• Title/Summary/Keyword: $Theta^*$

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Study on Relative Stability of Geometrically Constrained Cyclopropylcarbinyl Cation by $^{19}$F-NMR Spectroscopy (풀루오르 19-NMR을 이용한 구조적으로 고정된 사이크로프로필카르비닐 양이온의 상대적 안정도의 비교)

  • Jung Hyu Shin;Bo Hyeon Yoon
    • Journal of the Korean Chemical Society
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    • v.29 no.3
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    • pp.213-219
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    • 1985
  • The relative stability as a function of geometry in rigid cyclopropylcarbinyl cations was examined by $^{19}$F-nmr spectroscopy. 8-p-Fluorophenyl-tricyclo[3.3.1.0$^{2,7}$]octane-8-yl-(I), 9-p-fluorophenyl-tricyclo[3.3.1.0$^{2,8}$]nonane-9-yl (II), and 10-p-fluorophenyl-tricyclo[4.3.1.0$^{2,9}$]decane-10-yl cation(Ⅲ) were prepared from the corresponding carbinols in FSO$_3$H-SO$_2$ClF solution at -120$^{\circ}C$. $^{19}$F-nmr data indicate that the symmetrical bisected geometry of cyclopropane ring for ${\sigma}$-conjugation is a very impotant factor in charge delocalization. However, varied orientation of the bond angle ${\theta}$ within the bisected conformation does not affect the charge delocalization into the cyclopropane ring.

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Phosphorylation of $Ser^{246}$ Residue in Integrin-linked Kinase 1 by Serum- and Glucocorticoid-induced Kinase 1 is Required to Form a Protein-protein Complex with 14-3-3

  • Chun, Jae-Sun;Kang, Sang-Sun
    • Animal cells and systems
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    • v.9 no.3
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    • pp.161-171
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    • 2005
  • Integrin-linked kinase 1 (ILK1) regulates several protein kinases, including PKB/Akt kinase and glycogen synthase kinase ${\beta}$. ILK1 is also involved distinctively in the cell morphological and structural functions by interacting with the components of the extracellular matrix or integrin. According to the information of serum- and glucocorticoid-induced kinase 1 (SGK1) substrate specificity (R-X-R-X-X(S/T)-${\phi};{\phi}$ indicates a hydrophobic amino acid), two putative phosphorylation sites, $Thr^{181}\;and\;Ser^{246}$, were found in ILK1. We showed that ILK1 fusion protein and two fluorescein-labeled ILK1 peptides, $FITC-^{174}RTRPRNGTLN^{183}$ and $FITC-^{239}CPRLRIFSHP^{248}$, were phosphorylated by SGK1 in vitro. We also identified that 14-3-3 ${\theta}\;{\varepsilon}\;and\;{\xi}$, among several 143-3 isotypes $({\beta},\;{\gamma},\;{\varepsilon},\;{\eta},\;{\sigma},\;{\theta},\;{\tau}\;and\;{\xi})$ formed protein complex with ILK1 in COS-1 cells. Furthermore, the phosphorylation of $Ser^{246}$ by SGK1 induced the binding with 14-3-3. It was also demonstrated that 14-3-3-bound ILK1 has reduced kinase activity. Thus, these data suggest that SGK1 phosphorylates $Thr^{181}\;and\;Ser^{246}$ of ILK1 and the phosphorylation of its $Ser^{246}$ makes ILK1 bind to 14-3-3, resulting in the inhibition of ILK1 kinase activity.

Physicochemical Properties of Starch from Cow Pea (동부 전분의 이화학적 특성)

  • Kim, Hyang-Sook;Kweon, Mee-Ra;Ahn, Seung-Yo
    • Korean Journal of Food Science and Technology
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    • v.19 no.1
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    • pp.18-22
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    • 1987
  • Starch granules of cow pea were oval with their sizes of $6-22{\mu}$m. X-ray diffraction pattern of starch granules showed some crystallinity at $2{\theta}$ $15^{\circ}$, $17.1^{\circ}$, $18.1^{\circ}$, $22.9^{\circ}$. The blue value of starch was 0.370, amylose contents 28.1% and water binding capacity 70.6%. Swelling power of the starch increased rapidly from $65^{\circ}C$ to $75^{\circ}C$ thereafter increased less rapidly. Solubility showed the same pattern as the swelling power. Optical transmittance of 0.2% starch suspension was increased rapidly from $70^{\circ}C$ and the gelatinization between $70^{\circ}C$ and $90^{\circ}C$ was single stage. Amylogram of 4% starch solution showed no peak viscosity but 6% starch solution showed peak viscosity.

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Properties of $SiO_2$Deposited by Remote Plasma Chemical Vapor Deposition(RPCVD) (원거리 플라즈마 화학증착법으로 증착된 이산화규소박막의 물성)

  • Park, Yeong-Bae;Gang, Jin-Gyu;Lee, Si-U
    • Korean Journal of Materials Research
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    • v.5 no.6
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    • pp.706-714
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    • 1995
  • Silicon oxide thin films were deposited by remote plasma chemical vapor deposition (RPCYD). The effect of the operating variables, such as plasma power, deposition temperature and partial pressure of reactant on the material Properties of the silicon oxide film was investigated. By XPS, it was found out that the film was suboxide (O/Si<2) and small amount of nitrogen due to the plasma excitation was accumulated at the Si/SiO$_2$interface. The amount of dangling bonds at the Si/SiO$_2$interfaces were measured by ESR and the concentration of hydrogen bond was obtained by SIMS and FT-IR. The bond angle distribution(d$\theta$/$\theta$) was shown to be similiar to thermal oxide above 20$0^{\circ}C$ but the etch rate was higher than that of the thermal oxides due to the structural difference and the stress between silicon substrate and silicon oxide film.

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On-Glass Vehicle Antennas Using a Multi-Loop Structure (다중 루프 형태의 차량용 글래스 안테나)

  • Ahn, Seung-Beom;Kay, Young-Chul;Choo, Ho-Sung
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.20 no.3
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    • pp.230-239
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    • 2009
  • In this paper, we propose a novel on-glass antenna for FM radio reception in a recreation vehicle(RV). We use a multi-loop structure that takes advantage of a broad matching bandwidth and a high vertical radiation gain by efficiently utilizing a given space of a quarter glass in spite of the simple planar structure. Transparency of the antenna is also improved by adjusting the stripline widths based on the induced current distributions. The proposed antenna is printed on a quarter glass of a commercial vehicle and antenna performances such as the return loss and the gain are measured in a semi-anechoic chamber. The result shows the average gain of -9.67 dBi along the bore-sight direction($\theta=90^{\circ}$, $\phi=270^{\circ}$) in the FM radio band(80$\sim$l10 MHz), which is higher than a commercial monopole typed on-glass antenna($G_{ave}$=-12.49 dBi) and micro-antenna($G_{ave}$=-19.24 dBi) mounted on the roof of the RV.

Characteristics comparison of food parallel type high frequency resonant inverter by driving signal control method (구동신호 제어기법에 의한 부하병렬형 고주파 인버터의 특성비교)

  • 이봉섭;원재선;김동희
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.17 no.1
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    • pp.94-102
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    • 2003
  • This paper describes the load parallel type full-bridge high frequency resonant inverter can be used as power source. Output control method of proposed circuit is compared with pulse frequency modulation(PFM), pulse width modulation(PWM) and pulse phase variation(Phase-Shift). The analysis of the proposed circuit is generally described by using the normalized parameters. The principle of basic operating and the its characteristics are estimated according to the parameters such as switching frequency(${\mu}$), pulse width($\theta$d) the variation of phase angle($\phi$) by three driving signal patterns. Experimental results are presented to verify the theoretical analysis result. In future, Characteristics by three driving signal control method is provided as useful data in case of output control of a power supply in various fields as induction heating application, DC-DC converter etc.

Structural and optical properties of $CuInS_2$ thin films fabricated by electron-beam evaporation (전자빔 층착으로 제조한 $CuInS_2$ 박막의 구조적 및 광학적 특성)

  • 박계춘;정운조
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.193-196
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    • 2001
  • Single phase CuInS$_2$ thin film with the highest diffraction peak (112) at diffraction angle (2$\theta$) of 27.7$^{\circ}$ and the second highest diffraction peak (220) at diffraction angle (2$\theta$) of 46.25$^{\circ}$ was well made with chalcopyrite structure at substrate temperature of 70 $^{\circ}C$, annealing temperature of 25$0^{\circ}C$, annealing time of 60 min. The CuInS$_2$ thin film had the greatest grain size of 1.2 ${\mu}{\textrm}{m}$ and Cu/In composition ratio of 1.03. Lattice constant of a and c of that CuInS$_2$ thin film was 5.60 $\AA$ and 11.12 $\AA$ respectively. Single phase CuInS$_2$ thin films were accepted from Cu/In composition ratio of 0.84 to 1.3. P-type CuInS$_2$ thin films were appeared at over Cu/In composition ratio of 0.99. Under Cu/In composition ratio of 0.96, conduction types of CuInS$_2$ thin films were n-type. Also, fundamental absorption wavelength, the absorption coefficient and optical energy band gap of p-type CuInS$_2$ thin film with Cu/In composition ratio of 1.3 was 837 nm, 3.0x10 $^4$ $cm^{-1}$ / and 1.48 eV respectively. When CuAn composition ratio was 0.84, fundamental absorption wavelength, the absorption coefficient and optical energy band gap of n-type CuInS$_2$ thin film was 821 nm, 6.0x10$^4$ $cm^{-1}$ / and 1.51 eV respectively.

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The Local Scour around a Slender Pile in Combined Waves and Current (파랑과 흐름이 결합된 공존역에서 파일 주변의 국부세굴)

  • Park, Jong-Hwan;Kim, Kyoung-Ho
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.22 no.6
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    • pp.405-414
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    • 2010
  • In the study, experiments are performed in the mixing region combined wave and current to investigate the characteristics of local scour around a slender pile. Wave generator and current generator are used for the experiments and currents are co-directions with the waves. The local scour depths around the pipeline are obtained according to the various pipe diameters, wave periods, wave heights, and current velocities. The experiments show that the maximum equilibrium local scour depth increases with pipe diameter, wave period, wave height, and current velocity. Using the experimental results, the correlations of scour depth and parameters such as Shields parameter ($\theta$), Froude number (Fr), Keulegan-Carpenter number (KC), Ursell number ($U_R$), modified Ursell number ($U_{RP}$) and ratio of velocities ($U_c/U_c+U_m$) are analyzed. In the mixing region combined with waves and currents, The Froude number of single parameters is the main parameter to cause the local scour around a slender pile due to waves and current and this means that current governs the scour within any limits of the currents.

Reflection of Porous Wave Absorber Using Quasi-linear Numerical Model (준선형 수치모델을 이용한 투과성 소파장치의 반사율)

  • Ko, Chang-hyun;Cho, Il-Hyoung
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.30 no.1
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    • pp.1-9
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    • 2018
  • In present study, we suggested the quasi-linear model that linearizes the quadratic drag representing the energy loss across the porous plate. The quasi-linear model was solved by Boundary Element Method (BEM) for development of the porous wave absorber suitable for 2-D wave tank. The drag coefficient at the porous plate was newly obtained through comparison of experimental results. It is found that the porous wave absorber with porosity 0.1, submergence depth d/h = 0.1, and inclined angle $10^{\circ}{\leq}{\theta}{\leq}20^{\circ}$ shows the effective wave absorption. Using the developed quasi-linear numerical model, the optimal design of various types of a porous wave absorber will be applied.

A Study on the Multi-sensory Stimulation of Aroma and Color Temperature effects on Neuro-energy (아로마 및 색온도의 다감각자극이 뉴로에너지에 미치는 영향)

  • Kim, Jung-Min;Seo, Kwang-Soo;Kim, Myung-Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.5
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    • pp.3579-3586
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    • 2015
  • In this study, EEG, HRV, and Vibra image were compared and analyzed in the environmental test room due to stimulation of aroma and color temperature. The condition of the environmental test room was in temperature $25[^{\circ}C]$, relative humidity 50[RH%], air current speed 0.02[m/s] and illuminance 1000[lux] with setting up different sensory stimulation condition which are before exposure, single-sensory stimulation of Jasmine scent, single-sensory stimulation of RED color lighting, and multi-sensory stimulation of Jasmine scent and RED color lighting. The result of this study, at multi-sensory stimulation of Jasmine scent and RED color lighting, relative $S{\alpha}$ wave, SEF50, $SMR/{\theta}$ and SDNN were revitalized, and both sides ${\alpha}$ wave asymmetry index, stress index, fatigue degree, and HRT were decreased. Also, Viba image of tension/anxiety and stress were declined. Therefore multi-sensory stimulation of Jasmine scent and RED color lighting effects to increase the Neuro-energy like amenity, productivity of work efficiency, and concentration.