• Title/Summary/Keyword: $Na^+-Pi\

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Photo-enhanced Reduction of Conjugated Enones with NaBH$_4$

  • Shim, Sang-Chul;Yeo, Ho-Seop
    • Bulletin of the Korean Chemical Society
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    • v.8 no.3
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    • pp.202-205
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    • 1987
  • The reduction of some cyclic conjugated enones with electron-donating substituent on C-3 by sodium borohydride was accelerated on irradiation. The photo-enhanced reduction seems to undergo through zwitterionic species formed from the (n, ${\pi}^{\ast}$) triplet state of conjugated enones, followed by hydride attack to yield unsaturated or saturated alcohols.

Synthesis, Structures and Photoluminescent Properties of Two Novel Zinc(II) Compounds Constructed from 5-Sulfoisophthalic Acid

  • Zhu, Yu-Lan;Tang, Xue-Ling;Ma, Kui-Rong;Chen, Hao;Ma, Feng;Zhao, Lian-Hua
    • Bulletin of the Korean Chemical Society
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    • v.31 no.7
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    • pp.1881-1886
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    • 2010
  • Hydrothermal reaction of zinc(II) salts with 5-sulfoisophthalic acid monosodium salt ($NaO_3SC_6H_3$-1,3-(COOH)$_2$, $NaH_2$-SIP) and 1,10-phenanthroline (phen) led to two new compounds, [Zn(phen)$_3$$\cdot2H_2SIP\cdot4H_2O$ (1) and [Zn(phen)$_2(H_2O)_2]\cdot2H_2SIP\cdot2H_2O$ (2). They were characterized by element analysis, IR spectroscopy, thermalgravimetric analysis (TGA), X-ray powder diffraction (XRD), and single-crystal X-ray diffraction. Both compounds 1-2 represent the first example of Zn/phen/SIP system. The Zn (II) ion in 1 is six-coordinated by six nitrogen atoms from three phen molecules, and the $H_2SIP^-$ ligands engage in the formation of hydrogen bond. The Zn(II) ion in 2 is coordinated by four nitrogen atoms from two phen molecules and two oxygen atoms from two water molecules. Moreover, both 1 and 2 are assembled into 3D supramolecular architectures by hydrogen bonds (O-H$\ldots$O) and $\pi-\pi$ interactions. Solvent water molecules occupying voids of the compounds serve as receptors or donors of the extensive O-H$\ldots$O hydrogen bonds.

Effects of age on intestinal phosphate transport and biochemical values of broiler chickens

  • Li, Jianhui;Yuan, Jianmin;Miao, Zhiqiang;Guo, Yuming
    • Asian-Australasian Journal of Animal Sciences
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    • v.30 no.2
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    • pp.221-228
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    • 2017
  • Objective: The objective of this experiment was to characterize the mRNA expression profile of type IIb sodium-inorganic phosphate cotransporter (NaPi-IIb) and the biochemical values of serum alkaline phosphatase (AKP), calcium, inorganic phosphorus, tibial ash and minerals of broiler chickens with aging. Methods: A total of 56 one-day-old Arbor Acres male broiler chickens were used. Broiler chickens were weighed and samples were collected weekly from day 1. Results: The result showed that before the growth inflection point, ash, calcium, and phosphorus content in the tibia of broiler chickens increased with growth (before 3 weeks of age), although there were no significant differences in chicks at different ages in the later period of the experiment and weight gain rate was relatively slow at this stage (4 to 6 weeks). NaPi-IIb gene expression in the small intestine in the early growth stage was higher than that in the later growth stage. Expression of calbindin and the vitamin D receptor protein in the intestinal mucosa increased with age in the duodenum and jejunum. Serum AKP activity first increased and subsequently decreased after peaking at 1 week of age, but there was no significant difference after 3 weeks of age. Conclusion: These results show that compared with the early growth stage, the weight-gain rate of broiler chickens in the late growth stage gradually decreased with gradual tibia maturation, along with weaker positive transport of phosphorus in the intestine and reinforced re-absorption of phosphorus in the kidney, which might be the reason that phosphorus requirement in the late growth stage was decreased.

A Study on the Electrochemical Characteristics of Al-Si Casting Alloys in NaCl Solution (NaCl 수용액에서 Al-Si계 주조용 합금의 전기화학적 특성 연구)

  • Woo, Sang-Hyun;Son, Young-Jin;Lee, Byung-Woo
    • Journal of Power System Engineering
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    • v.18 no.6
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    • pp.29-33
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    • 2014
  • The electrochemical characteristics of Al-Si casting alloys (Al-10%Si, Al-9%Si, Al-7%Si) in 3.5% NaCl solution at room temperature was studied using potentiodynamic techniques. The electrochemical values of corrosion potential($E_c$), corrosion current density($I_c$) and corrosion rate(mpy) were examined. The Al-Si alloys had several compounds such as $Mg_2Si$, ${\pi}$-$Al_8Si_6Mg_2Fe$ and $Al_2CuMg$ which could affect corrosion resistance significantly. The potentiodynamic polarization curve exhibited typical active behavior in anodic polarization curve. The major corrosion mechansim for the Al-Si alloys were pitting and grain boundary corrosion. As increasing Si and Cu contents, their corrosion resistance was decreased.

Studies on Antibiotic Resistance and Growth Characteristics of Shigella Sonnei Isolated from Patients of Shigellosis (이질환자에서 분리한 Shigella Spp.의 항생제 내성과 성장특성)

  • 이영희;박나영;이신호
    • Journal of Food Hygiene and Safety
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    • v.16 no.1
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    • pp.27-32
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    • 2001
  • Antibiotic resistance of thirty strains of Shigella sonnei isolatedfrom patient of Shigellosis outbreke at Young Cheon area in 1998 was tested. Twenty-seven strains were resistant to Tr(Trimethoprim-Sulfamethoxazol) and Shigella sonnei SG-48 was resistant to Tr(Trimethopirm-Sulfamethoxazol), Ap(Ampicillin), Cp(Cephalothin) and Pi(Piperacillin). Shigella sonnei SG-49, SG-66, and SG-73 were senstive to all tested antibiotics. Physiological charactristics of isolated Shigella sonnei SG-48, SG-49, SG-57, and SG-73 such as effect of pH, NaCl concentration and temperature on the growth, survival in adverse condition and heat resistance were investigated Growth of the strains were inhibited at pH 4 and pH 9. All strains were grown in Tryptic soy broth containing 6% of NaCl but inhibited in TSB containing 9% of NaCl except Shigella sonnei SG-73 after incubation for 18hrs at 37$^{\circ}C$. Selected strains grew during storage at 10 but did not grow at 4. The strains were survived in 1% pepton solution for 15 days at 37$^{\circ}C$. Viable cell of selected strains were decreased 45 log cycle after heat treatment for 30 mins at 6$0^{\circ}C$ but did not detect by heat treatment for 5 mins at 7$0^{\circ}C$.

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Physiological Response of Winter Barley to Salt Stress at Seedling Stage (보리 유묘기의 염처리가 생리적 반응에 미치는 영향)

  • Choi, Won-Yul;Kwon, Yong-Woong;Park, Jong-Hwan
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.42 no.5
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    • pp.534-538
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    • 1997
  • Some physiological characteristics and cultivar differences of winter barley to salt stress were studied during seedling stage. Salt stress was caused by adding NaCl solution to the pot culture soil. Measurements of the responses to salt stress and of the responses after relief from stress were done in terms of leaf water potential, chlorophyll and free proline contents, seedling height and seedling dry weight, and survival rate of leaves. Under salt stress ($\Psi_{\pi}$ =-20bar) seedling height and seedling weight were decreased by 2~22% and by 25~39% respectively, showing some differences among cultivars. Chlorophyll contents was decreased by 33~49%, and free proline content was remarkably increased from control 0.2~0.3mg to salt stress 9.6~14.7mg. The leaf water potential of seedling grown under salt stress with NaCl solution($\Psi_{\pi}$ =-10 or -20bar) was decreased from control -3.3bar to salt stress -9.0bar or -16.2bar respectively but there were no large differences among cultivars with time after relief from salt stress. Leaf survival rate was high in order of Baegdong, Milyang12, Olbori, Durubori and Hyangmaeg, and decrease rate of seedling dry weight was low in the order of Baegdong, Olbori, Hyangmaeg, Milyang12, Durubori. The increase in free proline contents was high in the order of Milyang12, Hyangmaeg, Baegdong, Durubori and Olbori.

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Effects of NaCl on the Growth and Physiological Characteristics of Crepidiastrum sonchifolium (Maxim.) Pak & Kawano (NaCl 처리가 고들빼기의 생장과 생리적 특성에 미치는 영향)

  • Lee, Kyeong Cheol;Han, Sang Kyun;Yoon, Kyeong Kyu;Lee, Hak bong;Song, Jae Mo
    • Korean Journal of Medicinal Crop Science
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    • v.28 no.1
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    • pp.1-8
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    • 2020
  • Background: This study was conducted to investigate the effects of NaCl concentration on the photosynthetic parameters, chlorophyll fluorescence and growth characteristics of Crepidiastrum sonchifolium. Methods and Results: As treatments, we subjected C. sonchifolium plants to four different concentrations of NaCl (0, 50, 100 and 200 mM). We found that the photosynthetic parameters maximum photosynthesis rate (PN max), net apparent quantum yield (Φ), maximum carboxylation rate (Vcmax), and maximum electron transport rate (Jmax) were significantly reduced at an NaCl concentration greater than 100 mM. In contrast, there was an increase in water-use efficiency with increasing NaCl concentration, although in terms of growth performances, leaf dry weight, root dry weight, stem length, and total dry weight all decreased with increasing NaCl concentration. Furthermore, leakage of electrolytes, as a consequence of cell membrane damage, clearly increased in response to an increase in NaCl concentration. Analysis of the polyphasic elevation of chlorophyll a fluorescence transients (OKJIP) revealed marked decrease in flux ratios (ΦPO, ΨO and ΦEO) and the PIabs, performance index in response to treatment with 200 mM NaCl, thereby reflectings the relatively reduced state of photosystem II. This increase in fluorescence could be due to a reduction in electron transport beyond Q-A. We thus found that the photosynthetic parameters, chlorophyll fluorescence and growth characteristics of C. sonchifolium significantly increased in response to treatment with 200 mM NaCl. Conclusions: Collectively, the findings of this study indicate that C. sonchifolium shows relatively low sensitivity to NaCl stress, although photosynthetic activity was markedly reduced in plants exposed to 200 mM NaCl.

Implementation of The Personal Secretary System using Raspberry-Pi (라즈베리파이를 이용한 개인 비서 시스템 구현)

  • Park, Na-Hyun;Park, Ji-Hyun;Yun, So-Hyun;Park, Jeong-Sik;Kim, Tai-Woo
    • Journal of Internet of Things and Convergence
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    • v.3 no.1
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    • pp.1-8
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    • 2017
  • Information and time are very important for a modem life, and researches about the personal secretary system that provides specific information for each individual are being studied. In this research, we developed the personal secretary system called Genie which provides the user with desired informations such as weather, news, and traffic information with time. It is expected that the Genie system will provide information on news, weather, traffic information including bus arrival times, and memos with time so that users can find their own leisure time and live a comfortable life.

Transient Response Improvement at Startup of Three Phase AC/DC Converter for DC Distribution System in Building Applications (빌딩용 직류배전 시스템의 3상 AC/DC 컨버터의 기동 시 과도상태 응답 개선)

  • Shin, Soo-Cheol;Lee, Hee-Jun;Lee, Jung-Hyo;Na, Jong-Kuk;Won, Chung-Yuen
    • The Transactions of the Korean Institute of Power Electronics
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    • v.18 no.2
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    • pp.138-144
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    • 2013
  • Most of the DC loads have had the sensitive characteristics electrically for input voltage. In this system, power converter is operated after connecting with DC loads to minimize the overshoot of the control voltage that may occur during connection of the loads. But whenever starting the power converter, parameters in circuit are different because power converter has been connected with diverse load types at each startup time. This is cause of a disadvantage to PI controller design of power converter. In this paper, the novel voltage control method using sliding mode control theory has proposed. This control method minimizes the overshoot of control voltage at startup of power converter. Despite the variations of the system parameters, the proposed voltage controller has fast response and robustness characteristics such as PI and sliding mode controllers. The proposed controller was applied to the three-phase AC/DC converter and each performance of controller was verified.

Effect of Grating Structures and Mirror Positions on Characteristics of 1.55$\mu\textrm{m}$ DFB Lasers (1.55 $\mu\textrm{m}$ DFB 레이저의 특성에 미치는 Grating구조와 Mirror 위치의 영향)

  • Kwon, Kee-Young
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.31A no.9
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    • pp.128-138
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    • 1994
  • In 1.55.mu.m DFB lasers with two non-AR mirrors, I have analyzed the effect of the sturctures of indes and/or gain gratings and mirror positions on the threshold gains, the lasing frequencies, and the beam profiles in longitudinal direction of lasers. I have obtained the optimum condition of static characteristics that ${\Delta}{\Omega}$(the phase difference betweeen index grating and gain grating is 3${\pi}$/4, $({\kappa}L)_{i}$=4~6 in case of $({\kappa}L)_{i}$=0.9 and $({\kappa}L)_{i}$=3~5 in case of $({\kappa}L)_{i}$=0.7. The modal selectivity and intensity uniformity of this optimum condition are 2~2.5 times better than those of the gain-coupled DFB lasers ${\Delta}{\Omega}$=0). The gain-coupled DFB lasers${\Delta}{\Omega}$=0) have 10$^{10) times better modal selectivity and intensity uniformity than the loss-coupled DFB lasers(TEX>${\Delta}{\Omega}$=${\pi}$).

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