DOI QR코드

DOI QR Code

A Study on the Electrochemical Characteristics of Al-Si Casting Alloys in NaCl Solution

NaCl 수용액에서 Al-Si계 주조용 합금의 전기화학적 특성 연구

  • Woo, Sang-Hyun (Department of Material System Engineering, Graduate School, Pukyung University) ;
  • Son, Young-Jin (Department of Material System Engineering, Graduate School, Pukyung University) ;
  • Lee, Byung-Woo (Department of Material System Engineering, Pukyung University)
  • Received : 2014.07.30
  • Accepted : 2014.10.28
  • Published : 2014.12.31

Abstract

The electrochemical characteristics of Al-Si casting alloys (Al-10%Si, Al-9%Si, Al-7%Si) in 3.5% NaCl solution at room temperature was studied using potentiodynamic techniques. The electrochemical values of corrosion potential($E_c$), corrosion current density($I_c$) and corrosion rate(mpy) were examined. The Al-Si alloys had several compounds such as $Mg_2Si$, ${\pi}$-$Al_8Si_6Mg_2Fe$ and $Al_2CuMg$ which could affect corrosion resistance significantly. The potentiodynamic polarization curve exhibited typical active behavior in anodic polarization curve. The major corrosion mechansim for the Al-Si alloys were pitting and grain boundary corrosion. As increasing Si and Cu contents, their corrosion resistance was decreased.

Keywords

References

  1. K. T. Kim, 2011, "High Strength Aluminum Alloy for Die Casting". Journal of Korea Foundry Society Vol.31, pp. 101-105. https://doi.org/10.7777/jkfs.2011.31.3.101
  2. B. W. Lee and H. L. Choi, 2006, "Corrosion characterization of Fe-aluminide alloys with various sulphuric acid solution", KSPSE vol.10, No.2, pp. 83-88.
  3. Y. C. Kim, C. Y. Kang, B. H. Jung, 2011, "The effect of alloying elements and heat treatment on the uniform corrosion of 440A martensitic stainless steel. KSPE v.15, No.2, pp. 42-48. https://doi.org/10.9726/kspse.2011.15.2.042
  4. ASTM E112-13, 1980, "Standard Test Methods for Determining Average Grain Size", ASTM, pp. 192-210.
  5. Wislei R. Osorio. et al., 2008, "Effect of silicon content on microstructure and electrochemical behavior of hypoeutectic Al-Si alloys", Materials Letter vol. 62, pp. 365-369. https://doi.org/10.1016/j.matlet.2007.05.051
  6. Q. G. Wang and C. J. Davidson, 2001, "Solidification and precipitation behaviour of Al-Si-Mg casting alloys", Journal of Material Science vol. 36, pp. 739-750. https://doi.org/10.1023/A:1004801327556
  7. L. Backerud et al., 1990, "Solidification Characteristics of Aluminium alloys, Vol. 2", AFS/SKANAluminium, Des Plaines, IL, USA, p. 128.
  8. R. Escalera-Lozano. et al., 2010, "The Role of Mg2Si in the Corrosion Behavior of Al-Si-Mg Alloys for Pressureless Infiltration", The Open Corrosion Journal vol. 3, pp. 73-79. https://doi.org/10.2174/1876503301003010073
  9. Cristian Vargel, 2004, "Corrosion of Aluminum", ELSEVIER, pp. 115-116.
  10. Joseph R. Davis, 1999, "Corrosion of Aluminum and Aluminum alloys", ASM International, pp. 36-38.