• Title/Summary/Keyword: $SrCu_2O_2$

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Fishing Effect of BiPbSrCaCuO Superconductor (BiPbSrCaCuO 초전도체의 Fishing 효과)

  • Lee, Sang-Heon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.05b
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    • pp.177-179
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    • 2004
  • Suspension effect has been studied by using superconductor of BiPbSrCaCuO ceramics containing $Ag_2O$. It has been cleared that $Ag_2O$ acts as pinning center which plays an important role to the suspension effect. Magnetic repulsive force which affects a superconductor located in magnetic flux from toroidal magnet has been investigated. It has been concluded that the suspension effect arises from the interaction between the pinning effect and the diamagnetic effect.

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Suspension Mechanism of BiPbSrCaCuO Superconductor (BiPbSrCaCuO 초전도체의 자기부양 메커니즘)

  • Lee, Sang-Heon;Lee, Young-Hie;Nam, Sung-Pil;Lee, Sung-Gap
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.90-92
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    • 2004
  • Suspension effect has been studied by using superconductor of BiPbSrCaCuO ceramics containing $Ag_2O$. It has been cleared that $Ag_2O$ acts as pinning center which plays an important role to the suspension effect. Magnetic repulsive force which affects a superconductor located in magnetic flux from toroidal magnet has been investigated. It has been concluded that the suspension effect arises from the interaction between the pinning effect and the diamagnetic effect.

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Effect of Nitrogen Treatment on the Structure and Magnetic Properties of $RuSr_2(EuCe)Cu_2O_z$ Compound (질소 열처리에 따른 $RuSr_2(EuCe)Cu_2O_z$ 계의 구조 및 자기적 특성)

  • Lee, H.K.;Kim, Y.I.;Kim, Y.C.
    • Progress in Superconductivity
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    • v.13 no.3
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    • pp.178-183
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    • 2012
  • Two $RuSr_2(EuCe)Cu_2O_z$ samples (as prepared and after $N_2$ treatment) have been investigated by thermogravimetric (TC) analysis, high-resolution x-ray powder diffraction and magnetization measurements. TG measurements which were carried out in $H_2/Ar$ atmosphere showed that the $N_2$ treatment of the as-prepared sample at $650^{\circ}C$ for 2h leads to a decrease in the oxygen content z by about 0.25. This oxygen depletion was accompanied by an increase in the magnetic transition temperature from 54.0 K to 114.9 K. This magnetic behavior is discussed in connection with the results of Rietveld analysis of the x-ray diffraction data which showed that the $N_2$ treatment resulted in both a significant increase in the rotation angle of the $RuO_6$ octahedra and a decrease in c-lattice parameter of the sample.

Microstructure and Superconducting Properties of Ag-$Bi_{1.84}Pb_{0.34}Sr_{1.91}Ca_{2.03}Cu_{3.06}O_{10+{\delta}}$ Composites (Ag-$Bi_{1.84}Pb_{0.34}Sr_{1.91}Ca_{2.03}Cu_{3.06}O_{10+{\delta}}$ 복합체의 미세구조와 초전도특성)

  • 이민수
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.6
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    • pp.249-256
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    • 2003
  • Samples with the nominal composition, Ag-$Bi_{1.84}Pb_{0.34}Sr_{1.91}Ca_{2.03}Cu_{3.06}O_{10+{\delta}}$ high $T_{c}$ superconductors containing Ag as an additive were fabricated by a solid-state reaction method. Samples with Ag of 10 wt%, 30 wt%, and 50 wt% each were sintered at $860^{\circ}C$~$870^{\circ}C$ for 24 hours. The structural characteristics, the microstructures and the critical temperature with respect to the each samples were investigated by XRD, four-prove methode, SEM and EDS respectively. The $T_{c}\;^{zero}$ of the sample with the 50 wt% Ag additive at the surface showed 94 K.

Establishment of Preparation Conditions for High-Tc Superconducting Y-Ba-Cu-O Thin Film by Chemical Vapor Deposition (화학증착법에 의한 고온 초전도 Y-Ba-Cu-O 박막의 제조 조건 확립에 관한 연구)

  • Park, Joung-Shik;Cho, Ik-Joon;Kim, Chun-Yeong;Lee, Hee-Gyoun;Won, Dong-Yeon;Shin, Hyung-Shik
    • Applied Chemistry for Engineering
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    • v.3 no.3
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    • pp.412-421
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    • 1992
  • The superconducting thin films have shown a growing possibility for practical application in microelectronic fields in recent years. In this study, the high Tc superconducting Y-Ba-Cu-O thin films were prepared on various substrates by chemical vapor deposition method using organic metal chelates of $Y(thd)_3$, $Ba(thd)_2$, and $Cu(thd)_2$ as source materials. The deposition reactions were carried out on single crystalline MgO(100), YSZ(100), $SrTiO_3(100)$, and polycrystalline $SrTiO_3$ substrates. Deposition thickness of thin films was linearly increased with the increase of deposition time. It turned out that the Y-Ba-Cu-O thin films on MgO(100), YSZ(100), and $SrTiO_3(100)$ single crystal substrates showed superconductivities above liquid nitrogen temperature($T_{c,onset}=87{\sim}89K$, $T_{c,zero}=85{\sim}86K$), but the one on polycrystalline $SrTiO_3$ substrate did not.

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Crystallographic Site Dependent $^{16}\textrm{O}^{18}\textrm{O}$ Exchange Reaction in Bi-2212 High $\textrm{T}_{\textrm{c}}$ Oxide Superconductors (Bi-2212산화물 고온초전도체의 결정학적 위치에 의존하는 $^{16}\textrm{O}^{18}\textrm{O}$ 교환반응)

  • Kim, Byeong-Guk
    • Korean Journal of Materials Research
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    • v.7 no.2
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    • pp.157-161
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    • 1997
  • The crystallographic site dependent substitution of $^{18}O$ for $^{16}O$ in $Bi_{2}Sr_{2}Ca_{0.8}Y_{0.2}Cu_{2}^{16}O_{8+\delta}$ has heen investigated. In the Kaman spectra of $Bi_{2}Sr_{2}Ca_{0.8}Y_{0.2}Cu_{2}^{16}O_{8+\delta}$ three prominent Raman bands are observed at 297. 464, and $623cm^{-1}$. As the $^{16}O$ arc replaced hy $^{18}O$, all the three bands shift to lower wavewnumbers. The rate of this isotopic shift is similar for the hands at 397 and $464cm^{-1}$. whereas it is quite slower for the hand at $623cm^{-1}$ '['his implys that the $^{16}O-^{18}O$ exchange reaction is crystallographic sites dependent. .Assuming a tetragonal symmetry, we assign the bands at 623. 464, and $297cm^{-1}$ to the vibrations of $O_{pl}(A_{g}),\;O_{ap}\;and\;O_{Bi}$ respectively.

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Ce0.8Sm0.2O2 Sol-gel Modification on La0.8Sr0.2Mn0.8Cu0.2O3 Cathode for Intermediate Temperature Solid Oxide Fuel Cell

  • Lee, Seung Jin;Kang, Choon-Hyoung;Chung, Chang-Bock;Yun, Jeong Woo
    • Journal of the Microelectronics and Packaging Society
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    • v.22 no.4
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    • pp.77-82
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    • 2015
  • To increase the performance of solid oxide fuel cell operating at intermediate temperature ($600^{\circ}C{\sim}800^{\circ}C$), $Sm_{0.2}Ce_{0.8}O_2$ (SDC) thin layer was applied to the $La_{0.8}Sr_{0.2}Mn_{0.8}Cu_{0.2}O_3$ (LSMCu) cathode by sol-gel coating method. The SDC was employed as a diffusion barrier layer on the yttria-stabilized zirconia(YSZ) to prevent the interlayer by-product formation of $SrZrO_3$ or $La_2Zr_2O_7$. The by-products were hardly formed at the electrolyte-cathode interlayer resulting to reduce the cathode polarization resistance. Moreover, SDC thin film was coated on the cathode pore wall surface to extend the triple phase boundary (TPB) area.