• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.07b
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• pp.917-921
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• 2002

In this paper, we made different types of non-thermal plasma reactors such as Metal-particle reactor with $Al_2O_3$ to measure NOx removal characteristic and the dielectric effect for NOx removal. NOx removal rate is not so good when we use just dielectric of $Al_2O_3$ at the Metal-particle reactor, also we just put sludge pellets(100%) without Metal-particle reactor with $Al_2O_3$ and dielectric such as $TiO_2$, $BaTiO_3$ to measure the effect of sludge for NOx removal so that NOx removal rate is almost the same. However NOx removal rate is more than 90% in case of the reactor of composition shape used both dielectric of $Al_2O_3$ and sludge pellets at the same time. In case of the shape of plasma reactor with dielectric, the Metal-particle reactor with $Al_2O_3$, and the metal-particle reactor with both $Al_2O_3$ and dielectric such as $TiO_2$, $BaTiO_3$ at the same time, they are almost the same effect for NOx removal, so we made MNPR(Metal-particle Non-thermal Plasma Reactor with $Al_2O_3$) to reduce these kinds of demerits. Finally, we think MNPR should be much better than other reactors for NOx removal.

• Journal of Korean Society for Atmospheric Environment
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• v.12 no.4
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• pp.449-457
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• 1996

The main purpose of this study was to investigate sulfur dioxide removal performance of flue gas desulfurization system utilizing a Spray Absorption/Drying Reactor. In this system, the size of droplets was considered the most significant factor and tested using a PDA system. Lime slurry flow rate, operating temperature, calcium/sulfur (Ca/S) ratio and applied air pressure were selected as major operation variables and tested/analyzed in terms of system performance. The results are as follows. 1. The $SO_2$ removal efficiencies were 49%, 74%, 85% for Ca$(OH)_2$ slurry flow rate of 10, 20, 30 ml/min, which implies that the increase of slurry flow rate improves removal efficiency. The optimum slurry flow rate in this study was, however, considered 20 ml/min because of constraints of system troubles and absorbent utilization. 2. As Ca/S ratio increased, $SO_2$ removal efficiency was observed to increase. 3. As air pressure, at the atomizing nozzole, increased from 3 to 5 $kg/cm^2, SO_2$ removal efficiency increased from 74% to 80%, because of droplet size reduction due to pressure increase during atomizing process and the increase of surface area, helping mass transfer between gas and liquid phase.

• Journal of the Korean Institute of Gas
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• v.10 no.2 s.31
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• pp.14-21
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• 2006

An experimental apparatus for the removal of $SO_2$ gas using microporous hollow-fiber membrane G-L contactors was setup. Various performance experiments were carried out with commercial membrane modules and the membrane modules made by KIER. The $SO_2$ removal efficiency was outstanding. When the hollow-fiber membrane was used for the removal of $SO_2$, the selection of absorbers and additives, membrane material, operating conditions of membrane manufacture were significant variables to develop optimal G-L contactors. More experiment works will be done for the development of compact, cost-effective and better G-L contactors.

• Journal of the Korean Society of Safety
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• v.6 no.4
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• pp.26-33
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• 1991

To remove SO$_2$ from flus gas, cupric oxide, manganese oxide and iron oxide were studied with varying loading value. The experiment was carried out in a flow reactor and the reactants were prepared by impregnation method using alumina. The reaction temperature was varied from 30$0^{\circ}C$ to 45$0^{\circ}C$. Experimental results showed that all of these metal oxides were effective on SO$_2$ removal reaction and cupric oxide was the best reactant. The sample with 10wt％ loading value was better reactant than with 20wt％ because in case of 20wt％ loading, metal dispersion on the alumina surface was not uniform. And the SO$_2$ removal efficiency was increased with the reaction temperature.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.48 no.3
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• pp.215-220
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• 1999

$SO_2$and CO gas removal characteristics of a wire-to-cylinder type nonthermal discharge plasma reactor in various applied voltage (-dc, ac, fast rising pulse and high frequency pulse) and a crossed dc magnetic field have been investigated. The experiment has been emphasized on the oxidizing characteristics of $SO_2$ and CO gas by $O_3$ and the applying of a crossed magnetic field, which would induce the cyclotronic and drift motions of electrons making the residual time longer in the removal airgap space. And it also would enhance the energy of electrons and the electrophysicochemical actions to remove the pollutant gases effectively. It is found thatthe corona onset voltage and the breakdown voltage were decreased with increasing the crossed magnetic field and decrease initial fed $SO_2$and CO concentration. As a result, a higher ozone generation and $SO_2$ and CO gas removal rate of 20[%] can be obtained with -dc, ac and fast rising pulse corona discharges in the crossed dc current-induced magnetic field. But high frequency pulse didn't show effect in applying of a crossed magnetic field.

• Clean Technology
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• v.3 no.1
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• pp.96-105
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• 1997

The objectives of this study were to investigate $SO_2$ removal efficiency of anthracite - bituminous coal blend combustion in a fludized bed coal combustor with Ca/S, anthracite ratio, bed temperature, and waste paper sludge particle size. The experimental results were presented as follow ; the effect of the desulfurization by the particle size of waste paper sludge was a great and $SO_2$ removal efficiency was heigest in paper sludge dia $1016{\mu}m$. And the difference of $SO_2$ removal efficiency according to air velocity was not too large. As Ca/S mole ratio incresed, $SO_2$ removal efficiency incresed rapidly up to Ca/S mole ratio 3 while the desulfurization rates did not increse too largely in the range of more than the level. The bed temperature had a great deal of effect on the desulfurization rate. So the $SO_2$ removal efficiency was a graet using waste paper sludge that the properbility of paper sludge as sorbent was conformed.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2006.11a
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• pp.91-94
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• 2006

The way to shorten a construction period is considered to an very important technology development element as reducing the formwork removal periods with promoting strength revelation own concrete. This study executed experiment to review usability of early strength revelation chemical admixture which is judged in ways effective with premature removal of form about concrete. Use of early strength revelation AE water reducin admixture is apperaing so that strength revelation by early hydration promotions is excellent. The results of being applied proposed work process are that compressive strength are appeared more than 5MPa within 16 hours so that removal of vertical form was possible. the concrete compressive strength satisfied with a more than 2/3 of specified concrete strength for removal of horizontal form are appeared in 42 hours of 27 MPa proportioning strength, in 36 hours of 30, 35 MPa proportioning strength so that the 6 days cycle time of concrete structural frame work is cut by 2 days as shortening delayed period in works of removing slab forms. So construction cost reductions and a construction period shortening are judged so that it is possible.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.16 no.3
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• pp.247-252
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• 2003

In this paper, we made four types of metal particle $Al_2$O$_3$ barrier reactors with and without dielectric of BaTiO$_3$ between metal particle and $Al_2$O$_3$ barrier to investigate NOx removal characteristic and the effect of dielectric on Nox removal. And Nox removal rate is measured when sludge pellets are put at down stream of plasma reactor. Nox removal rate in the reactor with $Al_2$O$_3$ barrier is much better than that in the reactor without $Al_2$O$_3$ barrier, Nox removal rate is not so good in metal particle-Al$_2$O$_3$ barrier reactor with BaTiO$_3$ between metal particle and $Al_2$O$_3$ barrier, however, Nox removal rate is about 40% in metal particle-Al$_2$O$_3$ barrier reactor with TiO$_2$. The most of NO is conversed to NO$_2$ in these kind of reactor. When sludge pellets are put at down stream of plasma reactor, Nox removal rate is greatly improved up to 90%. It indicates that sludge pellets have great effect on the NO$_2$ removal and the improvement of Nox removal rate, however, dielectric materials between metal particle and $Al_2$O$_3$ barrier have not effect. Organic materials included in sludge may react with NO$_2$ and ozone so that Nox removal rate is greatly improved.

• Korean Chemical Engineering Research
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• v.47 no.4
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• pp.512-517
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• 2009

$SO_2$ concentrations in oxy-fuel combustion flue gases increases about three times as high as that of conventional air combustion system owing to the flue gas recirculation for the control of combustion temperature. So the desulfurization reaction is different from that of the conventional air combustion system due to exceptionally high $CO_2$ and $SO_2$ concentration. In this study, drop tube furnace(DTF) system was used to investigate the desulfurization characteristics of limestone in oxy-fuel combustion furnace. The experiments were performed under $O_2/CO_2$ atmosphere to examine the effect of operating variables such as reaction temperatures, Ca/S ratios and inlet $SO_2$ concentrations on the $SO_2$ removal efficiencies. $SO_2$ removal efficiency increased with reaction temperature, Ca/S ratio and inlet $SO_2$ concentration. And the addition of water vapor resulted in about 4~6% of increase in $SO_2$ removal efficiency.

• Journal of Korean Society on Water Environment
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• v.31 no.6
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• pp.619-624
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• 2015

This study experimentally determined the effect of titanium tetrachloride (TiCl₄) concentration ([TiCl₄]) (0.25-0.55 mM) and initial pH (3-11) on phosphorus (P) removal in synthetic wastewater (2 mg P/L). The P removal efficiency increased when [TiCl₄] increased. The P removal efficiency showed a parabolic trend with an inflection point at pH 7. At the molar ratio of TiCl₄ and P>6.2, the P removal efficiency was over 90% and the residual P concentration was less than 0.2 mg/L. Within the design boundaries, the complete P removal could be achieved at 7.0≤initial pH≤8.5 and 0.43≤[TiCl₄]≤0.55 mM. The final pH was over 5.8 at initial pH≥7.7 and [TiCl₄]≥0.35 mM. The results showed that TiCl4 was effective in P removal in water so that it could be an alternative chemical for P removal.