACS2, respectively. And then the concentration of dissolved aluminum was 0.02 mg/L at pH 7.44, 0.07 mg/L at pH 7.96, 0.12 mg/L at pH 8.16, 0.39 mg/L at pH 8.38 showing the concentration increase with pH in the coagulation process. It was noteworthy that rapid increase was observed at pH above 8.0 next the rapid mixing. Therefore it is necessarily required to control pH below 7.8 in the coagulation process in order to meet drinking water quality standard of aluminum for high pH raw water into WTP, $CO_2$ injection could control pH successfully at about 7.3 even for the raw water of high pH above 8.0. In addition it was found that the pH control by $CO_2$ injection was significantly effective for coagulation in terms of turbidity removal, coagulant dosage, and residual dissolved aluminum concentration.

Effects of Pretense Treatment on Functional Properties of Soymilk Protein (단백분해 효소처리가 두유단백질의 기능성에 미치는 영향)

  • 변진원;황인경
    • Korean journal of food and cookery science
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    • v.11 no.1
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    • pp.26-32
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    • 1995
  • This study was carried out to investigate the effect of protease on the functionality of soymilk protein. The protease from Bacillus polymyxa was selected because of the least production of bitter taste and calcium-aggregation. The results are summarized as follows: 1. Solubility of SMP(soymilk protein) and SPI(soyprotein isolate) were lowest at pH 4.7 and increased as the pH value reached closer to either ends. PT-SMP(pretense treated soymilk protein) showed higher solubility at all pH range, especially at pH 4.7 than SMP, SPI. 2. Emulsion activity of three samples was lowest at pH 4.7 and significantly increased as pH approched higher acidic or alkaline regions. PT-SMP showed similar activity to other samples, but less stability. 3. Foam capacity of PT-SMP was lowest at pH 8 and increased in acidic, alkaline pH. PT-SMP showed higher foam capacity at all pH range, but lower foam stability than SMP and SPI. 4. PT-SMP showed higher heat coagulability than other samples at all pH range except pH 4.7.

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Study on Rumen Cellulolytic Bacterial Attachment and Fermentation Dependent on Initial pH by cPCR (cPCR 기법을 이용한 초기배양 pH에 의한 반추위 섬유소 분해 박테리아의 부착 및 발효에 관한 연구)

  • Kim, M.S.;Sung, H.G.;Kim, H.J.;Lee, Sang-S.;Chang, J.S.;Ha, J.K.
    • Journal of Animal Science and Technology
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    • v.47 no.4
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    • pp.615-624
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    • 2005
  • The cPCR technique was used to monitor rumen fermentation and attachment of Fibrobacter succinogenes to cellulose at different pH in the in vitro culture medium. The target fragments of 16S rDNA(445 bp) were amplified from genomic DNA of F. succinogenes with specific primers and internal controls(205 bp) were constructed. Cell counts were estimated from the amounts of genomic DNA, which was calculated from cPCR results. F. succinogenes in pH 6.8 and 6.2 showed apparently higher attachment than in pH 5.8 during all incubation time. There were some difference between pH 6.8 and 6.2 in the degree of attachment, but the different was not significant (P>0.05). Cellulose degradation increased in process of incubation time and the increasing rate was higher when initial pH was higher. The pH in culture medium decreased regardless of initial pH in course of incubation time. After 24 h of incubation, medium pH was dropped by 0.24, 0.58 and 0.16 units from original medium pH 6.8, 6.2 and 5.8, respectively. More gas was produced at higher initial pH in the same manner as in cellulose degradation. In summery, Initial pH of rumen culture in vitro significantly influenced cellulose digestion, gas production, pH change and bacterial attachment. Especially, low pH(5.8) resulted in much lower bacterial attachment and fiber digestion compared to higher medium pH.