• Title/Summary/Keyword: $NH_3-NH_4^+$

Search Result 3,827, Processing Time 0.032 seconds

Growth dynamics of the seagrass, Zostera marina in Jindong Bay on the southern coast of Korea

  • Kim, Young-Kyun;Kim, Jong-Hyeob;Kim, Seung-Hyeon;Kim, Jae-Woo;Park, Sang-Rul;Lee, Kun-Seop
    • ALGAE
    • /
    • v.27 no.3
    • /
    • pp.215-224
    • /
    • 2012
  • Growth dynamics of the seagrass, Zostera marina were examined at the two stations (Myungju and Dagu) in Jindong Bay on the southern coast of Korea. Eelgrass leaf productivities, underwater irradiance, water temperature, dissolved inorganic nitrogen (DIN) in water column and sediments, and tissue carbon (C) and nitrogen (N) content were monitored monthly from March 2002 to January 2004. Underwater irradiance fluctuated highly without a clear seasonal trend, whereas water temperature showed a distinct seasonal trend at both study stations. Water column DIN concentrations were usually less than $5{\mu}M$ at both study sites. Sediment pore water $NH_4{^+}$ and $NO_3{^-}+NO_2{^-}$ concentrations were higher at the Myungju site than at the Dagu site. Eelgrass leaf productivity at both study sites exhibited a distinct seasonality, increasing during spring and decreasing during summer. Seasonal variation of eelgrass productivity was not consistent with seasonal patterns of underwater irradiance, or water temperature. Eelgrass tissue C and N content at both study sites also showed significant seasonal variations. Relationships between tissue C and N content and leaf productivities exhibited usually negative correlations at both study sites. These negative correlations implied that the growth of Z. marina at the study sites was probably limited by C and N supplies during the high growth periods.

METHODS TO IMPROVE UTILIZATION OF RICE STRAW III. EFFECT OF UREA AMMONIA TREATMENT AND UREA MOLASSES BLOCKS SUPPLEMENTATION ON INTAKE, DIGESTIBILITY, RUMEN AND BLOOD PARAMETERS

  • Badurdeen, A.L.;Ibrahim, M.N.M.;Ranawana, S.S.E.
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.7 no.3
    • /
    • pp.363-372
    • /
    • 1994
  • In two separate experiments with crossbred bulls (Sahiwal $\times$ indigenous) the effect of access to a urea-molasses lickblock (MOL-U-MIN) on straw diets was studied. The animals were given either untreated (US) or urea treated (TS) rice straw with or without lickblock supplementation. In experiment 1, individual dry matter intake (DMI) and dry matter digestibility (DMD) were measured, while in experiment 2 in addition to the above rumen (pH, ammonia, minerals) and blood (protein, minerals and haemotological) parameters were also measured. With both experiments urea treatment did not effect DMI, but lickblock supplementation significantly (p < 0.05) increased DMI. The DMD values obtained in both experiments for TS were significantly (p < 0.05) higher than for US, but lickblock supplementation did not effect the DMD of either US or TS fed animals. Both urea treatment (6.97 vs 6.93) and lickblock supplementation (6.98 vs 6.92) significantly (p < 0.001) reduced the rumen pH. Urea treatment and lickblock supplementation increased the rumcn $NH_3-N$ concentration (mg/100 ml) from 8.7 to 11.9 and 9.2 to 11.4, respectively. Both US and TS diets fed with or without lickblock increased the molar ratio of Na : K in saliva. Phosphorus content in blood plasma was significantly (p < 0.01) increased due to lickblock supplementation, whereas the Fc content in blood was significantly increased (p < 0.01) by urea treatment. Haemoglobin content in blood ranged from 11.3 to 11.7 g/dl, and was not influenced by urea treatment or lickblock supplementation. Lickblock significantly reduced the number of red blood cells, but increased the mean corpuscular volume. It is concluded that feeding urea treated straw with proper mineral supplementation could be a more economical alternative to lickblock supplementation.

Size Control of Nickel Powders from Nickel Chloride Solution Containing Ammonia in DEA Solutions (DEA 용액에서 암모니아를 함유한 염화니켈 수용액으로부터 니켈 분말의 입경 제어)

  • Choi Eun Young;Lee Yoon Bok;Yoon Suk Young;Kim Kwang Ho;Kim Jin Chun;Rhyim Young Mok;Kim Hyong Kuk;Kim Yang Do
    • Journal of Powder Materials
    • /
    • v.12 no.3
    • /
    • pp.201-207
    • /
    • 2005
  • Nickel powders were synthesized by the hydrazine reduction of nickel chloride solution containing ammonia in DEA solutions. The size distribution of nickel powders were investigated as a function of ammonia concentration, hydrazine concentration and the mixed composition ratio of diethanolammine (DEA) and triethanolammine (TEA). Nickel powders with the size in submicron range were obtained at $185^{\circ}C$ for 45 minutes by hydrazine reduction of nickel chloride solution in DEA solutions. The hydrazine concentrations showed significant effects on the particle size and shape distribution of nickel powders under $NH_3/Ni^{2+}$ molar ratio of 2.0 condition. As the mixed volume ratio of TEA and DEA increased, nickel powders with relatively larger particle size and low agglomeration were obtained. Nickel powders with particle size in the ranged from 0.4 to $0.9\;{\mu}m$ were obtained at the 50 $vol.%$ of TEA.

Studies on the Amino Acid Composition of Korean Fermented Soybean Meju Products and the Evaluation of the Protein Quality (장류제품의 아미노산 조성과 그 단백질 품질평가에 관한 연구)

  • Lee, Cherl-Ho
    • Korean Journal of Food Science and Technology
    • /
    • v.5 no.4
    • /
    • pp.210-214
    • /
    • 1973
  • This study analyses and compares the amino acid composition and available lysine content between Korean fermented soybean Meju and its products as well as home-made and commercially made products. The protein quality of the products was evaluated by the result, and the biological value of the proteins was estimated by using the regression equation for chemical score to biological value as calculated by B.O. Eggum. The amino-N content of soybean is found to be 85% of the total nitrogen content and is reduced to approximately 75% in the fermented products except home-made soysauce, where as the content of ammonia-N and other N-compounds is increased. The difference in protein quality between home-made and commercially made products is not found to be significant. The protein quality of soybean is not damaged greatly in the making of Meju but is seriously damaged during the long periods of ripening. After the ripening the chemical score of the products' protein is reduced to approximately one half of the original soybean protein and the available lysine content to $1/3{\sim}1/2$.

  • PDF

Application of MBBR Process in the Activated Sludge Process (기존 활성슬러지 공정의 MBBR 공정 적용가능성 평가)

  • Park, Woon-Ji;Lee, Hae-Seung;Lee, Chan-Ki;Kim, Sung-Gun
    • Journal of Korean Society on Water Environment
    • /
    • v.20 no.5
    • /
    • pp.457-465
    • /
    • 2004
  • The objective of this study is to evaluate the possibility to apply the Moving Bed Biofilm Reactor(MBBR) in the activated sludge treatment process with existing aerobic HRT. Optimal operation conditions were assumed according to the analysis of organic matter and nutrients removal efficiencies depending on loading variations. The process was operated under different conditions: RUN I(HRT=7.14hr, $I{\cdot}R=100%$), RUN II(HRT=6.22hr, $I{\cdot}R=100%$), RUN III(HRT=6.22 hr, $I{\cdot}R=150%$), RUN IV(HRT=6.22hr, $I{\cdot}R=200%$), the TBOD removal efficien cies are 88%, 88.5%, 94.6%, 97.6%, respectively. Overall TSS removal efficiency is 90%, and it is increasing in RUN IV. In the case of Nitrogen, the highest removal efficiency of 90% was observed in RUN III and RUN IV, Nitrification and Denitrification rates are 0.013-0.016kg $NH_3-N/kg$ Mv-d and 0.009-0.019kg $NO_3/kg$ Mv-d, respectively. Phosphorus removal efficiencies are 89.6% in RUN I, 91.5% in RUN II, 84.3% in RUN III, and 76.4% in RUN IV. The process under shorter SRT yields better performance in terms of phosphorus removal. It was noticed that to achieve the effluent phosphorus concentration ofless than 1mg/L and removal efficiency higher than 80%, SRT should not be longer than 10 days. Experimental result shows that HRT of 6.22 hours is suitable for this treatment process, and, as a result, the aerobic reactor including moving media and DO depletion tank have a sufficient effect to the process performance.

Sewage Treatment Using Water Hyacinth (Eichhornia crassipes) and Watercress (Oenanthe Javanica) (부레옥잠과 미나리를 이용한 연속식 하수처리에서 COD, N 및 P의 제거)

  • Park, Jin-Sick
    • Korean Journal of Environmental Agriculture
    • /
    • v.21 no.2
    • /
    • pp.144-148
    • /
    • 2002
  • This study was carried out to investigate sewage treatment efficiencies using water hyacinth (Eichhornia crassipes) and watercress (Oenanthe Javanica). In the hyacinth system about 30% of COD introduced was removed during 2 days of hydraulic retention time, and about 30$\sim$50% of COD was removed in the watercress system during 1.2$\sim$2 days of hydraulic retention time. Therefore, COD loading of $76\sim170$ kg $COD/ha{\cdot}day$ was removed during 2$\sim$3 days of hydraulic retention time at the 0.18 $m^2$ area in the water hyacinth-watercress continuous system. Also 40$\sim$50% of N and P in the sewage were removed in the tested water hyacinth-watercress system Although COD, N and P concentrations in the final effluent were still higher than the limits of waste discharge, applicability of this waste water treatment system should be further investigated as an alternative method far small scale sewage treatments.

Effect of Induction Hardening on Mechanical Properties in Gas Nitrocarburized SM35C Steel (가스 침질탄화처리한 SM3SG강의 기계적 성질에 미치는 고주파퀜칭의 영향)

  • Kim, H.S.;Lee, K.B.;Yu, C.H.;Kim, H.T.;Jang, H.Y.
    • Journal of the Korean Society for Heat Treatment
    • /
    • v.13 no.4
    • /
    • pp.224-230
    • /
    • 2000
  • Garbon steel(SM35C) was gas nitrocarburized at $580^{\circ}C$ in $55%N_2-40%NH_3-5%CO_2$ mixed gas atmosphere, and then the steel was induction hardened at $850^{\circ}C$. The microstructure of gas nitrocarburized surface layer was observed by optical microscope and SEM. The phase analysis was carried out by X-ray diffraction method. The mechanical properties of gas nitrocarburized SM35C steel was evaluated by hardness, wear and fatigue test. The thickness of compound and diffusion layer were increased with increasing the gas nitrocarburizing time and the densest compound layer was obtained at 3 hours gas nitrocarburizing time. In case of 15sec induction hardening after gas nitrocarburizing, the surface hardness was decreased from 800Hv to 630Hv owing to the decomposition of compound layer, but wear resistance was increased because of increased hardness of diffusion layer. The fatigue strength of induction hardened steel after gas nitrocarburizing, $58kgf/mm^2$, was higher than $41.5kg/mm^2$ of gas nitrocarburized steel and $45kg/mm^2$ of induction hardened steel, respectively.

  • PDF

The Powder Synthesis of (Bi,Pb)-2223 System Superconductor by Oxalate Method and Thick Film Preparation (옥살산염법에 의한 (Bi, Pb)-2223계 초전도 분말 합성과 후막 제조)

  • 하성원;김형태;이응상
    • Journal of the Korean Ceramic Society
    • /
    • v.34 no.10
    • /
    • pp.1083-1091
    • /
    • 1997
  • As one of the chemical powder fabrication methods, the powder preparation method by using oxalate has the following advantages; (1) easy to control the chemical stoichiometry, (2) easy to fabricate homogeneous and fine particles, and (3) easy to be thermaly decomposed at low temperature. In the present study, the initial morphology and size distribution of the powder were controlled and the homogeniaty was improved. By carefully controlling the pH with NH4OH, the Bi(Pb)-Sr-Ca-Cu-O superconducting powders were prepared and investigated for their properties. The microstructures and the superconducting properties of the pelletized samples were investigated. Also, the microstructures and electrical properties of the samples prepared by tape casting method were investigated. The fabricated powders were spherical with less than 400 nm, but most of them were agglomerated to be 1~3 ${\mu}{\textrm}{m}$ in size. The critical temperature of the pelletized sample annealed at 84$0^{\circ}C$ for 72 hours in air was 110K. And the critical currents of annealed samples in air prepared by tape casting process for 24 hours and 72 hours were 0.6 A (Jc=600A/$\textrm{cm}^2$) and 1.9A (Jc=1, 900A/$\textrm{cm}^2$) respectively.

  • PDF

THE MONITORING OF AEROBIC FLOC-LIKE SLUDGE INFLUENCED BY CALCIUM IONS

  • Yoon, Young H.;Park, Jae-Ro;Kim, In-S.
    • Environmental Engineering Research
    • /
    • v.11 no.3
    • /
    • pp.127-133
    • /
    • 2006
  • Aerobic floc-like sludge was formed in a batch reactor and the effect of cations on the formation of aerobic floc-like sludge was studied. In order to enhance the formation (rate) of aerobic floc-like sludge, cations such as $K^+$, $Na^+$, $Ca^{2+}$, and $Mg^{2+}$ were added to the seed sludge. It was found that $Ca^{2+}$ had positive effect on the formation of floc-like sludge, as measured by sludge volume index (SVI) for settle ability. The formation of floc-like sludge was confirmed by the microscopic observation after DAPI staining. The scattered forms of sludge samples at the initial stage became aggregated to form floes after $Ca^{2+}$ addition. To ensure the functions of sludge floes in a treatment plant, the gradient of ionic species around the surfaces of floc-like sludge was monitored by ion selective microelectrodes for ${NH_4}^+,\;{NO_3}^-$, and pH. The effective concentration of $Ca^{2+}$ ion to form floc-like sludge was determined to be 750 mg/L (0.15 mg $Ca^{2+}/mg$ MLSS). Under the effective $Ca^{2+}$ condition, the SVI value was the lowest and large distribution of nitrifying bacteria at the outer surface was observed in the aerobic floc-like sludge. From the results, it was found that the calcium ion functioned as an agent for the formation of aerobic floc-like sludge, resulting in the enhanced nitrification.

Degradation Characteristics of Aqueous MEA Solution by Corrosion Products and Absorption Conditions (흡수 조건 및 부식 생성물에 의한 MEA 수용액의 변성 특성)

  • NAM, SUNGCHAN;SONG, YOONAH;BAEK, ILHYUN;YOON, YEOIL;YOU, JEONGKYUN;LEE, CHANGHA
    • Journal of Hydrogen and New Energy
    • /
    • v.27 no.3
    • /
    • pp.290-297
    • /
    • 2016
  • The absorbent loss due to degradation in $CO_2$ capture process using aqueous alkanol amine solution has adverse effect on the economics of overall process. The degradation causes absorbent loss, equipment corrosion, foaming, adhesive material producing and viscosity increase in operation. In this study, the degradation characteristics of $CO_2$ capture process using MEA (monoehtanolamine) under various conditions such as $O_2$ partial pressure, $CO_2$ loading and absorbent temperature. The effects of iron, which generated from the equipment corrosion, on absorbent degradation were studied using $Fe_2SO_4$ containing MEA solution. The produced gases were analyzed by FT-IR(Fourier Transform Infrared Spectrophotometer) and the specifically measured $NH_3$ concentration was used as a degradation degree of aqueous MEA solution. The experiments showed that the higher $CO_2$ loadings (${\alpha}$), $O_2$ fraction ($y_{O2}$) and reaction temperature enhanced the more degradation of aqueous MEA solution. Comparing other operation parameters, the reaction temperature most affected on the degradation. Therefore, it could be concluded that the above parameters affects on degradation should be considered for the selections of $CO_2$ absorbent and operating conditions.