• Title/Summary/Keyword: $Mg_3N_2$

Search Result 4,710, Processing Time 0.032 seconds

MgO doping and annealing effect on high temperature electrical resistivity of AlN-Y2O3 ceramics (MgO doping 및 annealing이 AlN-Y2O3 세라믹스의 고온전기저항에 미치는 영향)

  • Yu, Dongsu;Lee, Sung-Min;Hwang, Kwang-Taek;Kim, Jong-Young;Shim, Wooyoung
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.28 no.6
    • /
    • pp.235-242
    • /
    • 2018
  • High temperature electrical conductivity of Aluminum Nitride (AlN) ceramics sintered with $Y_2O_3$ as a sintering aid has been investigated with respect to various sintering conditions and MgO-dopant. When magnesium oxide is added as a dopant, liquid glass-film and crystalline phases such as spinel, perovskite are formed as second phases, which affects their electrical properties. According to high temperature impedance analysis, MgO doping leads to reduction of activation energy and electrical resistivity due to AlN grains. On the other hand, the activation energy and electrical resistivity due to grain boundary were increased by MgO doping. This is a result of the formation of liquid glass film in the grain boundary, which contains Mg ions, or the elevation of schottky barrier due to the precipitation of Mg in the grain boundary. For the annealed sample of MgO doped AlN, the electrical resistivity and activation energy were increased further compared to MgO doped AlN, which results from diffusion of Mg in the grains from grain boundary as shown in the microstructure.

매립지 주변 지하수오염 조사

  • 이창수
    • Proceedings of the Korean Environmental Sciences Society Conference
    • /
    • 2004.11a
    • /
    • pp.133-135
    • /
    • 2004
  • 1. 침출수 수질 조사결고, pH는 $3.7\~5.0,\;COD_{Mn}$$760\~1,800mg/\ell,\;NO_3-N\;26.124\~78.150mg/\ell,\;NH_3-N$$144.5\~350mg/\ell,\;Cl^-$$13272.0\~34137.0mg/\ell$,는 $450\~1620mg/\ell$, SS는 $81.2\~652.7mg/\ell$, T-N은 $228\~430mg/\ell$, T-P는 $0.921\~1.108mg/\ell$로 분석되었으며, 중금속류는 거의 검출되지 않았다. 2. 지하수 수질조사결과, 수질상태는 지하수를 생활용수, 농업용수, 어업용수 및 공업용수로 이용하는 수질기준을 모두 만족시키고 있으며, 또한 분석을 실시한 항목에 대한 전조사지점이 대장균군을 제외한 수질조사 항목의 먹는 샘물기준을 만족시키고 있는 것을 확인할 수 있다. 3. 토양오염도 조사결과, 농경지 및 산업지역의 토양오염 우려기준을 크게 밑도는 것으로 분석되어 대상 매립지에서 발생하는 침출수 및 소각재 등의 주변지역 토양오염에 미치는 영향은 미약한 것으로 추정된다.

  • PDF

Protocols for Estrus Synchronization in Awassi Ewes under Arid Environmental Conditions

  • Abdullah, A.Y.;Husein, M.Q.;Kridli, R.T.
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.15 no.7
    • /
    • pp.957-962
    • /
    • 2002
  • In July, three trials were conducted to evaluate the best sponge type and optimum PMSG dose to be administered to sheep under the Jordanian Badia (arid) conditions. In trial 1, three flocks (n=77, n=18 and n=47 for flocks 1, 2 and 3, respectively) were administered with 40 mg fluorogestone acetate (FGA) intravaginal sponges for 12 days before receiving 600 IU of PMSG at the time of sponge removal. In trial 2, 95 ewes were assigned to 4 groups to receive 300 (n=25), 450 (n=27), 600 (n=22) or 750 (n=21) IU of PMSG following a 12 d FGA 40 mg sponge insertion period. In trial 3, 60 ewes were assigned to 3 groups (n=20) to receive either FGA 30 mg, FGA 40 mg or medroxyprogesterone acetate (MAP) 60 mg intravaginal sponges all followed by an administration of 600 IU of PMSG at sponge removal. In all trials, rams were isolated 1 day before sponge insertion and were allowed back with the ewes at sponge removal. Estrual responses and lambing data were collected. The effects of treatment, milking status and face color on estrual responses and lambing data were examined. In trial 1, greater first cycle conception rate (p<0.05), twinning rate (p<0.01) and the number of lambs born/served ewe (p<0.01) were observed in flock 2 compared with flocks 1 and 3. Neither face color nor milking status had any influence on the measured parameters (p>0.05). Despite low lambing rate in trial 2, ewes receiving 600 IU of PMSG had greater (p<0.05) number of lambs born/served ewe compared with ewes receiving 450 IU of PMSG. Regardless of PMSG dose, intervals to detected estrus occurred 10 h earlier (p<0.01) in dry than lactating ewes. Similar to trial 2, lambing rate was depressed in trial 3. The expression of estrus was advanced (p<0.05) in ewes receiving MAP 60 mg sponges compared with those receiving FGA 30 and FGA 40 mg sponges (42$\pm$3.1, 49$\pm$3.1 and 49$\pm$3.1 h post sponge removal in ewes receiving MAP 60 mg, FGA 30 mg and FGA 40 mg sponges, respectively). Other parameters were not influenced (p>0.05) by sponge type, milking status and face color. Data show that a 600 IU dose of PMSG tends to give the best lambing results. In addition, results indicate that the use 60 mg MAP sponges for estrus synchronization may be more appropriate under the Jordanian Badia conditions during late seasonal anestrus.

Luminescence Characteristics of Sr3MgSi2O8:Eu Blue Phosphor for Light Emitting Diodes (LED용 Sr3MgSi2O8:Eu청색 형광체의 발광특성)

  • 최경재;박정규;김경남;김창해;김호건
    • Journal of the Korean Ceramic Society
    • /
    • v.41 no.8
    • /
    • pp.573-577
    • /
    • 2004
  • We have synthesized a Eu$^{2+}$-activated Sr$_3$MgSi$_2$ $O_{8}$ blue phosphor and investigated an attempt to develop blue LEDs by combining it with a InGaN blue LED chip (Len=405 nm). The InGaN-based Sr$_3$MgSi$_2$ $O_{8}$:Eu LED Lamp shows two bands at 405 nm and 460 nm. The 405 nm emission band is due to a radiative recombination from a InGaN active layer. This 405 nm emission was used as an optical transition of the Sr$_3$MgSi$_2$ $O_{8}$:Eu phosphor. The 460 m emission band is ascribed to a radiative recombination of Eu$^{2+}$ impurity ions in the Sr$_3$MgSi$_2$ $O_{8}$ host matrix. As a consequence of a preparation of W blue LED Lamp using the Sr$_3$MgSi$_2$ $O_{8}$:Eu blue phosphor, the highest luminescence efficiency was obtained at the ration of epoxy/blue phosphor(1/0,202). At this time, the CIE chromaticity was x=0.1417 and y=0.0683.

Effects of MLSS Concentration and Influent C/N Ratio on the Nitrogen Removal Efficiency of Alternately Intermittently Aerated Nonwoven Fabric Filter Bioreactors (교차 간헐 포기식 부직포 여과막 생물반응조에서 MLSS 농도 및 유입수 C/N 비가 질소 제거효율에 미치는 영향)

  • Jung, Kyoung-Eun;Bae, Min-Su;Lee, Jong-Ho;Cho, Yun-Kyung;Cho, Kwang-Myeung
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.28 no.5
    • /
    • pp.501-510
    • /
    • 2006
  • To investigate the effects of MLSS concentration and influent C/N ratio on the nitrogen removal efficiency of alternately intermittently aerated nonwoven fabric filter bioreactors, the MLSS concentrations of the reactors were maintained at approximately 5,500 mg/L, 10,000 mg/L and 15,000 mg/L, and the influent TCOD/TKN ratio was decreased gradually from 5 to 2 by adding $NH_4Cl$. The influent was prepared by diluting a food waste leachate to a TCOD concentration of about 300 mg/L. The results of the experiment showed F/M ratios less than 0.112 g TCOD/g MLSS-day, average TCOD removal efficiencies of above 95%, and an average observed microbial yield coefficient of 0.283 g MLSS/g COD removed. The nitrification efficiencies were computed to be always better than 96% except one case where the nitrification efficiency was 90.5% when the MLSS concentration and the influent TCOD/TKN ratio was 5,500 mg/L and 2, respectively. The denitrification efficiency deteriorated as the influent TCOD/TKN ratio decreased. The average denitrification efficiency at the MLSS concentration of 10,000 mg/L was 10.7% better than that at the MLSS concentration of 5,500 mg/L, and the denitrification rate improved at a rate of 2.66 mg NL as the MLSS concentration increased by 1,000 mg/L. When the MLSS concentration was 15,000 mg/L, however, the average denitrification efficiency was merely 4.6% higher compared to when the MLSS concentration was 5,500 mg/L, and the denitrification rate increased at a rate of 0.75 mg N/L per 1,000 mg/L MLSS increase. Therefore, no strict proportional relationship was found between MLSS concentration and endogenous denitrification rate. The average alkalinity consumption rate was 3.36 mg alkalinity/mg T-N removed, which is similar to the theoretical value of 3.57 mg alkalinity/mg T-N removed, but the rate increased as the influent TCOD/TKN ratio decreased.

Soil Mineral Nutrients and Microbes Are Responsible for Large Patch Disease Caused by Rhizoctonia solani AG2-2 in Zoysiagrass Turf (골프장 한국잔디의 Rhizoctonia solani AG2-2에 의한 Large Patch 발생 토양에서 근권 미생물과 무기영양 평가)

  • Chang, Tae-Hyun;Ru, Yeon-Ju;Lee, Yong-Se
    • Asian Journal of Turfgrass Science
    • /
    • v.21 no.2
    • /
    • pp.113-126
    • /
    • 2007
  • Mineral nutrients and population dynamics of soil microbes in the root zones of zoysiagrass infected by Rhizoctonia solani AG2-2 and that of healthy plants were sampled from ten golf courses using a cup cutter(diameter $10\;cm\;{\times}\;8\;cm$ deep). Analysis of variance(ANOVA) showed significant differences in content of $NO_3$-N(P = 0.05), $NH_4$-N(P = 0.1), and K(P = 0.1) between infected and healthy samples. The content of $NO_3$-N in the soils of large patch was 9.49 mg/kg and that in soil of healthγ plants was 7.02 mg/kg. However, the content of $NH_4$-N in the soil of large patch was 12.02 mg/kg whereas 14.40 mg/kg for the soil under the healthy plants. The content of K in the soil of large patch was lower than that of soil of healthy plants. There was few numbers of Pseudomonas colonies In the soils of large patch compared to that of healthy plants. These results indicated that the content of $NO_3$-N, NH4-N, and K and the microbial population dynamics in root zones correlated to occurrence of large patch.

Effect of Aeration on Nitrous Oxide ($N_2O$) Emission from Nitrogen-Removing Sequencing Batch Reactors

  • Kim, Dong-Jin;Kim, Yuri
    • Journal of Microbiology and Biotechnology
    • /
    • v.23 no.1
    • /
    • pp.99-105
    • /
    • 2013
  • In this study, nitrous oxide ($N_2O$) emission was compared between the operations of two different sequencing batch reactors, conventional sequencing batch reactor (CNVSBR) and simultaneous nitrification and denitrification sequencing batch reactor (SND-SBR), using synthetic wastewater. The CNV-SBR consisted of anoxic (denitrification) and aerobic phases, whereas the SND-SBR consisted of a microaerobic (low dissolved oxygen concentration) phase, which was achieved by intermittent aeration for simultaneous nitrification and denitrification. The CNV-SBR emitted 3.9 mg of $N_2O$-N in the denitrification phase and 1.6 mg of $N_2O$-N in the nitrification phase, resulting in a total emission of 5.5mg from 432mg of $NH_4^+$-N input. In contrast, the SND-SBR emitted 26.2mg of $N_2O$-N under the microaerobic condition, which was about 5 times higher than the emission obtained with the CNV-SBR at the same $NH_4^+$-N input. From the $N_2O$ yield based on $NH_4^+$-N input, the microaerobic condition produced the highest yield (6.1%), followed by the anoxic (0.9%) and aerobic (0.4%) conditions. It is thought that an appropriate dissolved oxygen level is critical for reducing $N_2O$ emission during nitrification and denitrification at wastewater treatment plants.

Reduction of Operating Voltage of GaN-based Blue-violet Laser Diode by using Highly Mg Doped GaN Layer (고농도의 Mg가 도핑된 GaN층을 이용한 GaN계 청자색 레이저다이오드의 동작 전압 감소)

  • 곽준섭
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.17 no.7
    • /
    • pp.764-769
    • /
    • 2004
  • In order to reduce operating voltage of the GaN based blue-violet laser diodes, the effect of highly Mg doped GaN layer, which was grown below ohmic contact metals, on contact resistivity as well as operating voltage has been investigated. The addition of the highly Mg doped GaN layer greatly reduced contact resistivity of Pd/Pt/Au ohmic contacts from $5.2 \times {10}^-2 \Omegaㆍ$\textrm{cm}^2$ to 7.5 \times {10}^-4 \Omegaㆍ$\textrm{cm}^2$$. In addition, it also decreased device voltage at 20 mA by more than 3 V. Temperature- dependent sheet resistivity of the highly Mg doped GaN layer suggested that the reduction of the contact resistivity could be attributed to predominant current flow at the interface between the Pd/Pt/Au contacts and p-GaN through a deep level defect band, rather than the valence band.

Evaluation of Tar Dyes Used in Commercial Foods (식품 중 합성첨가물 사용실태 조사 연구 -타르색소 중심으로-)

  • 윤미혜;김국주;김정임;황선일;문수경;정은주;김재관
    • Journal of Food Hygiene and Safety
    • /
    • v.15 no.2
    • /
    • pp.108-113
    • /
    • 2000
  • This study was carried out to propose a simple method for the extraction of seven tar dyes such as tartrazine, sunset yellow FCF, amaranth, erythrosine, allura red, brilliant blue FCF and indigo carmine using aminopropyl amine cartridge and to determine the content of the dyes in candies, soft drinks, ice bars and okchuns produced in Korea. The tar dyes were simultaneously analyzed by reverse phase high performance liquid chromatography(HPLC). The recovery rates of the dyes ranged from 65.8% to 99.6%. The contents of the dyes in candies, soft drinks, ice bars and octhuns were N.D.∼50.1 mg/kg, N.D.∼49.9 mg/kg, N.D.∼56.0 mg/kg and N.D.∼867.3 mg/kg, respectively. The types of the dyes used most frequently for candies, soft drinks and ice bars were tartrazine, brilliant blue and amaranth, respectively. Of the samples, tartrazine was used frequently, and indigo carmine was not used at all.

  • PDF

Runoff Characteristics of Non-point Source Pollutants from Road Area During Rainfall Events (강우시 도로지역 비점오염물질 유출특성)

  • Park, Woon Ji;Lee, Su In;Lee, Hae Seung;Lee, Young Joon;Choi, Joong Dae
    • Proceedings of the Korea Water Resources Association Conference
    • /
    • 2015.05a
    • /
    • pp.403-403
    • /
    • 2015
  • 본 연구에서는 강우시 도로지역에서 발생하는 비점오염물질 유출 및 수질특성을 살펴보고자 도로지역(국도 46호선)을 대상으로 총 16회의 강우사상에 대해 분석하였다. 모니터링 기간(2014년 5월~9월)동안 연구대상지역에는 3.2~80.3 mm의 강우가 발생하였으며, 강우강도는 0.39~11.29 mm/hr의 범위로 나타났다. 선행무강우일수는 0.3~20.1일이며, 총 유출량은 0.1~6.8 ㎥, 유출율은 0.24~0.85(평균 0.6)의 범위로 나타났다. 강우 모니터링 결과, 유량가중평균농도(Event Mean Concentration, EMC)는 TOC 4.9~56.2 mg/L(평균 18.0 mg/L), BOD 3.1~21.5 mg/L(평균 7.5 mg/L), COD 6.7~58.6 mg/L(평균 23.6 mg/L), SS 2.1~281.9 mg/L(평균 59.4 mg/L), T-N 1.07~13.46 mg/L(평균 4.89 mg/L) 그리고 T-P 0.065~0.680 mg/L(평균 0.23 mg/L)의 범위로 나타났으며, 강우계급별로 살펴보면 0~10 mm일 때 BOD 9.3 mg/L, COD 30.5 mg/L, SS 84.1 mg/L, T-N 5.42 mg/L, T-P 0.27 mg/L로, 10~30 mm일 때 BOD 6.6 mg/L, COD 22.0 mg/L, SS 29.0 mg/L, T-N 4.9 mg/L, T-P 0.20 mg/L로, 50 mm 이상의 강우에서는 BOD 3.6 mg/L, COD 7.1 mg/L, SS 46.4 mg/L, T-N 3.42 mg/L, T-P 0.10 mg/L로 강우계급별 EMC는 대부분 수질항목에 있어 10 mm 이하 계급의 평균 EMC가 높은 수준으로 나타났다. 그리고 각 강우사상에 대한 단위면적당 오염부하는 TOC 0.06~3.5 kg/ha, $BOD_5$ 0.03~1.6 kg/ha, CODMn 0.09~4.74 kg/ha, SS 0.09~35.99 kg/ha, T-N 0.012~2.600 kg/ha, T-P 0.001~0.062 kg/ha의 범위로 산정되었다. 도로지역은 불투수층 면적비율이 높아 누적강우량 10 mm 이하에서도 유출이 발생하는 것으로 분석되었으며, 작은 강우에도 초기유출이 발생하고 유출되는 오염물질 농도가 높은 경향을 나타내었다.

  • PDF