• Title/Summary/Keyword: $TiO_2$ nanofiber

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Electrochemical Characteristics of added $TiO_2$ Nanofiber for Dye-Sensitized Solar Cells ($TiO_2$ 나노파이퍼를 첨가한 염료감응형 태양전지의 전기화학적 특성)

  • Jin, En-Mei;Park, Kyung-Hee;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.06a
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    • pp.243-244
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    • 2009
  • The $TiO_2$ nanofiber doped $TiO_2$ electrode area applied to dye-sensitized solar cells(DSSCs). The mixtures of $TiO_2$ nanofiber to $TiO_2$ photoelectrode has larger surface area than $TiO_2$ photoelectrode. In this research added 2.5, 5 and 10wt% $TiO_2$ nanofibers and the optimum condition of 5 wt% $TiO_2$ nanofiber's high surface area contributing the improvement of short-circuit photocurrent. The open-circuit voltage was 0.7V and solar energy conversion efficiency was 5.4%.

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Effect of performance in $TiO_2$ paste for Dye-Sensitized Solar Cells by $TiO_2$ nanofiber ($TiO_2$ 나노파이버를 첨가한 광전극용 $TiO_2$ 페이스트가 염료감응 태양전지의 광전변환 특성에 미치는 영향)

  • Baek, Hyoung-Youl;Li, Hu;Jin, En-Mei;Park, Kyung-Hee;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.358-359
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    • 2008
  • Solar cell based on dye-sensitized photoelectric conversion was studied by investigating the effects of the amount of $TiO_2$ nanofiber added to the $TiO_2$ paste, on surface morphology, good electric of the $TiO_2$ films and on the solar cell performance. Energy conversion efficiency was found to increased with $TiO_2$ nanofiber addition up to 7wt% in $TiO_2$ films. Maximum increase upto 15% in the efficiently was observed at 7 wt. % of $TiO_2$ nanofiber in $TiO_2$ electrode.

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A Study on the Preparation and Application of Au/TiO2 Nanofiber from AAO Template (AAO Template를 이용한 Au/TiO2 나노섬유 제조 및 응용에 관한 연구)

  • Eom, Seon-Mi;Park, Sang-Sun;Kim, Young-Deok;Kim, Yong-Rok;Shul, Yong-Gun
    • Journal of the Korean Electrochemical Society
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    • v.12 no.1
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    • pp.47-53
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    • 2009
  • In this study, highly ordered AAO (Anodic Aluminum Oxide) with nanopores was prepared by commercial grade Al substrate containing 3.5 wt.% impurities through two step anodizing method. Nanopores of prepared AAO arrays were used as templates for preparing nanofiber. $TiO_2$ was deposited by using DP (deposition-precipitation) method into AAO pores to grow nanofiber. Au particles were loaded on this $TiO_2$ nanofiber which was grown vertically. Prepared 2 wt.% $Au/TiO_2$ nanofiber was characterized by XRD, SEM and Raman. The crystal structure was analyzed by the XRD. SEM was used to observe pore size and pore wall thickness. Photocatalytic activity of co-oxidation was compared with $TiO_2$ and $Au/TiO_2$ nanofiber on AAO arrays.

Application of Metal Oxide Nanofiber for Improving Photovoltaic Properties of Dye-Sensitized Solar Cells (염료감응형 태양전지의 광전기적 특성 개선을 위한 금속산화물 나노파이버의 응용)

  • Dong, Yong Xiang;Jin, En Mei;Jeong, Sang Mun
    • Clean Technology
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    • v.24 no.3
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    • pp.249-254
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    • 2018
  • In order to improve the photo conversion efficiency (${\eta}$) of dye-sensitized solar cells (DSSCs), the electrospun $TiO_2$, $SiO_2$, $ZrO_2$ and $SnO_2$ nanofibers were added into the hydrothermally prepared $TiO_2$ nanoparticles for application to a photoelectrode for DSSCs. The $TiO_2$ nanofiber added photoelectrode exhibited a higher photo current density ($J_{sc}$) compared to the bare $TiO_2$ nanoparticles, which is caused from acceleration of the transfer of excited electron from dye molecule due to the nanofiber structure. The DSSCs with $SiO_2$ nanofibers shows a higher open circuit voltage ($V_{oc}$) of 0.67 V and the highest photo conversion efficiency was found to be 6.24%.

Fabrication of Electrospun Titania Nanofiber (전기방사법을 이용한 산화티탄 나노섬유의 제조)

  • Park, Sooil;Lee, Deuk-Yong;Lee, Myung-Hyun;Lee, Se-Jong;Kim, Bae-Yeon
    • Journal of the Korean Ceramic Society
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    • v.42 no.8 s.279
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    • pp.548-553
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    • 2005
  • $TiO_2$ nanofibers were fabricated by annealing electrospun $TiO_2$/PVP nanofibers for 3 h at $500^{\circ}C$ in air. Size and uniformity of electrospun $TiO_2$ nanofiber diameters were evaluated via XRD and SEM by varying electric field, PVP concentration, Ti tetraisopropoxide concentration and precursor flow rate. Experimental results revealed that the effect of PVP concentration on size and uniformity of electrospun $TiO_2$ nanofiber diameters was most profound, however, the other effects were relatively small. Uniform fibers with no beads were observed for the electrospun anatase titania nanofibers with a diameter of 170 nm.

Ti02/CNT Hybrid Nanofiber Electrode for Energy Conversion Devices (에너지 전환 소자용 $TiO_{2}/CNT$ 하이브리드 나노 섬유 전극)

  • Seo, Jae-Sub;Kim, Joo-Yong;Jin, Hyoung-Joon;Kang, Min-Sung
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.323-325
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    • 2007
  • $TiO_{2}$ electrode electrospun directly onto the substrate was developed for energy conversion device. To enhance energy conversion efficiency of dye-sensitized solar cell, electrodes should have higher surface area to absorb more dyes and higher conductivity to reduce recombination of generated electrons. $TiO_{2}$ nanofibers with higher surface areas were fabricated by annealing electrospun $TiO_{2}/PVP$ nanofibers at $500^{\circ}C$ for 3 hrs in air. it was revealed that $TiO_{2}$ nanofiber electrodes is hybrid with MWNT showed higher conductivity than $TiO_{2}$ semiconductor electrode possibly due to band gap change.

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Synthesis and Electromagnetic Wave Absorbing Property of BaTiO3@Fe Nanofibers with Core-Shell Structure (코어-쉘 구조를 갖는 BaTiO3@Fe 나노섬유의 합성 및 전자파 흡수 특성)

  • Lee, Young-In;Jang, Dae-Hwan;Sung, Ki-Hoon;Lee, Kyuman;Choa, Yong-Ho
    • Journal of Powder Materials
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    • v.23 no.1
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    • pp.38-42
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    • 2016
  • $BaTiO_3$-coated Fe nanofibers are synthesized via a three-step process. ${\alpha}-Fe_2O_3$ nanofibers with an average diameter of approximately 200 nm are first prepared using an electrospinning process followed by a calcination step. The $BaTiO_3$ coating layer on the nanofiber is formed by a sol-gel process, and a thermal reduction process is then applied to the core-shell nanofiber to selectively reduce the ${\alpha}-Fe_2O_3$ to Fe. The thickness of the $BaTiO_3$ shell is controlled by varying the reaction time. To evaluate the electromagnetic (EM) wave-absorbing abilities of the $BaTiO_3@Fe$ nanofiber, epoxy-based composites containing the nanofibers are fabricated. The composites show excellent EM wave absorption properties where the power loss increases to the high frequency region without any degradation. Our results demonstrate that the $BaTiO_3@Fe$ nanofibers obtained in this work are attractive candidates for electromagnetic wave absorption applications.

Development of photocatalytic PVA/$TiO_2$ nanofiber membrane by electrospinning and its application for Air Filtration

  • Linh, Nguyen Thuy Ba;Lee, Byong-Taek
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2010.05a
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    • pp.38.1-38.1
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    • 2010
  • Nanofibers have a large potential in air filtration applications. In this work, we have developed a photocatalytic polyvinyl alcohol PVA/$TiO_2$ nanofibers membrane for the treatment of air filtration by using electrospinning method. PVA were electrospun into nanofibrous membranes and $TiO_2$ nanoparticles were loaded in PVA nanofibers in various contents from 10% (w/w) to 50% (w/w). The UV-Vis spectra were conducted for testing the existence of $TiO_2$ nanoparticles in PVA fibers. SEM analysis indicated that $TiO_2$ nanoparticles were loaded on the surface of PVA fibers and dispersed linearly along the fiber direction, which originated from the effect of polarization and orientation caused by high electric field. X-ray diffraction (XRD) was used to determine the crystalline of the membrane. Tensile strength was measured to evaluate the physical properties of the membrane. Therefore, our work suggested that PVA/$TiO_2$ nanofiber membrane has a potential application in air filtration area.

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Electrospinning Fabrication of Poly(vinyl alcohol)/Pullulan/TiO2 Nanofibers (전기방사를 이용한 Poly(vinyl alcohol)/Pullulan/TiO2 나노부직포의 제조)

  • Yang, Seong Baek;Choi, Woo Seok;Hyun, Jae Min;Shin, Jae Cheon;Choi, Jin Hyun;Yeum, Jeong Hyun
    • Textile Coloration and Finishing
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    • v.26 no.3
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    • pp.195-200
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    • 2014
  • Poly(vinyl alcohol)(PVA)/pullulan/titanium dioxide($TiO_2$) composite nanofibers were produced at different $TiO_2$ concentrations(1 and 3 wt.%) using the electrospinning method. The parameters of electrospinning including polymer contents, voltage and tip-to-collector distance(TCD) were optimized for fabrication process. The study showed that the best condition to make PVA/pullulan nanofiber and effect of $TiO_2$ nanoparticles. The PVA/pullulan/$TiO_2$ nanofibers were characterized by scanning electron microscope(SEM), transmission electron microscope(TEM), Thermogravimetric analysis (TGA) and X-ray diffraction(XRD).