• Title/Summary/Keyword: $Ni_2O_3$

Search Result 1,942, Processing Time 0.031 seconds

Seasonal Variation and Statistical Analysis of Particulate Pollutants in Urban Air (도시대기립자상물질중 오염성분의 계절적 변동 및 통계적 해석)

  • 이승일
    • Journal of environmental and Sanitary engineering
    • /
    • v.9 no.2
    • /
    • pp.8-23
    • /
    • 1994
  • During the period from Mar., 1991 to Feb., 1992 66 tSP samples were collected by Hi volume air sampler at 1 sampling site in Seoul and the amount of concentration of 21 components(SO$_{4}$$^{2-}$, NO$_{3}$$^{-}$, NH$_{4}$$^{+}$, Cl$^{-}$, Al, Ba, Ca, Cd, Cr, Cu, Fe, It Mg, Mn, Na, Ni, Pt Si, Ti, Zn, Zr ) were measured. And monthly and seasonal variation were surveyed and the principal component analysis( PCA ) were carried out with respect to these amount of pollutants, minimum of visibility and radiation on a horizontal surface. The total amount of soluble ion in water was high in order o(SO$_{4}$$^{2-}$> NO$_{3}$$^{-}$> N%'>Cl$^{-}$ and metal ion was high in order of Na> Ca>Si> Fe> Al> K> Mg> Zn> Pb> Cu>Ti> Mn > Ba> Cr> Zr> Ni> Cd. There was Seasonal variation in concentration for SO$_{4}$$^{2-}$, NH$_{4}$$^{+}$, Cl$^{-}$, Na, Al, Ca, Bt Mg, Fe and Si. It was assumed that the components of the highest concentration on April were depend on yellow sand and the frequency of wind velocity and direction. As the results of PCA, the amount of pollution components was able to characterized with two principal components(Z$_{1}$, Z$_{2}$ ). The first principal components Z$_{1}$ was considered to be a factor indicating the pollutants originated from natural generation and The second principal components Z$_{2}$ was considered to be a factor indicating the pollutants originated from human work. The monthly concentration of pollutants in ISP, minimum of visibility and radiation on a horizontal surface was possible to evaluate by the use of these two principal components Z$_{1}$ and Z$_{2}$ .

  • PDF

Fabrication of coated conductor by continuous PVD methods (연속 공정 PVD 방법에 의한 coated conductor 제조)

  • Ko, Rock-Kil;Chung, Jun-Ki;Kim, Ho-Sup;Ha, Hong-Soo;Shi, Dongqi;Park, Yu-Mi;Choe, Su-Jeong;Song, Kyu-Jeong;Yoo, Sang-Im;Moon, Seung-Hyun;Park, Chan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2004.07a
    • /
    • pp.93-96
    • /
    • 2004
  • 다층의 산화물 박막 구조를 갖는 coated conductor의 장선 제조를 위해서는 연속 증착 공정이 필요하다. 본 연구에서는 RABiTs와 IBAD 공정을 사용한 texture template을 사용하였으며, 금속 테잎을 연속적으로 이동하면서 증착할 수 있는 박막증착 장치(PLD, sputtering, evaporation)를 구축하여 PVD 방법으로 coated conductor를 제조하였다. $CeO_2/YSZ/Y_2O_3$의 완충층을 sputtering 과 evaporation을 이용하여 2축배향성을 가지는 NiW 위에 연속적으로 증착하였다. YBCO 초전도층은 연속 PLD 방법으로 증착하고, Tc, Ic, XRD, SEM을 통해 그 특성을 분석하였다. 그 결과 RABiTS template을 사용하여 Ic가 34A/cm(@77K)인 0.4m 길이의 coated conductor를 제조하였다. IBAD template를 사용하여 Ic가 34A/cm(@77K)인 0.5m길이의 coated conductor를 제조하였고, Jc는 $1.2MA/cm^2$ 이였다.

  • PDF

Nano-Composite Solder Technology for the Improvement of Solder Joint Properties (무연솔더 접합부 특성향상을 위한 나노복합솔더 기술)

  • Ki, Won-Myoung;Lee, Young-Kyu;Lee, Chang-Woo;Yoo, Se-Hoon
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.18 no.3
    • /
    • pp.9-17
    • /
    • 2011
  • Nano-composite solders have been studied to improve the properties of Pb-free solder joints. The nanoparticles in the composite solders were carbon nanotubes(CNTs), metals (Ag, Ni, Cr, etc.), ceramics (SiC, $ZrO_2$, $TiB_2$, etc.). To fabricate the nano-composite solders, mechanical mixing methods and in-situ fabrication method has been used for well-dispersed nano phase. The characteristic properties of the nano-composite solders were high creep resistance, low undercooling, low IMC growth rate and fine microstructures. More researches on the nano-composite solders are required to improve the processibility and the reliability of the nano-composite solder joints.

Enhancement of Mechanical Properties of 2K Polyurethane Adhesives via Forming Ionic Bonds (이온결합 형성에 따른 이액형 폴리우레탄 접착제의 기계적 특성 향상)

  • Kwon, Haeun;Kim, Doo Hun;Kim, Gu Ni
    • Journal of Adhesion and Interface
    • /
    • v.22 no.4
    • /
    • pp.128-135
    • /
    • 2021
  • In this study, the acid polyols containing acid groups were synthesized, the novel polyurethane adhesive was developed by introducing the acid polyol by content. The acid polyols were introduced, the mechanical properties showed the maximum value when the acid content was 0.1 to 0.3 wt%, and it was confirmed that the mechanical properties and adhesive strength decreased at the content higher than 0.5 wt%. As the acid group, carboxylic acid and sulfuric acid were introduced to compare properties, and carboxylic acid showed stronger hydrogen bonding potential than sulfuric acid and improved mechanical properties. In addition, the correlation between particle size and mechanical properties was confirmed by introducing ZnO and CaCO3. When ZnO and CaCO3 were introduced, an ionic bond was formed with an acid group, and it was confirmed that mechanical properties were increased.

The Effects of Al-Alloying Elements on the Melt Oxidation l. Weight Gain by Oxidation (Al합금의 원소가 용융산화에 미치는 영향(l. 산화에 의한 무게증가))

  • Jo, Chang-Hyeon;Jo, Chang-Hyeon;Kim, Il-Su;Kim, Cheol-Su;Kim, Chang-Uk
    • Korean Journal of Materials Research
    • /
    • v.7 no.7
    • /
    • pp.564-570
    • /
    • 1997
  • 용융산화에 의한 AI$_{2}$O$_{3}$복합재료의 형성에 미치는 합금원소의 영향을 연구하였다. AI-Mg-3Si 합금이 가장 우수한 산화거동을 보였다. 우수한 3원계로 선정된 AI-1Mg-3Si합금에 제 4원소 Sn, Cu, Ni, Zn을 양을 달리하여 각각 첨가하여 산화거동을 살펴보았다. 1273K, 1373K, 1473K, 에서 20시간 각각 산화실험을 한 결과, 1473K에서는 모든 합금계가 우수했으나 1373K, 1273K에서는 산화가 거의 일어나지 않았다.

  • PDF

A Geochemical Study on the Behaviors of Major and Trace Elements in the Ulsan Granite and Its Contact Serpentinite (울산화강암 및 인접 사문암 중 주/미량 원소의 거동에 관한 지화학적 연구)

  • Lee, Jae Yeong;Lee, In Ho
    • Economic and Environmental Geology
    • /
    • v.28 no.1
    • /
    • pp.53-67
    • /
    • 1995
  • Geochemical characteristics of iron-related Ulsan granite was studied in comparison with the Cretaceous granitoids from the metallogenic provinces of copper, lead-zinc and lead-zinc/molybdenum in the Gyeongsang Basin, and the variation of cheminal compositions at the Ulsan granite/serpentinite contact was investigated. Ulsan granite is plotted in the regions of granite and granodiorite of Streckeisen's diagram. It shows differentiation trend of calc-alkali magma, and the magmatic evolution from granodiorite to granite is consistant with the general crystallization path of the Cretaceous the granitoids in Gyeongsang Basin. Differentiation index(D.I.) of Ulsan granite is 86~95, which is higher than those of Jindong granites (D.I.=45~70) and Onjongri granites (D.I.=67~84), and there are differences in the content of some major and trace elements between Ulsan granite and other Cretaceous granitoids. At the Ulsan granite/serpentinite contact $SiO_2$, $K_2O$, $Na_2O$, $Al_2O_3$, Rb, Sr, Ba which are abundant in Ulsan granite decrease toward serpentinite, while T.Fe, MgO, Ni, Cr which are abundant in serpentinite decrease toward Ulsan granite. Therefore, the geochemical characteristics of Ulsan granite is applicable to distinguish iron province from different metallogenic provinces where other Cretaceous granitoids occur in the Gyeongsang Basin, and it is possible to find serpentinite which was intruded by granite on the basis of chemical variations.

  • PDF

Analysis of Electrode Polarization in MCFC by a Reference Electrode (기준 전극을 이용한 용융탄산염 연료전지의 분극 특성 해석)

  • Han Jonghee;Lee Kab Soo;Chung Chang-Yeol;Yoon Sung-Pil;Nam Suk-Woo;Lim Tae-Hoon;Hong Seong-Ahn
    • Journal of the Korean Electrochemical Society
    • /
    • v.4 no.3
    • /
    • pp.125-131
    • /
    • 2001
  • A long-term variation of electrode polarization in the MCFC has been analyzed successfully using a single cell with a Au, $CO_2/O_2$ reference electrode Four different cells with different components were operated and their electrode polarizations were analyzed. As published in the literatures, the cathode polarization was larger than that of the anode. The more stable operation of a single cell with the Al-coated cell frame up to 6,000hrs indicates that the corrosion at the cell frame, particularly wet seal area, plays an important role to determine the lifetime of a MCFC. At the initial stage of the cell operation, the voltage of the cell using a cathode stabilized by the $LiCoO_2$ coating was relatively low due to the high cathode polarization. As the cell was operated and the stabilized cathode was lithiated sufficiently, the cathode polarization decreased and the cell voltage was recovered. It was observed that the voltage of the cell using the $Li_2CO_3/Na_2CO_3$ electrolyte fluctuated with operation time and the cathode polarization fluctuated along with the cell voltage quite similarly. Although the mechanisms of the voltage fluctuation were not clear yet, the results imply that the voltage fluctuation was related with a reaction in the cathode side. After testing every single cell, the cathode polarization increased with the steep decrease in the cell voltage. Thus, the cathode should be improved in order to develop more durable MCFC.

A small-scale survey of intestinal helminthic infections among the residents near Pakse, Laos (라오스 메콩강 유역 Pakse 지역 주민의 장내 윤충류 감염률 조사)

  • ;Bouasy Hongvanthong
    • Parasites, Hosts and Diseases
    • /
    • v.36 no.1
    • /
    • pp.55-58
    • /
    • 1998
  • A small-scale epidemiological survey was undertaken on the residents along the Mekong River near Pakse, Laos, to know the status of helminthic infections. A total of 137 fecal samples were collected from the staffs of the provincial government, their family, and primary schoolchildren in Pakse City, Champassak Province, and examined by Kato- katz smear technique. The overall helminth positive rate was 75.9%, and the helminths detected were Opisthorchis viuerrini (43.8%), Asccris lumbricoines (26.3%), fichuris trichiurn (19.0%), hookworms (19.0%), Strongyle컸os stercoraLis (2.2%), Taenio sp. (0.7%), and Schistosoma mekongi (1.5%). To obtain the adult worm of the liver fluke, three infected persons were treated with praziquantel and purged with magnesium sulfate. Five, 10, and 395 adult flukes, respectively, were collected from their diarrheic stools, all of which were morphologically identified as 0. viueni,ni. The results represent that the liver fluke and soil-transmitted helminths are highly prevalent, and the life cycle of 5. mekowi is likely to be maintained in this area.

  • PDF

A Study on the Removal of an Heavy Metal Ions by an Functional Nano Fibers (기능성 나노섬유에 의한 중금속 이온의 제거에 관한 연구)

  • An Hyung-Hwan
    • Journal of the Korean Society of Safety
    • /
    • v.19 no.3 s.67
    • /
    • pp.57-64
    • /
    • 2004
  • This is the study for the removal of a toxic heavy metal ions and the recycling of expanded polystyrene wastes. Thus expanded polystyrene wastes collected from the packing materials of TV or chemicals and dissolved by $80wt.\%$ solvent(N, N-Dimethylacrylamide), electrospun in DC 20kV by power supply. Generally, the electrospinning is a process of manufacture to the fibers of nanosize from polymer solution. Manufactured nanofiber mats by electrospinning were sulfonated by cone.-sulphuric acid with $Ag_2S_O_4$ catalysts for the exchange capacity of heavy metal ions and the properties of structure with sulfonated time investigated by FESEM(Feild Emission Scaning Electron Microscope). The ion exchange capacity of light metal$(Na^+)$, Cd(II) and Ni(II), and by a nanofiber mats were 1.94[mmo1/g-dry-mat), 1.72(mmol/g-dry-mat), 1.24(mmol/g-dry-mat), respectively., and water uptake content showed a similar trend with IEC. and The selectivity coefficients $K^M_H$ of Cd(II), Ni((II) ions showed 0.324, 0.228. respectively.

A Study on Zirconia/Metal.Functionally Gradient Materials by Sintering Method(1) (소결법에 의한 $ZrO_2/Metal$계 경사기능재료에 관한 연구(1))

  • 정연길;최성철
    • Journal of the Korean Ceramic Society
    • /
    • v.31 no.3
    • /
    • pp.321-329
    • /
    • 1994
  • Functionally gradient materials(FGM), which have the continuous or stepwise variation in a composition and microstructure, are being noticed as the material that solves problems caused by heterogeneous interface of coating or joining. And these materials also expect new functions occured by gradient composition itself. Therefore, to examine possibility of thermal barrier materials, TZP/Mo·FGM and TZP/Ni·FGM were fabricated by sintering method. As to the sintered specimens, sintering shrinkage, relative density and Vicker's hardness in each composition were examined. The phenomena due to the difference of sintering shrinkage velocity during sintering process and the thermal stress induced through differences of thermal expansion coefficient in FGM were discussed. And the structure changes at interface and microsturcture of FGM were investigated. As a results, the difference of shrinkage between ceramic and metal was about 14% in TZP/Mo and 7% in TZP/Ni. The relative density and hardness were considerably influenced by metal content changes. Owing to unbalance of sintering shrinkage velocity between ceramic and metal, various sintering defects were occured. To control these sintering defects and thermal stress, gradient composition of FGM should be narrow. The microstructure changes of FGM depended on the ceramic or metal volume percents and were analogous to the theoretical design.

  • PDF