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제지용(製紙用) 섬유(纖維)의 화학적(化學的) 개질(改質)에 관한 연구(硏究) (I) - Partial Carboxymethylation 처리에 의한 물성(物性) 향상(向上) - (A Study on Chemical Modification of Papermaking Fibers (I) - Improved Physical Characteristics from Partial Carboxymethylated Pulps -)

  • 최정헌;조병묵;오정수
    • Journal of the Korean Wood Science and Technology
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    • 제23권2호
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    • pp.37-46
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    • 1995
  • The substitution of carboxymethylated hydroxyl group in pulp revealed more hydrophilic than hydroxyl group. And then fibers were more flexible, swell more which leads to better conformation between fibers in turn this raise paper strength. In this paper, we tried to chemical modifyings of recycled fiber, OCCs(old corrugated containers). Many researchers have examined chemical modification of papermaking fiber by partial carboxymethylation(PCM) using a organic solvent processes. We made modified PCM processes adapted waters m replace of the organic solvent. Our testings for the optimum conditions on the new method, conditions as reaction time, temperature, liquor ratios were designed likely plant system. Freenesses(SR$^{\circ}$) were increased following on carboxyl content of the samples. Handsheets of untreated samples and partial carboxymethylated OCCs were made by optimum conditions on different concentrations of the reagent. As results, maximum 25% strength increasing effects were obtained by the new method.

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Lyocell 섬유를 함유한 종이의 제조 및 적용에 관한 연구( I ) (A study on the application and manufacture of paper sheet containing lyocell fiber( I ))

  • 김종열;류운형;유성종;김정열;신창호;김영호
    • 한국연초학회지
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    • 제22권1호
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    • pp.99-106
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    • 2000
  • In order to investigate the applicability of lyocell fiber to filter paper, papper sheets were manufactured with the addition of lyocell fibers in various length(1.5 denier: 2, 3, 4mm) and content(10, 30, 50%) and their physical characters, such as fibrilation rate, adsorption efficiency of methylene blue(MB), paper formation, and crimping ability, etc, were tested. The level of main fibrilation from lyocell fiber was higher in wet beating process than that in free beating because of the higher strength of lyocell fiber compared with wood fiber. Fibrilation could be observed at the degree of beating over 30$^{\circ}$ SR in wet beating with Valley beater. The air permeability and tear factor of the paper increased and the paper formation index decreased according to the increase of fiber length. The weak binding force of lyocell fiber in spite of its higher fiber strength, might be a limitng factor in addition of lyocell fiber to the natural wood pulp in manufacturing the paper having the needed physical properties. High contents of wood pulp decreased air permeability, the breaking length, tear factor, the bursting strength, and paper formation index in paper sheets. As the contents of lyocell increased from 10% to 100%, the adsorption efficiency of MB was elevated to 1.7-7.9 times compared with that in 100% wood pulp. But the length of lyocell fiber did not affect the MB adsorption.

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ABSORBED INTERNAL DOSE CONVERSION COEFFICIENTS FOR DOMESTIC REFERENCE ANIMALS AND PLANT

  • Keum, Dong-Kwon;Jun, In;Lim, Kwang-Muk;Choi, Yong-Ho
    • Nuclear Engineering and Technology
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    • 제42권1호
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    • pp.89-96
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    • 2010
  • This paper describes the methodology of calculating the internal dose conversion coefficient in order to assess the radiological impact on non-human species. This paper also presents the internal dose conversion coefficients of 25 radionuclides ($^3H,\;^7Be,\;^{14}C,\;^{40}K,\;^{51}Cr,\;^{54}Mn,\;^{59}Fe,\;^{58}Co,\;^{60}Co,\;^{65}Zn,\;^{90}Sr,\;^{95}Nb,\;^{99}Tc,\;^{106}Ru,\;^{129}I,\;^{131}I,\;^{136}Cs,\;^{137}Cs,\;^{140}Ba,\;^{140}La,\;^{144}Ce,\;^{238}U,\;^{239}Pu,\;^{240}Pu$) for domestic seven reference animals (roe deer, rat, frog, snake, Chinese minnow, bee, and earthworm) and one reference plant (pine tree). The uniform isotropic model was applied in order to calculate the internal dose conversion coefficients. The calculated internal dose conversion coefficient (${\mu}Gyd^{-1}$ per $Bqkg^{-1}$) ranged from $10^{-6}$ to $10^{-2}$ according to the type of radionuclides and organisms studied. It turns out that the internal does conversion coefficient was higher for alpha radionuclides, such as $^{238}U,\;^{239}Pu$, and $^{240}Pu$, and for large organisms, such as roe deer and pine tree. The internal dose conversion coefficients of $^{239}U,\;^{240}Pu,\;^{238}U,\;^{14}C,\;^3H$, and $^{99}Tc$ were independent of the organism.

Newly developed MSAP analysis reveals the different polymorphism patterns in transgenic tobacco plants with the dsRNA MET1 gene

  • Oh, Yun Jung;Chung, Hee;Yu, Jae Gyeong;Park, Young Doo
    • Plant Biotechnology Reports
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    • 제3권2호
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    • pp.139-145
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    • 2009
  • DNA methylation is known to play an important role in the regulation of gene expression in eukaryotes. In this study, we isolated NtMET1 from Nicotiana tabacum cv. Havana (SR1) and obtain transgenic plants that reduced MET1 expression level with the double-strand RNA (dsRNA) MET1 gene. Transgenic tobacco plants showed dwarf and abnormal flower development when compared with the wild type. Using methylation-sensitive amplified polymorphism (MSAP) analysis, the patterns of cytosine methylation in transformed plants and the wild type were compared. MseI/HpaII selection primers showed an interesting polymorphism, and 153 DNA bands of interest were detected. Among these, 30 selective fragments were sequenced and analyzed with a BLAST search by successful MSAP modifications. The homology search showed that the transposons and tandem repeated sequences were related to the phenotypes. These results suggested that the decreased degree of methylation by dsRNA strategy caused abnormal growth and development in N. tabacum.

한국남부(韓國南部)의 백악기말(白堊紀末) 이후(以後)의 화성활동(火成活動)과 광화작용(鑛化作用)에 대(對)한 판구조론(板構造論)의 적용성(適用性) 연구(硏究)( I ) (Applicability of plate tectonics to the post-late Cretaceous igneous activities and mineralization in the southern part of South Korea( I ))

  • 민경덕;김옥준;윤석규;이대성;주승환
    • 자원환경지질
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    • 제15권3호
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    • pp.123-154
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    • 1982
  • Petrochemical, K-Ar dating, Sand Rb/Sr isotopes, metallogenic zoning, paleomagnetic and geotectonic studies of the Gyongsang basin were carried out to examine applicability of plate tectonics to the post-late Cretaceous igneous activity and metallogeny in the southeastern part of Korean Peninsula. The results obtained are as follows: 1. Bulgugsa granitic rocks range from granite to adamellite, whose Q-Ab-Or triangular diagram indicates that the depth and pressure at which the magma consolidated increase from coast to inland varying from 6 km, 0.5-3.3 kb in the coastal area to 17 km, 0.5-10 kb in the inland area. 2. The volcanic rocks in Gyongsang basin range from andesitic to basaltic rocks, and the basaltic rocks are generally tholeiitic in the coastal area and alkali basalt in the inland area. 3. The volcanic rocks of the area have the initial ratio of Sr^{87}/Sr^{86} varying from 0.706 to 0.707 which suggests a continental origin; the ratio of Rb/Sr changing from 0.079-0.157 in the coastal area to 0.021-0.034 in the inland area suggests that the volcanism is getting younger toward coastal side, which may indicate a retreat in stage of differentiation if they were derived from a same magma. The K_2O/SiO_2 (60%) increases from about 1.0 in the coastal area to about 3.0 in the inland area, which may suggest an increase indepth of the Benioff zone, if existed, toward inland side. 4. The K-Ar ages of volcanic rocks were measured to be 79.4 m.y. near Daegu, and 61.7 m.y. near Busan indicating a southeastward decrease in age. The ages of plutonic rocks also decrease toward the same direction with 73 m.y. near Daegu, and 58 m.y. near Busan, so that the volcanism predated the plutonism by 6 m.y. in the continental interior and 4 m.y. along the coast. Such igneous activities provide a positive evidence for an applicability of plate tectonics to this area. 5. Sulfur isotope analyses of sulfide minerals from 8 mines revealed that these deposits were genetically connected with the spacially associated ingeous rocks showing relatively narrow range of ${\delta}^{34}S$ values (-0.9‰ to +7.5‰ except for +13.3 from Mulgum Mine). A sequence of metallogenic zones from the coast to the inland is delineated to be in the order of Fe-Cu zone, Cu-Pb-Zn zone, and W-Mo zone. A few porphyry type copper deposits are found in the Fe-Cu zone. These two facts enable the sequence to be comparable with that of Andean type in South America. 6. The VGP's of Cretaceous and post Cretaceous rocks from Korea are located near the ones($71^{\circ}N$, $180^{\circ}E$ and $90^{\circ}N$, $110^{\circ}E$) obtained from continents of northern hemisphere. This suggests that the Korean peninsula has been stable tectonically since Cretaceous, belonging to the Eurasian continent. 7. Different polar wandering path between Korean peninsula and Japanese islands delineates that there has been some relative movement between them. 8. The variational feature of declination of NRM toward northwestern inland side from southeastern extremity of Korean peninsula suggests that the age of rocks becomes older toward inland side. 9. The geological structure(mainly faults) and trends of lineaments interpreted from the Landsat imagery reveal that NNE-, NWW- and NEE-trends are predominant in the decreasing order of intensity. 10. The NNE-trending structures were originated by tensional and/or compressional forces, the directions of which were parallel and perpendicular respectively to the subduction boundary of the Kula plate during about 90 m.y. B.P. The NWW-trending structures were originated as shear fractures by the same compressional forces. The NEE-trending structures are considered to be priginated as tension fractures parallel to the subduction boundary of the Kula plate during about 70 m.y. B.P. when Japanese islands had drifted toward southeast leaving the Sea of Japan behind. It was clearly demonstrated by many authors that the drifting of Japanese islands was accompanied with a rotational movement of a clock-wise direction, so that it is inferred that subduction boundary had changed from NNE- to NEE-direction. A number of facts and features mentioned above provide a suite of positive evidences enabling application of plate tectonics to the late Cretaceous-early Tertiary igneous activity and metallogeny in the area. Synthesizing these facts, an arc-trench system of continental margin-type is adopted by reconstructing paleogeographic models for the evolution of Korean peninsula and Japan islands. The models involve an extention mechanism behind the are(proto-Japan), by which proto-Japan as of northeastern continuation of Gyongsang zone has been drifted rotationally toward southeast. The zone of igneous activity has also been migrated from the inland in late-Cretaceous to the peninsula margin and southwestern Japan in Tertiary.

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a-Si:H TFT Using Ferroelectrics as a Gate Insulator

  • Hur, Chang-Wu;Kung Sung;Jung-Soo, Youk;Sangook Moon;Kim, Jung-Tae
    • 한국정보통신학회:학술대회논문집
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    • 한국해양정보통신학회 2004년도 SMICS 2004 International Symposium on Maritime and Communication Sciences
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    • pp.53-56
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    • 2004
  • The a-Si:H TFT using ferroelectric of SrTi $O_3$as a gate insulator is fabricated on glass. Dielectric characteristics of ferroelectric are superior to $SiO_2$and S $i_3$ $N_4$. Ferroelctric increases on-current, decreases thresh old voltage of TFT and also improves breakdown characteristics. The a-SiN:H has optical band gap of 2.61 eV, refractive index of 1.8~2.0 and resistivity of 10$^{13}$ - 10$^{15}$ $\Omega$cm, respectively. Insulating characteristics of ferroelectrics are excellent because dielectric constant of ferroelectric is about 60~100 and breakdown strength is over 1MV/cm. TFT using ferroelectric has channel length of 8~20${\mu}{\textrm}{m}$ and channel width of 80~200${\mu}{\textrm}{m}$. And it shows that drain current is 3.4$mutextrm{A}$ at 20 gate voltage, $I_{on}$ / $I_{off}$ is a ratio of 10$^{5}$ - 10$^{8}$ and $V_{th}$ is 4~5 volts, respectively. In the case of TFT without ferroelectric, it indicates that the drain current is 1.5 $mutextrm{A}$ at 20 gate voltage and $V_{th}$ is 5~6 volts. With the improvement of the ferroelectric thin film properties, the performance of TFT using this ferroelectric has advanced as a gate insulator fabrication technology is realized.zed.d.

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혼합전도체 LSCF(La0.6Sr0.4Co0.2Fe0.8O3) 양극의 기공률에 따른 양극분극 특성 (Effect of Cathode Porosity on the Cathodic Polarization Behavior of Mixed Conducting LSCF(La0.6Sr0.4Co0.2Fe0.8O3))

  • 윤중철;이종호;김주선;이해원;김병호
    • 한국세라믹학회지
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    • 제42권4호
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    • pp.251-259
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    • 2005
  • 혼합전도체 산화물, LSCF의 전극반응점 분포에 따른 분극현상을 관찰하기 위해 다공성 양극의 기공률을 변화시켜가며 분극특성을 관찰하였다. 전극의 기공률을 달리하기 위해 크기가 다른 두 종류의 LSCF 분말들을 혼합비를 달리하여 사용하였으며 GDC 전해질 기판에 스크린 인쇄법을 통해 전극을 구성한 후 반쪽전지 실험을 수행하였다. 제조된 후막전극의 기공률은 화상 분석법을 통해 측정하였으며 전극의 전체 비표면적을 유추하기 위해 2차원 이미지에서의 기공의 둘레 길이를 측정하였다. 교류 임피던스법을 이용해 분극 특성을 관찰한 결과 혼합전도체인 LSCF 양극에서의 전극반응은 i) 양극표면에서 이온화된 산소이온이 전해질과의 삼상계면까지 이동해 오는 단계, ii) 이동해온 산소이온이 양극으로부터 전해질로 전달되는 반응단계에 의해 제어됨을 알 수 있었다. 이러한 양극에서의 분극은 기공률의 증가에 따라 전극 반응에 필요한 활성 표면이 증가됨으로써 줄어드는 것을 알 수 있었다.

Brookhaven 醫學硏究用 原子爐에서의 氣體噴出物에 관한 硏究 (A Study on Gaseous Effluents from BMRR)

  • 황선태;박태순;하석호;최성숙
    • 한국대기환경학회지
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    • 제4권2호
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    • pp.1-10
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    • 1988
  • Brookhaven 의학연구용 원자로에서 방출되는 기체분출물에 관하여 연구 되었다. 모든 기체시료는 $\gamma$-선 분광계측에 의하여 분석되었다. 시료 중에 존재하는 것으로 확인된 핵종으로서, $^{82}Cl(T_{1/2}$ = 35.30 시간) 이 가장 뚜렷하였다. 그 외의 확인된 핵종은 $^{38}Cl(T_{1/2}$ = 37.24분), $^{41}Ar(T_{1/2}$ = 1.82시간), $^{106}Rh(T_{1/2}$ = 29.80묘), $^{133}Te(T_{1/2}$ = 12.45분)이었다. 3MW 원자로 출력에서 pre-filter bank를 통과한 기체분출물 중에서 $$^{41}Ar$의 농도는 2.436Bq/cc로 계산됨으로써 $^{41}Ar$의 방사능 방출율은 8.51 ${\times}10^9$Bq/MW - h로 산정되었다. filter bank의 방사능 원거효율(%)은 $^{38}Cl$의 경우 97.84%, $^{41}Ar$은 14.15%, ^{82}Br$은 98.70% 그리고 $^{106}Rh$은 98.81% 각각 산정되었다. 한편, charcoal trap과 millipore filter 에서 확인된 기타 핵종들로서 $^{24}Na$, $^{72}Ga$, $^{92}Sr$, $^{97}Zr$, $^{132}I$, $^{133}Te$, $^{141}Ce$, $^{153}Sm$$^{154}Pm$은 filter bank에 의해서 완전히 제거되었다.

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중국 Zhenzigou 연-아연 광상의 백색운모 산상과 화학조성 (Occurrence and Chemical Composition of White Mica from Zhenzigou Pb-Zn Deposit, China)

  • 유봉철
    • 광물과 암석
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    • 제35권2호
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    • pp.83-100
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    • 2022
  • Zhenzigou 연-아연 광상은 중국 동북지역에선 가장 규모가 큰 연-아연 광상 중의 하나로 지체구조상 Jiao Liao Ji belt내 Qingchengzi mineral field에 위치한다. 이 광상의 주변지질은 시생대의 그래뉼라이트(granulite)와 이를 관입한 고원생대의 미그마타이트질 화강암과 고-중원생대의 소딕(sodic) 화강암을 부정합으로 피복한 고원생대의 Liaohe 층군 및 이들을 관입한 중생대의 섬록암과 몬조나이틱 화강암으로 구성된다. 이 광상은 고원생대의 Liaohe 층군내 Langzishan 층 및 Dashiqiao 층내에서 층상 광체 및 맥상 광체로 산출되며 층준규제 퇴적분기형 또는 퇴적분기형 광상에 해당된다. 이 광상에서 산출되는 백색운모는 층상 광체에서만 산출되며 모암의 종류, 변질 정도, 광석광물의 유무 및 광체 형태에 따라 4 가지 형(I 형 백색운모 : 약변질(쇄설성 돌로마이트질 대리암), II 형 백색운모 : 강변질(돌로마이트질 쇄설성 암석), III 형 백색운모 : 층상광체(돌로마이트질 쇄설성 암석), IV 형 백색운모 : 층상 광체(쇄설성 돌로마이트질 대리암))으로 분류된다. I 형 백색운모는 약 변질정도를 갖는 쇄설성 돌로마이트질 대리암내 돌로마이트를 열수교대작용에 의한 돌로마이트화작용에 의해 형성된 돌로마이트와 함께 산출된다. II 형 백색운모는 강 변질정도를 갖는 돌로마이트질쇄설성 암석내 열수교대작용에 의한 칼리장석의 변질물이나 돌로마이트화작용에 의해 형성된 돌로마이트, 철백운석, 석영과 함께 산출된다. III 형 백색운모는 층상 광체를 갖는 돌로마이트질 쇄설성 암석내 열수교대작용에 의한 칼리장석의 변질물이나 돌로마이트화작용에 의해 형성된 철백운석, 방해석, 석영과 함께 산출된다. IV 형 백색운모는 층상 광체를 갖는 쇄설성 돌로마이트질 대리암내 열수교대작용에 의한 칼리장석의 변질물이나 돌로마이트, 석영과 함께 산출된다. 이들 백색운모의 화학조성은 각각 (K0.92-0.80Na0.01-0.00Ca0.02-0.01Ba0.00Sr0.01-0.00)0.95-0.83(Al1.72-1.57Mg0.33-0.20Fe0.01-0.00Mn0.00Ti0.02-0.00Cr0.01-0.00V0.00Sb0.02-0.00Ni0.00Co0.02-0.00)1.99-1.90(Si3.40-3.29Al0.71-0.60)4.00O10(OH2.00-1.83F0.17-0.00)2.00, (K1.03-0.84Na0.03-0.00Ca0.08-0.00Ba0.00Sr0.01-0.00)1.08-0.85(Al1.85-1.65Mg0.20-0.06Fe0.10-0.03Mn0.00Ti0.05-0.00Cr0.03-0.00V0.01-0.00Sb0.02-0.00Ni0.00Co0.03-0.00)1.99-1.93(Si3.28-2.99Al1.01-0.72)4.00O10(OH1.96-1.90F0.10-0.04)2.00, (K1.06-0.90Na0.01-0.00Ca0.01-0.00Ba0.00Sr0.02-0.01)1.10-0.93(Al1.93-1.64Mg0.19-0.00Fe0.12-0.01Mn0.00Ti0.01-0.00Cr0.01-0.00V0.00Sb0.00Ni0.00Co0.05-0.01)2.01-1.94(Si3.32-2.96Al1.04-0.68)4.00O10(OH2.00-1.91F0.09-0.00)2.00 및 (K0.91-0.83Na0.02-0.01Ca0.02-0.00Ba0.01-0.00Sr0.00)0.93-0.83(Al1.84-1.67Mg0.15-0.08Fe0.07-0.02Mn0.00Ti0.04-0.00Cr0.06-0.00V0.02-0.00Sb0.02-0.01Ni0.00Co0.00)2.00-1.92(Si3.27-3.16Al0.84-0.73)4.00O10(OH1.97-1.88F0.12-0.03)2.00 로써 이론적인 이중팔면체형 운모류 값보다 Si가 높고 K, Na, Ca는 낮으며 모두 백운모에 해당된다. 특히, Zhenzigou 연-아연 광상에서 산출되는 백색운모의 화학조성 변화는 팬자이틱 또는 Tschermark 치환[(Al3+)VI+(Al3+)IV <-> (Fe2+ 또는 Mg2+)VI+(Si4+)IV] 메카니즘에 의해 일어났으며 백색운모의 Fe는 Fe2+와 Fe3+ 로써 존재하지만 주로 Fe2+ 우세함을 의미한다. 따라서 Zhenzigou 연-아연 광상의 층상 광체에서 산출되는 백색운모들은 고원생대의 화성활동 및 녹색편암상의 변성작용에 의한 열수교대작용으로 기존에 산출되었던 광물들의 재용융 및 재침전 과정에서 형성되었으며 이들 백색운모의 화학조성 변화는 열수교대작용 동안 모암인 돌로마이트 및 쇄설성 암석의 함량 차이, 변질 정도 및 광석광물의 유무에 따른 팬자이틱 또는 Tschermark 치환[(Al3+)VI+(Al3+)IV <-> (Fe2+ 또는 Mg2+)VI+(Si4+)IV] 메카니즘에 의해 일어났음을 알 수 있다.