• 공업화학
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• 제3권3호
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• pp.440-450
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• 1992

함희토류광물로부터 3가지 희토류성분의 추출공정이 국산 monazite에 대한 적절한 추출공정을 찾기위해 조사되었다. 본 연구에서 조사된 3가지 공정은 황산법, 알칼리법및 황산암모늄 분해법이었다. 실험결과로부터 황산법 및 알칼리법이 국산 monazite에 더욱 효과적인 추출공정이었음이 조사되었다. 국산 monazite에 대한 황산법의 적절한 반응조건은 반응온도 $210^{\circ}C$, 반응시간 40분, monazite에 대한 $H_2SO_4$의 고액비 1.5, 황산의 농도 95%였으며, 이 조건하에서 98%의 희토류성분이 추출되었다. 또한 알칼리법에 대한 적절한 반응조건은 반응온도 $140^{\circ}C$, monazite에 대한 NaOH의 무게비 3.0, NaOH의 농도 50%, 침출시간 3시간이었으며, 이 초건하에서 97%의 희토류성분이 추출되었다.

• 한국재료학회지
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• 제22권11호
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• pp.620-625
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• 2012

A general synthetic method to make $Fe_3O_{4-{\delta}}$ (activated magnetite) is the reduction of $Fe_3O_4$ by $H_2$ atmosphere. However, this process has an explosion risk. Therefore, we studied the process of synthesis of $Fe_3O_{4-{\delta}}$ depending on heat-treatment conditions using $FeC_2O_4{\cdot}2H_2O$ in Ar atmosphere. The thermal decomposition characteristics of $FeC_2O_4{\cdot}2H_2O$ and the ${\delta}$-value of $Fe_3O_{4-{\delta}}$ were analyzed with TG/DTA in Ar atmosphere. ${\beta}-FeC_2O_4{\cdot}2H_2O$ was synthesized by precipitation method using $FeSO_4{\cdot}7H_2O$ and $(NH_4)_2C_2O_4{\cdot}H_2O$. The concentration of the solution was 0.1 M and the equivalent ratio was 1.0. ${\beta}-FeC_2O_4{\cdot}2H_2O$ was decomposed to $H_2O$ and $FeC_2O$4 from $150^{\circ}C$ to $200^{\circ}C$. $FeC_2O4$ was decomposed to CO, $CO_2$, and $Fe_3O_4$ from $200^{\circ}C$ to $250^{\circ}C$. Single phase $Fe_3O_4$ was formed by the decomposition of ${\beta}-FeC_2O_4{\cdot}2H_2O$ in Ar atmosphere. However, $Fe_3C$, Fe and $Fe_4N$ were formed as minor phases when ${\beta}-FeC_2O_4{\cdot}2H_2O$ was decomposed in $N_2$ atmosphere. Then, $Fe_3O_4$ was reduced to $Fe_3O_{4-{\delta}}$ by decomposion of CO. The reduction of $Fe_3O_4$ to $Fe_3O_{4-{\delta}}$ progressed from $320^{\circ}C$ to $400^{\circ}C$; the reaction was exothermic. The degree of exothermal reaction was varied with heat treatment temperature, heating rate, Ar flow rate, and holding time. The ${\delta}$-value of $Fe_3O_{4-{\delta}}$ was greatly influenced by the heat treatment temperature and the heating rate. However, Ar flow rate and holding time had a minor effect on ${\delta}$-value.

• 대한화학회지
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• 제48권4호
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• pp.358-366
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• 2004

두개의 sulphato로 다리걸친 착물 $[Cr_2(NH_2)_2(H_2O)_2(SO_4)_2]{\cdot}2H_2O$, 말단 3개의 isocyanato $[Cr(NCO)_3(H_2O)]{\cdot}3H_2O$ 화합물과 갈철광 $[FeO(OH)]{\cdot}0.2H_2O$ 화합물들은 각각의 $Cr_2(SO_4)_3{\cdot}xH_2O, Cr(CH_3COO)_3, Fe_2(SO_4)_3$과 $80^{\circ}C$, 수용액에서 요소와 반응으로 합성되었다. 생성물들의 IR 스펙트럼에서 요소(urea)의 띠가 나타나지 않지만, 결합된 아마이드(amide), 물, 연결된 sulphato와 isocyanato 그룹에 대해서 특징적인 띠를 보인다. 착물들에 대한 열무게분석(TG)과 시차열분석법(DTA) 측정을 기록하였다. 얻어진 데이터들은 예상했던 구조화 잘 일치한다. 형성에 대한 설명과 화합물의 열역학적 분해에 대한 일반적인 메커니즘을 제시하였다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
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• pp.1151-1154
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• 2003

Ultraviolet rays, OH H O radical and $O_3$ produced by the streamer discharge in water are widely used to deactivate microorganisms and remove organic contaminants in water and the dominant factor of these decomposition is the oxidized reaction of hydrogen peroxide and dissolved $O_3$ in water. In this paper, the barrier discharge was used to create plasma in a gas, liquid and solid medium and the electrode with the reactor combined barrier with packed type(BPR) was made as noncontact way against water so that the effect of water characteristic change by the erosion of electrodes exposing in water should be minimized. The active radical and $O_3$ gas generated in plasma region were reacted into the water as electrode so that at the same time a dissolved $O_3$ and hydrogen peroxide were formed in water and The change of pH and conductivity were measured.

• Journal of Electrochemical Science and Technology
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• 제10권1호
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• pp.55-60
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• 2019

Herein, the effect of counter anions on the formation of a solid electrolyte interphase (SEI) in a propylene carbonate (PC)-based electrolyte solution was investigated. Although the reversible capacities were different, reversible intercalation and de-intercalation of lithium ions occurred in the graphite negative electrode in the PC-based electrolyte solutions containing 1 M $LiClO_4$, $LiPF_6$, $LiBF_4$, and $LiCF_3SO_3$ at low temperature ($-15^{\circ}C$). This indicated that the surface films acted as an effective SEI to suppress further co-intercalation and decomposition reactions at low temperature. However, the SEIs formed at the low temperature were unstable in 1 M $LiPF_6$ and $LiBF_4/PC$ at room temperature ($25^{\circ}C$). On the other hand, increasing reversible capacity was confirmed in the case of $LiCF_3SO_3/PC$ at room temperature, because the SEI formed at the low temperature was still maintained. These results suggest that counter anions are an important factor to consider for the formation of effective SEIs in PC-based electrolyte solutions.

• 한국정보과학회논문지:소프트웨어및응용
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• 제36권2호
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• pp.169-177
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• 2009

본 논문에서는 뉴스 기사 분할 관점에서, 뉴스 비디오 샷 경계 탐지 알고리즘의 특성을 고려한 다음과 같은 설계 기준을 제시하고, 이를 모두 만족하는 새로운 샷 경계 탐지 알고리즘을 제안하고자 한다. 1) 뉴스 비디오 샷 경계 탐지의 재현율을 높임으로써, 앵커 샷 탐지 단계에서 입력으로 사용될 데이타의 오류를 최소화한다; 2) 급격한 장면 변환과 점증적 장면 변환을 하나의 알고리즘으로 탐지함으로써 한번의 데이타 탐색으로 샷 분할을 수행한다; 3) 분할된 샷들을 정적 샷과 동적 샷으로 분류함으로써 앵커샷 탐지 단계의 탐색 공간을 축소한다. 제안된 뉴스 비디오 샷 경계 탐지 알고리즘은 특이간 분해를 기반으로 점증적 클러스터링 알고리즘과 머서 커널을 결합한 구조로서, 위에서 제시한 기준을 모두 만족하도록 설계되었다. 제안된 방법론은 특이간 분해를 통해 특징 벡터의 차원축소 뿐만 아니라, 뉴스 비디오를 구성하는 연속적인 프레임에서의 잡음과 아주 작은 변화를 제거함으로써 분류 성능을 높일 수 있다. 또한 머서 커널의 도입은 쉽게 분류되지 않는 데이타를 고차원 공간으로 매핑함으로써 구분하기 어려운 샷 경계의 탐지 가능성을 높여준다. 실험을 통하여 제안된 방법론이 매우 높은 재현율을 보이며, 앵커 샷 탐지를 위한 탐색 공간 축소를 효과적으로 수행함을 보인다.

• Earthquakes and Structures
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• 제16권3호
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• pp.321-327
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• 2019

This study investigated the possibility of using the recorded micro tremor data on ground level as ambient vibration input excitation data for investigation and application Operational Modal Analysis (OMA) on the bench-scale earthquake simulator (The Quanser Shake Table) for model chimney. As known OMA methods (such as EFDD, SSI and so on) are supposed to deal with the ambient responses. For this purpose, analytical and experimental modal analysis of a model chimney for dynamic characteristics was performed. 3D Finite element model of the chimney was evaluated based on the design drawing. Ambient excitation was provided by shake table from the recorded micro tremor ambient vibration data on ground level. Enhanced Frequency Domain Decomposition is used for the output only modal identification. From this study, best correlation is found between mode shapes. Natural frequencies and analytical frequencies in average (only) 1.996% are different.

• 한국응용과학기술학회지
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• 제36권1호
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• pp.165-173
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• 2019

국문 우주항공 분야에서 널리 쓰이고 있는 하이드라진[hydrazine, $N_2H_4$]은 로켓연료로 사용되는 대표적인 추진제이지만 환경에 유해하고 독성이 강하다는 단점이 존재한다. 따라서 친환경적이고 독성이 적은 추진제가 다양하게 개발되고 있다. 본 연구에서는 수산화아민[hydroxylamine, $NH_2OH$]을 출발물질로 하여, 질산[nitric acid, $HNO_3$]과 산-염기 반응을 통해 얻어지는 친환경 추진제 HAN[hydroxylammonium nitrate, $NH_3OHNO_3$]의 물리 화학적 특성에 대하여 적외선분광법을 이용하여 합성물의 조성, 화학구조 및 작용기를 관찰하였고, 열중량분석을 통해 HAN의 분해온도를 확인하였다. 이온 크로마토그래피를 통해 합성한 HAN에 함유되어 있는 질산이온의 함량을 측정하였다. 즉, N-H와 N-O의 IR peak가 $3161cm^{-1}$와 $1324cm^{-1}$에서 각각 나타나는 것을 통해 생성한 화합물이 HAN임을 확인하였고, pH 5-7 근처에서 합성한 HAN은 분해온도가 $120-140^{\circ}C$인 반면, pH 8 정도인 HAN은 분해온도가 $140^{\circ}C$ 이상임을 알 수 있었다. 한편, pH 6-7 사이에서 HAN을 합성하였을 때, 가장 높은 질산이온의 농도는 70%인 것으로 나타났다.

• 한국멀티미디어학회논문지
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• 제9권12호
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• pp.1607-1616
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• 2006

The growing market of multimedia and digital signal processing requires significant data-path portions of SoCs. However, the common models for verification are not suitable for SoCs. A novel model--WGL (Weighted Generalized List) is proposed, which is based on the general-list decomposition of polynomials, with three different weights and manipulation rules introduced to effect node sharing and the canonicity. Timing parameters and operations on them are also considered. Examples show the word-level WGL is the only model to linearly represent the common word-level functions and the bit-level WGL is especially suitable for arithmetic intensive circuits. The model is proved to be a uniform and efficient model for both bit-level and word-level functions. Then Based on the WGL model, a backward-construction logic-verification approach is presented, which reduces time and space complexity for multipliers to polynomial complexity(time complexity is less than $O(n^{3.6})$ and space complexity is less than $O(n^{1.5})$) without hierarchical partitioning. Finally, a construction methodology of word-level polynomials is also presented in order to implement complex high-level verification, which combines order computation and coefficient solving, and adopts an efficient backward approach. The construction complexity is much less than the existing ones, e.g. the construction time for multipliers grows at the power of less than 1.6 in the size of the input word without increasing the maximal space required. The WGL model and the verification methods based on WGL show their theoretical and applicable significance in SoC design.

• 한국세라믹학회지
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• 제46권3호
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• pp.271-274
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• 2009

Redox investigation of Sn and S ion was attempted in alkaline earth borosilicate glass melts with only 1 mol% $Na_2O$ by means of Square Wave Voltammetry (SWV). According to voltammograms, there was only one peak due to $Sn^{4+}/Sn^{2+}$ in melt doped with $SnO_2$. The calculated standard enthalpy and entropy of the reduction of $Sn^{4+}$ to $Sn^{2+}$ were 116kJ/mole and 62 J/mol K, respectively. The determined redox ratio, [$Sn^{2+}$] / [$Sn^{4+}$] in the temperature range of $1300{\sim}1600^{\circ}C$ was in $0.4{\sim}2.1$. On the contrary, in the voltammogram of melt doped with $BaSO_4$ there was no peak due to $S^{4+}/S^o$ but shoulder that might be attributed to the adsorption of sulfur at the electrode. The absence of the peak related with $S^{4+}/S^o$ was discussed from the view-point of the thermal decomposition behavior of $BaSO_4$ in the glass batch.