• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.238-238
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• 2012

Ag (silver)의 일함수는 T-OLED (Top Emission Organic Light Emitting Diode)의 전극소자로 사용하기에는 다소 낮다는 단점이 있다(~4.3 eV). 이러한 단점을 해결하기 위한 대안으로 Ag 박막의 표면을 플라즈마 처리, UV 처리 및 열처리를 통하여 일함수를 높이는 연구가 진행 되어왔다(>5.0 eV). 하지만 현재의 대부분 연구는 후 처리된 박막의 일함수에 초점을 맞춰 연구가 진행 되어 박막의 nano-mechanical property에 대한 연구는 매우 부족하다. 따라서 본 논문에서는 AgOx 박막의 nano-mechanical property에 초점을 맞춰 분석을 실시하였다. 연구에 사용된 샘플은 Ag 박막을 유리기판 위에 rf-magnetron sputter 장치를 이용하여 100 W의 power로 150 nm 두께로 증착하였다. 증착된 Ag 박막은 $O_3$ 발생 UV 램프를 이용하여, 다양한 시간동안 UV 처리하였다(0~9분). 증착된 샘플은 Four-point probe, nanoindenter 장비를 이용하여 nano-mechanical property를 분석하였다. 실험 결과 UV 처리 시간이 0, 1분에서 면저항이 0.16, 0.50 ${\Omega}$/sq로 급격한 변화가 나타났으나, 반면 3분 이후 9분의 샘플의 경우, 0.55 ${\Omega}$/sq에서 0.24, 0.20, 0.15 ${\Omega}$/sq로 감소하여 전기적 특성변화를 볼 수 있었다. 또한 nanoindenting 결과 UV 처리한 박막의 극 표면 경도 값의 변화는 0~5분 처리한 샘플의 경우, 물리적인 경도가 증가하는 형태를 보이며 UV 처리를 5분간 했을때 7.89 GPa로 최고의 경도를 가진다. 그 이후부터는 6.97, 3.46 GPa의 결과로 박막의 경도가 감소되는 결과를 얻었다. 이러한 결과로부터 Ag 박막의 후처리에 따른 Ag 물질의 산화 및 결정상태에 따라 박막 내에 존재하는 residual stress를 분석할 수 있다.

• Journal of the Korean Chemical Society
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• v.42 no.6
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• pp.679-695
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• 1998

A series of ${\alpha}{\omega}-bis[4-(4'-(S)-(+)-2-methylbutylbiphenyl-4-carboxy)phenoxy]alkanes$, were synthesized, and their thermal and liquid crystalline properties were studied. The chain length of the central polymethylene spacers, x, of the chiral twin compounds was varied from 3 to 12. These compounds were characterized by elemental analysis, IR and NMR spectroscopy, differential thermal analysis (DSC), and crosspolarized microscopy. All compounds were found to be enantiotropic liquid crystalline, and the values of melting $(T_m)$ and isotropization temperature $(T_i)$ as well as ${\delta}H_I$ and ${\delta}S_I$ decreased in a zig-zag fashion, revealing the so called odd-even effect as x increased. Their mesomorphic properties fell into four categories depending upon x; (a) compounds with x=3, 4 and 5 formed only a cholesteric phase on heating, while on cooling they went through two transitions of isotropic (I)-to-cholesteric (Ch) and Ch-to-smectic $A\;(S_A)$ phases before crystallization. (b) compounds with x=6, 8 and 10 exhibited only a cholesteric phase both on heating and on cooling. (c) compounds with x=7 and 9 went through three transitions of crystal $(C)-to-S_A,\;S_A-to-Ch,$ and Ch-to-I phases on heating while on cooling they went through four transitions of I-to-Ch, $Ch-to-S_A,\;S_A-to-Smectic\;C\;(S_C),\;and\;S_c-to-C$ phases in that order, and (d) compounds with x=11 and 12 went reversibly through four transitions of $C-to-S_C,\;S_C-to-S_A,\;S_A-to-Ch,$ and Ch-to-I phases.

• Kyungpook Mathematical Journal
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• v.59 no.3
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• pp.415-431
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• 2019

In this paper we introduce a new class of operators which will be called the class of k-quasi-class A(s, t) operators. An operator $T{\in}B(H)$ is said to be k-quasi-class A(s, t) if $$T^{*k}(({\mid}T^*{\mid}^t{\mid}T{\mid}^{2s}{\mid}T^*{\mid}^t)^{\frac{1}{t+s}}-{\mid}T^*{\mid}^{2t})T^k{\geq}0$$, where s > 0, t > 0 and k is a natural number. We show that an algebraically k-quasi-class A(s, t) operator T is polaroid, has Bishop's property ${\beta}$ and we prove that Weyl type theorems for k-quasi-class A(s, t) operators. In particular, we prove that if $T^*$ is algebraically k-quasi-class A(s, t), then the generalized a-Weyl's theorem holds for T. Using these results we show that $T^*$ satisfies generalized the Weyl's theorem if and only if T satisfies the generalized Weyl's theorem if and only if T satisfies Weyl's theorem. We also examine the hyperinvariant subspace problem for k-quasi-class A(s, t) operators.

• Bulletin of the Korean Mathematical Society
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• v.22 no.2
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• pp.95-98
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• 1985

In [1], E.B. Lee and L. Markus described a sufficient condition for which the domain of null-controllability of a linear autonomous system is all of R$^{n}$ . The purpose of this note is to extend the result to a certain linear nonautonomous system. Thus we consider a linear control system dx/dt = A(t)x+B(t)u in the Eculidean n-space R$^{n}$ where A(t) and B(t) are n*n and n*m matrices, respectively, which are continuous on 0.leq.t<.inf. and A(t) is a periodic matrix of period .omega.. Admissible controls are bounded measurable functions defined on some finite subintervals of [0, .inf.) having values in a certain convex set .ohm. in R$^{m}$ with the origin in its interior. And we present a sufficient condition for which the domain of null-controllability is all of R$^{n}$ .

• Transactions of the Korean Society of Mechanical Engineers
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• v.11 no.1
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• pp.132-144
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• 1987

This paper presents the theroetical analysis of the crack tip stress intensity factor for a center crack in a finite width plate with variable thickness. The analyses were based on Laurent's expansions of complex stress potentials where the expansion coefficients are determined from the boundary conditions. The perturbation method was employed in numerical calculations. The correction factor F(.lambda.)is given in the form of power series of .lambda. [a numerical formula] where .lambda.=a/w$^{1}$; Dimensionless crack length, .betha.=t$_{2}$/t; Thickness ratio .omega.=w$_{2}$/w$_{1}$; width ratio The correction factor values vary with the width ratio .omega. and the maximum variation occurs around .betha.=1. For the case of .betha.=1 or .betha.=0 (uniform thickness plate0, the correction factor values agree well with Feddersen's formula. In all cases, as .lambda. approaches to 1 (thickness interface), the correction factor values are decreased rapidly for .betha.>1, and increased rapidly for .betha.<1.

• Journal of the Korean Society of Combustion
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• v.20 no.3
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• pp.8-12
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• 2015

The CO reduction characteristics of hot air stream diluted with exhaust gas in a perfectly stirred reactor (PSR) were investigated numerically. The dilution ratio ($\Omega$), inlet temperature ($T_{in}$), and residence time ($\tau$) were considered as parameters to investigate the effects of those on the emission indices for CO and $CO_2$ (EICO and $EICO_2$). The roles of dominant reactions and the production rates of major species were analyzed. It was found from the EICO trend that the supplied CO in the air stream was consumed. The EICO increased negatively with $T_{in}$ at fixed $\tau$ regardless of $\Omega$. However, the magnitude of EICO and minimum inlet temperature for CO reduction showed complicated trend according to the variation of $\tau$. It was identified that the OH radical, generated from the reactions, $O_2+H{\leftrightarrow}O+OH$ and $2OH{\leftrightarrow}H+H_2O$, affected the CO reduction by the reaction, $CO+OH{\leftrightarrow}H+CO_2$. However, the CO emission ratio increased at sufficiently high inlet temperature range due to the thermal dissociation of $CO_2$.

• Journal of applied mathematics & informatics
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• v.12 no.1_2
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• pp.81-105
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• 2003

This paper deals with the very interesting problem about the influence of piecewise smooth boundary conditions on the distribution of the eigenvalues of the negative Laplacian in R$^3$. The asymptotic expansion of the trace of the wave operator (equation omitted) for small ｜t｜ and i=√-1, where (equation omitted) are the eigenvalues of the negative Laplacian (equation omitted) in the (x$^1$, x$^2$, x$^3$)-space, is studied for an annular vibrating membrane $\Omega$ in R$^3$together with its smooth inner boundary surface S$_1$and its smooth outer boundary surface S$_2$. In the present paper, a finite number of Dirichlet, Neumann and Robin boundary conditions on the piecewise smooth components (equation omitted)(i = 1,...,m) of S$_1$and on the piecewise smooth components (equation omitted)(i = m +1,...,n) of S$_2$such that S$_1$= (equation omitted) and S$_2$= (equation omitted) are considered. The basic problem is to extract information on the geometry of the annular vibrating membrane $\Omega$ from complete knowledge of its eigenvalues by analysing the asymptotic expansions of the spectral function (equation omitted) for small ｜t｜.

• Journal of the Korean Chemical Society
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• v.36 no.3
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• pp.345-350
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• 1992

Proton lineshapes and chemical shifts of paramagnetic solutions of Ln$(NO_3)_3$ in DMF have been measured over the temperature range 240K to 3807K. Solvation sphere exchange rates and the thermodynamic exchange parameters for CHO group of the DMF molecules have been extracted from these data. The results were established through a detailed analysis and discussion of the temperature depending data of the 1/$T_2$ and ${\Dellta}{\omega}$ data were analyzed in detail, and it has been found that delocalization of the unpaired electron spin from some $Ln^{3+}$ ion to DMF molecules beyond the first solvation shell would occur, giving rise to a scalar relaxation contribution in the bulk solvent.

• Korean Journal of Microbiology
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• v.49 no.1
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• pp.58-63
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• 2013

A taxonomic study was carried out to assess the phylogenetic characteristics of isolate JJM57 from marine red algae Laurencia sp. collected from intertidal zone in Jeju Island, South Korea. Comparative analysis of 16S rRNA gene sequence shows that this isolate belongs to the genus Oceanisphaera. It shows 98.02% and 97.7% sequence similarity with Oceanisphera litoralis DSM $15406^T$ and Oceanisphera donghaensis KCTC $12522^T$, respectively. Strain JJM57 is a Gram-negative, aerobic, moderately halophilic bacterium able to grow in different NaCl concentration ranges from 0.5 to 8.0% and at varying temperatures from 4 to $37^{\circ}C$. Sharing some of the physiological and biochemical properties with O. litoralis and O. donghaensis, JJM57 strain differs in the utilization of ethanol, proline, and alanine. The G+C contents of the strain JJM57 is 61.94 mol% and it is rich in $C_{16:1}$ ${\omega}7c$ and/or iso-$C_{15:0}$ 2-OH, $C_{16:0}$, and $C_{18:1}$ ${\omega}7c$ fatty acids. The DNA-DNA relatedness data separates the strain JJM57 from other species such as O. litoralis and O. donghaensis. On the basis of these polyphasic evidences, present study proposed that strain JJM57 (=KCTC 22371 =AM983543 =CCUG 60764) represents a novel bacterial species of Oceanisphaera.

• Polymer(Korea)
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• v.34 no.2
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• pp.154-158
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• 2010

We first synthesized N-phenylcyclotrisiloxazane ($D_3^{NPh}$) through a cyclization of $\alpha$,$\omega$- dichlorohexamethyltrisiloxane with aniline and prepared poly(dimethylsiloxane-co-N-phenylsiloxazane) copolymer (PDMS-NPSOX) by a ring opening copolymerization of them with hexamethylcyclotrisiloxane $D_3$. An acrylate monomer modified with PDMS-NPSOX was synthesized by using chloroethyl methacrylate and copolymerized with methylmethacrylate (MMA) and n-butylacrylate. The composition of the copolymer was chosen to control their glass transition temperature ($T_g$) to 25 $^{\circ}C$. By changing the comonomer from PDMS to PDMS-NPSOX, $T_g$ and adhesive strength of the copolymer were increased from 20 to 25 $^{\circ}C$ and from 1.76 to 2.23 N/cm, respectively.