• Title/Summary/Keyword: $NO_2$ gas

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Simultaneous Removal Characteristics of NOx, SOx from Combustion Gases using Pulse Corona induced Plasma Chemical Processing (PPCP에 의한 연소가스 중 NOx, SOx 동시제거 특성)

  • Park, Jae-Yoon;Koh, Yong-Sul;Jung, Jang-Gun;Kim, Jung-Dal
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.2
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    • pp.211-216
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    • 2000
  • In this paper, experimental investigations were carried out to remove NOx, SOx simultaneously from a simulated combustion flue gas [$NO(0.02%)-SO_2(0.08%)-CO_2-Air-N_2$] by using a pulse corona induced plasma chemical processing. Discharge domain of wire-cylindrical plasma reactor was separated from a gas flow duct to avoid unstable discharge by aerosol particle deposited on discharge electrode and grounded electrode. The NOx, SOx removal was experimentally investigated by a reaction induced to ammonium nitrate, ammonium sulfate using a low price of aqueous NaOH solution and a small quantity of ammonia. Volume percentage of aqueous NaOH solution used was 20% and $N_2$ flow rate was $2.5{\ell}/min$ for bubbling aqueous NaOH solution. Ammonia gas(l4.82%) balanced by argon was diluted by air and was introduced to a main simulated flue gas duct through $NH_3$ injection system which was in downstream of reactor. The $NH_3$ molecular ratio(MR) was determined based on [$NH_3$] and [$NO+SO_2$]. MR is 1.5. The NOx removal rates increased in the order of DC, AC and pulse, but SOx removal rates was not significantly effected by source of electricity. The NOx removal rate slightly decreased with increasing initial concentration. but SOx removal rate was not significantly affected by initial concentration. The NOx, SOx removal rates decreased with increasing gas flow rate.

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Effects of Dietary Rosemary Supplementation on Performance, Microflora Population in the cecum and Noxious Gas Emission from Litter in Broilers (Rosemary의 급여가 육계의 생산성, 맹장내 균총 및 깔짚 중 유해가스 발생량에 미치는 영향)

  • Son, Jang-Ho
    • Korean Journal of Organic Agriculture
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    • v.23 no.2
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    • pp.335-346
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    • 2015
  • The objective of this study was to evaluate the effect of dietary rosemary on performance, microflora population in cecum and noxious gas emission from litter of broiler. A total of 216 broiler chicks at 7 days old were fed the commercial diet (control), added 0.5% level of dried rosemary leaves (5 g/kg diet, T1) and 1.0% level of dried rosemary leaves (10 g/kg diet, T2) for 4 weeks. The body weight gain and feed conversion ratio were improved by feeding rosemary at 7 to 35 days of age (P<0.05), but there was no difference between T1 and T2. Amount of feed intake and mortality were not different among the three group. There was an increase in the microflora population of Lactobacillus (P<0.05) and decreased in E. coli and salmonella (P<0.05) in the cecum contents at 21 and 35 days of age. Emission of ammonia gas from litter was significantly decreased by supplementary rosemary at 21 to 35 days of age (P<0.05), but there was no difference between T1 and T2. These results indicated that feeding 0.5 to 1.0% level of dried rosemary leaves during broiler production improved in the body weight gain and feed conversion ratio because of increasing nutrient digestibility from feed, also increase in intestinal beneficial bacteria and decrease in harmful bacteria in the cecum contents, and decreasing emission of ammonia gas from litter.

The prediction of performance, exhaust emissions and EGR effect of a spark ignition engine by cycle simmulation and experimental method (스파아크 점화기관의 사이클 시뮬레이션과 실험적 방법에 의한 성능, 배출가스, EGR효과의 예측에 관한 연구)

  • 정용일;성낙원
    • Journal of the korean Society of Automotive Engineers
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    • v.8 no.2
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    • pp.31-42
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    • 1986
  • The prediction of performance, exhaust emissions and EGR effect is made by the SI engine cycle simulation. In this simulation several models are employed - two zome, thermodynamic combustion, mass fraction burned, heat transfer, chemical equilibrium, chemical kinetics for NOx, laminar flame speed for ignition delay. The chemical species in burned gas considered are 13 species-CO$_{2}$, CO, $O_{2}$, H$_{2}$O, H$_{2}$,OH, H, O, N$_{2}$, NO$_{2}$, N, Ar - and the cylinder pressure, burned and unburned zone temperature and composition of gas are calculated at each crank angle through the compression, ignition delay, combustion and expansion process. To check the validity of the model, experimental study is done for measuring emissions, combustion pressure and engine output. The predicted values for pressure and emissions show qualitative agreement with the measured data and the EGR effect also shows similar tendency.

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Characteristics of Chemical Species in $PM_{205}$ during the Winter in Kangwha (강화도 지역에서 겨울철 $PM_{205}$의 화학적 성분 특성)

  • 여현구
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.4
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    • pp.309-316
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    • 2000
  • Chemical compositions of air pollutants with fine particles (<2.5 ${\mu}{\textrm}{m}$, PB2.5) were evaluated at background site. Kangwha. in Korea during the winter season. The data set was obtained for seventeed days with 24-hour sampling from December 11 to 16, 1996 and from January 9 to 1997. The chemical species have been measured {{{{ {SO }`_{4 } ^{2- } }}}}, {{{{ { NO}`_{3 } ^{- } }}}}, {{{{ { NH}`_{4 } ^{+ } }}}}. OC and EC in the particulate phase, NH3 HNO3, HCl and SO2 in the gas phase using the three stage filter pack method. Mean concentration ($\mu\textrm{g}$/m3) of this study were : 35.42 for PM2.5 8.78 for organic carbon (OC) 7.25 for nss {{{{ {SO }`_{4 } ^{2- } }}}}, 4.94 for {{{{ { NO}`_{3 } ^{- } }}}}, 3.58 for {{{{ { NH}`_{4 } ^{+ } }}}} and 1.48 for elemental carbon (EC) respectively. Contributive rates of major particulate components in PM2.5 were OC (25%) nss- {{{{ {SO }`_{4 } ^{2- } }}}}(20%) ,{{{{ { NO}`_{3 } ^{- } }}}}(14%) {{{{ { NH}`_{4 } ^{+ } }}}}(10%) and EC (4%) respectively and these components could be accounted for 73% of PM2.5 mass. Reactive forms of {{{{ { NH}`_{4 } ^{+ } }}}} were considered as NH4HO3 and NH4{{{{ {SO }`_{4 } ^{2- } }}}} during the sampling periods. {{{{ { NO}`_{3 } ^{- } }}}}/({{{{ { NO}`_{3 } ^{- } }}}} + HNO3) and {{{{ {SO }`_{4 } ^{2- } }}}}/({{{{ {SO }`_{4 } ^{2- } }}}} + SO2) were calculated 0.8 and 0.9 respectively. Most of these compounds might be formed in partiiculate phase in the air. Correlation coefficient between OC and EC was 0.866 which might have the same sources during the sampling periods,.

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Effects of Temperature, Pressure, and Gas Residence Time on Methane Combustion Characteristics of Oxygen Carrier Particle in a Pressurized Fluidized Bed Reactor (가압 유동층 반응기에서 산소공여입자의 메탄 연소 특성에 미치는 온도, 압력 및 기체체류시간의 영향)

  • Ryu, Ho-Jung;Park, Sang-Soo;Moon, Jong-Ho;Choi, Won-Kil;Rhee, Young-Woo
    • Journal of Hydrogen and New Energy
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    • v.23 no.2
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    • pp.173-182
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    • 2012
  • Effects of temperature, pressure, and gas residence time on methane combustion characteristics of mass produced oxygen carrier particle (OCN706-1100) were investigated in a pressurized fluidized bed reactor using methane and air as reactants for reduction and oxidation, respectively. The oxygen carrier showed high fuel conversion, high $CO_2$ selectivity, and low CO concentration at reduction condition and very low NO emission at oxidation condition. Moreover OCN706-1100 particle showed good regeneration ability during successive reduction-oxidation cyclic tests up to the 10th cycle. Fuel conversion and $CO_2$ selectivity decreased and CO emission increased as temperature increased. These results can be explained by trend of calculated equilibrium CO concentration. However, $CO_2$ selectivity increased as pressure increased and fuel conversion increased as gas residence time increased.

Adhesion and Interface Chemical Reactions of Cu/CuO/Polyimide System (Cu/CuO/Polyimide 시스템의 접착 및 계면화학 반응)

  • Lee, K.W.;Chae, H.C.;Choi, C.M.;Kim, M.H.
    • Korean Journal of Materials Research
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    • v.17 no.2
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    • pp.61-67
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    • 2007
  • The magnetron reactive sputtering was adopted to deposit CuO buffer layers on the polyimide surfaces for increasing the adhesion strength between Cu thin films and polyimide, varying $O_2$ gas flow rate from 1 to 5 sccm. The CuO oxide was formed through all the $O_2$ gas flow rates of 1 to 5 sccm, showing the highest value at the 3 sccm $O_2$ gas flow rate. The XPS analysis revealed that the $Cu_2O$ oxide was also formed with a significant ratio during the reactive sputtering. The adhesion strength is mainly dependent on the amount of CuO in the buffer layers, which can react with C-O-C or C-N bonds on the polyimide surfaces. The adhesion strength of the multi-layered Cu/buffer layer/polyimide specimen decreased linearly as the heating temperature increased to $300^{\circ}C$, even though there showd no significant change in the chemical state at the polyimide interface. This result is attributed to the decrease in surface roughness of deposited copper oxide on the polyimide, when it is heated.

POSITIONAL COINCIDENCE BETWEEN WATER MASERS AND A PLASMA TORUS IN NGC 1052

  • SAWADA-SATOH SATOKO;KAMENO SEIJI;SHIBATA KATSUNORI M.;INOUE MAKOTO
    • Journal of The Korean Astronomical Society
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    • v.38 no.2
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    • pp.183-186
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    • 2005
  • We present results of the VLBA observation toward the radio continuum and water maser emissions in a nearby LINER galaxy NGC 1052. The jet structure observed in 2000 is similar to that in 1998, and the two jet structures in 1998 and 2000 support the sub-luminal motion with apparent velocity of 0.26c. Distribution of water maser spots are located ${\~}$0.05 pc shifted to southwest from the component which is supported to be the nucleus, and no rapid positional change of the water maser gas with respect to the central engine is seen from 1995 to 2000. The maser gas is positionally coincident with a plasma torus, and the position of the maser gas relative to the nucleus is stable from 1995 to 2000. The maser gas in NGC 1052 could be explained to be associated with the nuclear circumnuclear torus or disk like the situation found in the nucleus of NGC 4258.

The characteristics of bead welding on steel with process parameter during the laser-arc hybrid welding(I) - Effect of flow rate of shield gas and distance between laser and arc - (강의 레이저-아크 하이브리드 용접시 공정변수에 따른 비드용접특성 (I) - 보호가스 유량 및 레이저 아크간 거리의 영향 -)

  • Kim, Jong-Do;Myung, Gi-Hoon;Song, Moo-Keun;Oh, Jae-Hwan;Suh, Jeong
    • Journal of Welding and Joining
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    • v.33 no.2
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    • pp.85-90
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    • 2015
  • Recently many studies for improvement of productivity and automation of process are in progress, and among others, laser-arc hybrid welding that combined laser and arc has attracted much attention. Since parameters by interactions as well as the parameters of each heat source should be considered, There are a lot of hardship in actual application, even though many researches have been done so far. Therefore in this study, bead welding was done to examine the effects of the flow rate of shield gas and the distance between laser and arc during laser-arc hybrid welding. As for hybrid heat source, disk laser and MIG were used. As experiment result, sound bead and weld with no defect were formed when the flow rate of front and rear shield gas were respectively 20 l/min and 15 l/min, and deep penetration was done at DLA=3 mm.

Characteristics of Immobilized PVA Beads in Nitrate Removal

  • Cho Kyoung-Sook;Park Kyoung-Joo;Jeong Hyun-Do;Nam Soo-Wan;Lee Sang-Joon;Park Tae-Joo;Kim Joong-Kyun
    • Journal of Microbiology and Biotechnology
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    • v.16 no.3
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    • pp.414-422
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    • 2006
  • Before applying PVA bio-beads to practical biological treatment of nitrate-containing wastewater, their characteristics were examined. PVA bio-beads could steadily produce nitrogen gas from nitrate for 28 batches with 0.04 ml/l/h of the maximum gas production rate; however, the maximum gas production rate dropped remarkably thereafter with apparent deformation of beads. Addition of 2.2% solution containing 1% casamino acid, 1% yeast extract, 0.1% mineral solution, and 0.1% vitamin solution to the culture medium resulted in not only recovery of activity of deactivated beads, but also a higher rate of gas production. Calculation of economic benefit for the use of bio-beads in a long-run operation indicated that reactivation of bio-beads by chemicals had economical advantages over packing new bio-beads in the system. The continuously stirred bioreactor exhibited a satisfactory performance at HRT of 20.0 h. With a 9.5 mg $NO_{3}^{-}N/l/h$ nitrate removal rate, nitrate could completely be removed without nitrite accumulation. The use of PVA bio-beads in nitrate removal appears very promising.

Sustainability Practices as Determinants of Financial Performance: A Case of Malaysian Corporations

  • Amacha, Ezeoha Bright;Dastane, Omkar
    • The Journal of Asian Finance, Economics and Business
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    • v.4 no.2
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    • pp.55-68
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    • 2017
  • This research is carried out to investigate the relationship between sustainability practices and performance in a financial sense for Malaysian Oil and Gas sector. Objectives include to study the state of sustainability disclosure among Malaysian oil and gas companies, to understand if companies that practiced sustainability had better performances to their financial bottom-line and to conduct a data analysis to understand the relationship between Environmental, social and governance performance [represented by the acronym ACSI] and financial performance. Sustainability performance is measured using ACSI checklist, which is an adaptation of the GRI 3.0 by Global reporting initiative while financial performance was measured on financial and profitability parameters namely EBITDA, EPS and PE ratio. Secondary data sources are used which were then converted into a rating scale to develop quantitative data. SPSS 21 is used for the analysis. The result shows that the majority of oil and gas companies in Malaysia had poor performance in terms of sustainability disclosure. On all three chosen profitability parameters, the companies that practiced sustainability were found to perform better than their counterparts that did not. Strong and significant relationship exists between sustainability practices and better financial performance.