• Title/Summary/Keyword: $NO_x$ and CO

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A Study of Shielding Properties of X-ray and Gamma in Barium Compounds

  • Seenappa, L.;Manjunatha, H.C.;Chandrika, B.M.;Chikka, Hanumantharayappa
    • Journal of Radiation Protection and Research
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    • v.42 no.1
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    • pp.26-32
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    • 2017
  • Background: Ionizing radiation is known to be harmful to human health. The shielding of ionizing radiation depends on the attenuation which can be achieved by three main rules, i.e. time, distance and absorbing material. Materials and Methods: The mass attenuation coefficient, linear attenuation coefficient, Half Value Layer (HVL) and Tenth Value Layer (TVL) of X-rays (32 keV, 74 keV) and gamma rays (662 keV) are measured in Barium compounds. Results and Discussion: The measured values agree well with the theory. The effective atomic numbers ($Z_{eff}$) and electron density (Ne) of Barium compounds have been computed in the wide energy region 1 keV to 100 GeV using an accurate database of photon-interaction cross sections and the WinXCom program. Conclusion: The mass attenuation coefficient and linear attenuation coefficient for $BaCO_3$ is higher than the $BaCl_2$, $Ba(No_3)_2$ and BaSO4. HVL, TVL and mean free path are lower for $BaCO_3$ than the $BaCl_2$, $Ba(No_3)_2$ and $BaSO_4$. Among the studied barium compounds, $BaCO_3$ is best material for x-ray and gamma shielding.

An Effect of Operating Conditions on Exhaust Emissions in a Small Turbocharged D.I. Engine (직접 분사식 소형 과급 디젤엔진의 운전조건이 배기 배출물에 미치는 영향)

  • Jang, S.H.;Koh, D.K.;Ahn, S.K.
    • Journal of Power System Engineering
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    • v.6 no.2
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    • pp.12-17
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    • 2002
  • Recently, the world is faced with very serious problems related to the air pollution due to the exhaust emissions of the diesel engine. So, many of researchers have studied to reduce the exhaust emissions of diesel engine. This study was investigated for various exhaust emissions according to operating conditions in a turbocharged D.I. diesel engine. As a result of experiments in a test engine, the $CO_2\;and\;NO_x$ increased with increasing load, the $CO_2$ and CO decreased with increasing charge air pressure in manifold, the CO decreased with increasing cooling fresh water temperature, and the $NO_x$ decreased with worming cooling fresh water before engine start.

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Magnetic Characteristics of BaFe12-2xCoxTixO19 Particles Prepared by Sol-gel Synthesis (졸-겔 합성에 의한 BaFe12-2xCoxTixO19 미립자의 자기적 특성)

  • 최현승;정지형;박효열;김태옥
    • Journal of the Korean Ceramic Society
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    • v.40 no.1
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    • pp.62-68
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    • 2003
  • Ba-ferrite particles added with Co and Ti, which were known well the additives for the control in coercivity, were synthesized by sol-gel method. In the range 90 to 120 minute reaction time, a stable sol solution which showed no change with temperature, pH, viscosity and aging time. After dried and heat treatment of sol solution, Ba-ferrite phase formed at $700^{\circ}C$ with Differential Thermal Analysis(DTA) and X-Ray Diffractometer(XRD) measurement. The crystallinity became to be better with increasing the temperature. It were showed by Scanning Electron Microscopy(SEM) that Ba-ferrite increased to particle sizes as increasing heating temperature and obtained of narrow particles size distribution. Also, magnetic characteristics of Ba-ferrite powders Co and Ti added were observed by a Vibrating Sample Magnetometer(VSM). Saturation magnetization$(M_s)$ was not much changed, however. the coercivity$(H_c)$dramatically dropped with addition of Co and Ti.

Structural and Magnetic Properties of (Mn, Cr)xCo1-xFe2O4 Thin Films Prepared by Sol-gel Method (졸-겔 방법을 이용하여 제작된 (Mn, Cr)xCo1-xFe2O4 박막의 구조적, 자기적 특성)

  • Kim, Kwang-Joo;Kim, Hee-Kyung;Park, Young-Ran;Park, Jae-Yun
    • Journal of the Korean Magnetics Society
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    • v.16 no.1
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    • pp.23-27
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    • 2006
  • By substituting Mn or Cr for Co in inverse spinel $CoFe_2O_4,\;Mn_xCo_{1-x}Fe_2O_4\;and\;Cr_xCo_{1-x}Fe_2O_4$ and thin films were prepared by sol-gel method and their structural and magnetic properties were investigated. X-ray diffraction indicates that the cubic lattice constant increase for the Mn substitution while it hardly changes for the Cr substitution. Substitution of $Mn^{2+}$ for octahedral $Co^{2+}$ sites can explain the increase of lattice constant in $Mn_xCo_{1-x}Fe_2O_4$. On the other hand, Substitution of $Cr^{3+}$ for octahedral $Co^{2+}$ and subsequent reduction of $Fe^{3+}$ ion into $Fe^{2+}$ are expected to happen. Mossbauer spectroscopy measurements on $Cr_xCo_{1-x}Fe_2P_4$ indicate the existence of tetrahedral $Fe^{2+}$ ions that are created through reduction of tetrahedral $Fe^{3+}$ ions in order to compensate charge imbalance happened by $Cr^{3+}$ substitution for octahedral $Co^{2+}$ sites. On the other hand, no $Fe^{2+}$ ions were detected by Mossbauer spectroscopy for $Mn_xCo_{1-x}Fe_2O_4$. A migration of $Fe^{3+}$ ions from octahedral to tetrahedral sites In $Mn_xCo_{1-x}Fe_2O_4$ was detected by Mossbauer spectroscopy for x>0.47. Vibrating sample magnetometry measurements on the samples at room temperature revealed that the saturation magnetization increases by Mn and Cr substitution for certain range of x, qualitatively explainable in terms of the comparison of spin magnetic moment among the related transition-metal ions.

Performance Evaluation of Nitrogen Oxide Removal by Air Purification Blocks with Titanium Dioxide (이산화티타늄을 이용한 대기정화 블록의 질소산화물 제거 성능 평가)

  • Oh, Ri-On;Kim, Hwang-Hee;Park, Sung-Ki;Cha, Sang-Sun;Park, Chan-Gi
    • Journal of The Korean Society of Agricultural Engineers
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    • v.62 no.5
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    • pp.39-46
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    • 2020
  • This study evaluated the nitrogen oxide (NOx) removal efficiency by air purification concrete blocks with titanium dioxide (TiO2). The concrete in the mixtures had a 30% water:cement ratio, to which TiO2 was added at 0%, 5%, and 10% of cement weight. The compressive strength reduction rate and removal efficiency of NOx were investigated. The result of the compressive strength test in the study indicated that addition rate of TiO2 did not lead to signifcant effect. In terms of the average removal efficiency of NOx, mix No. 1 using a TiO2 mixing ratio of 0% had a removal efficiency of 0.57% on average; thus, the removal effect w as not significant. For the other samples prepared by mixing, the average removal efficiencies for mix No. 2 (5% TiO2) were 58.86% and 62.05% for normal and washing surface treatments, respectively, and those of sample No. 3 (10% TiO2) were 59.94% and 67.61%. mixs No. 4 (5%) and No. 5 (10%), in which TiO2 diluted with distilled water was sprayed onto the block surface, had an average NOx removal efficiency of 61.72% and 68.48%, respectively. In terms of NOx removal efficiency, Mixs No. 3 and No. 5 with 10% TiO2 were better than Mixs No. 2 and No. 4 with 5% TiO2. In addition, analyzing the NOx removal efficiency results from the fixing method, it was capable to apply mixing (washing) and the diluted spray methods. Therefore, it was found that the diluted spray method applied in this study can be employed in any manufacture of air purification concrete blocks.

A Study on the Comparison of Areas Near Gunsan according to the Revision of the National Air Pollutant Emissions (CAPSS) in 2020 (국가대기오염물질 배출량(CAPSS)의 2020년 산정 방법 개정에 따른 군산 인근지역 비교에 관한 연구)

  • Sang-Hun Park;Seong-Cheon Kim
    • Journal of Environmental Health Sciences
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    • v.49 no.4
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    • pp.190-200
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    • 2023
  • Background: Gunsan has been constantly affected by pollutants generated by the Saemangeum development and the construction industry since the completion of the Saemangeum seawall on April 27, 2010. However, there are limitations to its study, such as taking into consideration weather conditions, geographical factors, and foreign inflows. Objectives: In this study, we compared the Existing-CAPSS emissions of Gunsan with Recalculated-CAPSS emissions data to analyze the differences in emissions characteristics by year (2016~2019). Methods: Using Existing data on CAPSS emissions (2016~2019) and Recalculated-CAPSS emissions (2016~2019) for Gunsan, which were Recalculated following the improvement of emissions calculations for 2020, we organized CO, NOX, SOX, PM10, VOCS, and NH3 emissions by substance and investigated the differences and characteristics of the Recalculated emissions by year. Results: For Re-CO and Re-PM10, the emission characteristics of CO were examined as energy industry combustion and PM10 emission characteristics were examined as ship cargo from non-road transportation sources, as ship leisure sources were excluded from non-road transportation source emissions. Conclusions: Comparing the emissions of Existing-CAPSS and Recalculated-CAPSS in Gunsan, the emissions of Recalculated-CAPSS by substance decreased by 39.76% for CO, 9.98% for PM10, 5.53% for VOCS, and 9.24% for NH3, while Re-NOX increased by 2.86% and Re-SOX increased by 1.97%. On the other hand, when comparing the emissions characteristics of Existing-CAPSS and Recalculated-CAPSS in Gunsan, Jeonju, and Iksan, the emission characteristics of Re-NOX, Re-SOX, Re-VOCS and Re-NH3 were similar to those of Ex-NOX, Ex-SOX, Ex-VOCS, and Ex-NH3. As such, Gunsan, Iksan, and Jeonju, showed differences in the comparison of different emission characteristics due to the geographical characteristics of the region (population, area, topography, weather factors) and the characteristics of the industrial complex (metal, petrochemical).

Role of Atmospheric Purification by Trees in Urban Ecosystem -in the Case of Yongin- (도시생태계 수목의 대기정화 역할 -용인시를 사례료-)

  • 조현길;안태원
    • Journal of the Korean Institute of Landscape Architecture
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    • v.29 no.3
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    • pp.38-45
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    • 2001
  • This study quantified annual $CO_2$, SO$_2$ and NO$_2$ uptake and annual $O_2$ production by trees in Yongin´s urban ecosystem, and explored values of urban tree plantings in atmospheric purification. Woody plant cover was only 7.7% with planting density of 1. trees/100$m^2$, and the tree-age structure was largely characterized by a young, growing tree population. Annual per capita pollutant emissions from fossil fuel consumption were 7.3t/yr for $CO_2$, 7.6kg/yr for SO$_2$, and 26.6kg/yr for NO$_{x}$. Carbon dioxide storage per unit urban area by trees was 13.1t/ha and the economic value for $CO_2$ storage was ₩6.6millions/ha. Annual atmospheric purification was 2.0t/ha/yr for $CO_2$ uptake, 2.0kg/ha/yr for SO$_2$ uptake, 4.0kg/ha/yr for NO$_2$ uptake and 1.5t/ha/yr for $O_2$ production, and the annual economic value for the atmospheric purification was ₩1.5millions/ha/yr. Urbantrees stored an amount of $CO_2$ equivalent to about 3.1% of the total annual $CO_2$ emissions, and annually offset total $CO_2$ emissions by 0.5%. Annual SO$_2$ and NO$_2$ uptake by trees equaled 0.5% of total SO$_2$ emissions and 0.3% of total NO$_{x}$ emissions, respectively. Urban trees also played an important role through producing annually 9.2 of the $O_2$ requirement for Yongin´s total population, despite relatively poor tree plantings. Future active plantings and greenspace enlargement in the study city could enhance the role of atmospheric purification by urban trees. The results from this study are expected to be useful in emphasizing environment benefits of urban trees, and in urging the continuous necessity for tree planting and management budget.get.

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An Experiment of SCR System On-board Ship

  • Choi Jae-Sung;Cho Kwon-Hae;Lee Jae-Hyun;Lee Jin-Wook;Kim Jeong-Gon;Jang Sung-Hwan;Yang Hee-Sung;Ko Jun-Ho;Park Ki-Yong
    • Journal of Advanced Marine Engineering and Technology
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    • v.29 no.3
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    • pp.306-312
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    • 2005
  • IMO $NO_x$ levels are generally possible to meet by means of primary on-engine measures. Further significant follow-on reductions are likely to require a secondary after-treatment technique. SCR(Selective Catalytic Reduction) technology is used almost exclusively for $NO_x$ removal in stationary combustion systems. In order to develop a practical SCR system for marine application on board ship, a primary SCR system using urea was made. The SCR system was set up on the ship, 'HANNARA' as a test vessel. employed a two-stroke cycle diesel engine as main propulsion, which is a training ship of Korea Maritime University. The purpose of this paper is to report the results about the basic effects of the below system parameters, The degree of $NO_x$ removal depends on some parameters, such as the amount of urea solution added, space velocity, reaction gas temperature and activity of catalyst.

A Study of Numerical Analysis on Mixed Combustion Characteristics in a Gasoline Direct Injection Engine with Premixed Hydrogen (수소 예혼합 가솔린 직접분사 엔진의 혼소특성에 관한 수치해석 연구)

  • Bae, Jaeok;Choi, Minsu;Suh, Hyunuk;Jeon, Chunghwan
    • Journal of Hydrogen and New Energy
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    • v.24 no.6
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    • pp.524-534
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    • 2013
  • Gasoline direct injection(GDI) engine has a high thermal efficiency, but it has a problem to increase carbon emissions such as soot and $CO_x$. In this study, the objective is to analyze numerically a problem for adding the hydrogen during the intake stroke so as to reduce the injected amount of gasoline in GDI engines. For selection of the base model, the cylinder pressure of simulation is matched to experimental data. The numerical analysis are carried out by a CFD model with the hydrogen addition of 2%, 3% and 4% on the volume basis. In the case of 3% hydrogen addition, the injected gasoline amount is only changed to match the maximum pressure of simulation to that of the base model for additional study. It is found that the combustion temperature and pressure increase with the hydrogen addition. And NO emission also increases because of the higher combustion temperature. $CO_x$ emissions, however, are reduced due to the decrease of injected gasoline amount. Also, as the injected gasoline amount is reduced for the same hydrogen addition ratio, the gross indicated work is no significant, But NO and $CO_x$ emissions are considerably decreased. On the order hand, $CO_x$ emissions of two cases are more decreased and their gross indicated works are higher obtained than those of the base model.

Fabrication and characteristics of NOx gas sensors using WO3 and In2O3 thick films to monitor air pollution

  • Son, M.W.;Choi, J.B.;Hwang, H.I.;Yoo, K.S.
    • Journal of Sensor Science and Technology
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    • v.18 no.4
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    • pp.263-268
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    • 2009
  • With the increasing number of automobiles, the problem of air pollution from the exhaust gases of automobiles has become a critical issue. The principal gases that cause air pollution are nitrogen oxide or NO$_x$(NO and NO$_2$), and CO. Because NO$_x$ gases cause acid rain and global warming and produce ozone(O$_3$) that leads to serious metropolitan smog from photochemical reaction, they must be detected and reduced. Mixtures of WO$_3$ and $In_2O_3$(WO$_3$:$In_2O_3$=10:0, 7:3, 5:5, 3:7, and 0:10 in wt.%), which are NO$_x$ gas-sensing materials, were prepared, and thick-film gas sensors that included a heater and a temperature sensor were fabricated. Their sensitivity to NO$_x$ was measured at 250$\sim$400$^{\circ}C$ for NO$_x$ concentrations of 1$\sim$5 ppm. The $In_2O_3$ thick-film sensor showed excellent sensitivity($R_{gas}/R_{air}$=10.22) at 300$^{\circ}C$ to 5-ppm NO. The response time for 70 % saturated sensitivity was about 3 seconds, and the sensors exhibited very fast reactivity to NO$_x$.