• Title/Summary/Keyword: $SO_3$ decomposition

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Synthesis and Thermal Degradation of Poly(oxydiethylene adipate urethane) Composites Containing Cloisite 30B and Melamine Phosphate (Cloisite 30B와 멜라민포스페이트를 함유한 Poly(oxydiethylene adipate urethane) Composites의 합성과 열분해 특성)

  • Shin, Seung-Wook;Lee, Sang-Ho
    • Polymer(Korea)
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    • v.36 no.5
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    • pp.643-650
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    • 2012
  • In order to improve the thermal stability of polyurethane, we synthesized poly(adipate urethane) (PAU) and three PAU composites, PAU/30B (2.7 wt% 30B), PAU/MP (2.2 wt% MP), PAU/30B/MP (2.2 wt% 30B and 2.2 wt% MP), from poly(oxydiethylene adipate)-diol (PAD), 4,4'-methylene diphenyl diisocyanate (MDI), Cloisite 30B (30B), and melamine phosphate (MP). 30B and MP were introduced into the reactant mixture at the initial stage of the esterification between adipic acid and diethylene glycol, so 30B and MP were evenly dispersed in the PAU composites for long period. At temperatures lower than $250^{\circ}C$, the PAU composites were degraded faster than pristine PAU, mainly due to the decomposition of 30B and MP. At higher temperatures, the 30B and MP enhanced the thermal stability of the PAU composites. Compared with the pristine PAU, the thermal decomposition rates of the PAU composites decreased by 13~17%. In air, the residual weights of PAU/30B, PAU/MP, and PAU/30B/MP were 2.4, 2.3, and 7.3 wt% at $700^{\circ}C$, respectively.

Decomposition of Wave Components in Sea Level Data using Discrete Wavelet Transform (이산형 웨이블릿 변환을 통한 조위 자료 내 파고 성분 분리)

  • Yoo, Younghoon;Lee, Myungjin;Lee, Taewoo;Kim, Soojun;Kim, Hung Soo
    • Journal of Wetlands Research
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    • v.21 no.4
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    • pp.365-373
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    • 2019
  • In this study, we investigated the effect of wave height in coastal areas using discrete wavelet transform in Taehwa river basin in Ulsan. Through the decomposition result of tide data using daubechies level 7 wavelet and Curve Fitting Function, we confirmed that detail components of d3 and d4 were semidiurnal and diurnal components and approximation component(a6) was the long period of lunar fortnight constituent. The decomposed tide data in six level was divided into tide component with periodicity and wave component with non-periodicity using autocorrelation function and fourier transform. Finally, we confirmed that the tide component is consisted 66% and wave component is consisted 34%. So, we quantitatively assessed the effect of wave on coastal areas. The result could be used for coastal flood risk management considering the effect of wave.

Synthesis of Zn-intermediate from alkali agents and its transformation to ZnO crystallinity (알칼리 침전제에 의해 제조된 아연 중간생성물 및 산화아연 결정화)

  • Jang, Dae-Hwan;Kim, Bo-Ram;Kim, Dae-Weon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.31 no.6
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    • pp.270-275
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    • 2021
  • ZnO was synthesized according to the transformation behavior and crystallization conditions of Zn-intermediate obtained by zinc sulfate as a precursor and NaOH, Na2CO3 as a alkali agents. For ZnO crystallization, Zn4(OH)6SO4·H2O and Zn5(OH)6(CO3)2·H2O as a Zn-intermediate were calcined at 400℃ and 800℃ for 1 h, respectively, based on decomposition temperature from TGA. Zn4(OH)6SO4·H2O was confirmed to have mixed Zn4(OH)6SO4·H2O and ZnO at 400℃, and was completely thermally decomposed at 800℃ to form ZnO phase. The prepared Zn5(OH)6(CO3)2·H2O as a Zn-intermediate by the reaction with Na2CO3 was transformed to a complete ZnO crystallization over 400℃. Nano-sized ZnO can be synthesized at a relatively lower calcination temperature through the reaction with Na2CO3.

Composting Characteristics of a Continuous Aerated Pilot-scale Reactor Vessel for Commercial Composting (상업용 퇴비화를 위한 연속 통기식 파이로트 규모 반응조의 퇴비화 특성)

  • 홍지형;최병민
    • Journal of Animal Environmental Science
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    • v.4 no.2
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    • pp.149-160
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    • 1998
  • Hog manure slurry amended with sawdust was composted in pilot-scale reactor vessels using continuous aeration nuder different C/N ratios and pH conditions during composting high rate (decomposition) process. For each material two replicated piles were built and monitored over a period of three weeks. The compost piles had an initial volume of 0.18 ㎥. In this study we evaluated the temperature in compost O2 and CO2 evolution, aeration rate, NH3 concentration etc. and investigated the stability of compost during composting high rate process. According to measured results, while the maximum NH3 concentration during composting high rate process. According to measured results, while the maximum NH3 concentration during composting high rate was in the range of 213 to 412 ppm on 5th day which was near the optimum C/N(22∼24) and pH(7.5∼7.9). And then, the NH3 concentration reduced to between 22∼26 ppm by 13th day. The maximum NH3 concentration for the lower C/N(18∼19) and pH value of 6 reached 574∼1,063 ppm by the 16th through 11th days and the NH3 concentration during continuous aerated composting high rate process, it was more important to manage NH3 gas so that compost odor is reduced.

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Calcium Phosphate Bone Cement Based on Wet Prepared Dicalcium Phosphate

  • Chang, Myung Chul
    • Journal of the Korean Ceramic Society
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    • v.55 no.5
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    • pp.480-491
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    • 2018
  • Calcium phosphates (CaP) were prepared by a wet chemical method. Micro-crystalline dicalcium phosphate (DCPD) was precipitated at $37^{\circ}C$ and pH 5.0 using $Ca(OH)_2$ and $H_3PO_4$. The precipitated DCPD solution was kept at $37^{\circ}C$ for 96 h. Artificial bone cement was composed of DCPD, $Ca(H_2PO_4)_2{\cdot}H_2O$ (MCPM), and $CaSO_4{\cdot}1/2H_2O$, $H_2O$ and aqueous poly-phosphoric acid solution. The wet prepared CaP powder was used as a matrix for the bone cement recipe. With the addition of aqueous poly-phosphoric acid, the cement hardening reaction was started and the CaP bone cement blocks were fabricated for the mechanical strength measurement. For the tested blocks, the mechanical strength was measured using a universal testing machine, and the microstructure phase analysis was done by field emission scanning electron microscopy and X-ray diffraction. The cement hardening reaction occurred through the decomposition and recrystallization of MCPM and $CaSO_4{\cdot}1/2H_2O$ added on the surface of the wet prepared CaP, and this resulted in grain growth in the bone cement block.

PHOTOMETRIC PROPERTIES OF THE BRIGHT LENTICULAR GALAXY NGC 5102

  • Sohn, Young-Jong;Chun, Mun-Suk;Byun, Yong-Ik
    • Journal of The Korean Astronomical Society
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    • v.24 no.2
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    • pp.151-159
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    • 1991
  • Using the photographic imagery of the SO galaxy NGC 5102, the equivalent luminosity profile and the fractional integrated luminosity curve have been derived. Several photometric parameters of the galaxy, such as a total magnitude ($B_T$), equivalent radius ($r^*_e$), effective surface brightness (${\mu}^*_e$), and concentration indices ($C_{21}$, $C_{32}$) were derived from the luminosity profiles. According to the decomposition method from the nonlinear least squares fitting, photometric parameters of the bulge (${\mu}_e$, $r_e$) and the exponential disk (${\mu}(0)$, ${\alpha}^{-1}$), and the bulge to total luminosity ratio (B/T) were obtained. The derived central disk surface brightness (${\mu} (0)\;=\;22.06\;{\pm}\;0.18\;mag/\Box"$) and the evaluated B/T ratio (= 0.52) of the NGC 5102 are close to the mean values (${\mu} (0)\;=\;21.65\;{\pm}\;0.3\;mag/\Box"$, B/T=0.63) of the SO galaxies. Analysis showed that a lens-like hump is embedded in the equivalent luminosity profile of the NGC 5102.

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Preparation of the Cobalt Oxide Powder by Hot Petroleum Drying Method (석유증발법에 의한 Cobalt Oxide의 분말제조)

  • 윤상옥;정형진
    • Journal of the Korean Ceramic Society
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    • v.24 no.3
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    • pp.257-262
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    • 1987
  • The characteristics of cobalt oxide powders prepared by hot petroleum drying method from the cobalt acetate were evaluated by DTA/TGA, XRD, BET, SEM and density measurement. The cobalt oxide powder could be prepared by hot petroleum drying of the emulsion of cobalt acetate salt solution and the subsequent thermal decomposition of the acetate at 300$^{\circ}C$. As the concentration of the salt solution and the calcination temperature of the dried powder increased, the surface area of the synthesized powder decreased due to the particle growth, so that after sintering the density and grain size decreased. For the same concentration of the salt solution, the surface area and sinterability of the powder by hot petroleum drying increased in comparision with those by conventional drying.

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A study of Polymerization and Thermal Characteristics of Core-Shell Emulsion particles

  • Kim, Nam-Seok
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.1
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    • pp.10-14
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    • 2011
  • Emulsion polymerization was carried out using RMA like MMA, EMA, BMA and Styrene(St.) as monomer for core-shell latex preparation. It was synthesized at $80^{\circ}C$ in the presence of anionic surfactant SLS. FT-IR, TGA and DSC analysis are used to confirm synthesized core-shell emulsion latexes and to investigate the thermal characteristics of them. From analysis of TGA and DSC, the differences of the decomposition rate and the activation energy are not so large. It considers that the pendent group is not affect of the thermal characteristics and stability on core-shell latexes, which is synthesized with RMA and Styrene.

Development of a Package for the Multi-Location Problem by Genetic Algorithm (유전 알고리즘을 이용한 복수 물류센터 입지분석용 패키지의 개발)

  • Yang, Byung-Hak
    • IE interfaces
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    • v.13 no.3
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    • pp.479-485
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    • 2000
  • We consider a Location-Allocation Problem with the Cost of Land(LAPCL). LAPCL has extremely huge size of problem and complex characteristic of location and allocation problem. Heuristics and decomposition approaches on simple Location-Allocation Problem were well developed in last three decades. Recently, genetic algorithm(GA) is used widely at combinatorics and NLP fields. A lot of research shows that GA has efficiency for finding good solution. Our main motive of this research is developing of a package for LAPCL. We found that LAPCL could be reduced to trivial problem, if locations were given. In this case, we can calculate fitness function by simple technique. We built a database constructed by zipcode, latitude, longitude, administrative address and posted land price. This database enables any real field problem to be coded into a mathematical location problem. We developed a package for a class of multi-location problem at PC. The package allows for an interactive interface between user and computer so that user can generate various solutions easily.

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High-Precision Surface Servo Methodology (고정밀 서피스 서보 방법론)

  • Jung, Kwangsuk;Park, Junkyu;Shim, Kibon
    • Journal of Institute of Convergence Technology
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    • v.3 no.1
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    • pp.1-8
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    • 2013
  • High-precision surface actuator, in which in-plane motion is realized by not two-dimensional actuator superposing linear actuators but integrated planar actuator, has been developed to cope with the severe target performance like precise motion with large envelope. It is very difficult to accomplish the performance with the traditional actuating principle. So, various methods have been tried to break through the problem. This paper discusses some meaningful trials performed in the Nano Measurement and Precision Motion Control Lab. of Korea National University of Transportation.

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