• Title/Summary/Keyword: $SM_{10}(f)$

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A cytotaxonomic study of Atractylodes japonica Koidz. ex Kitam. and A. macrocephala Koidz.

  • Chung, Gyu-Young;Kim, Mi-Suk
    • Plant Resources
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    • v.3 no.3
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    • pp.179-183
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    • 2000
  • The present study was carried out to clarify the chromosome numbers and karyotype of Atractylodes japonica Koidz. ex Kitam. and A. macrocephala Koidz.. The somatic chromosome numbers of two species were same; basic chromosome number x=12, and somatic chromosome numbers 2n=24. The present result of A. japonica Koidz. ex Kitam. was same to previously reports and that of A. macrocephala Koidz. was reported first in this study. Size and shape of chromosome were some different from A. japonica Koidz. ex Kitam. and A. macrocephala Koidz.. The karyotype of A. japonica Koidz. ex Kitam. was described as follows; 2n : 24 : 8L + 14M +2S : 2 $A^{sm}$ +2 $B^{m}$ +2 $C^{m}$ +2 $D^{st}$ + 2 $E^{m}$ +2 $F^{m}$ +2 $G^{m}$ +2 $H^{sm}$ + 2 $I^{m}$ + 2 $J^{m}$ + 2 $K^{m}$ + 2 $L^{m}$ . And the karyotype of A. macrocephata Koidz. was described as follows; 2n : 24 : 10L +12M +25 : 2 $A^{m}$ +2 $B^{sm}$ +2 $C^{sm}$ +2 $D^{sm}$ +2 $E^{sm}$ +2 $E^{sm}$ +2 $G^{sm}$ +2 $H^{m}$ +2 $I^{m}$ 2 $J^{m}$ +2 $K^{m}$ +2 $L^{m}$ . .

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Structural and Luminescent Properties of Gd2WO6:RE3+ (RE = Dy, Sm, Dy/Sm) Phosphors for White Light Emitting Devices (백색광 소자 응용을 위한 Gd2WO6:RE3+ (RE = Dy, Sm, Dy/Sm) 형광체의 구조 및 발광 특성)

  • Park, Giwon;Jung, Jaeyong;Cho, Shinho
    • Journal of the Korean institute of surface engineering
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    • v.53 no.4
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    • pp.131-137
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    • 2020
  • A series of Dy3+, Sm3+, and Dy3+/Sm3+ doped Gd2WO6 phosphors were synthesized by the conventional solid-state reaction. The X-ray diffraction patterns revealed that all of the diffraction peaks could be attributed to the monoclinic Gd2WO6 crystal structure, irrespective of the type and the concentration of activator ions. The photoluminescence (PL) excitation spectra of Dy3+-doped Gd2WO6 phosphors contained an intense charge transfer band centered at 302 nm in the range of 240-340 nm and two weak peaks at 351 and 386 nm. Under an excitation wavelength of 302 nm, the PL emission spectra consisted of two strong blue and yellow bands centered at 482 nm and 577 nm. The PL emission spectra of the Sm3+-doped Gd2WO6 phosphors had a series of three peaks centered at 568 nm, 613 nm, and 649 nm, corresponding to the 6G5/26H5/2, 6G5/26H9/2, and 6G5/26H11/2 transitions of Sm3+, respectively. The PL emission spectra of the Dy3+- and Sm3+-codoped Gd2WO6 phosphors showed the blue and yellow emission lines originating from the 4F9/26H15/2 and 4F9/24H13/2 transitions of Dy3+ and reddish-orange and red emission bands due to the 4G5/26H7/2 and 4G5/26H9/2 transitions of Sm3+. As the concentration of Sm3+ increased from 1 to 15 mol%, the intensities of two PL spectra emitted by the Dy3+ ions gradually decreased, while those of the three emission bands due to the Sm3+ ions slowly increased, thus producing the color change from white to orange. The CIE color coordinates of Gd2WO6:5 mol% Dy3+, 1 mol% Sm3+ phosphors were (0.406, 0.407), which was located in the warm white light region.

Study of electronic structures of insulating rare-earth compounds by x-ray photoelectron spectroscopy (광전자분광법을 이용한 희토류 부도체 화합물들의 전자구조 연구)

  • 조은진;오세정
    • Journal of the Korean Vacuum Society
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    • v.5 no.4
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    • pp.315-326
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    • 1996
  • The electronic structures of 3d and 4d core-levels of rare-earth atoms in the insulating rare-earth (Sm, Eu, Gd, and Tb) compounds were studied with x-ray photoelectron spectroscopy(XPS). It is shown that the intrinsic satellite structure due to the hybridization disappears for chemically stable-earth trivalent heavy rare-earth insulating compounds as the hybridization between f electrons of rare-earth atoms and p electrons of anion atoms decreases due to the lanthanide contraction. Eu atoms at the surface of the stable insulating trivalent Eu compounds are found to be divalent. The satellite peak of Eu 3d core-level spectra at about 10eV higher binding energy side relative the main peak comes from the multiplet structures of $\underline{3d}4f^6$ configuration. The satellite structure appearing at about 15 eV higher binding energy side relative to the main peak in all insulating rare-earth compounds is due to an energy loss process of creating a plasmon.

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Effect of the Dietary Supplementation of Fermented Spent Mushroom (Pleurotus eryngii) Substrates on the Growth Performance and Carcass Characteristics in Hanwoo Steers (새송이버섯 수확 후 배지 발효산물 첨가급여가 한우 거세우의 성장과 도체등급에 미치는 영향)

  • Gal, Sang-Wan;Moon, Yea-Hwang;Cho, Soo-Jeong
    • Journal of Life Science
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    • v.21 no.12
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    • pp.1705-1709
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    • 2011
  • This study was carried out to investigate the feeding effects of the dietary supplementation of fermented spent mushroom (Pleurotus eryngii) substrates with Bacillus amyloliquefaciens CS47 and Saccharomyces cerevisiae (F-SMS) on growth performance and carcass characteristics of Hanwoo steers. Thirty two Hanwoo steers were allocated into two feeding groups and assigned equally to two dietary treatments; Control (commercial formula feed for Hanwoo steers and rice straw) and TMR including 30% F-SMS. The nutritional values of TMR including 30% F-SMS was higher crude protein (11.67%) and TDN (72.11%) than rice straw, but not significantly different from commercial formula feed (p<0.05). Feed intake was significantly greater in the TMR including 30% F-SMS than the control (p<0.05), but body weight gain and carcass grades were not influenced by the experimental diets. Based on this study, fermented spent mushroom (Pleurotus eryngii) substrate with Bacillus amyloliquefaciens CS47 and Saccharomyces cerevisiae is may be used as an ingredient of feed in TMR for Hanwoo steer.

Luminescent Properties and Anti-Counterfeiting Applications of SrWO4:RE3+ (RE=Dy, Sm, Dy/Sm) Phosphors Doped with Several Activator Ions (다양한 활성제 이온이 도핑된 SrWO4:RE3+ (RE=Dy, Sm, Dy/Sm) 형광체의 특성과 위조 방지 응용)

  • Yoon, Soohwan;Cho, Shinho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.5
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    • pp.393-399
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    • 2020
  • A series of phosphors, SrWO4:5 mol% Dy3+, SrWO4:5 mol% Sm3+, and SrWO4:5 mol% Dy3+:x Sm3+ (x=1~15 mol%), were prepared using a facile co-precipitation. The crystal structure, morphology, photoluminescence properties, and application in anti-counterfeiting fields were investigated. The crystalline structures of the prepared phosphors were found to be tetragonal systems with the dominant peak occurring at the (112) plane. The excitation spectra of the Dy3+ singly-doped SrWO4 phosphors were composed of an intense charge-transfer band centered at 246 nm in the range of 210~270 nm and two weak peaks at 351 nm and 387 nm due to the 6H15/26P7/2 and 6H15/24I13/2 transitions of Dy3+ ions, respectively. The wavelength of 246 nm was optimum for exciting the luminescence of Dy3+ and Sm3+ co-doped SrWO4 phosphors. The emission spectra consisted of two intense blue and yellow emission bands at 480 nm and 573 nm corresponding to the 4F9/26H15/2 and 4F9/26H13/2 transitions of Dy3+, and two strong emission peaks at 599 nm and 643 nm originating from the 4G5/26H7/2 and 4G5/26H9/2 transitions of Sm3+, respectively. As the concentration of Sm3+ ions increased, the emission intensities of Dy3+ rapidly decreased, while the emission intensities of Sm3+ gradually increased. These results suggest that the color of the emission light can be tuned from yellow to white by changing the concentration of Sm3+ ions at a fixed 5 mol% Dy3+. Furthermore, the fluorescent security inks were synthesized for use in anti-counterfeiting applications.

ELD용 형광체의 특성

  • 이상윤
    • 전기의세계
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    • v.38 no.10
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    • pp.13-22
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    • 1989
  • 본 연구에서는 EL에 사용되고 있는 분말형광체에 대한 물리적 제현상을 소개하고 아울러 본 연구실에서 연구해 온 ZnS : Mn, Zns : TbF$_{3}$, Zns : SmF$_{3}$, CaS : EuCl$_{3}$, SrS: CeCl$_{3}$ 형광체 및 박막EL 소자에 관한 실험과 내용을 바탕으로 형광체의 특성을 종합 분석하고 현상을 고찰, 검토하고자 한다.

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Kinetic Study of the Anaerobic Digestion of Swine Manure at Mesophilic Temperature: A Lab Scale Batch Operation

  • Kafle, Gopi Krishna;Kim, Sang-Hun
    • Journal of Biosystems Engineering
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    • v.37 no.4
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    • pp.233-244
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    • 2012
  • Purpose: The kinetic evaluation was performed for swine manure (SM) degradation and biogas generation. Methods: The SM was anaerobically digested using batch digesters at feed to inoculum ratio (F/I) of 1.0 under mesophilic conditions ($36.5^{\circ}C$). The specific gas yield was expressed in terms of gram total chemical oxygen demand (mL/g TCOD added) and gram volatile solids added (mL/g VS added) and their effectiveness was discussed. The biogas and methane production were predicted using first order kinetic model and the modified Gompertz model. The critical hydraulic retention time for biomass washout was determined using Chen and Hashimoto model. Results: The biogas and methane yield from SM was 346 and 274 mL/ TCOD added, respectively after 100 days of digestion. The average methane content in the biogas produced from SM was 79% and $H_2S$ concentration was in the range of 3000-4108 ppm. It took around 32-47 days for 80-90% of biogas recovery and the TCOD removal from SM was calculated to be 85%. When the specific biogas and methane yield from SM (with very high TVFA concentration) was expressed in terms of oven dried volatile solids (VS) basis, the gas yield was found to be over estimated. The difference in the measured and predicted gas yield was in the range of 1.2-1.5% when using first order kinetic model and 0.1% when using modified Gompertz model. The effective time for biogas production ($T_{Ef}$) from SM was calculated to be in the range of 30-45 days and the critical hydraulic retention time ($HRT_{Critical}$) for biomass wash out was found to be 9.5 days. Conclusions: The modified Gompertz model could be better in predicting biogas and methane production from SM. The HRT greater than 10 days is recommended for continuous digesters using SM as feedstock.

A Study on Fatigue Behavior according to Effective Case Depth in Induction Case Hardened SM45C Steel (고주파표면경화한 SM45C 강에서 유교경화층깊이가 피로거동에 미치는 영향)

  • 오세욱;호정원;박원조
    • Journal of Ocean Engineering and Technology
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    • v.5 no.1
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    • pp.71-80
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    • 1991
  • This paper reveals the effect of the effective case depth(ECD) on the fatigue behavior of a high-frequency induction hardened SM45C in rotated bending fatigue test. In addition, the effects of fracture modes(surface origin type, inner origin type) on it are discussed. The fatigue limit of the induction hardened steel is remarkably increased compared with that of base metal. In addition, the fatigue limit is linearly increased as the effective casedepth grows deep in the region of this experiment (ECD/R;0.23-0.49). The S-N curve and fracture mode in the induction case hardened steel are classified into two kinds, as a result : N$_{f}$<10$^{5}$ ;surface origin type fracture(at high stress), N$_{f}$>10$^{5}$ ; in ner origin type fracture(at low stress). In case of inner origin type fracture; as the effective case depth(ECD) gets deep, the fatigue limit is increased by the reason that the fracture origin moves toward center; in reverse, is decreased by reason that the compressive residual stress gets low. As a result, the increasing effect of the former is much bigger than the decreasing effect of the latter, and the fatigue limit is increased as the ECD gets deep.eep.

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Electrochemical Impedance Spectroscopy and Cyclic Voltammetry Methods for Monitoring SmCl3 Concentration in Molten Eutectic LiCl-KCl

  • Shaltry, Michael R.;Allahar, Kerry N.;Butt, Darryl P.;Simpson, Michael F.;Phongikaroon, Supathorn
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.1
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    • pp.1-18
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    • 2020
  • Molten salt solutions consisting of eutectic LiCl-KCl and concentrations of samarium chloride (0.5 to 3.0 wt%) at 500℃ were analyzed using both cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The CV technique gave the average diffusion coefficient for Sm3+ over the concentration range. Equipped with Sm3+ diffusion coefficient, the Randles-Sevcik equation predicted Sm3+ concentration values that agree with the given experimental values. From CV measurements; the anodic, cathodic, and half-peak potentials were identified and subsequently used as a parameter to acquire EIS spectra. A six-element Voigt model was used to model the EIS data in terms of resistance-time constant pairs. The lowest resistances were observed at the half-peak potential with the associated resistance-time constant pairs characterizing the reversible reaction between Sm3+ and Sm2+. By extrapolation, the Voigt model estimated the polarization resistance and established a polarization resistance-concentration relationship.

Luminescence Properties of La2MoO6:RE3+ (RE = Eu, Sm) Phosphors Subjected to the Different Concentrations of Activator Ions (활성제 이온의 농도 변화에 따른 La2MoO6:RE3+ (RE = Eu, Sm) 형광체의 발광 특성)

  • Kim, Gayeon;Shin, Johngeon;Cho, Shinho
    • Journal of the Korean institute of surface engineering
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    • v.50 no.4
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    • pp.282-288
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    • 2017
  • $Eu^{3+}$- or $Sm^{3+}$-doped $La_2MoO_6$ phosphors were synthesized with different concentrations of activator ions via a solid-state reaction. The X-ray diffraction patterns exhibited that crystalline structures of all the phosphors were tetragonal systems with the dominant peak occurring at (103) plane, irrespective of the concentration and the type of activator ions. The crystallites showed the pebble-like crystalline shapes and the average crystallite size increased with a tendency to agglomerate as the concentration of $Eu^{3+}$ ions increased. The excitation spectra of $Eu^{3+}$-doped $La_2MoO_6$ phosphors contained an intense charge transfer band centered at 331 nm in the range of 250-370 nm and three weak peaks at 381, 394, and 415 nm, respectively, due to the $^7F_0{\rightarrow}^5L_7$, $^7F_0{\rightarrow}^5L_6$, and $^7F_0{\rightarrow}^5D_3$ transitions of $Eu^{3+}$ ions. The emission spectra under excitation at 331 nm exhibited a strong red band centered at 620 nm and two weak bands at 593 and 704 nm. As the concentration of $Eu^{3+}$ increased from 1 to 20 mol%, the intensities of all the emission bands gradually increased. For the $Sm^{3+}$-doped $La_2MoO_6$ phosphors, the emission spectra consisted of an intense emission band at 607 nm arising from the $^4G_{5/2}{\rightarrow}^6H_{7/2}$ transition and three relatively small bands at 565, 648, and 707 nm originating from the $^4G_{5/2}{\rightarrow}^6H_{5/2}$, $^4G_{5/2}{\rightarrow}^6H_{9/2}$, and $^4G_{5/2}{\rightarrow}^6H_{11/2}$ transitions of $Sm^{3+}$, respectively. The intensities of all the emission bands approached maxima when concentration of $Sm^{3+}$ ions was 5 mol%. These results indicate that the optimum concentrations for highly-luminescent red and orange emission are 20 mol% of $Eu^{3+}$ and 5 mol% of $Sm^{3+}$ ions, respectively.